CN108753470A - 一种衣物用除甲醛剂 - Google Patents

一种衣物用除甲醛剂 Download PDF

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CN108753470A
CN108753470A CN201810563033.5A CN201810563033A CN108753470A CN 108753470 A CN108753470 A CN 108753470A CN 201810563033 A CN201810563033 A CN 201810563033A CN 108753470 A CN108753470 A CN 108753470A
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clothing
graphene oxide
removing formaldehyde
formaldehyde
polyethylene glycol
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林荣铨
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Chenzhou Bo Superfine Graphite Ltd By Share Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
    • C11D3/3742—Nitrogen containing silicones
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明提供了一种衣物用除甲醛剂，包括如下按质量百分比计的组分：羧甲基壳聚糖1%~5%、有机硅季铵盐0.5%~2%、天然精油0.1%~0.5%、氧化石墨烯溶液0.1%~0.3%、月桂醇0.2%~0.5%、聚乙二醇5%~15%、余量水。本发明产品无毒，无腐蚀性，安全，对衣物本身的去除甲醛效果好，且能保护衣物，同时还具备较好的稳定性，保证较好的去除甲醛和保护衣物效果。

Description

一种衣物用除甲醛剂
技术领域
本发明属除甲醛产品技术领域，更具体地，涉及一种衣物用除甲醛剂。
背景技术
甲醛由于其具备很强的毒性，在空气中达到一定浓度时，人体会出现不适，同时对人体造成损伤，例如对人的皮肤、器官粘膜等具有强烈刺激性，对人体的各个功能器官具备很强的损害，容易引发癌变等等，衣物等纺织品织物中，通常会采用染色工艺，而染色过程中会将甲醛渗入衣服中，因而衣物的甲醛含量极易超标，2010年国家质量监督检验总局发布了GB18401-2010《国家纺织产品基本安全技术规范》的强制性标准，其对直接接触皮肤的纺织产品甲醛含量规定不得大于75mg/kg，非直接接触皮肤的纺织产品甲醛含量不得大于300mg/kg，因此，研发一种能够有效去除衣物上的甲醛，且对环境无害的产品尤为重要。
发明内容
本发明的目的在于针对现有技术的缺陷和不足，提供一种衣物用除甲醛剂。
本发明上述目的通过如下技术方案予以实现：
一种衣物用除甲醛剂，包括如下按质量百分比计的组分：
羧甲基壳聚糖1％～5％、有机硅季铵盐0.5％～2％、天然精油0.1％～0.5％、氧化石墨烯溶液0.1％～0.3％、月桂醇0.2％～0.5％、聚乙二醇5％～15％、余量水。
其中，本发明中羧甲基壳聚糖可以与甲醛反应，因而具备去除甲醛的目的。同时，有机硅季铵盐作为衣物保护剂，可以保护衣物不受损伤。天然精油具备一定的去除甲醛效果，同时还能留香。月桂醇作为乳化剂，在与氧化石墨烯溶液一起作用时，能够很好的促进氧化石墨烯进入衣物中，去除甲醛，同时较快的溶于溶液中，聚乙二醇对整体体系具备较好的稳定效果，能够协助以上几种物质发挥作用。
优选地，所述有机硅季铵盐为聚硅氧烷季铵盐。
优选地，氧化石墨烯溶液中氧化石墨烯的浓度为1％～5％。
优选地，天然精油为茶树精油或桉树精油。
优选地，聚乙二醇为聚乙二醇400。
本发明提供所述衣物用除甲醛剂的制备方法，将氧化石墨烯溶液超声分散后，加入羧甲基壳聚糖和有机硅季铵盐混匀，再加入天然精油、月桂醇聚乙二醇和水后得到所述产品。
与现有技术相比，本发明具备如下优点：
本发明产品无毒，无腐蚀性，安全，对衣物本身的去除甲醛效果好，且能保护衣物，同时还具备较好的稳定性，保证较好的去除甲醛和保护衣物效果。
具体实施方式
以下结合实施例对本发明作进一步说明，但本发明要求保护的范围并不局限于实施例表述的范围。
实施例1
一种衣物用除甲醛剂，包括如下按质量百分比计的组分：
羧甲基壳聚糖3％、聚硅氧烷季铵盐1％、天然精油0.2％、氧化石墨烯溶液0.2％、月桂醇0.2％、聚乙二醇40010％、余量水。氧化石墨烯溶液中氧化石墨烯的浓度为2％。天然精油为茶树精油或桉树精油。
将氧化石墨烯溶液超声分散后，加入羧甲基壳聚糖和有机硅季铵盐混匀，再加入天然精油、月桂醇、聚乙二醇400和水后得到衣物用除甲醛剂。
实施例2
一种衣物用除甲醛剂，包括如下按质量百分比计的组分：
羧甲基壳聚糖5％、聚硅氧烷季铵盐2％、天然精油0.5％、氧化石墨烯溶液0.5％、月桂醇0.5％、聚乙二醇40010％、余量水。氧化石墨烯溶液中氧化石墨烯的浓度为3％。天然精油为茶树精油或桉树精油。
将氧化石墨烯溶液超声分散后，加入羧甲基壳聚糖和有机硅季铵盐混匀，再加入天然精油、月桂醇、聚乙二醇400和水后得到衣物用除甲醛剂。
对比例1
一种衣物用除甲醛剂，包括如下按质量百分比计的组分：
羧甲基壳聚糖5％、聚硅氧烷季铵盐2％、天然精油0.5％、月桂醇0.5％、聚乙二醇40010％、余量水。天然精油为茶树精油或桉树精油。
将羧甲基壳聚糖和有机硅季铵盐混匀，再加入天然精油、月桂醇、聚乙二醇400和水后得到衣物用除甲醛剂。
对比例2
一种衣物用除甲醛剂，包括如下按质量百分比计的组分：
羧甲基壳聚糖3％、聚硅氧烷季铵盐1％、天然精油0.2％、氧化石墨烯溶液0.2％、聚乙二醇40010％、余量水。氧化石墨烯溶液中氧化石墨烯的浓度为2％。天然精油为茶树精油或桉树精油。
将氧化石墨烯溶液超声分散后，加入羧甲基壳聚糖和有机硅季铵盐混匀，再加入天然精油、聚乙二醇400和水后得到衣物用除甲醛剂。
先取纺织衣物放入10％的甲醛溶液中浸泡1h，然后将浸泡过的纺织衣物晾干，检测残留的甲醛含量，将实施例和对比例的产品浸泡清洗衣物2h，晾干后再次检测甲醛含量。结果见表1：
实施例1 实施例2 对比例1 对比例2
净化率％ 84.2 89.4 70.8 75.9
净化率＝(纺织衣物清洗前的甲醛含量-纺织衣物清洗后的甲醛含量)/纺织衣物清洗前的甲醛含量×100％。
从表1中可以看出，对比例1中缺少氧化石墨烯溶液的除甲醛效果大大降低，而对比例2中缺少了乳化剂的加入后，其除甲醛效果仍然不理想。

Claims (6)

1.一种衣物用除甲醛剂，其特征在于，包括如下按质量百分比计的组分：
羧甲基壳聚糖1%~5%、有机硅季铵盐0.5%~2%、天然精油0.1%~0.5%、氧化石墨烯溶液0.1%~0.3%、月桂醇0.2%~0.5%、聚乙二醇5%~15%、余量 水。
2.根据权利要求1所述的衣物用除甲醛剂，其特征在于，所述有机硅季铵盐为聚硅氧烷季铵盐。
3.根据权利要求1所述的衣物用除甲醛剂，其特征在于，氧化石墨烯溶液中氧化石墨烯的浓度为1%~5%。
4.根据权利要求1所述的衣物用除甲醛剂，其特征在于，天然精油为茶树精油或桉树精油。
5.根据权利要求1所述的衣物用除甲醛剂，其特征在于，聚乙二醇为聚乙二醇 400。
6.一种权利要求1所述衣物用除甲醛剂的制备方法，其特征在于，将氧化石墨烯溶液超声分散后，加入羧甲基壳聚糖和有机硅季铵盐混匀，再加入天然精油、月桂醇、聚乙二醇和水后得到所述产品。
CN201810563033.5A 2018-06-01 2018-06-01 一种衣物用除甲醛剂 Withdrawn CN108753470A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109675429A (zh) * 2019-02-15 2019-04-26 安徽欧霖环保科技有限公司 一种车用除甲醛固体制剂

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109675429A (zh) * 2019-02-15 2019-04-26 安徽欧霖环保科技有限公司 一种车用除甲醛固体制剂

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Application publication date: 20181106