CN108753470A - A kind of clothing is with removing formaldehyde agent - Google Patents
A kind of clothing is with removing formaldehyde agent Download PDFInfo
- Publication number
- CN108753470A CN108753470A CN201810563033.5A CN201810563033A CN108753470A CN 108753470 A CN108753470 A CN 108753470A CN 201810563033 A CN201810563033 A CN 201810563033A CN 108753470 A CN108753470 A CN 108753470A
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- CN
- China
- Prior art keywords
- clothing
- graphene oxide
- removing formaldehyde
- formaldehyde
- polyethylene glycol
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of clothings with removing formaldehyde agent, including component by mass percentage as follows：Carboxymethyl chitosan 1% ~ 5%, organosilicon quaternary ammonium salt 0.5% ~ 2%, natural essential oil 0.1% ~ 0.5%, graphene oxide solution 0.1% ~ 0.3%, laruyl alcohol 0.2% ~ 0.5%, polyethylene glycol 5% ~ 15%, excess water.Product of the present invention is nontoxic, non-corrosive, safety, good to the removal effect of formaldehyde of clothing itself, and can protect clothing, while being also equipped with preferable stability, ensures preferable removal formaldehyde and protection clothing effect.
Description
Technical field
The invention belongs to remove formaldehyde products technical field, more particularly, to a kind of clothing with removing formaldehyde agent.
Background technology
Formaldehyde is since it has very strong toxicity, and when reaching a certain concentration in air, human body will appear discomfort, while right
Human body causes to damage, such as has intense irritation to skin, organ mucous membrane of people etc., has to each Functional tissue of human body
Very strong damage is easy to cause canceration etc., in the textile fabrics such as clothing, it will usually use dyeing, and dyeing course
In formaldehyde can be penetrated into clothes, thus the content of formaldehyde of clothing is easily exceeded, national quality supervision and inspection general bureau hair in 2010
Cloth GB18401-2010《National general safety technical code for textile products》Mandatory standard, to being in direct contact skin
Textile product content of formaldehyde regulation is not greater than 75mg/kg, and the textile product content of formaldehyde of non-direct contact skin is not greater than
Therefore 300mg/kg researches and develops a kind of formaldehyde that can be effectively removed on clothing, and the product of environmental sound is particularly important.
Invention content
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of clothings with removing formaldehyde agent.
Above-mentioned purpose of the present invention is achieved by following technical solution：
A kind of clothing is with removing formaldehyde agent, including component by mass percentage as follows：
Carboxymethyl chitosan 1%~5%, organosilicon quaternary ammonium salt 0.5%~2%, natural essential oil 0.1%~0.5%, oxidation
Graphene solution 0.1%~0.3%, laruyl alcohol 0.2%~0.5%, polyethylene glycol 5%~15%, excess water.
Wherein, carboxymethyl chitosan can be reacted with formaldehyde in the present invention, thus have the purpose of removal formaldehyde.Meanwhile
Organosilicon quaternary ammonium salt can protect clothing injury-free as clothing protective agent.Natural essential oil has certain removal formaldehyde effect
Fruit, while can also lasting.Laruyl alcohol is as emulsifier, when working with graphene oxide solution one, can be good at promoting
Graphene oxide enters in clothing, removes formaldehyde, while being dissolved in solution faster, polyethylene glycol has preferably integral system
Stablizing effect, can assist in above several substances and play a role.
Preferably, the organosilicon quaternary ammonium salt is polysiloxane quaternary ammonium.
Preferably, in graphene oxide solution graphene oxide a concentration of 1%~5%.
Preferably, natural essential oil is tea tree ethereal oil or eucalyptus oil.
Preferably, polyethylene glycol is polyethylene glycol 400.
The present invention provides the clothing and is added after graphene oxide solution ultrasonic disperse with the preparation method for removing formaldehyde agent
Enter carboxymethyl chitosan and organosilicon quaternary ammonium salt mixing, add after natural essential oil, laruyl alcohol polyethylene glycol and water obtain it is described
Product.
Compared with prior art, the present invention has following advantage：
Product of the present invention is nontoxic, non-corrosive, safety, good to the removal effect of formaldehyde of clothing itself, and can protect clothing,
It is also equipped with preferable stability simultaneously, ensures preferable removal formaldehyde and protection clothing effect.
Specific implementation mode
The invention will be further described with reference to embodiments, but the scope of protection of present invention is not limited to reality
Apply the range of example statement.
Embodiment 1
A kind of clothing is with removing formaldehyde agent, including component by mass percentage as follows：
Carboxymethyl chitosan 3%, polysiloxane quaternary ammonium 1%, natural essential oil 0.2%, graphene oxide solution 0.2%,
Laruyl alcohol 0.2%, polyethylene glycol 400 10%, excess water.A concentration of the 2% of graphene oxide in graphene oxide solution.Naturally
Essential oil is tea tree ethereal oil or eucalyptus oil.
After graphene oxide solution ultrasonic disperse, carboxymethyl chitosan and organosilicon quaternary ammonium salt mixing is added, adds
Clothing is obtained after natural essential oil, laruyl alcohol, polyethylene glycol 400 and water with removing formaldehyde agent.
Embodiment 2
A kind of clothing is with removing formaldehyde agent, including component by mass percentage as follows：
Carboxymethyl chitosan 5%, polysiloxane quaternary ammonium 2%, natural essential oil 0.5%, graphene oxide solution 0.5%,
Laruyl alcohol 0.5%, polyethylene glycol 400 10%, excess water.A concentration of the 3% of graphene oxide in graphene oxide solution.Naturally
Essential oil is tea tree ethereal oil or eucalyptus oil.
After graphene oxide solution ultrasonic disperse, carboxymethyl chitosan and organosilicon quaternary ammonium salt mixing is added, adds
Clothing is obtained after natural essential oil, laruyl alcohol, polyethylene glycol 400 and water with removing formaldehyde agent.
Comparative example 1
A kind of clothing is with removing formaldehyde agent, including component by mass percentage as follows：
Carboxymethyl chitosan 5%, polysiloxane quaternary ammonium 2%, natural essential oil 0.5%, laruyl alcohol 0.5%, polyethylene glycol
40010%, excess water.Natural essential oil is tea tree ethereal oil or eucalyptus oil.
By carboxymethyl chitosan and organosilicon quaternary ammonium salt mixing, add natural essential oil, laruyl alcohol, polyethylene glycol 400 and
Clothing is obtained after water with removing formaldehyde agent.
Comparative example 2
A kind of clothing is with removing formaldehyde agent, including component by mass percentage as follows：
Carboxymethyl chitosan 3%, polysiloxane quaternary ammonium 1%, natural essential oil 0.2%, graphene oxide solution 0.2%,
Polyethylene glycol 400 10%, excess water.A concentration of the 2% of graphene oxide in graphene oxide solution.Natural essential oil is tea tree essence
Oil or eucalyptus oil.
After graphene oxide solution ultrasonic disperse, carboxymethyl chitosan and organosilicon quaternary ammonium salt mixing is added, adds
Clothing is obtained after natural essential oil, polyethylene glycol 400 and water with removing formaldehyde agent.
It first takes textile clothes to be put into 10% formalin and impregnates 1h, then dry the textile clothes impregnated, examine
Remaining content of formaldehyde is surveyed, by the product soaking and washing clothing 2h of embodiment and comparative example, detects content of formaldehyde after drying again.
It the results are shown in Table 1：
| Embodiment 1 | Embodiment 2 | Comparative example 1 | Comparative example 2 | |
| Purifying rate % | 84.2 | 89.4 | 70.8 | 75.9 |
Purifying rate=(content of formaldehyde after content of formaldehyde-textile clothes cleaning before textile clothes cleaning)/textile clothes
Content of formaldehyde × 100% before cleaning.
From table 1 it follows that lack in comparative example 1 graphene oxide solution except effect of formaldehyde substantially reduces, and it is right
After the addition for having lacked emulsifier in ratio 2, except effect of formaldehyde is still undesirable.
Claims (6)
1. a kind of clothing is with removing formaldehyde agent, which is characterized in that including component as follows by mass percentage：
Carboxymethyl chitosan 1% ~ 5%, organosilicon quaternary ammonium salt 0.5% ~ 2%, natural essential oil 0.1% ~ 0.5%, graphene oxide solution
0.1% ~ 0.3%, laruyl alcohol 0.2% ~ 0.5%, polyethylene glycol 5% ~ 15%, excess water.
2. clothing according to claim 1 is with removing formaldehyde agent, which is characterized in that the organosilicon quaternary ammonium salt is polysiloxanes
Quaternary ammonium salt.
3. clothing according to claim 1 is with removing formaldehyde agent, which is characterized in that graphene oxide in graphene oxide solution
A concentration of 1% ~ 5%.
4. clothing according to claim 1 is with removing formaldehyde agent, which is characterized in that natural essential oil is tea tree ethereal oil or eucalyptus essence
Oil.
5. clothing according to claim 1 is with removing formaldehyde agent, which is characterized in that polyethylene glycol is polyethylene glycol 400.
6. a kind of preparation method for removing formaldehyde agent of clothing described in claim 1, which is characterized in that surpass graphene oxide solution
After sound dispersion, carboxymethyl chitosan and organosilicon quaternary ammonium salt mixing is added, add natural essential oil, laruyl alcohol, polyethylene glycol and
The product is obtained after water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810563033.5A CN108753470A (en) | 2018-06-01 | 2018-06-01 | A kind of clothing is with removing formaldehyde agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810563033.5A CN108753470A (en) | 2018-06-01 | 2018-06-01 | A kind of clothing is with removing formaldehyde agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108753470A true CN108753470A (en) | 2018-11-06 |
Family
ID=64002528
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810563033.5A Withdrawn CN108753470A (en) | 2018-06-01 | 2018-06-01 | A kind of clothing is with removing formaldehyde agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108753470A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109675429A (en) * | 2019-02-15 | 2019-04-26 | 安徽欧霖环保科技有限公司 | It is a kind of automobile-used except formaldehyde solid pharmaceutical preparation |
-
2018
- 2018-06-01 CN CN201810563033.5A patent/CN108753470A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109675429A (en) * | 2019-02-15 | 2019-04-26 | 安徽欧霖环保科技有限公司 | It is a kind of automobile-used except formaldehyde solid pharmaceutical preparation |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20181106 |