CN108728190A - A kind of Bio-fuel oil energy saver - Google Patents

A kind of Bio-fuel oil energy saver Download PDF

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Publication number
CN108728190A
CN108728190A CN201810593191.5A CN201810593191A CN108728190A CN 108728190 A CN108728190 A CN 108728190A CN 201810593191 A CN201810593191 A CN 201810593191A CN 108728190 A CN108728190 A CN 108728190A
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parts
bio
fuel oil
take
energy saver
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CN108728190B (en
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刘菊花
陈炎
刘红妹
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Beijing Zhonglinlihe Petrochemical Co ltd
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Foshan Teng Carp Amperex Technology Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/18—Organic compounds containing oxygen
    • C10L1/192—Macromolecular compounds
    • C10L1/198—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1983—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/30—Organic compounds compounds not mentioned before (complexes)
    • C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)

Abstract

The invention discloses a kind of Bio-fuel oil energy savers, belong to new energy field.The present invention takes 3 ~ 6 parts of emulsifiers, 4 ~ 7 parts of surfactants, 2 ~ 5 parts of auxiliary agents, 5 ~ 7 parts of thickeners, 5 ~ 10 parts of sodium citrates, 20 ~ 35 parts of the lichen bacillus ferments processed materials, 20 ~ 30 parts of polyarylate resin compounds, 20 ~ 30 parts of water；In 70 ~ 80 DEG C of water-bath, take polyarylate resin compound, emulsifier, sodium citrate, water mixing, 40 ~ 60min is stirred with 300 ~ 350r/min, it is cooled to 30 ~ 40 DEG C, surfactant, auxiliary agent, thickener, the mixing of the lichen bacillus ferments processed material is added, ultrasonic wave disperses 10 ~ 15min to get Bio-fuel oil energy saver.The present invention solves current fuel oil and will produce toxic gas, and the problem that the big utilization rate of energy consumption is low in combustion.

Description

A kind of Bio-fuel oil energy saver
Technical field
The invention belongs to new energy fields, and in particular to a kind of Bio-fuel oil energy saver.
Background technology
In the modern life, fuel oil for we live arround tool usually need it is to be used, it is small to oil tanker, aircraft greatly To locomotive, generator, these are required for fuel oil to generate power, and fuel oil is refined by natural crude oil, we produce, Dosage in life is more and more big, keeps non-renewable petroleum resource consumption too fast, and petroleum fuel burning generates a large amount of harmful Substances on human's existence causes high risks, and as oil price height is grown, is also improved using oil-fired cost and much wanted Reduce the common recognition that petroleum fuel dosage is people.At present to substituting the oil-fired research in part much with alcohol, ether etc., There are many applications, but find the cheap environment-friendly energy-saving fuel that can reduce petroleum fuel dosage still to have positive reality Meaning.
It is main former that existing fuel economizing product, which is to have slight erosion or the abstersive chemicals of tool mostly, Material eliminates carbon distribution in engine by reacting, and achievees the effect that clean engine, but can not be fully solved pernicious gas Emission problem, and oil-saving effect is limited.Therefore, produce a kind of fuel energy saving agent that can be solved the above problems have it is prodigious Market prospects.
Invention content
The technical problems to be solved by the invention：Toxic gas, and energy are will produce in combustion for current fuel oil The low problem of big utilization rate is consumed, a kind of Bio-fuel oil energy saver is provided.
In order to solve the above technical problems, the present invention is using technical solution as described below：
A kind of Bio-fuel oil energy saver includes following component, 3 ~ 6 parts of emulsifiers, 4 ~ 7 parts of surfactants, 2 according to the mass fraction ~ 5 parts of auxiliary agents, 5 ~ 7 parts of thickeners, 5 ~ 10 parts of sodium citrates, 20 ~ 30 parts of water, which is characterized in that further include 20 ~ 35 parts of lichens buds Spore bacillus fermentation processed material, 20 ~ 30 parts of polyarylate resin compounds.
The emulsifier is any one in polyoxyethylene stearic acid ester, OP-10, polyoxylethylene abietate, this Pan 80.
The surfactant is in mass ratio 1:3 ~ 4 take laureth sodium sulfovinate, neopelex mixed It closes to get surfactant.
The auxiliary agent is in mass ratio 5：1~2：3 take nano-carbon powder, nano-nickel powder, cornstarch mixing to get auxiliary agent.
The thickener is in mass ratio 1：2~4：8 ~ 12 take sodium carboxymethylcellulose, Arabic gum, water mixed in 65 ~ 80 DEG C It closes to get thickener.
The preparation of the polyarylate resin compound：Take soybean oil in mass ratio 4：1 ~ 2, which is added glycerine, is mixed, and rises Temperature adds the oxygen of the castor oil and soybean oil quality 0.1 ~ 0.5% of soybean oil quality 25 ~ 40% to 150 ~ 160 DEG C of 1 ~ 2h of heat preservation Change calcium, keep the temperature 2 ~ 3h in 200 ~ 210 DEG C, be cooled to 150 ~ 160 DEG C, be added 1.5 times of castor-oil plant oil quality phthalic anhydride and The dimethylbenzene of castor-oil plant oil quality 60% is stirred 2 ~ 3h in 180 ~ 210 DEG C, is cooled to room temperature, obtains polyarylate resin compound.
The preparation of the lichen bacillus ferments processed material, includes the following steps：
（1）Take bacillus licheniformis powder in mass ratio 1:10 ~ 15 be added sterile waters mixing, obtain bacterium solution, take bacterium solution by 8% inoculation Amount is seeded to activation medium, is cultivated 2 ~ 4 days in 26 ~ 32 DEG C, obtains activation culture liquid, activation culture liquid is taken to be connect by 8% inoculum concentration Kind cultivates 3 ~ 6 days in 26 ~ 32 DEG C to seed culture medium, obtains seed culture fluid, spare；
（2）Pre-process watermelon seeds compound：Watermelon seeds cleaning, drying are taken, are pulverized and sieved, sieving particle in mass ratio 1 is taken：3~6 HCl solution mixing is added, impregnates, filtering takes filter residue in 80 ~ 90 DEG C in mass ratio 1:2~4:3:7, which are added rosin, peach gum, water, mixes Stirring is closed, is evaporated under reduced pressure to the 30 ~ 45% of original volume to get pretreatment watermelon seeds compound；
（3）According to the mass fraction, 20 ~ 40 parts of pretreatment carp eggs, 15 ~ 30 parts of pretreatment watermelon son compounds, 10 ~ 15 parts of Portugals are taken Grape juice, 3 ~ 6 parts of spare seed culture fluids, in 28 ~ 32 DEG C, constant temperature stirring fermentation 3 ~ 6 days, discharging obtains zymotic fluid, takes zymotic fluid Ultraviolet sterilization, rotary evaporation are concentrated under reduced pressure, and obtain concentrate, collect concentrate refrigeration, and filtering takes filter residue to be passed through nitrogen protection, roasts It burns, it is cooling, it discharges to get the lichen bacillus ferments processed material.
The activation medium：According to the mass fraction, take 40 ~ 60 portions of potatos, 15 ~ 25 parts of lactose, 5 ~ 10 parts of yeast extracts, 2 ~ 6 parts of dipotassium hydrogen phosphates, 0.05 ~ 0.09 part of magnesium sulfate, 0.03 ~ 0.07 part of calcium chloride, 0.5 ~ 1 part of disodium hydrogen phosphate, 0.03 ~ 0.07 part of vitamin B1, 1000 parts of water, the 20min that sterilize in 121 DEG C are to get activation medium.
The seed culture medium：According to the mass fraction, 20 ~ 40 parts of casein peptones, 15 ~ 20 parts of soy peptones, 30 ~ 50 are taken Part potato, 12 ~ 20 parts of glucose, 0.07 ~ 0.1 part of magnesium sulfate, 3 ~ 8 parts of NaCl, 3 ~ 6 parts of urea, 0.5 ~ 1 part of phosphoric acid hydrogen two Sodium, 0.05 ~ 0.09 part of vitamin B1, 1000 parts of water, the 20min that sterilize in 121 DEG C are to get seed culture medium.
The pretreatment carp egg：It takes carp egg, high-speed organization break process that must be homogenized, takes homogenate that homogenate quality 3 is added ~ 6 times of Na2CO3Solution is mixed, and stands, and is concentrated under reduced pressure, and is evaporated in vacuo to the 30 ~ 40% of original volume to get pretreatment carp Ovum.
Compared with other methods, advantageous effects are the present invention：
（1）The present invention is cultivated, fermentation process using bacillus licheniformis as raw material, can generate a variety of organic matters, is provided a large amount of Teichoic acid, carry stronger negative electrical charge, can Liquidity limit, have stronger absorption to metal ions such as Cd, Zn, Cu, Pb Ability makes the heavy metal ion in fuel oil no longer become in harmful compound emission to air after burned, can reduce Pollution to air decomposes the carbon distribution in colloid and fuel oil equipment in fuel oil using the effect of biological enzyme, fuel oil can be improved Utilization rate, saves the energy, and the nano-nickel powder in compounding aid can enhance the stability and carbon cleaning effect of original formulation again；
（2）The present invention is esterified by phthalic anhydride and glycerine, generates alkyd resin, the soybean oil of semi-drying and not The castor oil of dryness carries out reaction modifying to alkyd resin, and alkyd resin molecular backbone is polar aromatic ring polyester, and side chain is non- Polar aliphatic acid adjusts polyester ratio using soybean oil, the castor oil compared with long oil, so that double bond contained by resin is increased, improve Calorific value, while the active function groups in molecular resin are reduced, and can be extended the usage time of biological ENERGY-SAVING AGENT FOR, persistently be provided effect.
Specific implementation mode
Emulsifier：Any one in polyoxyethylene stearic acid ester, OP-10, polyoxylethylene abietate, this Pan 80.
Surfactant：In mass ratio 1:3 ~ 4 take laureth sodium sulfovinate, neopelex mixing, i.e., Obtain surfactant.
Auxiliary agent：In mass ratio 5：1~2：3 take nano-carbon powder, nano-nickel powder, cornstarch mixing to get auxiliary agent.
Thickener：In mass ratio 1：2~4：8 ~ 12 take sodium carboxymethylcellulose, Arabic gum, water mixed in 65 ~ 80 DEG C of water-bath It closes uniformly to get thickener.
Activation medium：According to the mass fraction, 40 ~ 60 portions of potatos, 15 ~ 25 parts of lactose, 5 ~ 10 parts of yeast extracts, 2 ~ 6 are taken Part dipotassium hydrogen phosphate, 0.05 ~ 0.09 part of magnesium sulfate, 0.03 ~ 0.07 part of calcium chloride, 0.5 ~ 1 part of disodium hydrogen phosphate, 0.03 ~ 0.07 Part vitamin B1, 1000 parts of water, the 20min that sterilize in 121 DEG C are to get activation medium.
Seed culture medium：According to the mass fraction, 20 ~ 40 parts of casein peptones, 15 ~ 20 parts of soy peptones, 30 ~ 50 portions of horses are taken Bell potato, 12 ~ 20 parts of glucose, 0.07 ~ 0.1 part of magnesium sulfate, 3 ~ 8 parts of NaCl, 3 ~ 6 parts of urea, 0.5 ~ 1 part of disodium hydrogen phosphate, 0.05 ~ 0.09 part of vitamin B1, 1000 parts of water, the 20min that sterilize in 121 DEG C are to get seed culture medium.
Pre-process carp egg：Carp egg is taken, historrhexis's machine is put into and 10 ~ 20min of processing is smashed to pieces with 3000 ~ 4000r/min, It must be homogenized, take homogenate that the Na that the mass fraction of 3 ~ 6 times of quality of homogenate is 8% is added2CO3Solution mixes, and is stirred with 250 ~ 300r/min 20 ~ 40min is mixed, 1 ~ 2h is stood, is concentrated under reduced pressure, is evaporated in vacuo to the 30 ~ 40% of original volume to get pretreatment carp egg.
The preparation of polyarylate resin compound：Take soybean oil in mass ratio 4：1 ~ 2 is added glycerine in reaction kettle, and mixing is stirred It mixes, is warming up to 150 ~ 160 DEG C of 1 ~ 2h of heat preservation, adds the castor oil and soybean oil quality 0.1 ~ 0.5% of soybean oil quality 25 ~ 40% Calcium oxide, keep the temperature 2 ~ 3h in 200 ~ 210 DEG C, naturally cool to 150 ~ 160 DEG C, the adjacent benzene two of 1.5 times of castor-oil plant oil quality is added The dimethylbenzene of formic anhydride and castor-oil plant oil quality 60% is stirred 2 ~ 3h in 180 ~ 210 DEG C, is cooled to room temperature, obtains polyarylate resin Compound.
The preparation of the lichen bacillus ferments processed material, includes the following steps：
（1）Take bacillus licheniformis powder in mass ratio 1:10 ~ 15 be added sterile waters mixing, obtain bacterium solution, take bacterium solution by 8% inoculation Amount is seeded to activation medium, is cultivated 2 ~ 4 days in 26 ~ 32 DEG C, obtains activation culture liquid, activation culture liquid is taken to be connect by 8% inoculum concentration Kind cultivates 3 ~ 6 days in 26 ~ 32 DEG C to seed culture medium, obtains seed culture fluid, spare；
（2）Pre-process watermelon seeds compound：Watermelon seeds is taken to clean, in 70 ~ 80 DEG C of oven dryings to water content 1% hereinafter, crushing 80 mesh sieve is crossed, sieving particle in mass ratio 1 is taken：3 ~ 6 are added the HCl solution mixing of concentration 0.01mol/L, impregnate 40 ~ 60min, Filtering, takes filter residue in 80 ~ 90 DEG C in mass ratio 1 of water-bath:2~4:3:7 are added rosin, peach gum, water mixing, with 250 ~ 300r/min 25 ~ 40min is stirred, is evaporated under reduced pressure to the 30 ~ 45% of original volume to get pretreatment watermelon seeds compound；
（3）According to the mass fraction, 20 ~ 40 parts of pretreatment carp eggs, 15 ~ 30 parts of pretreatment watermelon son compounds, 10 ~ 15 parts of Portugals are taken Grape juice, 3 ~ 6 parts of spare seed culture fluids are put in fermentation tank, in 28 ~ 32 DEG C, under 180 ~ 220r/min, constant temperature stirs fermentation 3 ~ 6 days, discharging, obtain zymotic fluid, take zymotic fluid 1 ~ 3h of ultraviolet sterilization, move to Rotary Evaporators, in temperature be 80 ~ 95 DEG C, 500 ~ Under 600kPa, 4 ~ 6h is concentrated under reduced pressure, obtains concentrate, collects concentrate and refrigerates 10 ~ 12h at 4 DEG C, filter, take filter residue in tubular type Stove is passed through nitrogen protection with 60 ~ 80mL/min rates, at 100 ~ 110 DEG C, roasts 45 ~ 60min, closes heat source, natural cooling To room temperature, discharge to get the lichen bacillus ferments processed material.
A kind of preparation method of Bio-fuel oil energy saver, includes the following steps：
（1）According to the mass fraction, 3 ~ 6 parts of emulsifiers, 4 ~ 7 parts of surfactants, 2 ~ 5 parts of auxiliary agents, 5 ~ 7 parts of thickeners, 5 ~ 10 are taken Part sodium citrate, 20 ~ 35 parts of the lichen bacillus ferments processed materials, 20 ~ 30 parts of polyarylate resin compounds, 20 ~ 30 parts of water；
（2）In 70 ~ 80 DEG C of water-bath, polyarylate resin compound, emulsifier, sodium citrate, water mixing are taken, with 300 ~ 350r/min 40 ~ 60min is stirred, is cooled to 30 ~ 40 DEG C, surfactant, auxiliary agent, thickener, the lichen bacillus ferments processed material is added Mixing, ultrasonic wave disperse 10 ~ 15min to get Bio-fuel oil energy saver.
Emulsifier：Polyoxyethylene stearic acid ester.
Surfactant：In mass ratio 1:3 take laureth sodium sulfovinate, neopelex mixing to get Surfactant.
Auxiliary agent：In mass ratio 5：1：3 take nano-carbon powder, nano-nickel powder, cornstarch mixing to get auxiliary agent.
Thickener：In mass ratio 1：2：8 take sodium carboxymethylcellulose, Arabic gum, water to be uniformly mixed for 65 DEG C in water-bath, i.e., Obtain thickener.
Activation medium：According to the mass fraction, 40 portions of potatos, 15 parts of lactose, 5 parts of yeast extracts, 2 parts of phosphoric acid hydrogen two are taken Potassium, 0.05 part of magnesium sulfate, 0.03 part of calcium chloride, 0.5 part of disodium hydrogen phosphate, 0.03 part of vitamin B1, 1000 parts of water, in 121 DEG C 20min sterilize to get activation medium.
Seed culture medium：According to the mass fraction, take 20 parts of casein peptones, 15 parts of soy peptones, 30 portions of potatos, 12 parts Glucose, 0.07 part of magnesium sulfate, 3 parts of NaCl, 3 parts of urea, 0.5 part of disodium hydrogen phosphate, 0.05 part of vitamin B1, 1000 parts of water, 20min is sterilized in 121 DEG C to get seed culture medium.
Pre-process carp egg：Carp egg is taken, historrhexis's machine is put into and processing 10min is smashed to pieces with 3000r/min, must be homogenized, Take homogenate that the Na that the mass fraction of 3 times of quality of homogenate is 8% is added2CO3Solution mixes, and stirs 20min with 250r/min, stands 1h is concentrated under reduced pressure, and is evaporated in vacuo to the 30% of original volume to get pretreatment carp egg.
The preparation of polyarylate resin compound：Take soybean oil in mass ratio 4：1 is added glycerine in reaction kettle, and mixing is stirred It mixes, is warming up to 150 DEG C of heat preservation 1h, adds the calcium oxide of the castor oil and soybean oil quality 0.1% of soybean oil quality 25%, in 200 DEG C of heat preservation 2h, naturally cool to 150 DEG C, and the phthalic anhydride and castor-oil plant oil quality 60% of 1.5 times of castor-oil plant oil quality is added Dimethylbenzene, be stirred 2h in 180 DEG C, be cooled to room temperature, obtain polyarylate resin compound.
The preparation of the lichen bacillus ferments processed material, includes the following steps：
（1）Take bacillus licheniformis powder in mass ratio 1:10 are added sterile water mixing, obtain bacterium solution, bacterium solution is taken to be connect by 8% inoculum concentration Kind cultivates 2 days in 26 DEG C to activation medium, obtains activation culture liquid, activation culture liquid is taken to be seeded to seed by 8% inoculum concentration Culture medium is cultivated 3 days in 26 DEG C, obtains seed culture fluid, spare；
（2）Pre-process watermelon seeds compound：Watermelon seeds is taken to clean, in 70 DEG C of oven dryings to water content 1% hereinafter, crushed 80 mesh sieve, and take sieving particle in mass ratio 1：3 are added the HCl solution mixing of concentration 0.01mol/L, impregnate 40min, filtering takes Filter residue is in 80 DEG C in mass ratio 1 of water-bath:2:3:7 are added rosin, peach gum, water mixing, stir 25min with 250r/min, decompression is steamed The 30% of original volume is sent to get pretreatment watermelon seeds compound；
（3）According to the mass fraction, take 20 parts of pretreatment carp eggs, 15 parts of pretreatment watermelon son compounds, 10 portions of grape juices, 3 parts Spare seed culture fluid is put in fermentation tank, in 28 DEG C, under 180r/min, constant temperature stirring fermentation 3 days, discharging obtains zymotic fluid, Zymotic fluid ultraviolet sterilization 1h is taken, Rotary Evaporators are moved to, is 80 DEG C, under 500kPa in temperature, 4h is concentrated under reduced pressure, obtains concentrate, It collects concentrate and refrigerates 10h at 4 DEG C, filter, take filter residue in tube furnace, nitrogen protection is passed through with 60mL/min rates, in 100 At DEG C, 45min is roasted, closes heat source, cooled to room temperature discharges to get the lichen bacillus ferments processed material.
A kind of preparation method of Bio-fuel oil energy saver, includes the following steps：
（1）According to the mass fraction, take 3 parts of emulsifiers, 4 parts of surfactants, 2 parts of auxiliary agents, 5 parts of thickeners, 5 parts of sodium citrates, 20 parts of the lichen bacillus ferments processed materials, 20 parts of polyarylate resin compounds, 20 parts of water；
（2）In 70 DEG C of water-bath, polyarylate resin compound, emulsifier, sodium citrate, water mixing are taken, is stirred with 300r/min 40min is cooled to 30 DEG C, and surfactant, auxiliary agent, thickener, the mixing of the lichen bacillus ferments processed material, ultrasonic wave is added Disperse 10min to get Bio-fuel oil energy saver.
Emulsifier：Polyoxylethylene abietate.
Surfactant：In mass ratio 1:4 take laureth sodium sulfovinate, neopelex mixing to get Surfactant.
Auxiliary agent：In mass ratio 5：2：3 take nano-carbon powder, nano-nickel powder, cornstarch mixing to get auxiliary agent.
Thickener：In mass ratio 1：4：12 take sodium carboxymethylcellulose, Arabic gum, water to be uniformly mixed for 80 DEG C in water-bath, Up to thickener.
Activation medium：According to the mass fraction, 60 portions of potatos, 25 parts of lactose, 10 parts of yeast extracts, 6 parts of phosphoric acid hydrogen two are taken Potassium, 0.09 part of magnesium sulfate, 0.07 part of calcium chloride, 1 part of disodium hydrogen phosphate, 0.07 part of vitamin B1, 1000 parts of water, go out in 121 DEG C Bacterium 20min is to get activation medium.
Seed culture medium：According to the mass fraction, take 40 parts of casein peptones, 20 parts of soy peptones, 50 portions of potatos, 20 parts Glucose, 0.1 part of magnesium sulfate, 8 parts of NaCl, 6 parts of urea, 1 part of disodium hydrogen phosphate, 0.09 part of vitamin B1, 1000 parts of water, in 121 DEG C of sterilizing 20min are to get seed culture medium.
Pre-process carp egg：Carp egg is taken, historrhexis's machine is put into and processing 20min is smashed to pieces with 4000r/min, must be homogenized, Take homogenate that the Na that the mass fraction of 6 times of quality of homogenate is 8% is added2CO3Solution mixes, and stirs 40min with 300r/min, stands 2h is concentrated under reduced pressure, and is evaporated in vacuo to the 40% of original volume to get pretreatment carp egg.
The preparation of polyarylate resin compound：Take soybean oil in mass ratio 4：2 are added glycerine in reaction kettle, and mixing is stirred It mixes, is warming up to 160 DEG C of heat preservation 2h, adds the calcium oxide of the castor oil and soybean oil quality 0.5% of soybean oil quality 40%, in 210 DEG C of heat preservation 3h, naturally cool to 160 DEG C, and the phthalic anhydride and castor-oil plant oil quality 60% of 1.5 times of castor-oil plant oil quality is added Dimethylbenzene, be stirred 3h in 210 DEG C, be cooled to room temperature, obtain polyarylate resin compound.
The preparation of the lichen bacillus ferments processed material, includes the following steps：
（1）Take bacillus licheniformis powder in mass ratio 1:15 are added sterile water mixing, obtain bacterium solution, bacterium solution is taken to be connect by 8% inoculum concentration Kind cultivates 4 days in 32 DEG C to activation medium, obtains activation culture liquid, activation culture liquid is taken to be seeded to seed by 8% inoculum concentration Culture medium is cultivated 6 days in 32 DEG C, obtains seed culture fluid, spare；
（2）Pre-process watermelon seeds compound：Watermelon seeds is taken to clean, in 80 DEG C of oven dryings to water content 1% hereinafter, crushed 80 mesh sieve, and take sieving particle in mass ratio 1：6 are added the HCl solution mixing of concentration 0.01mol/L, impregnate 60min, filtering takes Filter residue is in 90 DEG C in mass ratio 1 of water-bath:4:3:7 are added rosin, peach gum, water mixing, stir 40min with 300r/min, decompression is steamed The 45% of original volume is sent to get pretreatment watermelon seeds compound；
（3）According to the mass fraction, take 40 parts of pretreatment carp eggs, 30 parts of pretreatment watermelon son compounds, 15 portions of grape juices, 6 parts Spare seed culture fluid is put in fermentation tank, in 32 DEG C, under 220r/min, constant temperature stirring fermentation 6 days, discharging obtains zymotic fluid, Zymotic fluid ultraviolet sterilization 3h is taken, Rotary Evaporators are moved to, is 95 DEG C, under 600kPa in temperature, 6h is concentrated under reduced pressure, obtains concentrate, It collects concentrate and refrigerates 12h at 4 DEG C, filter, take filter residue in tube furnace, nitrogen protection is passed through with 80mL/min rates, in 110 At DEG C, 60min is roasted, closes heat source, cooled to room temperature discharges to get the lichen bacillus ferments processed material.
A kind of preparation method of Bio-fuel oil energy saver, includes the following steps：
（1）According to the mass fraction, take 6 parts of emulsifiers, 7 parts of surfactants, 5 parts of auxiliary agents, 7 parts of thickeners, 10 parts of sodium citrates, 35 parts of the lichen bacillus ferments processed materials, 30 parts of polyarylate resin compounds, 30 parts of water；
（2）In 80 DEG C of water-bath, polyarylate resin compound, emulsifier, sodium citrate, water mixing are taken, is stirred with 350r/min 60min is cooled to 40 DEG C, and surfactant, auxiliary agent, thickener, the mixing of the lichen bacillus ferments processed material, ultrasonic wave is added Disperse 15min to get Bio-fuel oil energy saver.
Emulsifier：This Pan 80.
Surfactant：In mass ratio 1:3 take laureth sodium sulfovinate, neopelex mixing to get Surfactant.
Auxiliary agent：In mass ratio 5：1：3 take nano-carbon powder, nano-nickel powder, cornstarch mixing to get auxiliary agent.
Thickener：In mass ratio 1：3：10 take sodium carboxymethylcellulose, Arabic gum, water to be uniformly mixed for 72 DEG C in water-bath, Up to thickener.
Activation medium：According to the mass fraction, 50 portions of potatos, 20 parts of lactose, 8 parts of yeast extracts, 4 parts of phosphoric acid hydrogen two are taken Potassium, 0.07 part of magnesium sulfate, 0.05 part of calcium chloride, 0.7 part of disodium hydrogen phosphate, 0.05 part of vitamin B1, 1000 parts of water, in 121 DEG C 20min sterilize to get activation medium.
Seed culture medium：According to the mass fraction, take 30 parts of casein peptones, 17 parts of soy peptones, 40 portions of potatos, 16 parts Glucose, 0.08 part of magnesium sulfate, 7 parts of NaCl, 5 parts of urea, 0.7 part of disodium hydrogen phosphate, 0.07 part of vitamin B1, 1000 parts of water, 20min is sterilized in 121 DEG C to get seed culture medium.
Pre-process carp egg：Carp egg is taken, historrhexis's machine is put into and processing 15min is smashed to pieces with 3500r/min, must be homogenized, Take homogenate that the Na that the mass fraction of 5 times of quality of homogenate is 8% is added2CO3Solution mixes, and stirs 30min with 275r/min, stands 1h is concentrated under reduced pressure, and is evaporated in vacuo to the 35% of original volume to get pretreatment carp egg.
The preparation of polyarylate resin compound：Take soybean oil in mass ratio 4：1 is added glycerine in reaction kettle, and mixing is stirred It mixes, is warming up to 155 DEG C of heat preservation 1h, adds the calcium oxide of the castor oil and soybean oil quality 0.3% of soybean oil quality 32%, in 205 DEG C of heat preservation 2h, naturally cool to 155 DEG C, and the phthalic anhydride and castor-oil plant oil quality 60% of 1.5 times of castor-oil plant oil quality is added Dimethylbenzene, be stirred 2h in 195 DEG C, be cooled to room temperature, obtain polyarylate resin compound.
The preparation of the lichen bacillus ferments processed material, includes the following steps：
（1）Take bacillus licheniformis powder in mass ratio 1:13 are added sterile water mixing, obtain bacterium solution, bacterium solution is taken to be connect by 8% inoculum concentration Kind cultivates 3 days in 29 DEG C to activation medium, obtains activation culture liquid, activation culture liquid is taken to be seeded to seed by 8% inoculum concentration Culture medium is cultivated 4 days in 29 DEG C, obtains seed culture fluid, spare；
（2）Pre-process watermelon seeds compound：Watermelon seeds is taken to clean, in 75 DEG C of oven dryings to water content 1% hereinafter, crushed 80 mesh sieve, and take sieving particle in mass ratio 1：5 are added the HCl solution mixing of concentration 0.01mol/L, impregnate 50min, filtering takes Filter residue is in 85 DEG C in mass ratio 1 of water-bath:3:3:7 are added rosin, peach gum, water mixing, stir 34min with 275r/min, decompression is steamed The 37% of original volume is sent to get pretreatment watermelon seeds compound；
（3）According to the mass fraction, take 30 parts of pretreatment carp eggs, 22 parts of pretreatment watermelon son compounds, 13 portions of grape juices, 4 parts Spare seed culture fluid is put in fermentation tank, in 30 DEG C, under 200r/min, constant temperature stirring fermentation 5 days, discharging obtains zymotic fluid, Zymotic fluid ultraviolet sterilization 2h is taken, Rotary Evaporators are moved to, is 87 DEG C, under 550kPa in temperature, 5h is concentrated under reduced pressure, obtains concentrate, It collects concentrate and refrigerates 11h at 4 DEG C, filter, take filter residue in tube furnace, nitrogen protection is passed through with 70mL/min rates, in 105 At DEG C, 52min is roasted, closes heat source, cooled to room temperature discharges to get the lichen bacillus ferments processed material.
A kind of preparation method of Bio-fuel oil energy saver, includes the following steps：
（1）According to the mass fraction, take 5 parts of emulsifiers, 5 parts of surfactants, 3 parts of auxiliary agents, 6 parts of thickeners, 7 parts of sodium citrates, 27 parts of the lichen bacillus ferments processed materials, 25 parts of polyarylate resin compounds, 25 parts of water；
（2）In 75 DEG C of water-bath, polyarylate resin compound, emulsifier, sodium citrate, water mixing are taken, is stirred with 325r/min 50min is cooled to 35 DEG C, and surfactant, auxiliary agent, thickener, the mixing of the lichen bacillus ferments processed material, ultrasonic wave is added Disperse 13min to get Bio-fuel oil energy saver.
Comparative example 1：It is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking the lichen bacillus ferments Processed material.
Comparative example 2：It is essentially identical with the preparation method of embodiment 2, it has only the difference is that lacking polyarylate resin compound.
Comparative example 3：The Bio-fuel oil energy saver of company of Zhengzhou City production.
Fuel energy saving agent and 93# merchantable gasolines prepared in example are mixed with the ratio of volume ratio 1: 1, will be added Item, test result are as shown in table 1 as a comparison for the 93# merchantable gasolines of the fuel energy saving agent of reference examples.
Table 1：
In summary, fuel energy saving agent of the invention substantially increases fuel utilization ratio, and unit oil consumption mileage is obviously improved and is A environment amenable product, is worth of widely use.

Claims (10)

1. a kind of Bio-fuel oil energy saver includes following component, 3 ~ 6 parts of emulsifiers, 4 ~ 7 parts of surface-actives according to the mass fraction Agent, 2 ~ 5 parts of auxiliary agents, 5 ~ 7 parts of thickeners, 5 ~ 10 parts of sodium citrates, 20 ~ 30 parts of water, which is characterized in that further include 20 ~ 35 parts of ground Clothing fermentation of bacillus processed material, 20 ~ 30 parts of polyarylate resin compounds.
2. a kind of Bio-fuel oil energy saver according to claim 1, which is characterized in that the emulsifier is stearic acid polyoxy second Any one in enester, OP-10, polyoxylethylene abietate, this Pan 80.
3. a kind of Bio-fuel oil energy saver according to claim 1, which is characterized in that the surfactant is in mass ratio 1：3 ~ 4 take laureth sodium sulfovinate, neopelex mixing to get surfactant.
4. a kind of Bio-fuel oil energy saver according to claim 1, which is characterized in that the auxiliary agent is in mass ratio 5：1~2： 3 take nano-carbon powder, nano-nickel powder, cornstarch mixing to get auxiliary agent.
5. a kind of Bio-fuel oil energy saver according to claim 1, which is characterized in that the thickener is in mass ratio 1：2~ 4：8 ~ 12 take sodium carboxymethylcellulose, Arabic gum, water in 65 ~ 80 DEG C of mixing to get thickener.
6. a kind of Bio-fuel oil energy saver according to claim 1, which is characterized in that the system of the polyarylate resin compound It is standby：Take soybean oil in mass ratio 4：1 ~ 2, which is added glycerine, is mixed, and is warming up to 150 ~ 160 DEG C of 1 ~ 2h of heat preservation, adds soybean The calcium oxide of the castor oil and soybean oil quality 0.1 ~ 0.5% of oil quality 25 ~ 40% keeps the temperature 2 ~ 3h in 200 ~ 210 DEG C, is cooled to 150 ~ 160 DEG C, the dimethylbenzene of the phthalic anhydride and castor-oil plant oil quality 60% of 1.5 times of castor-oil plant oil quality is added, in 180 ~ 210 DEG C it is stirred 2 ~ 3h, is cooled to room temperature, obtains polyarylate resin compound.
7. a kind of Bio-fuel oil energy saver according to claim 1, which is characterized in that the lichen bacillus ferments processing The preparation of object, includes the following steps：
（1）Take bacillus licheniformis powder in mass ratio 1:10 ~ 15 be added sterile waters mixing, obtain bacterium solution, take bacterium solution by 8% inoculation Amount is seeded to activation medium, is cultivated 2 ~ 4 days in 26 ~ 32 DEG C, obtains activation culture liquid, activation culture liquid is taken to be connect by 8% inoculum concentration Kind cultivates 3 ~ 6 days in 26 ~ 32 DEG C to seed culture medium, obtains seed culture fluid, spare；
（2）Pre-process watermelon seeds compound：Watermelon seeds cleaning, drying are taken, are pulverized and sieved, sieving particle in mass ratio 1 is taken：3~6 HCl solution mixing is added, impregnates, filtering takes filter residue in 80 ~ 90 DEG C in mass ratio 1:2~4:3:7, which are added rosin, peach gum, water, mixes Stirring is closed, is evaporated under reduced pressure to the 30 ~ 45% of original volume to get pretreatment watermelon seeds compound；
（3）According to the mass fraction, 20 ~ 40 parts of pretreatment carp eggs, 15 ~ 30 parts of pretreatment watermelon son compounds, 10 ~ 15 parts of Portugals are taken Grape juice, 3 ~ 6 parts of spare seed culture fluids, in 28 ~ 32 DEG C, constant temperature stirring fermentation 3 ~ 6 days, discharging obtains zymotic fluid, takes zymotic fluid Ultraviolet sterilization, rotary evaporation are concentrated under reduced pressure, and obtain concentrate, collect concentrate refrigeration, and filtering takes filter residue to be passed through nitrogen protection, roasts It burns, it is cooling, it discharges to get the lichen bacillus ferments processed material.
8. a kind of Bio-fuel oil energy saver according to claim 7, which is characterized in that the activation medium：By mass parts Number meter, takes 40 ~ 60 portions of potatos, 15 ~ 25 parts of lactose, 5 ~ 10 parts of yeast extracts, 2 ~ 6 parts of dipotassium hydrogen phosphates, 0.05 ~ 0.09 part of sulfuric acid Magnesium, 0.03 ~ 0.07 part of calcium chloride, 0.5 ~ 1 part of disodium hydrogen phosphate, 0.03 ~ 0.07 part of vitamin B1, 1000 parts of water, go out in 121 DEG C Bacterium 20min is to get activation medium.
9. a kind of Bio-fuel oil energy saver according to claim 7, which is characterized in that the seed culture medium：By mass parts Number meter, takes 20 ~ 40 parts of casein peptones, 15 ~ 20 parts of soy peptones, 30 ~ 50 portions of potatos, 12 ~ 20 parts of glucose, 0.07 ~ 0.1 Part magnesium sulfate, 3 ~ 8 parts of NaCl, 3 ~ 6 parts of urea, 0.5 ~ 1 part of disodium hydrogen phosphate, 0.05 ~ 0.09 part of vitamin B1, 1000 parts of water, 20min is sterilized in 121 DEG C to get seed culture medium.
10. a kind of Bio-fuel oil energy saver according to claim 7, which is characterized in that the pretreatment carp egg：Take carp Ovum, high-speed organization break process must be homogenized, and take homogenate that 3 ~ 6 times of Na of homogenate quality are added2CO3Solution is mixed, and stands, decompression Concentration is evaporated in vacuo to the 30 ~ 40% of original volume to get pretreatment carp egg.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109957861A (en) * 2019-02-28 2019-07-02 常州凯途纺织品有限公司 A kind of heat-resisting oxidation-resistance spinning oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1944585A (en) * 2006-09-29 2007-04-11 孙洪生 High efficiency fuel energy saving agent and its producing method and equipment for emulsifying heavy oil with it
CN107011957A (en) * 2017-04-25 2017-08-04 南宁市钱隆汽车租赁有限公司 Gasoline one case is net
CN107653011A (en) * 2017-10-18 2018-02-02 王天石 A kind of automobile specified gasolene cleaner and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1944585A (en) * 2006-09-29 2007-04-11 孙洪生 High efficiency fuel energy saving agent and its producing method and equipment for emulsifying heavy oil with it
CN107011957A (en) * 2017-04-25 2017-08-04 南宁市钱隆汽车租赁有限公司 Gasoline one case is net
CN107653011A (en) * 2017-10-18 2018-02-02 王天石 A kind of automobile specified gasolene cleaner and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109957861A (en) * 2019-02-28 2019-07-02 常州凯途纺织品有限公司 A kind of heat-resisting oxidation-resistance spinning oil

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