CN1086957A - 控制昆虫的方法 - Google Patents
控制昆虫的方法 Download PDFInfo
- Publication number
- CN1086957A CN1086957A CN93116804A CN93116804A CN1086957A CN 1086957 A CN1086957 A CN 1086957A CN 93116804 A CN93116804 A CN 93116804A CN 93116804 A CN93116804 A CN 93116804A CN 1086957 A CN1086957 A CN 1086957A
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- aphis
- insect
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- aphid
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Abstract
本发明涉及用游离形式或农业化学上可接受的
盐形式的式I化合物控制昆虫的方法,该化合物的相
应应用,相应杀虫剂组合物以及涉及该组合物的制备
方法和应用。
Description
本发明涉及A:一种控制昆虫的方法,其中使用了游离形式或农业化学上可接受的盐形式的式(Ⅰ)化合物,
其中所控制的具体昆虫是半翅目昆虫,以及涉及这些化合物的相应应用、其活性成分选自这些化合物的相应的杀昆虫组合物、这些组合物的制备方法和使用方法。根据情况,属于这一段中的一个、数个或所有本发明目的在下面均以符合“A”表示。
本发明涉及(B):一种保护植物繁殖材料免遭害虫侵害的方法,其中使用了游离形式或农业化学上可接受的盐形式的式(Ⅰ)化合物,
以及涉及这些化合物的应用、其活性成分选自这些化合物的相应的农药组合物、这些组合物的制备方法和使用方法以及免遭害虫侵害的植物繁殖材料。根据情况,属于这一段的一个、数个或所有本发明目的在下面均以符号“B”表示。
对Ⅰ化合物农业化学上可接受的盐是例如酸加成盐。这些盐是通过与例如强无机酸、强有机羧酸或有机磺酸反应形成。强无机酸的例子有:高氯酸、硫酸、硝酸、亚硝酸、磷酸或氢卤酸;强有机羧酸的例子有:未取代或取代(如卤代)C1-C4链烷羧酸如甲酸、乙酸或三氟乙酸,不饱和或饱和二元羧酸如草酸、丙二酸、琥珀酸、马来酸、富马酸或邻苯二甲酸,羟基羧酸如抗坏血酸、乳酸,苹果酸、酒石酸或柠檬酸,或苯甲酸;有机磺酸的例子有:未取代或取代(如卤代)C1-C4链烷磺酸或芳基磺酸,如甲烷磺酸或对甲苯磺酸。由于游离形式和农业化学上可接受的盐形式的式Ⅰ化合物之间存在密切关系,因此下面所指的任何游离式Ⅰ化合物或其农业化学上可接受的盐均应被理解为包括其相应的农业化学上可接受的盐或游离式Ⅰ化合物。按照本发明,优选游离形式的式Ⅰ化合物。
根据连接上面公开的结构式中所示的两个杂环的(-N=C(H)-)局部结构是否具有(E)或(Z)构型,游离形式或其农业化学上可接受的盐形式的式Ⅰ化合物分别为(E)或(Z)异构体形式。因此,即使在没有具体提到的情况下,上文和下文中所说的游离形式或农业化学上的可接受的盐形式的式Ⅰ化合的应被理解为纯的(E)或(Z)异构体或(E)/(Z)混合物。
游离形式或农业化学上可接受的盐形式的Ⅰ化合物可为互变异构体形式。例如,根据上面所公开的结构式,具有(N(H)-C(=O)-)局部结构的式Ⅰ化合物可与具有(-N=C(OH)-)局部结构的互变异构体处于平衡状态。因此,上文和下文中所指的式Ⅰ化合物根据情况也应被理解为包括相应的互变异构体,即使后面没有具体提到亦是如此。
本发明所用的式Ⅰ化合物是已知的,且在例如EP-A-0314615中有所记载。EP-A-0314615。对游离形式或酸加成盐形式的式(Ⅱ)化合物在控制害虫,主要是昆虫,更主要是虱目、鞘翅目、双翅目、异翅亚目、同翅目、膜翅目、等翅目、鳞翅目、食毛目、直翅目、
虫目、蚤目、缨翅目和缨尾目昆虫,尤其是幼虫、特别是属于同翅目的蚜科昆虫方面的活性进行了一般描述。
其中
R1为氢、C1-C12烷基、C3-C6环烷基、C1-C4烷氧-C1-C6烷基、卤代-C1-C2烷基、苯基、苄基、苯乙基、苯丙基、苯丁基或苯戊基,或被卤素、C1-C5烷基、卤代-C1-C2烷基、甲氧基和/或乙氧基单取代或双取代的苯基、苄基、苯乙基、苯丙基、苯丁基或苯戊基,且
R2为氢、C1-C6烷基或C3-C6环烷基,或为未被取代或被C1-C12烷基、卤素或卤代-C1-C12烷基取代的苯基,或
R1和R2共同形成一饱和或不饱和三元至七元碳环,
R3为氢或C1-C6烷基,且
Z为-N=CH-或-NH-CH2-。
但是,EP-A-0314615具体提到,式Ⅱ化合物仅对同翅目的三个种,即属于蚜科蚜属和瘤蚜属的豆蚜、豆已矛蚜和桃蚜的昆虫以及对双翅目的一个种即属于蚊科伊蚊属的埃及伊蚊种的昆虫具有活性,而对同翅目中除蚜科外的其它科昆虫没有活性,同样对蚜属中除豆蚜、豆卫矛蚜种之外的种也没有活性。最后,EP-A-0314625中也没有提到将式Ⅱ化合物用于保护植物繁殖材料免遭害虫侵害。
鉴于上面讨论的EP-A-0314615中所公开的内容,现已意想不到的并令人惊奇地发现:(A),式Ⅰ化合物尤其适用于控制同翅目的某些其它昆虫,即控制属于同翅目粉虱科、叶蝉科和飞虱科的昆虫;属于同翅目蚜科无网蚜属、短尼蚜属、短棒蚜属、西圆尾蚜属、大尾蚜属、长管蚜属、疣蚜属、缢管蚜属、扎圆尾蚜属、二叉蚜属和声蚜属的昆虫;以及属于同翅目蚜科蚜属棉蚜种和苹果蚜科的昆虫;(B),式Ⅰ化合物尤其适用于保护植物繁殖材料免遭害虫侵害。
尽管式Ⅰ化合物落入EP-A-0314615中公开的式Ⅱ化合物的范围之内,并且甚至在EP-A-0314615的实施例H、3中被具体公开,但式Ⅰ化合物按照(A)在控制同翅目特定昆虫方面以及按照(B)在保护植物繁殖材料免遭害虫侵害方面的良好适用性仍令人惊奇,因为EP-A-0314615根本没有提到本发明所提到的良好活性或适用性,式Ⅱ化合物既没有象(A)中所述的那样对同翅目昆虫具有尤其显著的活性,又没有象(B)中所述的那样对保护植物繁殖材料免遭害虫侵害具有尤其显著的适用性,而只有可被看作是式Ⅱ化合物中的一个特殊亚类的本发明式Ⅰ化合物具有相应的尤其显著的活性或适用性。
对于控制昆虫或害虫领域的使用者来说,按照(A)控制昆虫和按照(B)保护植物繁殖材料免遭害虫侵害非常重要,如果没有针对性地控制这些昆虫和害虫,将会因它们对农作物的破坏而产生巨大的经济损失。
在本发明的目的(A)范围内,尤其可控制:
(1)粉虱科昆虫,主要是伯粉虱属和粉虱属昆虫;
(2)叶蝉科昆虫,主要是小绿叶蝉属和斑叶蝉属昆虫;
(3)飞虱科昆虫,主要是灰飞属和褐飞虱属昆虫,更主要是灰飞虱和褐飞虱种昆虫;
(4)蚜科的无网蚜属、短尾蚜属、短棒蚜属、西圆尾蚜属、大尾蚜属、长管蚜属、疣蚜属、缢管蚜属、扎圆尾蚜属、二叉蚜属和声蚜属昆虫;主要是无网蚜属、短棒蚜属、大尾蚜属、长管蚜属、扎圆尾蚜属、二叉蚜属和声蚜属,较好是短棒蚜属、大尾蚜属、长管蚜属、疣蚜属和声蚜属,更好是甘蓝蚜、桃粉大尾蚜、马铃薯长管蚜,忽布疣蚜、桔声蚜和桔蚜;
(5)属于蚜科蚜属的棉蚜和苹果蚜昆虫;
(6)选自以下昆虫种的昆虫:(a)豌豆蚜;(b)棉蚜;(c)苹果蚜;(d)木薯粉蚜;(e)桃黑短尾蚜;(f)甘蓝蚜;(g)苹果红西圆尾蚜;(h)车前圆尾蚜;(i)小绿叶蝉;(j)葡萄斑叶蝉;(k)桃粉大尾蚜;(l)灰飞虱;(m)麦长管蚜;(n)马铃薯长管蚜;(o)蔷薇长管蚜;(p)褐飞虱;(q)忽布疣蚜;(r)苹果缢管蚜;(5)禾谷缢管蚜;(t)萝卜蚜;(u)梨圆尾蚜;
(V)麦二叉蚜;(W)桔声蚜;(X)桔蚜和(Y)温室粉虱,在本发明的目的(B)范围内,主要可控制:
(7)动物害虫;
(8)昆虫,蝉螨目昆虫;
(9)鳞翅目昆虫,例如长翅卷蛾,褐带卷蛾科,透翅蛾科,切根虫科,棉叶波纹夜蛾,Amylios spp.,黎豆夜蛾,黄卷蛾科,银带卷叶蛾科,纹夜蛾科,玉米楷夜蛾,粉斑螟,桃小食心虫,禾草螟科,冷杉芽蛾科,葡萄果蠹科,纵卷叶螟科,云卷蛾科,Cochylis spp.鞘蛾科,Crocidolomia binotalis,苹果异形小卷蛾,小卷叶蛾科,异草螟科,展叶松夜蛾,魏氏夜蛾科,粉斑螟科,小卷叶蛾科;女贞细卷蛾,黄毒蛾科,褐色夜蛾科,食心虫科,广翅小卷蛾,棉铃虫科,菜心野螟,美国白蛾,番茄蠹蛾,旋纹潜蛾,细蛾科,Lobesia botrana,毒蛾科,潜蛾科,天幕毛虫科,甘蓝夜蛾,烟草天蛾,冬天蛾科,欧洲玉米螟,葡萄蛀蛾科,桔卷叶蛾科,小眼夜蛾,棉红铃虫,马铃薯麦蛾,菜粉蝶,粉蝶科,小菜蛾,花巢蛾科,白禾螟科,大螟科,卷叶蛾科,翅蛾科,透翅蛾科,带蛾科,卷叶蛾科,Trichoplusiani和巢蛾科;
鞘翅目昆虫,例如叩甲科,花菜隐食甲,甜菜胫跳甲,黑筒象科,象甲科,皮蠹科,条叶甲科,植瓢虫科,蟋螽科,马铃薯甲虫,稻象甲科,鳃角金龟科,锯谷盗科,斑额象虫科,Phlyctinus spp.,丽金龟科,木虱科,劫根蠹科,金龟子科,朱象科,麦蛾科,粉虫科,拟谷盗科和皮蠹科;
直翅目昆虫,例如蜚廉科,小廉科,蝼蛄科,蜚廉,
飞蝗科,大廉科和蚱蜢科;
等翅目昆虫,例如犀白蚁科;
啮虫目昆虫,例如书虱科;
虱目昆虫,例如血虱科,长颚虱科,虱科,瘿绵蚜科,根瘤蚜科;
食毛目昆虫,例如鸟虱科和羽虱科;
缨翅目昆虫,例如花蓟马科,蓟马科,带蓟马科;棕黄蓟马,棉蓟马和非洲桔硬蓟马;
异翅亚目昆虫,例如臭虫科,可可盲蝽科,红蝽科;Euchistus spp.,扁盾蝽科,稻缘蝽科,网蝽科,红腹猎蝽科,可可褐盲蝽科,稻黑蝽科,和猎蝽科;
同翅亚目昆虫,例如绵粉虱,Aleyrodes brassicae,圆盔蚧科,蚜科,蚜虫科,圆盾蚧科,甘薯粉虱,蜡蚧科,茶褐圆蚧,蔷薇轮蚧,芒果褐软蚧,微叶蝉科,苹果绵蚜,红斑叶蝉科,Gascardia spp.稻灰虱科,褐灰蜡蚧,蛎蚧科,长管蚜科,瘤额蚜科,叶蝉类科,褐飞虱科,Paratoria spp.瘿绵蚜科,臀纹粉蚧科,桑盾蚧科,粉蚧科,木虱科,绵蚧科,盾蚧科,缢管科,盔蚧科,叶蝉科,二叉蚜科,长管蚜科,温室粉虱,木虱科和桔盾蚧;
膜翅目昆虫,例如Acrmyrmex,切叶蚁科,茎蜂科,锯节叶蜂科,松叶蜂科,云杉叶蜂,叶蜂科,田蚁科,小家蚁,锯角叶蜂科,火蚁科和胡蜂科;
双翅目昆虫,例如伊蚁科,Antherigona soccata,毛蚊,红头丽蝇,实蝇科,金蝇科,库蚊科,疽蝇科,寡毛实蝇科,黄猩猩果蝇,厕蝇科,翅胃蝇科,舌蝇科,皮蝇科,Hyppobosca spp.,瑞典麦杆蝇,菠菜潜叶蝇,花蝇科,苹果实蝇,蕈蝇属,螫蝇科,虻蝇科,夜蝉科和大蚊科;
蚤目昆虫,例如角叶蚤科,鼠蚤;
缨尾目昆虫,如衣鱼;
(10)蜱螨目昆虫,例如粉脚粉螨,桔芽瘿螨科,苹刺瘿螨,花蜱科,隐喙啤科,方头蜱科,短须螨科,苜蓿苔螨,Calipitrimerus spp.,鸡皮刺螨,物耳枥绍叶螨,四足螨科,璃眼蜱科,硬蜱科,草地小爪螨,钝喙蜱科,全爪螨科,柑桔锈螨,侧多食跗线螨,痒螨科,扇头蜱科,雕根螨科,疥螨科,跗线螨科和红叶螨科;
即使在以低浓度应用于控制昆虫(A)和控制害虫(B)时,本发明式(Ⅰ)化合物亦是具有预防和/或治疗价值的活性成分,同时它又能被温血运动、鱼、益虫和植物耐受。本发明的活性成分对正常敏感的和抗性的(A)中的昆虫和(B)中的害虫的所有发育阶段或单个发育阶段有效。本发明所使用的活性成分的活性可通过(A)中昆虫或(B)中害虫立即死亡或在一定时间后死亡而直接得以证实,或通过产卵减少和/或孵化率减少而间接得到证实,良好的活性相当于致死率至少为50-60%。本发明所使用的活性成分的显著不同在于对有用昆虫如Amblyseius fallacis、普通草蛉、七星瓢虫、Orius majjusculus和Typhlodromus pyri以及鸟类无害。
本发明所使用的活性成分,按照(A),尤其可用于控制即抑制或破坏存在于植物,尤其是农业、畜牧业和林业上有用的植物和观赏植物上或存在于植物的某一部分如果、花、叶、茎、块茎或根上的昆虫,在某些情况下,同时使得后来生长的植物部分也得到保护,免遭昆虫侵害,按照(B),可控制即抑制或破坏存在于植物繁殖材料,尤其是存在于农业、畜牧业、林业上有用的植物和观赏植物上的繁殖材料上的害虫,同时使后来长出的植物部分也得到抵抗这类害虫的保护,即该保护作用一直延续到形成成熟的抗性植株,繁殖材料或由其发育成的植株所获得的保护既包括抵抗侵害植株地上部分的害虫,也包括抵抗生活在土壤中的害虫。
(A)中所作用的作物和(B)中所作用的植物繁殖材料主要包括如下作物及其繁殖材料:谷物,如小麦、大麦、黑麦、燕麦、玉米或高梁;甜菜作物,如甜菜;水果,如梨果、核果,如苹果、梨、李、桃、杏、樱桃或浆果,如草莓、木莓;豆科作物,如大豆、小扁豆、豌豆或黄豆;油料作物,如油菜、芥末、罂栗、橄榄、向日葵、椰子、蓖麻、可可豆或落花生;瓜类植物,如黄瓜、葫芦或甜瓜;纤维作物,如棉花、亚麻、***或黄麻;柑桔水果,如柑桔、柠檬、葡萄或中国柑桔;蔬菜,如菠菜、莴苣、龙须菜、卷心菜、胡萝卜、洋葱、西红柿、马铃薯或红辣椒;或烟草、坚果、咖啡、茄子、甘蔗、茶叶、胡椒、蔓草、蛇麻草、香蕉、天然橡胶植物或观赏植物;优选谷物、水果、豆科植物、瓜类植物、棉花、柑桔、蔬菜、茄子、蔓草、蛇麻草或观赏植物,更优选的是桃、大豆、豌豆、葫芦、柑桔、卷心菜、西红柿、马铃薯或茄子,最优选的是桃、葫芦、西红柿或马铃薯。
在本发明目的(A)和(B)的范围内,尤其可控制:
a)存在于西红柿作物或其繁殖材料中的棉蚜、木薯粉蚜或温室粉虱,
b)存在于马铃薯作物或其繁殖材料中的棉蚜或马铃薯长管蚜,或
c)存在于瓜类作物或其繁殖材料中的棉蚜、木薯粉蚜或温室粉虱。
在本发明活性成分所应用的其它领域包括:保护贮藏物品或属种或材料或卫生区,尤其是保护家禽或生产性家畜免遭(A)中昆虫和(B)中害虫侵害。
因此,本发明也涉及相应的组合物,即用于(A)的杀虫剂组合物和用于(B)的农药组合物,如乳油、悬浮浓缩液、可在接喷雾或直接稀释的溶液、可涂敷膏状物、稀乳液、可湿性粉剂、可溶性粉剂、粉剂、颗粒剂或存在于聚合物中的包胶,这类组合物包括至少一种本发明化合物,配方的类型是依照预期的目的和主要环境而加以选择,对于方法(A)使用的是杀虫剂组合物,对于方法(B)使用的是农药组合物。
活性成分可直接使用,如使用具有一定粒径的固体活性成分,但优选与至少一种制药技术领域常用的辅助剂,如溶剂或固体载体等补充剂或表面活性剂结合使用。
合适的溶剂如:芳香烃或部分氢化的芳香烃,优选含8-12个碳原子的烷基苯,如二甲苯混合物、烷基化萘或四氢化萘;脂族或环脂族烃,如石蜡或环己烷;醇,如乙醇、丙醇、丁醇、二元醇及其醚和酯,如丙二醇、二丙二醇醚,乙二醇或乙二醇单甲醚或乙二醇单***;酮,如环己酮、异佛尔酮或双丙酮醇;强极性溶剂,如N-甲基吡咯烷-2-酮、二甲基亚砜或N,N-二甲基甲酰胺;水;植物油或环氧化植物油,如菜油、蓖麻油,椰子油或豆油、或环氧化菜油、蓖麻油、椰子油或豆油和硅酮油。
用于例如粉剂和可分散粉剂中的固体载体通常是天然无机填料,如方解石、滑石、高岭土、蒙脱土或绿坡缕石。为了改进其物理性质,也可加入高度分散的硅酸或高度分散的吸附聚合物。合适的粒化吸附载体为多孔型,如浮石、砖渣、海泡石或膨润土;合适的非吸附载体是例如方解石或砂子。另外,也可使用各种粒化的无机或有机材料,尤其是白云石或粉碎的植物残渣。
根据所要配制的化合物的性质,合适的表面活性化合物可以是具有良好乳化、分散和湿润性质的非离子型、阳离子型和/或阴离子型表面活性剂或表面活性剂混合物。下面所给出的表面活性剂仅仅是作举例,配药技术中常用的且适用于本发明的其它表面活性剂在有关文献中均有记载。
非离子型表面活性剂最好是脂族或环脂族醇、饱和或不饱和脂肪酸和烷基酚的聚乙二醇醚衍生物,该衍生物含有3-30个乙二醇醚基团,和在脂族烃部分中含有8-20个碳原子且在烷基酚的烷基部分含有6-18个碳原子。更合适的非离子型表面活性剂是聚环氧乙烷与聚丙二醇、乙二胺聚丙二醇和烷基聚丙二醇所形成的水溶性加合物,其中烷基链上含有1-10个碳原子,该加合物含有20-250个乙二醇醚基团和10-100个丙二醇醚基团,该化合物通常是每个丙二醇含有1-5个乙二醇单元。非离子型表面活性剂的代表性实例有:壬基酚聚乙氧乙醇、蓖麻油聚乙二醇醚、聚环氧丙烷/聚环氧乙烷加合物、三丁基苯氧基-聚乙氧乙醇、聚乙二醇和辛基苯氧基-聚乙氧乙醇。聚氧乙烯山梨糖醇酐的脂肪酸酯,如聚氧乙烯山梨糖醇酐三油酸酯也是合适的。
阳离子型表面活性剂主要是季铵盐,它含有至少一个C8-C22烷基作为N-取代基,且含有未取代或卤代低级烷基、苄基或羟基-低级烷基作为其它取代基、该盐最好为卤化物、甲基硫酸盐或乙基硫酸盐,如硬脂酰三甲基氯化铵或苄基二(2-氯乙基)乙基溴化铵。
水溶性皂和水溶性合成表面活性化合物均是合适的阴离子表面活性剂。合适的皂是高级脂肪酸(C10-C22)的碱金属盐、碱土金属盐、取代或未取代的铵盐,如油酸或硬脂酸的钠盐或钾盐,以及来自椰子油或动物脂油的天然脂肪酸混合物的盐,还可以提到的是脂肪酸甲基牛磺酸盐。但是,更常使用的是合成表面活性剂,尤其是脂肪磺酸盐、脂肪硫酸盐、磺化的苯并咪唑衍生物或烷基芳基磺酸盐。脂肪硫酸盐或脂肪磺酸盐通常为碱金属盐、碱土金属盐、取代或未取代的铵盐,并且一般带有8-22个碳原子的烷基,该烷基也包括酰基中的烷基部分,例如木素磺酸的钠或钙盐、十二烷基硫酸酯的钠或钙盐或用天然脂肪酸制得的脂肪醇硫酸钠或钙盐。该组中也包括脂肪醇/环氧乙烷加成物的硫酸酯和磺酸的盐。磺化的苯咪唑衍生物最好含有2个磺酰基和一个具有8-22个碳原子的脂肪酸残基。芳基烷基磺酸盐的例子有十二烷基苯磺酸、二丁基萘磺酸或萘磺酸/甲醛缩合产物的钠、钙或三乙醇胺盐。其它合适的化合物是相应的磷酸盐,如对-壬基酚/(4-14)环氧乙烷加成物的磷酯盐或磷脂盐。
该组合物通常包含0.1-99%,尤其是0.1-95%的活性成分和1-99.9%,尤其是5-99.9%的至少一种固体或液体助剂,其中表面活性剂通常占组合物的0-25%,尤其是0.1-20%(%均表示重量百分数)。市售的产品最好是配成浓缩液,而使用者则通常使用活性成分浓度大大降低的稀配方。较好的组合物具体由以下成分组成(%均为重量百分数):
乳油:
活性成分 1-90%,优选5-20%
表面活性剂 1-30%,优选10-20%
溶剂 5-98%,优选70-85%
粉剂:
活性成分 0.1-10%,优选0.1-1%
固体载体 99.9-90%,优选99.9%-99%
悬浮浓缩液
活性成分 5-75%,优选10-50%
水 94-24%,优选88-30%
表面活性剂 1-40%,优选2-30%
可湿性粉剂
活性成分 0.5-90%,优选1-80%
表面活性剂 0.5-20%,优选1-15%
固体载体 5-99%,优选15-98%
通过向本发明的组合物中加入其它活性成分如杀虫剂、杀螨剂和/或杀菌剂,可使其作用范围大大加宽并适用于普遍情况。合适活性成分添加剂的典型例子有:有机磷化合物、硝基酚及其衍生物、甲脒类、脲类、氨基甲酸酯类、拟除虫菊酯类、氯代烃类以及苏云金芽孢杆菌制剂。本发明的组合物也可包括其它固体或液体辅助剂,如稳定剂,如植物油或环氧化植物油(如环氧化椰子油、菜油或豆油);消泡剂,如硅酮油;防腐剂;粘度调节剂;粘合剂和/或增稠剂,以及肥料或用于获得特殊效果的其它活性成分,如杀细菌剂、杀线虫剂、杀软体动物剂或选择性除草剂。
本发明组合物是按本身已知的方法制备:例如,在无辅助剂的情况下,是通过粉碎和/或筛分成特定粒径或通过挤压固体活性成分来制备;在存在至少一种辅助剂的情况下,是通过将活性成分与辅助剂一起充分混合和/或研磨来制备。本发明也涉及制备本发明组合物的方法以及式Ⅰ化合物在制备这些组合物中的应用。
可根据所需的目的和具体的环境来选择合适的施用(A)组合物的方法,即控制(A)中昆虫的方法,如喷雾、雾化、撒粉、涂覆、撒播或泼浇、活性成分的使用浓度通常为0.1-1000ppm,优选0.1-500ppm,优选0.1-500ppm。具体地说,喷雾混合物中活性成分的浓度为50、100、200、300或500ppm。每公顷的施用量通常为1-2000g活性成分,尤其是10-1000g,优选20-600g。优选每分顷的施用量为100、200、250、300、400或450g活性成分。在植树时,优选的施用量为每树0.25、0.75、1.0或2.0g活性成分。(A)组合物的较好施用方法是施用给植物叶(叶片施药),施用次数和施用量取决于被具体昆虫传染的危险程度。但是,如果是用液体配方浇灌植株生长部位或如果活性成分是以固体形式加到植物生长的部位(如土壤中),则活性成分也可通过根渗透到植株上。对于水稻作物,可将颗粒剂定量加到稻田中。
施用(B)组合物的方法,即保护植物繁殖材料免遭害虫侵害的方法包括例如将相应的组合物施用于种植或播种点,使得施药与繁殖材料的种植或播种在空间上密切接近或在空间上一起。按照本发明,按与繁殖材料的种植或播种密切接近的方式施用组合物于种植或播种地点最好是在种植或播种繁殖材料之前在种植或播种繁殖材料的地点直接进行土壤施药,例如,最好是在播种前施用于种沟或种植或播种点周围一个很窄的范围内,可按与上述所述的(A)的土壤施药相似的方式进行(B)的土壤施药。相应组合物的施用与繁殖材料的种植或播种在空间上一起进行应被理解为将被组合物预处理过的繁殖材料种植或播种在种植或播种地点。根据所需的目的及具体的环境,繁殖材料的预处理可通过利用喷雾、雾化、撤粉、涂覆、撤播播或浇灌等方式将组合物施用于繁殖材料来完成,当繁殖材料是种子时,主要是通过拌种完成。在按照本发明进行拌种时,是在播种前将干的、湿的或浆状敷料(一种合适的(B)的农药组合物)加到拌种机中的种子上,并通过搅拌拌种机中的内容物和/或通过旋转和/或振荡整个拌种机使组合物均匀分散在种子上。进行拌种的特殊方法包括用液体组合物浸种、用固体组合物涂覆种子或通过将组合物加到用于预浸种子的水中而使活性成分渗透到种子中,按本发明进行拌种时,所用组合物的施用量一般为每千克种子0.1-20g活性成分,尤其是0.5-15g/kg,更好是1-10g/kg,(B)的其它施用方法、施用浓度和施用量与(A)的方法相同。本发明种子敷料的显著区别在于,由于所用活性成分毒性极低,从鸟类,例如常常从刚刚播种的地里偷种子的鸟类上观察到包衣种子的良好耐受性,这些鸟类如
、鸟、鸫、鸭、野鸡、鸣鸟、鹅、红雀、鸡、乌鸦、云雀、山雀属的鸟、海鸥、渡鸦、斑鸡、斑尾林鸽、金翅雀等鹦鹉。婴本发明的种子敷料也包括贮藏种子的敷料。
本发明也涉及已按本发明预处理过的并可上市的植物繁殖材料。
以下实施例用于说明本发明,但不限制本发明,温度为摄氏度。配制实施例(所有百分数为重量百分数)
实施例F1:溶液 a) b) c) d)
活性成分 80% 10% 5% 95%
乙二醇单甲醚 20% - - -
聚乙二醇(分子量400) - 70% - -
N-甲基-2-吡咯烷酮 - 20% - -
环氧化椰子油 - - 1% 5%
石油馏分(沸点范围160-190°) - - 94% -
上述溶液适用于以微滴形式施用。
实施例F2:颗粒剂 a) b) c) d)
活性成分 5% 10% 8% 21%
高岭土 94% - 79% 54%
高度分散的硅酸 1% - 13% 7%
绿坡缕 - 90% - 18%
将活性成分溶于二氯甲烷,溶液喷雾到载体上,并随后填空蒸发溶剂。
实施例F3:粉剂 a) b)
活性成分 2% 5%
高度分散的硅酸 1% 5%
滑石 97% -
高岭土 - 90%
待用粉剂是通过将载体与活性成分充分混合获得。
实施例F4:可湿性粉剂
活性成分 25%
硫酸钠 5%
蓖麻油聚乙二醇醚 10%
(36-37mol环氧乙烷)
硅酮油 1%
Agridex 2%
高度分散的硅酸 10%
高岭土粉剂 37%
亚硫酸盐废碱粉 5%
Ultravon W-300%(1-苄基-2-十七烷基苯并脒唑-X,X′-二磺酸二钠盐) 5%
将活性成分与辅助剂混合,并将混合物在合适的球磨机中粉碎,得到可湿性粉剂,它可用水稀释成所需浓度的悬浮液。
实施例F5:粉剂 a) b)
活性成分 5% 8%
滑石 95% -
高岭土 - 92%
通过将活性成分与载体混合,并在合适的球磨机中研磨混合物,得到待用粉剂。
实施例F6:挤压颗粒剂
活性成分 10%
木素磺酸钠 2%
羧甲基纤维素 1%
高岭土 87%
将活性成分与辅助剂混合并粉碎,然后用水湿润。挤压并粒化湿混合物,最好在气流中干燥颗粒。
实施例F7:涂覆颗粒
活性成分 3%
聚乙二醇(分子量200) 3%
高岭土 94%
在混合器中将细粉活性成分均匀加到被聚乙二醇湿润过的高岭土上。以此方式得到无尘涂覆颗粒。
实施例F8:悬浮浓缩液
活性成分 40%
乙二醇 10%
壬基酚聚乙二醇醚 6%
(15mol环氧乙烷)
木素磺酸钠 10%
羧甲基纤维素 1%
甲醛水溶液(37%) 0.2%
水溶性硅酮油乳液(75%) 0.8%
水 32%
将细粉活性成分与辅助剂充分混合,然后用水稀释成任何所需浓度的悬浮浓缩液。
实施例F9:乳油 a) b) c)
活性成分 25% 40% 50%
十二烷基苯磺酸钙 5% 8% 6%
蓖麻油聚乙二醇醚 5% - -
(36mol环氧乙烷)
三丁基酚聚乙二醇醚 - 12% 4%
(30mol环氧乙烷)
环己酮 - 15% 20%
二甲苯混合物 65% 25% 20%
用水稀释该乳油,可产生任何所需浓度的乳液。
实施例F10:可湿性粉剂 a) b) c)
活性成分 25% 50% 75%
木素磺酸钠 5% 5% -
十二烷基硫酸钠 3% - 5%
二异丁基萘磺酸钠 - 6% 10%
辛基酚聚乙二醇醚 - 2% -
(7-8mol环氧乙烷)
高度分散的硅酸 5% 10% 10%
高岭土 62% 27% -
将活性成分与辅助剂混合,并将混合物在合适的球磨机中粉碎,得到可湿性粉剂,可用水将其稀释成所需浓度悬浮液。
实施例F11:乳油
活性成分 10%
辛基酚聚乙二醇醚(4-5mol环氧乙烷) 3%
十二烷基苯磺酸钙 3%
蓖麻油聚乙二醇醚 4%
(36mol环氧乙烷)
环己酮 30%
二甲苯混合物 50%
用水稀释该乳油可得到所需浓度的乳液。
生物学实施例(除非特别说明,百分数均为重量百分数)
实施例B1:抗甘薯粉虱作用
将矮生菜豆置于纱笼中并用甘薯粉虱成虫侵害植株,产卵后除去所有成虫,并在10天后用含有50ppm试验化合物的水溶性悬浮液喷洒植物及其上的若虫。施药14天后,通过与未处理的对照比较计算出孵化率。
在该试验中,式Ⅰ化合物的效力为100%。
实施例B2:抗稻褐飞虱作用
用含有50ppm试验化合物的水溶性悬液处理两周令的水稻植株。喷酒涂层干燥后,用稻褐飞虱的若虫侵害植株,然后于28°放置14天。之后进行评估。通过比较处理植株上和未处理植株上新孵化的下代若虫数,测定下代减少百分数(活性百分数)。
在这一试验中,式Ⅰ化合物的效力为100%。
实施例B3:抗稻褐飞虱涂覆作用
将100g水稻种子和每千克种子足以产生0.1、1或10g活性成分的试验化合物配方加到玻璃瓶或塑料容器中。通过旋转或振荡容器,使试验化合物均匀分散在种子表面。将如此涂覆过的种子播种到花瓶中。发芽后,将幼株在温室中栽培两周,然后在Plexcglas圆筒中用20个稻褐飞虱的若虫侵害每一植株。将圆筒用网封住。侵害植株5天后进行评估。通过比较涂覆种子及未涂覆种子上长出的植株的存活个体数,测出种群减少的百分数(活性百分数)。
在这一试验中,式Ⅰ化合物显示出良好活性。
实施例B4:抗豆卫矛蚜涂覆作用
将100g大豆种子和足以为每千克种子产生0.1、1或10g活性成分的量的试验化合物配方加到玻璃瓶或塑料容器中。通过旋转和/或振荡容器使试验化合物均匀分散到种子表面。将如此涂覆的种子播种到花瓶中(每瓶三颗种子)。于25-30°温室中培养幼株至二叶令,然后用豆卫矛蚜侵害。在植株被侵害后6天进行评估、通过比较由涂覆种子和未涂覆种子上长出的植株的个体存活数,测定出种群减少百分数(活性百分数)。
在该试验中,式Ⅰ化合物显示出良好活性。
实施例B5:抗挑蚜涂覆作用
将100g甜菜种子和由可湿性粉剂和少量水制成的足以在每千克种子上产生0.1、1或10g活性成分的量的试验化合物的膏状配方加到玻璃瓶或塑料容器中,将密封的涂覆容器移至滚动床上,直至膏状物均匀分散到种子表面。干燥如此涂覆的种子,并播种到装有黄土的塑料瓶中。于24-26°、相对湿度为50-60%的温室中培养幼苗,每目的光照时间为14小时。发芽后4周,将高度为10cm的植株用混合桃蚜进行侵害。通过比较由涂覆种子和未涂覆种子上长出的植株的个体存活数,测定出种群减少百分数(活性百分数)。
在这一试验中,式Ⅰ化合物显示出良好活性。
Claims (35)
2、根据权利要求1的方法,其中所使用的活性成分为游离形式。
3、根据权利要求1或2的方法,它控制粉虱科昆虫。
4、根据权利要求1-3的方法,它控制伯粉虱属和粉虱属昆虫。
5、根据权利要求1-4的方法,它控制木薯粉蚜昆虫。
6、根据权利要求1-4的方法,它控制温室粉虱昆虫。
7、根据权利要求1或2的方法,它控制叶蝉科昆虫。
8、根据权利要求1、2或7的方法,它控制小绿叶蝉属和斑叶蝉属昆虫。
9、根据权利要求1或2的方法,它控制飞虱科的昆虫。
10、根据权利要求1、2或9的方法,它控制灰虱属和褐飞虱属的昆虫。
11、根据权利要求1或2的方法,它控制蚜科无网蚜属、短尾蚜属、短棒蚜属、西圆尾蚜属、大尾蚜属、长管蚜属、疣蚜属、缢管蚜属、扎圆尾蚜属、二叉蚜属和声蚜属的昆虫。
12、根据权利要求1、2或3的方法,它控制无网蚜属、短棒蚜属、大尾蚜属、长管蚜属、疣蚜属、缢管蚜属、扎圆尾蚜属、二叉蚜属和声蚜属的昆虫。
13、根据权利要求1、2、11或12的方法,它控制短棒蚜属、大尾蚜属、长管蚜属、疣蚜属、和声蚜属的昆虫。
14、根据权利要求1、2或11-13的方法,它控制马铃薯长管蚜。
15、根据权利要求1或2的方法,它控制属于蚜科蚜属的棉蚜和苹果蚜。
16、根据权利要求1、2或15的方法,它控制棉蚜。
17、一种用于权利要求1所述方法中的杀昆虫组合物,该组合物包括至少一种游离形式或农业化学上可接受的盐形式的式Ⅰ化合物作为活性成分〈
并根据需要还包括至少一种辅助剂。
18、一种制备如权利要求17所述的含有至少一种辅助剂的组合物的方法,其中活性成分与辅助剂充分混合和/或研磨。
19、游离形式或农业化学上可接受的盐形式的式Ⅰ化合物在制备权利要求17所述组合物中的应用。
20、权利要求17所述组合物在权利要求1所述方法中的应用。
22、根据权利要求21的方法,其中活性成分为游离形式。
23、根据权利要求21或22的方法,其中植物繁殖材料为种苗、根茎、插条或种子。
24、根据权利要求21-23的方法,其中种子为果实、块茎、谷粒或鳞茎。
25、根据权利要求21-24的方法,其中害虫为动物害虫。
26、根据权利要求21-25的方法,其中害虫为昆虫或蜱螨目的代表物。
27、根据权利要求21-26的方法,其中组合物是以土壤施用方式直接施用于繁殖材料的种植或播种地点或繁殖材料种植或播种地点周围非常有限的区域内。
28、根据权利要求21-27的方法,其中组合物是以土壤施用方式施用于种沟内。
29、根据权利要求21-26的方法,组合物的施用方式是将组合物预处理过的繁殖材料种植或播种到种植或播种地点。
30、根据权利要求21-26或29的方法,其中繁殖材料的预处理是拌种。
32、一种制各如权利要求31所述包含至少一种辅助剂的组合物的方法,其中活性成分与辅助剂被充分混合和/或研磨。
34、权利要求31所述组合物在权利要求21所述方法中的应用。
35、按权利要求29或30所述方法预处理过的植物繁殖材料。
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CH2847/921 | 1992-09-10 | ||
CH2847/92-1 | 1992-09-10 | ||
CH2847/92A CH684673A5 (de) | 1992-09-10 | 1992-09-10 | Verfahren zur Insektenbekämpfung. |
CH3558/92-0 | 1992-11-20 | ||
CH3558/920 | 1992-11-20 | ||
CH355892 | 1992-11-20 |
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CN1086957A true CN1086957A (zh) | 1994-05-25 |
CN1043947C CN1043947C (zh) | 1999-07-07 |
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US (1) | US5646145A (zh) |
JP (1) | JP3567333B2 (zh) |
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CN (1) | CN1043947C (zh) |
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BE (1) | BE1006552A3 (zh) |
BR (1) | BR9303739A (zh) |
CA (1) | CA2105723C (zh) |
CZ (1) | CZ286333B6 (zh) |
DE (1) | DE4330281B9 (zh) |
EG (1) | EG20178A (zh) |
ES (1) | ES2105927B1 (zh) |
FR (1) | FR2695298B1 (zh) |
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CN101637163B (zh) * | 2009-09-07 | 2012-07-04 | 山东农业大学 | 一种含哒螨灵和吡蚜酮的农药组合物 |
CN103875705A (zh) * | 2014-03-20 | 2014-06-25 | 黄业新 | 一种含吡蚜酮和噻唑磷的农药颗粒剂 |
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JP3810480B2 (ja) * | 1996-05-30 | 2006-08-16 | バイエルクロップサイエンス株式会社 | 殺菌殺虫組成物 |
BRPI9814318B1 (pt) * | 1997-12-23 | 2017-04-18 | Novartis Ag (Novartis Sa) (Novartis Inc ) | processo para controle de insetos em culturas de plantas transgênicas úteis expressando a proteína cry1ab |
CH696712A5 (de) | 2001-12-21 | 2007-10-15 | Kitagawa Ind Co Ltd | Uhr mit Kunststoffsubstrat und Räderwerkvorrichtung. |
JP4599943B2 (ja) * | 2004-08-27 | 2010-12-15 | 住友化学株式会社 | コナジラミ類防除剤 |
EP2002722A1 (en) * | 2007-06-15 | 2008-12-17 | Syngeta Participations AG | Methods of controlling insects |
GB0811300D0 (en) * | 2008-06-19 | 2008-07-30 | Syngenta Participations Ag | Methods of controlling neonicotinoid resistant insects |
EP2608665B1 (fr) | 2010-08-23 | 2014-08-06 | Université de Liège | Utilisation d'une composition comme attractant d'auxiliaires |
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US5179094A (en) * | 1989-04-06 | 1993-01-12 | Ciba-Geigy Corporation | Pest control agents |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101637163B (zh) * | 2009-09-07 | 2012-07-04 | 山东农业大学 | 一种含哒螨灵和吡蚜酮的农药组合物 |
CN103875705A (zh) * | 2014-03-20 | 2014-06-25 | 黄业新 | 一种含吡蚜酮和噻唑磷的农药颗粒剂 |
CN103875705B (zh) * | 2014-03-20 | 2015-10-21 | 陈光敏 | 一种含吡蚜酮和噻唑磷的农药颗粒剂 |
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