CN108610912A - A kind of coating electronic device new material and preparation method thereof - Google Patents
A kind of coating electronic device new material and preparation method thereof Download PDFInfo
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- CN108610912A CN108610912A CN201611126589.5A CN201611126589A CN108610912A CN 108610912 A CN108610912 A CN 108610912A CN 201611126589 A CN201611126589 A CN 201611126589A CN 108610912 A CN108610912 A CN 108610912A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of coating electronic device new materials and preparation method thereof.It is made of the raw material of following parts by weight:80 200 parts of polyethylene terephthalate, poly- 2,6 100 220 parts of (ethylene naphthalate)s, 20 30 parts of Isosorbide-5-Nitrae cyclohexanedimethanol polyester, 20 30 parts of silicone oil, 38 parts of graphene, 10 20 parts of levelling agent, 38 parts of curing agent, 30 80 parts of filler.The coating electronic device new material of the present invention has self-cleaning function, and resistance to corrosion is strong, such as moist in extreme environment, soda acid etc. is permanently effective, and the service life of product is long, and the holding time is long under cryogenic, it is not easy to cure, in room temperature in use, be easy to cure again, spray time is saved.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of coating electronic device new material and preparation method thereof.
Background technology
As the integrated level that electronic equipment requires is higher and higher, surface is easy by dust fall or spontaneous corrosion
It influences.It is required that the surface of electronic equipment has the function of self-cleaning and corrosion-resistant, it is general to coat anticorrosive paint to solve the problems, such as this.Mesh
Preceding anticorrosive paint self-cleaning function is not strong, and is easy by extreme environment such as moisture, and the corrosion and ageing of soda acid etc. loses effect.
Patent 201210191710.8 discloses a kind of anticorrosive paint, includes following raw materials according by weight:20-30 parts of chlorine
Vinegar resin, 10-20 parts of rosin modified phenolic resin, 5-10 parts of chlorinated paraffin, 2-8 parts of silane coupling agent, 6-20 parts
Ethylene glycol ether acetate, 5-15 parts of amino resins, 2-10 parts of filler.The coating agent resistance to salt water is strong, anti-corrosive properties, but
It is, it cannot be self-cleaning.Patent 201410735861.4 discloses a kind of anti-corrosion self-cleaning coating, by following raw material according to parts by weight
It is made, 20-30 parts of tetramethyl divinyl disiloxane;25-40 parts of MethylethoxylsiliconFluid Fluid;10-15 parts of hydroxyl hydrogen silicone oil;
15-20 parts of parachlorotoluene;1-5 parts of ethanedioic acid;0.1-0.5 parts of ring propyl alcohol;0.3-0.7 parts of catalyst.Though the anti-corrosion self-cleaning coating
So can be self-cleaning, still, coating property is bad, and weatherability is poor, and service life is short, is easy to be influenced by extreme environment.
Invention content
The purpose of the present invention is to provide a kind of coating electronic device new materials and preparation method thereof.
A kind of coating electronic device new material, is made of the raw material of following parts by weight:Polyethylene terephthalate
80-200 parts of ester, 100-220 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 20-30 parts of 1,4-CHDM polyester, poly-vinegar acid
20-30 parts of vinyl acetate, 20-30 parts of silicone oil, 3-8 parts of graphene, 10-20 parts of levelling agent, 3-8 parts of curing agent, 30-80 parts of filler.
The levelling agent be acrylate monomer, dimethylbenzene, toluene, polyacrylic acid, Propyleneimine, tetraethoxysilane,
Triethyl phosphate, the one or more in 2- amino -6- chloro benzothiazoles.
The curing agent is sodium carbonate, calcium lignosulfonate, calcium chloride, the formaldehyde condensation products of sulfonated acetone, sorbierite list
Laurate, 1H, 1H- perfluoro capryl amine, 4- trifluoromethylthio benzoic acid, the one or more in 3- thanatols.
The filler is chondroitin sulfate, mica powder, talcum powder, attapulgite, 4- bromobenzene hydrazine hydrochlorides, 5- nitryl furfurals
In one or more.
The preparation method of above-mentioned coating electronic device new material, carries out in accordance with the following steps:
(1) at normal temperatures, 80-200 parts of polyethylene terephthalate, poly- 2,6-naphthalenedicarboxylic acid are taken according to parts by weight
100-220 parts of glycol ester, 20-30 parts of 1,4-CHDM polyester, 20-30 parts of silicone oil are put into stirred tank, stir 4-
10 minutes;
(2) it is warming up to 45-60 DEG C, 3-8 parts of graphene, 10-20 parts of levelling agent is added, 30-80 parts of filler continues to stir 4-
10 minutes;
(3) it is cooled to 0-4 DEG C, 3-8 parts of curing agent is added, continues stirring 4-10 minutes, is made, 0-8 DEG C of Cord blood.
Beneficial effects of the present invention:The coating electronic device new material of the present invention has self-cleaning function, resistance to corrosion
By force, such as moist in extreme environment, soda acid etc. is permanently effective, and the service life of product is long, and the holding time is long under cryogenic, no
It is easy solidification, in room temperature in use, be easy to cure again, saves spray time.
Specific implementation mode
The specific implementation mode of the present invention is described in detail below, it is to be understood that protection scope of the present invention is not
It is restricted by specific implementation.
Embodiment 1
A kind of coating electronic device new material, is made of the raw material of following parts by weight:Polyethylene terephthalate
150 parts of ester, 160 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 25 parts of 1,4-CHDM polyester, 25 parts of silicone oil, graphene 6
Part, 15 parts of acrylate monomer, 5 parts of sodium carbonate, 50 parts of chondroitin sulfate.
The preparation method of above-mentioned coating electronic device new material, carries out in accordance with the following steps:
(1) at normal temperatures, 150 parts of polyethylene terephthalate, poly- 2,6-naphthalenedicarboxylic acid second are taken according to parts by weight
160 parts of diol ester, 25 parts of 1,4-CHDM polyester, 25 parts of silicone oil are put into stirred tank, are stirred 6 minutes;
(2) 50 DEG C are warming up to, 6 parts of graphene, 15 parts of acrylate monomer is added, 50 parts of chondroitin sulfate continues stirring 8
Minute;
(3) 2 DEG C are cooled to, 5 parts of sodium carbonate is added, continues stirring 6 minutes, is made, 4 DEG C of Cord bloods.
New material manufactured in the present embodiment is coated on electronic device surface, and salt tolerant is water-fast, acidproof, alkaline-resisting, when coating is dry
Between 37min, covering power 36g/m2, brush accessible, 4 DEG C of Cord bloods 2 years, re-coating uses, and property indices are normal.
Embodiment 2
A kind of coating electronic device new material, is made of the raw material of following parts by weight:Polyethylene terephthalate
80 parts of ester, 100 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 20 parts of 1,4-CHDM polyester, 20 parts of silicone oil, graphene 3
Part, 5 parts of dimethylbenzene, 5 parts of toluene, 3 parts of the formaldehyde condensation products of sulfonated acetone, 30 parts of talcum powder.
The preparation method of above-mentioned coating electronic device new material, carries out in accordance with the following steps:At normal temperatures, according to weight
Number takes 80 parts of polyethylene terephthalate, 100 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 1,4-CHDM to gather
20 parts of ester, 20 parts of silicone oil, is put into stirred tank, stirs 4 minutes;
(2) it is warming up to 45 DEG C, is added 3 parts of graphene, 5 parts of dimethylbenzene, 5 parts of toluene, 30 parts of talcum powder continues 4 points of stirring
Clock;
(3) it is cooled to 0 DEG C, 3 parts of the formaldehyde condensation products of sulfonated acetone are added, continues stirring 4 minutes, is made, 0 DEG C of low temperature is protected
It deposits.
New material manufactured in the present embodiment is coated on electronic device surface, and salt tolerant is water-fast, acidproof, alkaline-resisting, when coating is dry
Between 35min, covering power 33g/m2, brush accessible, 0 DEG C of Cord blood 2 years, re-coating uses, and property indices are normal.
Embodiment 3
A kind of coating electronic device new material, is made of the raw material of following parts by weight:Polyethylene terephthalate
200 parts of ester, 220 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 30 parts of 1,4-CHDM polyester, 30 parts of silicone oil, graphene 8
Part, 20 parts, 1H of 2- amino -6- chloro benzothiazoles, 8 parts of 1H- perfluoro capryls amine, 80 parts of 4- bromobenzenes hydrazine hydrochloride.
The preparation method of above-mentioned coating electronic device new material, carries out in accordance with the following steps:
(1) at normal temperatures, 200 parts of polyethylene terephthalate, poly- 2,6-naphthalenedicarboxylic acid second are taken according to parts by weight
220 parts of diol ester, 30 parts of 1,4-CHDM polyester, is put into stirred tank, stirs 10 minutes;
(2) 60 DEG C are warming up to, 8 parts of graphene, 20 parts of 2- amino -6- chloro benzothiazoles, 4- bromobenzenes hydrazine hydrochloride 80 is added
Part, continue stirring 10 minutes;
(3) 4 DEG C are cooled to, 1H is added, 8 parts of 1H- perfluoro capryls amine continues stirring 10 minutes, is made, 8 DEG C of Cord bloods.
New material manufactured in the present embodiment is coated on electronic device surface, and salt tolerant is water-fast, acidproof, alkaline-resisting, when coating is dry
Between 33min, covering power 34g/m2, brush accessible, 8 DEG C of Cord bloods 2 years, re-coating uses, and property indices are normal.
Embodiment 4
A kind of coating electronic device new material, is made of the raw material of following parts by weight:Polyethylene terephthalate
90 parts of ester, 170 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 22 parts of 1,4-CHDM polyester, 22 parts of silicone oil, graphene 5
Part, 15 parts of triethyl phosphate, 5 parts of 4- trifluoromethylthios benzoic acid, 48 parts of 5- nitryl furfurals.
The preparation method of above-mentioned coating electronic device new material, carries out in accordance with the following steps:
(1) at normal temperatures, 90 parts of polyethylene terephthalate, poly- 2,6-naphthalenedicarboxylic acid second two are taken according to parts by weight
170 parts of alcohol ester, 22 parts of 1,4-CHDM polyester, is put into stirred tank, stirs 8 minutes;
(2) 50 DEG C are warming up to, 5 parts of graphene, 15 parts of triethyl phosphate is added, 48 parts of 5- nitryl furfurals continue 6 points of stirring
Clock;
(3) 2 DEG C are cooled to, 5 parts of 4- trifluoromethylthios benzoic acid is added, continues stirring 7 minutes, is made, 3 DEG C of low temperature are protected
It deposits.
New material manufactured in the present embodiment is coated on electronic device surface, and salt tolerant is water-fast, acidproof, alkaline-resisting, when coating is dry
Between 35min, covering power 33g/m2, brush accessible, 3 DEG C of Cord bloods 2 years, re-coating uses, and property indices are normal.
Embodiment 5
A kind of coating electronic device new material, is made of the raw material of following parts by weight:Polyethylene terephthalate
150 parts of ester, 160 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 25 parts of 1,4-CHDM polyester, 25 parts of silicone oil, graphene 6
Part, 1 part of madecassoside, 15 parts of acrylate monomer, 5 parts of sodium carbonate, 50 parts of chondroitin sulfate.
The preparation method of above-mentioned coating electronic device new material, carries out in accordance with the following steps:
(1) at normal temperatures, 150 parts of polyethylene terephthalate, poly- 2,6-naphthalenedicarboxylic acid second are taken according to parts by weight
160 parts of diol ester, 25 parts of 1,4-CHDM polyester, 25 parts of silicone oil are put into stirred tank, are stirred 4-10 minutes;
(2) 50 DEG C are warming up to, 6 parts of graphene, 1 part of madecassoside, 15 parts of acrylate monomer, chondroitin sulfate is added
50 parts of element continues stirring 8 minutes;
(3) 2 DEG C are cooled to, 5 parts of sodium carbonate is added, continues stirring 6 minutes, is made, 4 DEG C of Cord bloods.
New material manufactured in the present embodiment is coated on electronic device surface, and salt tolerant is water-fast, acidproof, alkaline-resisting, when coating is dry
Between 22min, covering power 30g/m2, brush accessible, 4 DEG C of Cord bloods 4 years, re-coating uses, and property indices are normal.
Embodiment 6
A kind of coating electronic device new material, is made of the raw material of following parts by weight:Polyethylene terephthalate
80 parts of ester, 100 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 20 parts of 1,4-CHDM polyester, 20 parts of silicone oil, graphene 3
Part, 2,6- 3 parts of dichloro-quinoxalines, 5 parts of dimethylbenzene, 5 parts of toluene, 3 parts of the formaldehyde condensation products of sulfonated acetone, 30 parts of talcum powder.
The preparation method of above-mentioned coating electronic device new material, carries out in accordance with the following steps:At normal temperatures, according to weight
Number takes 80 parts of polyethylene terephthalate, 100 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 1,4-CHDM to gather
20 parts of ester, 20 parts of silicone oil, is put into stirred tank, stirs 4 minutes;
(2) 45 DEG C are warming up to, 3 parts of graphene, 2,6- 3 parts of dichloro-quinoxalines, 5 parts of dimethylbenzene, 5 parts of toluene, talcum is added
30 parts of powder continues stirring 4 minutes;
(3) it is cooled to 0 DEG C, 3 parts of the formaldehyde condensation products of sulfonated acetone are added, continues stirring 4 minutes, is made, 0 DEG C of low temperature is protected
It deposits.
New material manufactured in the present embodiment is coated on electronic device surface, and salt tolerant is water-fast, acidproof, alkaline-resisting, when coating is dry
Between 24min, covering power 24g/m2, brush accessible, 0 DEG C of Cord blood 3 years, re-coating uses, and property indices are normal.
Comparative example 1
A kind of coating electronic device new material, is made of the raw material of following parts by weight:Polyethylene terephthalate
200 parts of ester, 220 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 30 parts of 1,4-CHDM polyester, 30 parts of silicone oil, graphene 8
Part, 1H, 8 parts of 1H- perfluoro capryls amine, 80 parts of 4- bromobenzenes hydrazine hydrochloride.
The preparation method of above-mentioned coating electronic device new material, carries out in accordance with the following steps:
(1) at normal temperatures, 200 parts of polyethylene terephthalate, poly- 2,6-naphthalenedicarboxylic acid second are taken according to parts by weight
220 parts of diol ester, 30 parts of 1,4-CHDM polyester, 30 parts of silicone oil are put into stirred tank, are stirred 10 minutes;
(2) 60 DEG C are warming up to, 8 parts of graphene is added, 80 parts of 4- bromobenzenes hydrazine hydrochloride continues stirring 10 minutes;
(3) 4 DEG C are cooled to, 1H is added, 8 parts of 1H- perfluoro capryls amine continues stirring 10 minutes, is made, 8 DEG C of Cord bloods.
New material manufactured in the present embodiment is coated on electronic device surface, and salt tolerant is water-fast, acidproof, alkaline-resisting, when coating is dry
Between 37min, covering power 48g/m2, brush accessible, 8 DEG C of Cord bloods 1 year, re-coating uses, and property indices are normal.
Comparative example 2
A kind of coating electronic device new material, is made of the raw material of following parts by weight:Polyethylene terephthalate
90 parts of ester, 170 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 22 parts of 1,4-CHDM polyester, 22 parts of silicone oil, graphene 5
Part, 15 parts of triethyl phosphate, 5 parts of 4- trifluoromethylthios benzoic acid.
The preparation method of above-mentioned coating electronic device new material, carries out in accordance with the following steps:
(1) at normal temperatures, 90 parts of polyethylene terephthalate, poly- 2,6-naphthalenedicarboxylic acid second two are taken according to parts by weight
170 parts of alcohol ester, 22 parts of 1,4-CHDM polyester, 22 parts of silicone oil are put into stirred tank, are stirred 8 minutes;
(2) 50 DEG C are warming up to, 5 parts of graphene is added, 15 parts of triethyl phosphate continues stirring 6 minutes;
(3) 2 DEG C are cooled to, 5 parts of 4- trifluoromethylthios benzoic acid is added, continues stirring 7 minutes, is made, 3 DEG C of low temperature are protected
It deposits.
New material manufactured in the present embodiment is coated on electronic device surface, and salt tolerant is water-fast, acidproof, alkaline-resisting, when coating is dry
Between 38min, covering power 59g/m2, brush accessible, 3 DEG C of Cord bloods 1 year, re-coating uses, and property indices are normal.
Disclosed above is only specific embodiments of the present invention, and still, the present invention is not limited to this, any this field
What technical staff can think variation should all fall into protection scope of the present invention.
Claims (5)
1. a kind of coating electronic device new material, which is characterized in that be made of the raw material of following parts by weight:Poly- terephthaldehyde
Sour glycol ester 80-200 parts, 100-220 parts of poly- 2,6-naphthalenedicarboxylic acid glycol ester, 1,4-CHDM polyester 20-30
Part, 20-30 parts of silicone oil, 3-8 parts of graphene, 10-20 parts of levelling agent, 3-8 parts of curing agent, 30-80 parts of filler.
2. a kind of coating electronic device new material according to claim 1, which is characterized in that the levelling agent is acrylic acid
Ester monomer, dimethylbenzene, toluene, polyacrylic acid, Propyleneimine, tetraethoxysilane, triethyl phosphate, 2- amino -6- chlorobenzenes are simultaneously
One or more in thiazole.
3. a kind of coating electronic device new material according to claim 1, which is characterized in that the curing agent is carbonic acid
Sodium, calcium lignosulfonate, calcium chloride, the formaldehyde condensation products of sulfonated acetone, sorbitan monolaurate, 1H, 1H- perfluoro capryls
Amine, 4- trifluoromethylthio benzoic acid, the one or more in 3- thanatols.
4. a kind of coating electronic device new material according to claim 1, which is characterized in that the filler is chondroitin sulfate
Element, mica powder, talcum powder, attapulgite, 4- bromobenzene hydrazine hydrochlorides, the one or more in 5- nitryl furfurals.
5. described in claim 1 coat electronic device new material preparation method, which is characterized in that in accordance with the following steps into
Row:
(1) at normal temperatures, 80-200 parts of polyethylene terephthalate, poly- 2,6-naphthalenedicarboxylic acid second two are taken according to parts by weight
100-220 parts of alcohol ester, 20-30 parts of 1,4-CHDM polyester, 20-30 parts of silicone oil are put into stirred tank, 4-10 points of stirring
Clock;
(2) it is warming up to 45-60 DEG C, 3-8 parts of graphene, 10-20 parts of levelling agent is added, 30-80 parts of filler continues to stir 4-10 points
Clock;
(3) it is cooled to 0-4 DEG C, 3-8 parts of curing agent is added, continues stirring 4-10 minutes, is made, 0-8 DEG C of Cord blood.
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CN201611126589.5A CN108610912A (en) | 2016-12-09 | 2016-12-09 | A kind of coating electronic device new material and preparation method thereof |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1342181A (en) * | 1999-03-10 | 2002-03-27 | 克里斯塔尔公司 | Process for producing plastic web for coating metal substrate, laminate comprising this plastic web, and product or component produced therewith |
CN101842423A (en) * | 2007-08-02 | 2010-09-22 | 杜邦帝人薄膜美国有限公司 | The polyester film that applies |
CN103589281A (en) * | 2013-11-04 | 2014-02-19 | 上海电力学院 | High temperature resistant anticorrosion coating based on graphene and preparation method thereof |
-
2016
- 2016-12-09 CN CN201611126589.5A patent/CN108610912A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1342181A (en) * | 1999-03-10 | 2002-03-27 | 克里斯塔尔公司 | Process for producing plastic web for coating metal substrate, laminate comprising this plastic web, and product or component produced therewith |
CN101842423A (en) * | 2007-08-02 | 2010-09-22 | 杜邦帝人薄膜美国有限公司 | The polyester film that applies |
CN103589281A (en) * | 2013-11-04 | 2014-02-19 | 上海电力学院 | High temperature resistant anticorrosion coating based on graphene and preparation method thereof |
Non-Patent Citations (1)
Title |
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朱万强: "《涂料基础教程》", 30 June 2012, 西南交通大学出版社 * |
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