CN108565429A - 一种钠离子电池负极材料NaFeS2/C复合材料的制备方法 - Google Patents
一种钠离子电池负极材料NaFeS2/C复合材料的制备方法 Download PDFInfo
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- CN108565429A CN108565429A CN201810354012.2A CN201810354012A CN108565429A CN 108565429 A CN108565429 A CN 108565429A CN 201810354012 A CN201810354012 A CN 201810354012A CN 108565429 A CN108565429 A CN 108565429A
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- sodium
- nafes
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- ion battery
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- 239000002131 composite material Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title abstract description 10
- 229910001416 lithium ion Inorganic materials 0.000 title abstract description 10
- 239000010405 anode material Substances 0.000 title abstract description 8
- 229910001415 sodium ion Inorganic materials 0.000 claims abstract description 31
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 claims abstract description 30
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000011734 sodium Substances 0.000 claims abstract description 24
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 15
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 13
- 239000002002 slurry Substances 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 229910052742 iron Inorganic materials 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012299 nitrogen atmosphere Substances 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims description 11
- 238000004321 preservation Methods 0.000 claims description 11
- 238000000227 grinding Methods 0.000 claims description 7
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical group [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims description 6
- 235000019345 sodium thiosulphate Nutrition 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 229940062993 ferrous oxalate Drugs 0.000 claims description 5
- OWZIYWAUNZMLRT-UHFFFAOYSA-L iron(2+);oxalate Chemical group [Fe+2].[O-]C(=O)C([O-])=O OWZIYWAUNZMLRT-UHFFFAOYSA-L 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 4
- 229930006000 Sucrose Natural products 0.000 claims description 4
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000005720 sucrose Substances 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 3
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000006258 conductive agent Substances 0.000 claims description 3
- 239000011889 copper foil Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 230000005611 electricity Effects 0.000 claims description 3
- 239000008103 glucose Substances 0.000 claims description 3
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical group [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 229910052960 marcasite Inorganic materials 0.000 abstract description 8
- 229910052683 pyrite Inorganic materials 0.000 abstract description 8
- 239000005864 Sulphur Substances 0.000 abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 3
- 230000005540 biological transmission Effects 0.000 abstract description 3
- 230000009467 reduction Effects 0.000 abstract description 3
- 239000007790 solid phase Substances 0.000 abstract description 3
- 238000000498 ball milling Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 description 7
- 239000007772 electrode material Substances 0.000 description 5
- 229910052744 lithium Inorganic materials 0.000 description 5
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 238000009831 deintercalation Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 238000004146 energy storage Methods 0.000 description 3
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 3
- 238000009830 intercalation Methods 0.000 description 3
- 230000002687 intercalation Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 239000006230 acetylene black Substances 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000010532 solid phase synthesis reaction Methods 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 240000000111 Saccharum officinarum Species 0.000 description 1
- 235000007201 Saccharum officinarum Nutrition 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- -1 thio sulphur Chemical compound 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
- H01M4/5815—Sulfides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
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CN201810354012.2A CN108565429B (zh) | 2018-04-19 | 2018-04-19 | 一种钠离子电池负极材料NaFeS2/C复合材料的制备方法 |
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CN201810354012.2A CN108565429B (zh) | 2018-04-19 | 2018-04-19 | 一种钠离子电池负极材料NaFeS2/C复合材料的制备方法 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109574169A (zh) * | 2019-01-25 | 2019-04-05 | 东北师范大学 | 一种用低含铁污泥制备多硫铁钠的方法、污水处理的方法 |
CN109603856A (zh) * | 2018-11-07 | 2019-04-12 | 东北师范大学 | 由废水制备Erdite棒状颗粒应用于水处理的方法 |
CN111204815A (zh) * | 2020-01-09 | 2020-05-29 | 深圳第三代半导体研究院 | 一种絮状团聚结构硫铁钠材料及其制备方法 |
CN113140728A (zh) * | 2021-04-26 | 2021-07-20 | 燕山大学 | 一种钾铁硫化物薄膜电极及其制备方法和应用 |
CN113578351A (zh) * | 2021-08-03 | 2021-11-02 | 齐鲁工业大学 | 黄铁矿二硫化铁/二氧化钛复合材料及其制备方法和应用 |
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US20150180024A1 (en) * | 2012-06-12 | 2015-06-25 | Toyota Jidosha Kabushiki Kaisha | Positive electrode material for sodium batteries and method for producing same |
CN105810902A (zh) * | 2016-03-11 | 2016-07-27 | 天津大学 | 一种溶剂热制备纳米碳包覆氟磷酸亚铁钠的方法 |
CN106058251A (zh) * | 2016-08-12 | 2016-10-26 | 中南大学 | 一种钠离子电池正极Na2Fe2(SO4)3@氧化铝复合材料及其制备方法 |
CN106340627A (zh) * | 2016-10-12 | 2017-01-18 | 苏州大学 | 一种钠离子电池正极材料的制备方法 |
CN106848236A (zh) * | 2017-02-20 | 2017-06-13 | 中南大学 | 一种用于钠离子电池的硫酸亚铁钠/石墨烯复合正极材料及其制备方法 |
CN107293712A (zh) * | 2017-06-12 | 2017-10-24 | 湖南工程学院 | 一种适用于钠或锂离子电池正极材料六氟铁酸钠及其包覆材料的制备方法 |
CN107507978A (zh) * | 2017-07-28 | 2017-12-22 | 齐鲁工业大学 | 一种钠离子电池FeS2/Fe3O4/C负极材料及其制备方法 |
EP3293147A1 (fr) * | 2016-09-12 | 2018-03-14 | Commissariat à l'Energie Atomique et aux Energies Alternatives | Matériau silicaté de structure olivine |
-
2018
- 2018-04-19 CN CN201810354012.2A patent/CN108565429B/zh not_active Expired - Fee Related
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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US20150180024A1 (en) * | 2012-06-12 | 2015-06-25 | Toyota Jidosha Kabushiki Kaisha | Positive electrode material for sodium batteries and method for producing same |
CN105810902A (zh) * | 2016-03-11 | 2016-07-27 | 天津大学 | 一种溶剂热制备纳米碳包覆氟磷酸亚铁钠的方法 |
CN106058251A (zh) * | 2016-08-12 | 2016-10-26 | 中南大学 | 一种钠离子电池正极Na2Fe2(SO4)3@氧化铝复合材料及其制备方法 |
EP3293147A1 (fr) * | 2016-09-12 | 2018-03-14 | Commissariat à l'Energie Atomique et aux Energies Alternatives | Matériau silicaté de structure olivine |
CN106340627A (zh) * | 2016-10-12 | 2017-01-18 | 苏州大学 | 一种钠离子电池正极材料的制备方法 |
CN106848236A (zh) * | 2017-02-20 | 2017-06-13 | 中南大学 | 一种用于钠离子电池的硫酸亚铁钠/石墨烯复合正极材料及其制备方法 |
CN107293712A (zh) * | 2017-06-12 | 2017-10-24 | 湖南工程学院 | 一种适用于钠或锂离子电池正极材料六氟铁酸钠及其包覆材料的制备方法 |
CN107507978A (zh) * | 2017-07-28 | 2017-12-22 | 齐鲁工业大学 | 一种钠离子电池FeS2/Fe3O4/C负极材料及其制备方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109603856A (zh) * | 2018-11-07 | 2019-04-12 | 东北师范大学 | 由废水制备Erdite棒状颗粒应用于水处理的方法 |
CN109574169A (zh) * | 2019-01-25 | 2019-04-05 | 东北师范大学 | 一种用低含铁污泥制备多硫铁钠的方法、污水处理的方法 |
CN109574169B (zh) * | 2019-01-25 | 2019-07-30 | 东北师范大学 | 一种用低含铁污泥制备多硫铁钠的方法、污水处理的方法 |
CN111204815A (zh) * | 2020-01-09 | 2020-05-29 | 深圳第三代半导体研究院 | 一种絮状团聚结构硫铁钠材料及其制备方法 |
CN113140728A (zh) * | 2021-04-26 | 2021-07-20 | 燕山大学 | 一种钾铁硫化物薄膜电极及其制备方法和应用 |
CN113140728B (zh) * | 2021-04-26 | 2022-04-05 | 燕山大学 | 一种钾铁硫化物薄膜电极及其制备方法和应用 |
CN113578351A (zh) * | 2021-08-03 | 2021-11-02 | 齐鲁工业大学 | 黄铁矿二硫化铁/二氧化钛复合材料及其制备方法和应用 |
CN113578351B (zh) * | 2021-08-03 | 2023-05-23 | 齐鲁工业大学 | 黄铁矿二硫化铁/二氧化钛复合材料及其制备方法和应用 |
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