CN108484104A - 一种天青瓷陶瓷材料及其制备方法 - Google Patents
一种天青瓷陶瓷材料及其制备方法 Download PDFInfo
- Publication number
- CN108484104A CN108484104A CN201810296972.8A CN201810296972A CN108484104A CN 108484104 A CN108484104 A CN 108484104A CN 201810296972 A CN201810296972 A CN 201810296972A CN 108484104 A CN108484104 A CN 108484104A
- Authority
- CN
- China
- Prior art keywords
- parts
- idiosome
- celadon
- day
- ceramic material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910010293 ceramic material Inorganic materials 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 25
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000010453 quartz Substances 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 18
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 18
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000454 talc Substances 0.000 claims abstract description 18
- 229910052623 talc Inorganic materials 0.000 claims abstract description 18
- 235000012222 talc Nutrition 0.000 claims abstract description 18
- 239000004927 clay Substances 0.000 claims abstract description 16
- 229910000428 cobalt oxide Inorganic materials 0.000 claims abstract description 12
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910000484 niobium oxide Inorganic materials 0.000 claims abstract description 11
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002689 soil Substances 0.000 claims abstract description 11
- 229910021532 Calcite Inorganic materials 0.000 claims abstract description 10
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000420 cerium oxide Inorganic materials 0.000 claims abstract description 10
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 10
- 239000010459 dolomite Substances 0.000 claims abstract description 10
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims abstract description 10
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910052808 lithium carbonate Inorganic materials 0.000 claims abstract description 10
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000018 strontium carbonate Inorganic materials 0.000 claims abstract description 10
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- 239000004411 aluminium Substances 0.000 claims abstract description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910017569 La2(CO3)3 Inorganic materials 0.000 claims abstract description 8
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims abstract description 8
- 239000000440 bentonite Substances 0.000 claims abstract description 8
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 8
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000010433 feldspar Substances 0.000 claims abstract description 8
- NZPIUJUFIFZSPW-UHFFFAOYSA-H lanthanum carbonate Chemical compound [La+3].[La+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O NZPIUJUFIFZSPW-UHFFFAOYSA-H 0.000 claims abstract description 8
- 229960001633 lanthanum carbonate Drugs 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 8
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 6
- 238000000227 grinding Methods 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 238000010304 firing Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 210000001161 mammalian embryo Anatomy 0.000 claims description 6
- 238000002386 leaching Methods 0.000 claims description 5
- 238000007569 slipcasting Methods 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 238000005507 spraying Methods 0.000 claims description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims description 4
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims 1
- 239000000919 ceramic Substances 0.000 abstract description 9
- 230000035939 shock Effects 0.000 abstract description 5
- 229910001404 rare earth metal oxide Inorganic materials 0.000 abstract description 4
- 238000009377 nuclear transmutation Methods 0.000 abstract description 3
- 238000005245 sintering Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 239000013078 crystal Substances 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 3
- 229910052863 mullite Inorganic materials 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000010431 corundum Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/131—Inorganic additives
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/32—Burning methods
- C04B33/34—Burning methods combined with glazing
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/40—Metallic constituents or additives not added as binding phase
- C04B2235/402—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
一种天青瓷陶瓷材料及其制备方法。所述陶瓷材料的胚体包括铝粉、石英、长石、膨润土、贵州土、龙岩土、高岭土和滑石；所述釉层材料包括：石英、滑石、白云石、方解石、硅酸锆、熔块、苏州土、钾长石、高岭土、碳酸钡、碳酸镧、碳酸锂、氧化锌、三氧化二钇、碳酸锶、氧化铈、氧化钴以及氧化铌。相对普通陶瓷产品，该天青瓷不仅仅在产品强度、釉面硬度、光润性和抗热震性等理化性能指标方面得到进一步加强，而且通过添加多种稀土金属氧化物到釉料，利用其在烧制过程中的高温条件发生反应所产生的窑变，使得生产出来的产品釉面极具个性，且具有浑厚、饱满，青翠欲滴的特性。
Description
技术领域
本发明属于陶瓷领域，具体涉及一种天青瓷陶瓷材料及其制备方法。
背景技术
我国青瓷的烧制历史源远流长，从商周时候原始青瓷的出现，历经春秋战国时期的发展，至东汉年代开始有了突破并逐渐趋向成熟，在宋代则是达到了青瓷发展的高峰。在这长达3000多年的青瓷发展史上，青瓷逐渐与中国文明结下了不解之缘，有关青瓷的论述和赞美开卷可见。在中国历朝历代文人雅士的心目中，青瓷不仅仅具备玉石温柔敦厚的秉性，亦蕴含着着“重气节重操守”的道德观念和内涵，深受追捧。
随着现代人们生活水平的提高，消费者对日用陶瓷的要求也越来越高，除了陶瓷产品本身原始的功能外，对其艺术以及欣赏附加值也越来越看重。
发明内容
本发明克服现有技术缺陷，提供一种天青瓷陶瓷材料及其制备方法。
本发明技术方案如下。
一种天青瓷陶瓷材料，所述陶瓷材料的胚体包括铝粉8~14份、石英5~8份、长石20~25份、膨润土3~7份、贵州土4~7份、龙岩土30~36份、高岭土28~33份和滑石2~6份；
所述釉层材料包括：石英33-35份、滑石7~11份、白云石2~5份、方解石10~15份、硅酸锆2~6份、熔块15~20份、苏州土10~14份、钾长石36~38份、高岭土10~12份、碳酸钡4.5~5.5份、碳酸镧0.2~0.4份、碳酸锂1.6~1.8份、氧化锌4~6份、三氧化二钇0.6~0.8份、碳酸锶0.5~1份、氧化铈0.2~0.3份、氧化钴1~2份以及氧化铌0.8~1.5份。
本发明中最佳的比例如下：
所述陶瓷材料的胚体包括铝粉10份、石英6份、长石23份、膨润土5份、贵州土6份、龙岩土33份、高岭土30份和滑石4份；
所述釉层材料包括：石英34份、滑石8份、白云石4份、方解石13份、硅酸锆4份、熔块18份、苏州土12份、钾长石37份、高岭土11份、碳酸钡5份、碳酸镧0.3份、碳酸锂1.7份、氧化锌5份、三氧化二钇0.7份、碳酸锶0.8份、氧化铈0.2份、氧化钴1.8份以及氧化铌1.2份。
一种天青瓷陶瓷材料的制备方法，包括如下步骤：
（1）取计量的胚体材料，研磨致200~250目，按照胚体材料与水的质量比为2~3：2混合，然后取模具注浆后，脱模，自然烘干，修胚，在将胚体放置于100~110℃下烘烤4~5h，然后冷却到室温，在放入窑炉于500~860℃下烧制5~6h，取出烧制后的胚体，备用；
（2）将步骤（1）所得烧制后的胚体进行水洗，然后晾干备用；
（3）取计量的石英、滑石、白云石、方解石、硅酸锆、熔块、苏州土、钾长石、高岭土、碳酸钡、碳酸镧、碳酸锂、氧化锌、三氧化二钇、碳酸锶和氧化铈，研磨致200~250目；另取氧化钴和氧化铌，研磨致300~350目，然后量研磨后的物质混合，按照胚体材料与水混合，得到釉层浆料，将晾干后的胚体进行浸釉，然后在室温下晾干2~3h，然后在喷釉，晾干，与1250~1300℃下烧制12~14h，得到天青瓷陶瓷材料。
上述方法中，步骤（1）中，所述500~860℃下烧制5~6h的具体方法为：500℃下慢火烧制1~2h，然后升温只860℃下烧制1~2h，再降温致350℃，打开窑炉门，让胚体进行冷却。
本发明中，通过在釉料中加入多种稀土金属氧化物对陶瓷釉的光泽度进行改善，镧可使釉面更加晶莹夺目，铈具有较强的遮盖力，同时使得釉面光泽莹润，并可减少龟裂情况的发生；钇与镧、铝能够在烧结时形成稀土相，提高致密度、抗折强度和断裂韧性，同时降低烧结的温度。通过多种稀土金属氧化物之间产生的协同作用，使得天青瓷釉面的光泽度得到提高，釉面光滑，具有良好的硬度、抗折强度和断裂韧性。此外，为了使天青瓷呈现出晶莹纯净、类玉似冰的特点，本发明在胎釉配方中还加入了着色剂，为了确定着色氧化物的选择与配比，申请人通过对大量实验采集而来的数据进行分析，最后确定由氧化钴以及氧化铌以6:4的比例来合成天青瓷的着色剂。在烧成过程1300℃的高温条件下，着色剂会与天青瓷中的其他材料之间发生反应，产生窑变，最终形成天青瓷温润如玉的独特釉面。
本发明天青瓷在制作原料的选择中，有别于传统青瓷，采用了以高纯石英作为产品坯体的制作主原料，占比达到45%以上。石英石在常温下是一种稳定的矿物质，不溶于水和硫酸、盐酸、硝酸等大部分酸中，属于非可塑性原料，但其与粘土在高温条件中生成的莫来石晶体能够赋予陶瓷产品比较高的机械硬度和化学稳定性，还可增加坯体的半透明性。为了增强产品的理化性能，通过大量的实验测试，天青瓷的坯体原材料配方中最终决定采用细度控制在10um-30ym的高纯石英作为坯体的主原料，在高岭土-长石-石英三元***的配方基础上，还采用坯体强助溶剂，引入适量的矿化剂，通过在高温环境中使产品内部形成莫来石晶体和刚玉晶粒，形成起到增强作用的显微结构。其中莫来石晶体为微细针状晶体，互相交织成网络状均匀分布在坯体中，构成晶体骨架，而细化的刚玉晶体则是均匀分布在莫来石晶体骨架之间，起到弥散强化的作用。两者之间相互配合，使得天青瓷无论是在产品的抗折强度、釉面硬度、抗冲击性、还是在抗热震性方面，都比传统陶瓷产品要高。经国家陶瓷及水暖卫浴产品质量监督检验中心检测，天青瓷产品的各项技术指标都达到较好水平，部分指标填补了国内的空白，产品主要的技术性指标如下：
①吸水率≤0.5%；
②光泽度 95；
③抗折强度 117.1Mpa；
④抗热震性 180℃至20℃水一次热交换不开裂；
铅溶出量＜0.1mg/L和镉溶出量＜0.01mg/L。
与现有技术相比，本发明的优势在于：
相对普通陶瓷产品，该天青瓷不仅仅在产品强度、釉面硬度、光润性和抗热震性等理化性能指标方面得到进一步加强，而且通过添加多种稀土金属氧化物到釉料，利用其在烧制过程中的高温条件发生反应所产生的窑变，使得生产出来的产品釉面极具个性，且具有浑厚、饱满，青翠欲滴的特性。
具体实施方式
实施例1
（1）取铝粉10份、石英6份、长石23份、膨润土5份、贵州土6份、龙岩土33份、高岭土30份和滑石4份，研磨致200目，按照胚体材料与水的质量比为3：2混合，然后取模具注浆后，脱模，自然烘干，修胚，在将胚体放置于100℃下烘烤4h，然后冷却到室温，在放入窑炉，500℃下慢火烧制1h，然后升温只860℃下烧制2h，再降温致350℃，打开窑炉门，让胚体进行冷却，取出烧制后的胚体，备用；
（2）将步骤（1）所得烧制后的胚体进行水洗，然后晾干备用；
（3）取石英34份、滑石8份、白云石4份、方解石13份、硅酸锆4份、熔块18份、苏州土12份、钾长石37份、高岭土11份、碳酸钡5份、碳酸镧0.3份、碳酸锂1.7份、氧化锌5份、三氧化二钇0.7份、碳酸锶0.8份和氧化铈0.2份，研磨致200目；另取氧化钴18份以及氧化铌12份，研磨致300目，然后量研磨后的物质混合，按照胚体材料与水混合，得到釉层浆料，将晾干后的胚体进行浸釉，然后在室温下晾干2h，然后在喷釉，晾干，与1300℃下烧制12h，得到天青瓷陶瓷材料。
实施例2
（1）取铝粉8份、石英5份、长石25份、膨润土7份、贵州土4份、龙岩土36份、高岭土28份、滑石6份，研磨致250目，按照胚体材料与水的质量比为3：2混合，然后取模具注浆后，脱模，自然烘干，修胚，在将胚体放置于100℃下烘烤4h，然后冷却到室温，在放入窑炉， 500℃下慢火烧制2h，然后升温只860℃下烧制2h，再降温致350℃，打开窑炉门，让胚体进行冷却，取出烧制后的胚体，备用；
（2）将步骤（1）所得烧制后的胚体进行水洗，然后晾干备用；
（3）取计量的石英35份、滑石11份、白云石2份、方解石10份、硅酸锆2份、熔块15份、苏州土10份、钾长石38份、高岭土10份、碳酸钡5.5份、碳酸镧0.2份、碳酸锂1.8份、氧化锌6份、三氧化二钇0.8份、碳酸锶0.5份、氧化铈0.2份，研磨致250目；另取氧化钴2份以及氧化铌1.5份，研磨致300目，然后量研磨后的物质混合，按照胚体材料与水混合，得到釉层浆料，将晾干后的胚体进行浸釉，然后在室温下晾干2~3h，然后在喷釉，晾干，与1250℃下烧制14h，得到天青瓷陶瓷材料。
实施例3
（1）取铝粉14份、石英8份、长石25份、膨润土3份、贵州土7份、龙岩土30份、高岭土33份、滑石2份，研磨致200目，按照胚体材料与水的质量比为3：2混合，然后取模具注浆后，脱模，自然烘干，修胚，在将胚体放置于100℃下烘烤5h，然后冷却到室温，在放入窑炉， 500℃下慢火烧制2h，然后升温只860℃下烧制1h，再降温致350℃，打开窑炉门，让胚体进行冷却，取出烧制后的胚体，备用；
（2）将步骤（1）所得烧制后的胚体进行水洗，然后晾干备用；
（3）取计量的石英33份、滑石7份、白云石5份、方解石15份、硅酸锆6份、熔块20份、苏州土14份、钾长石36份、高岭土12份、碳酸钡4.5份、碳酸镧0.4份、碳酸锂1.6份、氧化锌4份、三氧化二钇0.6份、碳酸锶1份、氧化铈0.3份，研磨致200目；另取氧化钴1份以及氧化铌0.8份，研磨致350目，然后量研磨后的物质混合，按照胚体材料与水混合，得到釉层浆料，将晾干后的胚体进行浸釉，然后在室温下晾干3h，然后在喷釉，晾干，与1250℃下烧制13h，得到天青瓷陶瓷材料。
取实施例1~3所的产品进行测试，经过测试，实施例1所得产品吸水率为0.3%，实施例2的吸水率为0.4%，实施例3为0.4%；抗折强度为117Mpa，119Mpa，117Mpa。抗热震性 180℃至20℃水一次热交换不开裂；铅溶出量＜0.1mg/L和镉溶出量＜0.01mg/L。
Claims (5)
1.一种天青瓷陶瓷材料，其特征在于，所述陶瓷材料的胚体包括铝粉8~14份、石英5~8份、长石20~25份、膨润土3~7份、贵州土4~7份、龙岩土30~36份、高岭土28~33份和滑石2~6份；
所述釉层材料包括：石英33-35份、滑石7~11份、白云石2~5份、方解石10~15份、硅酸锆2~6份、熔块15~20份、苏州土10~14份、钾长石36~38份、高岭土10~12份、碳酸钡4.5~5.5份、碳酸镧0.2~0.4份、碳酸锂1.6~1.8份、氧化锌4~6份、三氧化二钇0.6~0.8份、碳酸锶0.5~1份、氧化铈0.2~0.3份、氧化钴1~2份以及氧化铌0.6~1.5份。
2.根据权利要求1所述天青瓷陶瓷材料，其特征在于，所述陶瓷材料的胚体包括铝粉10份、石英6份、长石23份、膨润土5份、贵州土6份、龙岩土33份、高岭土30份和滑石4份；
所述釉层材料包括：石英34份、滑石8份、白云石4份、方解石13份、硅酸锆4份、熔块18份、苏州土12份、钾长石37份、高岭土11份、碳酸钡5份、碳酸镧0.3份、碳酸锂1.7份、氧化锌5份、三氧化二钇0.7份、碳酸锶0.8份、氧化铈0.2份、氧化钴1份以及氧化铌0.6份。
3.根据权利要求1所述天青瓷陶瓷材料的制备方法，其特征在于，包括如下步骤：
（1）取计量的胚体材料，研磨致200~250目，按照胚体材料与水的质量比为2~3：2混合，然后取模具注浆后，脱模，自然烘干，修胚，在将胚体放置于100~110℃下烘烤4~5h，然后冷却到室温，在放入窑炉于500~860℃下烧制5~6h，取出烧制后的胚体，备用；
（2）将步骤（1）所得烧制后的胚体进行水洗，然后晾干备用；
（3）取计量的石英、滑石、白云石、方解石、硅酸锆、熔块、苏州土、钾长石、高岭土、碳酸钡、碳酸镧、碳酸锂、氧化锌、三氧化二钇、碳酸锶和氧化铈，研磨致200~250目；另取氧化钴和氧化铌，研磨致300~350目，然后量研磨后的物质混合，按照胚体材料与水混合，得到釉层浆料，将晾干后的胚体进行浸釉，然后在室温下晾干2~3h，然后在喷釉，晾干，与1290℃下烧制12h，得到天青瓷陶瓷材料。
4.根据权利要求3所述天青瓷陶瓷材料的制备方法，其特征在于，步骤（1）中，所述500~860℃下烧制5~6h的具体方法为：500℃下慢火烧制1~2h，然后升温只860℃下烧制1~2h，再降温致350℃，打开窑炉门，让胚体进行冷却。
5.根据权利要求3所述天青瓷陶瓷材料的制备方法，其特征在于，所述氧化钴和氧化铌的质量比为6：4。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810296972.8A CN108484104A (zh) | 2018-04-04 | 2018-04-04 | 一种天青瓷陶瓷材料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810296972.8A CN108484104A (zh) | 2018-04-04 | 2018-04-04 | 一种天青瓷陶瓷材料及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108484104A true CN108484104A (zh) | 2018-09-04 |
Family
ID=63314502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810296972.8A Pending CN108484104A (zh) | 2018-04-04 | 2018-04-04 | 一种天青瓷陶瓷材料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108484104A (zh) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108793957A (zh) * | 2018-07-10 | 2018-11-13 | 重庆锦晖陶瓷有限公司 | 酒瓶强化骨瓷胚料及采用该胚料制作酒瓶的制备工艺 |
| CN110903079A (zh) * | 2019-10-11 | 2020-03-24 | 湖南华联君窑艺术瓷有限公司 | 一种大容量高温瓷酒瓶釉及制备方法 |
| CN113185123A (zh) * | 2021-05-26 | 2021-07-30 | 李美煌 | 一种高强度天青釉瓷的制备工艺 |
| CN113636866A (zh) * | 2021-08-10 | 2021-11-12 | 广东易成陶瓷实业有限公司 | 一种砂粒釉陶瓷的制备方法 |
| CN114907094A (zh) * | 2022-05-23 | 2022-08-16 | 吴佘斌 | 一种实现超细缝隙的瓷砖及其生产工艺 |
| CN117125896A (zh) * | 2023-10-26 | 2023-11-28 | 佛山市东鹏陶瓷有限公司 | 一种易清洁仿古釉料及其制备方法、易清洁仿古陶瓷砖 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101659517A (zh) * | 2009-09-17 | 2010-03-03 | 广东顺祥陶瓷有限公司 | 一种高折射率日用陶瓷釉及其制作工艺 |
| CN105293913A (zh) * | 2015-09-07 | 2016-02-03 | 龙泉市金宏瓷业有限公司 | 一种青瓷釉及其制作方法 |
| CN105481476A (zh) * | 2015-12-17 | 2016-04-13 | 安徽省含山民生瓷业有限责任公司 | 一种青瓷及其制备方法 |
| CN105693200A (zh) * | 2016-02-02 | 2016-06-22 | 景德镇陶瓷学院 | 一种景德镇影青强化瓷及其制备方法 |
| CN105777066A (zh) * | 2016-03-21 | 2016-07-20 | 丽水学院 | 一种以稀土尾砂为原料制备的龙泉青瓷及其制造方法 |
-
2018
- 2018-04-04 CN CN201810296972.8A patent/CN108484104A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101659517A (zh) * | 2009-09-17 | 2010-03-03 | 广东顺祥陶瓷有限公司 | 一种高折射率日用陶瓷釉及其制作工艺 |
| CN105293913A (zh) * | 2015-09-07 | 2016-02-03 | 龙泉市金宏瓷业有限公司 | 一种青瓷釉及其制作方法 |
| CN105481476A (zh) * | 2015-12-17 | 2016-04-13 | 安徽省含山民生瓷业有限责任公司 | 一种青瓷及其制备方法 |
| CN105693200A (zh) * | 2016-02-02 | 2016-06-22 | 景德镇陶瓷学院 | 一种景德镇影青强化瓷及其制备方法 |
| CN105777066A (zh) * | 2016-03-21 | 2016-07-20 | 丽水学院 | 一种以稀土尾砂为原料制备的龙泉青瓷及其制造方法 |
Non-Patent Citations (2)
| Title |
|---|
| 杜正贤 等: "《中国古代名窑 南宋官窑》", 31 May 2016, 江西美术出版社 * |
| 陈虹: "《中国陶瓷古典釉颜料配方及工艺研究》", 31 December 2016, 江西高校出版社 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108793957A (zh) * | 2018-07-10 | 2018-11-13 | 重庆锦晖陶瓷有限公司 | 酒瓶强化骨瓷胚料及采用该胚料制作酒瓶的制备工艺 |
| CN108793957B (zh) * | 2018-07-10 | 2021-10-08 | 重庆锦晖陶瓷有限公司 | 酒瓶强化骨瓷胚料及采用该胚料制作酒瓶的制备工艺 |
| CN110903079A (zh) * | 2019-10-11 | 2020-03-24 | 湖南华联君窑艺术瓷有限公司 | 一种大容量高温瓷酒瓶釉及制备方法 |
| CN113185123A (zh) * | 2021-05-26 | 2021-07-30 | 李美煌 | 一种高强度天青釉瓷的制备工艺 |
| CN113636866A (zh) * | 2021-08-10 | 2021-11-12 | 广东易成陶瓷实业有限公司 | 一种砂粒釉陶瓷的制备方法 |
| CN114907094A (zh) * | 2022-05-23 | 2022-08-16 | 吴佘斌 | 一种实现超细缝隙的瓷砖及其生产工艺 |
| CN117125896A (zh) * | 2023-10-26 | 2023-11-28 | 佛山市东鹏陶瓷有限公司 | 一种易清洁仿古釉料及其制备方法、易清洁仿古陶瓷砖 |
| CN117125896B (zh) * | 2023-10-26 | 2024-02-06 | 佛山市东鹏陶瓷有限公司 | 一种易清洁仿古釉料及其制备方法、易清洁仿古陶瓷砖 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108484104A (zh) | 一种天青瓷陶瓷材料及其制备方法 | |
| CN106336116B (zh) | 一种陶瓷釉料及其制备方法、利用其制作陶瓷的方法 | |
| CN103524121B (zh) | 一种全抛釉瓷质砖及其制备方法 | |
| CN110117184A (zh) | 一种耐磨损日用陶瓷及其制备方法 | |
| CN105693207B (zh) | 一种茶叶末艺术瓷的制备方法 | |
| CN108821588B (zh) | 高铝钡陶瓷釉料、含高铝钡陶瓷釉料的喷墨陶瓷砖及其制备方法 | |
| CN106146043B (zh) | 一种骨质瓷及其烧结工艺 | |
| CN103641447B (zh) | 一种工程陶瓷耐酸耐碱容器的制备方法 | |
| CN105565666B (zh) | 陶瓷容器用立体赤栗磨砂艺术釉制备方法 | |
| CN108129129A (zh) | 黑底紫金油滴建盏及其制备工艺 | |
| CN108264332A (zh) | 一种耐高温的日用釉里红瓷制品及其制造工艺 | |
| CN107601896A (zh) | 一种无光泽蓝釉 | |
| CN110818264A (zh) | 一种高温全瓷裂纹釉和制备方法 | |
| CN110316968A (zh) | 一种快烧多晶型多色彩结晶釉及其制备方法和应用 | |
| CN110228993A (zh) | 一种具有内面非裂纹釉的裂纹青瓷化妆品瓶加工工艺 | |
| CN107082624A (zh) | 一种长石质强化骨瓷的制备方法 | |
| CN102503442B (zh) | 高温细瓷器具镶接方法 | |
| CN109053137A (zh) | 红土釉下彩工艺瓷及其制备方法 | |
| CN108314416A (zh) | 耐热陶瓷健康砂锅 | |
| CN104291785B (zh) | 一种高档瓷种水晶镁玉陶瓷及其制备方法 | |
| CN106082990A (zh) | 一种教学用陶瓷及其制备方法 | |
| CN110240477A (zh) | 一种釉下彩骨灰瓷的制备方法 | |
| CN104860645B (zh) | 一种利用黄土制备的琉璃瓦 | |
| CN104418336B (zh) | 一种合成硅灰石和含该合成硅灰石的蛋白瓷及其制造方法 | |
| CN104944906B (zh) | 一种色瓷及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180904 |