CN108484104A - A kind of day celadon ceramic material and preparation method thereof - Google Patents
A kind of day celadon ceramic material and preparation method thereof Download PDFInfo
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Abstract
A kind of day celadon ceramic material and preparation method thereof.The idiosome of the ceramic material includes aluminium powder, quartz, feldspar, bentonite, Guizhou clay, Longyan clay, kaolin and talcum；The glazing material layer includes：Quartz, talcum, dolomite, calcite, zirconium silicate, frit, Suzhou soil, potassium feldspar, kaolin, barium carbonate, lanthanum carbonate, lithium carbonate, zinc oxide, yttria, strontium carbonate, cerium oxide, cobalt oxide and niobium oxide.Opposite conventional ceramic product, this day celadon is not only further strengthened in terms of the physical and chemical indexs such as product strength, hardness of glaze surface, smoothness and thermal shock resistance, and by adding a variety of rare-earth oxides to glaze, it is reacted generated transmutation using its hot conditions in sintering procedure, so that the great individual character of product glaze produced, and there is simple and honest, full, is green and luxuriant characteristic.
Description
Technical field
The invention belongs to ceramic fields, and in particular to a kind of day celadon ceramic material and preparation method thereof.
Background technology
The firing history of China's celadon is of long standing and well established, from quotient's week when original celadon appearance, after the Spring and Autumn and the Warring States Periods
Development, break through until the Eastern Han Dynasty has begun in the age and gradually tend to ripe, be then the peak for having reached celadon and having developed in the Song Dynasty.
This is up in more than 3000 years celadon development history, and celadon gradually sets up their relationship with Chinese civilization, the discussion in relation to celadon
It is visible with praise uncoiling.In the mind of Chinese successive dynasties' successive dynasties refined scholars, celadon not only has that jade is gentle and kind to be grasped
Property, also contain the moral concept and intension of " weight moral weight personal integrity ", it is deep to be pursued.
With modern people's improvement of living standard, requirement of the consumer to domestic ceramics is also higher and higher, in addition to ceramics
Outside the original function of product itself, its art and appreciation added value are also increasingly valued.
Invention content
The present invention overcomes prior art defect, provides a kind of day celadon ceramic material and preparation method thereof.
Technical solution of the present invention is as follows.
A kind of day celadon ceramic material, the idiosome of the ceramic material include 8 ~ 14 parts of aluminium powder, 5 ~ 8 parts of quartz, feldspar 20 ~
2 ~ 6 parts of 25 parts, 3 ~ 7 parts of bentonite, 4 ~ 7 parts of Guizhou clay, 30 ~ 36 parts of Longyan clay, 28 ~ 33 parts of kaolin and talcum；
The glazing material layer includes：33-35 parts quartzy, 7 ~ 11 parts of talcum, 2 ~ 5 parts of dolomite, 10 ~ 15 parts of calcite, zirconium silicate 2
~ 6 parts, 15 ~ 20 parts of frit, 10 ~ 14 parts of Suzhou soil, 36 ~ 38 parts of potassium feldspar, 10 ~ 12 parts of kaolin, 4.5 ~ 5.5 parts of barium carbonate, carbon
0.2 ~ 0.4 part of sour lanthanum, 1.6 ~ 1.8 parts of lithium carbonate, 4 ~ 6 parts of zinc oxide, 0.6 ~ 0.8 part of yttria, 0.5 ~ 1 part of strontium carbonate,
0.8 ~ 1.5 part of 0.2 ~ 0.3 part of cerium oxide, 1 ~ 2 part of cobalt oxide and niobium oxide.
Best ratio is as follows in the present invention：
The idiosome of the ceramic material includes 10 parts of aluminium powder, 6 parts of quartz, 23 parts of feldspar, 5 parts of bentonite, 6 parts of Guizhou clay, Longyan
4 parts of 33 parts of soil, 30 parts of kaolin and talcum；
The glazing material layer includes：34 parts of quartz, 8 parts of talcum, 4 parts of dolomite, 13 parts of calcite, 4 parts of zirconium silicate, frit 18
Part, 12 parts of Suzhou soil, 37 parts of potassium feldspar, 11 parts of kaolin, 5 parts of barium carbonate, 0.3 part of lanthanum carbonate, 1.7 parts of lithium carbonate, zinc oxide 5
Part, 0.7 part of yttria, 0.8 part of strontium carbonate, 0.2 part of cerium oxide, 1.8 parts of cobalt oxide and 1.2 parts of niobium oxide.
The preparation method of a kind of day celadon ceramic material, includes the following steps：
（1）It takes the idiosome material of metering, grinding to cause 200 ~ 250 mesh, is 2 ~ 3 according to the mass ratio of idiosome material and water：2 mixing,
Then after the slip casting of modulus tool, demoulding, natural drying repaiies embryo, and 4 ~ 5h is toasted in the case where idiosome is positioned over 100 ~ 110 DEG C, then cold
But room temperature is arrived, 5 ~ 6h is fired at 500 ~ 860 DEG C being put into kiln, takes out the idiosome after firing, it is spare；
（2）By step（1）Idiosome after gained is fired is washed, and is then dried spare；
（3）Take quartz, talcum, dolomite, calcite, zirconium silicate, frit, Suzhou soil, potassium feldspar, kaolin, the carbonic acid of metering
Barium, lanthanum carbonate, lithium carbonate, zinc oxide, yttria, strontium carbonate and cerium oxide, grinding cause 200 ~ 250 mesh；Separately take cobalt oxide
And niobium oxide, grinding cause 300 ~ 350 mesh, then the material mixing after amount grinding, mixes with water according to idiosome material, obtains glaze layer
Idiosome after drying is carried out leaching glaze, then dries 2 ~ 3h at room temperature, then in glaze spraying, dried, with 1250 ~ 1300 by slurry
12 ~ 14h is fired at DEG C, obtains a day celadon ceramic material.
In the above method, step（1）In, the specific method that 5 ~ 6h is fired at described 500 ~ 860 DEG C is：Slow fire at 500 DEG C
1 ~ 2h is fired, then fires 1 ~ 2h at 860 DEG C of heating, then 350 DEG C of the cause that cools down, furnace door is opened, idiosome is allowed to be cooled down.
In the present invention, the glossiness of ceramic glaze is improved by the way that a variety of rare-earth oxides are added in glaze,
Lanthanum can make glaze more sparkling and crystal-clear brilliant, and cerium has stronger covering power, while make glaze gloss jade-like stone profit, and can reduce cracking feelings
The generation of condition；Yttrium can form rare-earth phase with lanthanum, aluminium in sintering, improve consistency, flexural strength and fracture toughness, drop simultaneously
The temperature of low frit.Pass through the synergistic effect generated between a variety of rare-earth oxides so that the glossiness of reddish black ceramic glaze surface
It is improved, glaze is smooth, has good hardness, flexural strength and fracture toughness.In addition, in order to make a day celadon show crystalline substance
Jade-like stone is pure, class is beautiful like the characteristics of ice, and the present invention is also added into colorant in tire glaze formula, in order to determine the choosing of coloring oxide
It selects and matches, applicant is finally determined by cobalt oxide and oxidation by analyzing the data that many experiments collect
Niobium is with 6:4 ratio synthesizes the colorant of day celadon.Under the hot conditions of 1300 DEG C of sintering process, colorant can with it is reddish black
It reacts between other materials in porcelain, generates transmutation, it is gentle such as beautiful unique glaze to ultimately form day celadon.
Day celadon of the present invention is different from traditional celadon in the selection for making raw material, uses using high purity quartz as production
The making main material of product green body, accounting reach 45% or more.Quartz is a kind of minerals of stabilization at normal temperatures, not soluble in water
In most of acid such as sulfuric acid, hydrochloric acid, nitric acid, belong to non-eductive raw material, but it is generated not with clay in hot conditions
The relatively high mechanical hardness of ceramic product and chemical stability can be assigned by carrying out stone crystal, can also increase the translucence of green body.
In order to enhance the physicochemical property of product, tests through a large number of experiments, finally determine to adopt in the green body formula for raw stock of day celadon
Use fineness control 10um-30ym high purity quartz as green body main material, in kaolin-feldspar-quartz ternary system
On the basis of formula, the strong cosolvent of green body is also used, suitable mineralizer is introduced, by making interiors of products be formed in the high temperature environment
Mullite crystal and corundum crystal grain form the microstructure for playing humidification.Wherein mullite crystal is fine acicular crystal,
Be interleaved with each other into it is network-like be evenly distributed in green body, constitute crystalline framework, and refine corundum crystal be then generally evenly distributed in
Between mullite crystal skeleton, play the role of dispersion-strengtherning.It cooperates between the two so that day celadon is either in product
Flexural strength, hardness of glaze surface, impact resistance still in terms of thermal shock resistance, it is all higher than traditional ceramics product.It makes pottery through country
Porcelain and water heating bathroom product quality supervision and inspection Spot detection, all technical of day celadon product all reach preferable level,
Part index number has filled up domestic blank, and the main technical index of product is as follows：
1. water absorption rate≤0.5%；
2. glossiness 95；
3. flexural strength 117.1Mpa；
4. a thermal shock resistance heat exchange of 180 DEG C to 20 DEG C water is not cracked；
Lead release ＜ 0.1mg/L and quantity of cadmium release ＜ 0.01mg/L.
Compared with prior art, advantage of the invention is that：
Opposite conventional ceramic product, this day celadon is not only in physics and chemistry such as product strength, hardness of glaze surface, smoothness and thermal shock resistances
It is further strengthened in terms of performance indicator, and by adding a variety of rare-earth oxides to glaze, is being fired using it
Hot conditions in the process react generated transmutation so that the great individual character of product glaze produced, and with muddy
Thick, full, is green and luxuriant characteristic.
Specific implementation mode
Embodiment 1
（1）Take 10 parts of aluminium powder, 6 parts of quartz, 23 parts of feldspar, 5 parts of bentonite, 6 parts of Guizhou clay, 33 parts of Longyan clay, 30 parts of kaolin
With 4 parts of talcum, grinding causes 200 mesh, is 3 according to the mass ratio of idiosome material and water：2 mixing take off then after the slip casting of modulus tool
Mould, natural drying repair embryo, toast 4h in the case where idiosome is positioned over 100 DEG C, are then cooled to room temperature, and are being put into kiln, 500 DEG C
Lower slow fire fires 1h, then fires 2h at 860 DEG C of heating, then 350 DEG C of the cause that cools down, and opens furnace door, idiosome is allowed to be cooled down,
The idiosome after firing is taken out, it is spare；
（2）By step（1）Idiosome after gained is fired is washed, and is then dried spare；
（3）Take quartz 34 parts, 8 parts of talcum, 4 parts of dolomite, 13 parts of calcite, 4 parts of zirconium silicate, 18 parts of frit, 12 parts of Suzhou soil,
37 parts of potassium feldspar, 11 parts of kaolin, 5 parts of barium carbonate, 0.3 part of lanthanum carbonate, 1.7 parts of lithium carbonate, 5 parts of zinc oxide, yttria
0.2 part of 0.7 part, 0.8 part of strontium carbonate and cerium oxide, grinding cause 200 mesh；12 parts of 18 parts of cobalt oxide and niobium oxide separately are taken, is ground
300 mesh are caused, then the material mixing after amount grinding, mixes with water according to idiosome material, obtain glaze layer slurry, by the embryo after drying
Body carries out leaching glaze, then dries 2h at room temperature, then in glaze spraying, dries, and 12h is fired at 1300 DEG C, obtains a day celadon pottery
Ceramic material.
Embodiment 2
（1）Take 8 parts of aluminium powder, quartz 5 parts, 25 parts of feldspar, 7 parts of bentonite, 4 parts of Guizhou clay, 36 parts of Longyan clay, 28 parts of kaolin,
6 parts of talcum, grinding cause 250 mesh, are 3 according to the mass ratio of idiosome material and water：2 mixing, then after the slip casting of modulus tool, demoulding,
Natural drying repaiies embryo, toasts 4h in the case where idiosome is positioned over 100 DEG C, is then cooled to room temperature, and is being put into kiln, at 500 DEG C
Slow fire fires 2h, then fires 2h at 860 DEG C of heating, then 350 DEG C of the cause that cools down, and opens furnace door, allows idiosome to be cooled down, take
Go out the idiosome after firing, it is spare；
（2）By step（1）Idiosome after gained is fired is washed, and is then dried spare；
（3）Take 15 parts of 2 parts of 10 parts of 2 parts of 11 parts of 35 parts of quartz, talcum, dolomite, calcite, zirconium silicate, frit, the Suzhou of metering
10 parts of soil, 38 parts of potassium feldspar, 10 parts of kaolin, 5.5 parts of barium carbonate, 0.2 part of lanthanum carbonate, 1.8 parts of lithium carbonate, 6 parts of zinc oxide, three
0.8 part of Y 2 O, 0.5 part of strontium carbonate, 0.2 part of cerium oxide, grinding cause 250 mesh；Separately take 2 parts of cobalt oxide and niobium oxide 1.5
Part, grinding causes 300 mesh, and then the material mixing after amount grinding, mixes with water according to idiosome material, obtain glaze layer slurry, will dry in the air
Idiosome after dry carries out leaching glaze, then dries 2 ~ 3h at room temperature, then in glaze spraying, dries, fires 14h at 1250 DEG C, obtain
To day celadon ceramic material.
Embodiment 3
（1）Take 14 parts of aluminium powder, quartz 8 parts, 25 parts of feldspar, 3 parts of bentonite, 7 parts of Guizhou clay, 30 parts of Longyan clay, 33 parts of kaolin,
2 parts of talcum, grinding cause 200 mesh, are 3 according to the mass ratio of idiosome material and water：2 mixing, then after the slip casting of modulus tool, demoulding,
Natural drying repaiies embryo, toasts 5h in the case where idiosome is positioned over 100 DEG C, is then cooled to room temperature, and is being put into kiln, at 500 DEG C
Slow fire fires 2h, then fires 1h at 860 DEG C of heating, then 350 DEG C of the cause that cools down, and opens furnace door, allows idiosome to be cooled down, take
Go out the idiosome after firing, it is spare；
（2）By step（1）Idiosome after gained is fired is washed, and is then dried spare；
（3）Take 20 parts of 6 parts of 15 parts of 5 parts of 7 parts of 33 parts of quartz, talcum, dolomite, calcite, zirconium silicate, frit, the Suzhou of metering
14 parts of soil, 36 parts of potassium feldspar, 12 parts of kaolin, 4.5 parts of barium carbonate, 0.4 part of lanthanum carbonate, 1.6 parts of lithium carbonate, 4 parts of zinc oxide, three
0.6 part of Y 2 O, 1 part of strontium carbonate, 0.3 part of cerium oxide, grinding cause 200 mesh；0.8 part of 1 part of cobalt oxide and niobium oxide separately are taken,
Grinding causes 350 mesh, and then the material mixing after amount grinding, mixes with water according to idiosome material, glaze layer slurry is obtained, after drying
Idiosome carry out leaching glaze, then dry 3h at room temperature, then in glaze spraying, dry, fire 13h at 1250 DEG C, obtain reddish black
Porcelain ceramic material.
Example 1 ~ 3 product tested, by test, 1 products obtained therefrom water absorption rate of embodiment be 0.3%, implement
The water absorption rate of example 2 is 0.4%, and embodiment 3 is 0.4%；Flexural strength is 117Mpa, 119Mpa, 117Mpa.180 DEG C of thermal shock resistance
It does not crack to the heat exchange of 20 DEG C of water；Lead release ＜ 0.1mg/L and quantity of cadmium release ＜ 0.01mg/L.
Claims (5)
1. a kind of day celadon ceramic material, which is characterized in that the idiosome of the ceramic material includes 8 ~ 14 parts of aluminium powder, quartz 5 ~ 8
Part, 20 ~ 25 parts of feldspar, 3 ~ 7 parts of bentonite, 4 ~ 7 parts of Guizhou clay, 30 ~ 36 parts of Longyan clay, 28 ~ 33 parts of kaolin and talcum 2 ~ 6
Part；
The glazing material layer includes：33-35 parts quartzy, 7 ~ 11 parts of talcum, 2 ~ 5 parts of dolomite, 10 ~ 15 parts of calcite, zirconium silicate 2
~ 6 parts, 15 ~ 20 parts of frit, 10 ~ 14 parts of Suzhou soil, 36 ~ 38 parts of potassium feldspar, 10 ~ 12 parts of kaolin, 4.5 ~ 5.5 parts of barium carbonate, carbon
0.2 ~ 0.4 part of sour lanthanum, 1.6 ~ 1.8 parts of lithium carbonate, 4 ~ 6 parts of zinc oxide, 0.6 ~ 0.8 part of yttria, 0.5 ~ 1 part of strontium carbonate,
0.6 ~ 1.5 part of 0.2 ~ 0.3 part of cerium oxide, 1 ~ 2 part of cobalt oxide and niobium oxide.
2. day celadon ceramic material according to claim 1, which is characterized in that the idiosome of the ceramic material includes aluminium powder 10
4 parts of part, 6 parts of quartz, 23 parts of feldspar, 5 parts of bentonite, 6 parts of Guizhou clay, 33 parts of Longyan clay, 30 parts of kaolin and talcum；
The glazing material layer includes：34 parts of quartz, 8 parts of talcum, 4 parts of dolomite, 13 parts of calcite, 4 parts of zirconium silicate, frit 18
Part, 12 parts of Suzhou soil, 37 parts of potassium feldspar, 11 parts of kaolin, 5 parts of barium carbonate, 0.3 part of lanthanum carbonate, 1.7 parts of lithium carbonate, zinc oxide 5
Part, 0.7 part of yttria, 0.8 part of strontium carbonate, 0.2 part of cerium oxide, 1 part of cobalt oxide and 0.6 part of niobium oxide.
3. the preparation method of day celadon ceramic material according to claim 1, which is characterized in that include the following steps：
（1）It takes the idiosome material of metering, grinding to cause 200 ~ 250 mesh, is 2 ~ 3 according to the mass ratio of idiosome material and water：2 mixing,
Then after the slip casting of modulus tool, demoulding, natural drying repaiies embryo, and 4 ~ 5h is toasted in the case where idiosome is positioned over 100 ~ 110 DEG C, then cold
But room temperature is arrived, 5 ~ 6h is fired at 500 ~ 860 DEG C being put into kiln, takes out the idiosome after firing, it is spare；
（2）By step（1）Idiosome after gained is fired is washed, and is then dried spare；
（3）Take quartz, talcum, dolomite, calcite, zirconium silicate, frit, Suzhou soil, potassium feldspar, kaolin, the carbonic acid of metering
Barium, lanthanum carbonate, lithium carbonate, zinc oxide, yttria, strontium carbonate and cerium oxide, grinding cause 200 ~ 250 mesh；Separately take cobalt oxide
And niobium oxide, grinding cause 300 ~ 350 mesh, then the material mixing after amount grinding, mixes with water according to idiosome material, obtains glaze layer
Idiosome after drying is carried out leaching glaze, then dries 2 ~ 3h at room temperature, then in glaze spraying, dried, burnt at 1290 DEG C by slurry
12h processed obtains a day celadon ceramic material.
4. the preparation method of day celadon ceramic material according to claim 3, which is characterized in that step（1）In, described 500 ~
The specific method of 5 ~ 6h of firing is at 860 DEG C：Slow fire fires 1 ~ 2h at 500 DEG C, and 1 ~ 2h is then fired at 860 DEG C of heating, then
Cooling causes 350 DEG C, opens furnace door, idiosome is allowed to be cooled down.
5. the preparation method of day celadon ceramic material according to claim 3, which is characterized in that the cobalt oxide and niobium oxide
Mass ratio be 6：4.
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Application publication date: 20180904 |