CN108275737B - Method for desalting seawater based on gas-liquid interface heating - Google Patents

Method for desalting seawater based on gas-liquid interface heating Download PDF

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CN108275737B
CN108275737B CN201810074225.XA CN201810074225A CN108275737B CN 108275737 B CN108275737 B CN 108275737B CN 201810074225 A CN201810074225 A CN 201810074225A CN 108275737 B CN108275737 B CN 108275737B
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dust
free paper
seawater
sponge
water
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CN108275737A (en
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叶苗苗
甘启茂
张土乔
陈蓉
朱科杭
王迅
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Zhejiang University ZJU
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/048Purification of waste water by evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08Seawater, e.g. for desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination

Abstract

The invention relates to a method for desalinating seawater based on gas-liquid interface heating, which comprises the following steps: 1) dispersing carbon nanotubes in water, and performing ultrasonic treatment to obtain a carbon nanotube suspension; 2) carrying out vacuum filtration on the carbon nanotube suspension on the dust-free paper, and then drying the dust-free paper to obtain carbon nanotube-loaded dust-free paper; 3) the sponge floats on the surface of the seawater to be desalinated after the seawater to be desalinated is sucked, the dust-free paper carrying the carbon nano tubes is attached to the sponge to obtain the carbon nano tube-dust-free paper-sponge which floats on the surface of the seawater to be desalinated, and then illumination distillation is carried out on the sponge to distill the seawater to be desalinated. The method takes the carbon nano tube, the dust-free paper and the sponge as the photo-thermal conversion material, fully utilizes heat energy, reduces heat loss and accelerates seawater distillation.

Description

Method for desalting seawater based on gas-liquid interface heating
Technical Field
The invention relates to the field of seawater desalination, in particular to a method for desalinating seawater based on gas-liquid interface heating.
Background
At present, people more than 1/3 live in water resource shortage areas globally, and the shortage of fresh water resources is becoming serious, which becomes a global environmental problem and even a political problem. Desalination of sea water is considered to be the most practical and effective method for continuously providing a source of fresh water. The seawater desalination method can be divided into an evaporation method, a membrane method, a crystallization method, a solvent extraction method, an ion exchange method and the like according to the separation process, and the most widely practical application mainly comprises the evaporation method (distillation method) and the membrane method.
At present, the most common methods of seawater desalination in engineering are multi-stage flash evaporation and reverse osmosis. However, although the two existing seawater desalination processes have been developed and matured, the two existing seawater desalination processes still have the defect of huge electric energy consumption. The use of electrical energy not only increases the cost of water management, but also causes air pollution and greenhouse effect if coal electricity is used. In addition, the two seawater desalination processes need to establish a complex operation system, and are not suitable for islands and remote areas. In order to reduce energy consumption, clean renewable energy sources such as solar energy, wind energy, geothermal energy and the like are good choices for solving the problem of seawater desalination power. According to the distribution of the solar energy in the world, water-deficient areas have more abundant solar energy resources, so that the desalination of solar seawater becomes one of important means for solving the problem of water resource shortage under the water crisis and environmental pollution predicament.
Research shows that the water evaporation only occurs at the interface of air and water, the same water evaporation effect can be achieved only by heating the surface seawater, and the energy can be greatly saved. Therefore, a solar seawater desalination technology based on 'gas-liquid interface' heating is produced. The technology takes a black material or a noble metal nano material as a photo-thermal conversion material, the photo-thermal conversion material floats on the surface of seawater in various different modes, the seawater on the surface is heated by utilizing the high sunlight absorption rate of the black material or the surface plasma heating effect of the noble metal nano material, and then fresh water is prepared by condensing and evaporating water. However, in the existing "gas-liquid interface" heating technology, when the seawater at the "gas-liquid interface" is heated by solar energy, heat is transferred through the non-evaporated seawater at the lower part, so that heat loss is caused, and the seawater desalination efficiency is reduced.
Disclosure of Invention
The invention aims to provide a method for desalinating seawater based on gas-liquid interface heating, which takes carbon nano tubes, dust-free paper and sponge as a photothermal conversion material, fully utilizes heat energy, reduces heat loss and accelerates seawater distillation.
The technical scheme provided by the invention is as follows:
a method for desalinating seawater based on gas-liquid interface heating comprises the following steps:
1) dispersing carbon nanotubes in water, and performing ultrasonic treatment to obtain a carbon nanotube suspension;
2) carrying out vacuum filtration on the carbon nanotube suspension on the dust-free paper, and then drying the dust-free paper to obtain carbon nanotube-loaded dust-free paper;
3) the sponge floats on the surface of the seawater to be desalinated after the seawater to be desalinated is sucked, the dust-free paper carrying the carbon nano tubes is attached to the sponge to obtain the carbon nano tube-dust-free paper-sponge which floats on the surface of the seawater to be desalinated, and then illumination distillation is carried out on the sponge to distill the seawater to be desalinated.
According to the technical scheme, the carbon nano tube-dust-free paper-sponge is used as the photo-thermal conversion material, so that heat energy can be fully utilized, and heat loss is reduced. The main reason is that the sponge has porosity and heat insulation, the porosity can promote the seawater at the lower part to automatically flow to the surface for heating and evaporation by utilizing the capillary action, and the heat insulation prevents the heat of the carbon nano tube light absorption conversion from being transferred to the non-evaporation part of the lower water body through heat conduction, namely, the generated heat is stored and is used for intensively heating water molecules on a 'gas-water interface', so that the heat energy is fully utilized, and the heat loss is reduced.
In addition, the carbon nano tube particles are large and cannot float on the surface of seawater, and the dust-free paper has porosity and can enhance water absorption by utilizing capillary action, but also cannot float on the surface of the seawater, so that the special structure of the carbon nano tube, the dust-free paper and the sponge is adopted, so that the photothermal conversion material can float on the surface of the seawater, and the heating of a gas-liquid interface is realized.
Preferably, the power of the ultrasonic treatment in the step 1) is 600-700W, and the time is 30-60 min. Under the condition, the carbon nano tubes can be uniformly dispersed, the phenomenon that the carbon nano tubes are not uniform when loaded on the dust-free paper is avoided, and meanwhile, the micro appearance of the carbon nano tubes cannot be excessively damaged.
Preferably, the feeding ratio of the carbon nanotubes to the water in the step 1) is 5-30mg:40 ml. More preferably 5-15mg:40ml, and the use amount of the carbon nano tubes is controlled to avoid the increase of the thickness of the carbon nano tubes on the surface of the dust-free paper due to excessive use amount, so as to prevent the evaporation of water vapor and reduce the evaporation rate of the water.
Preferably, the vacuum degree of the vacuum filtration in the step 2) is-0.015 to-0.02 MPa.
Preferably, the dust-free paper in the step 2) is circular dust-free paper with the diameter of 3-5 cm. The dust-free paper is used as a direct carrier of the carbon nano tube, and the capillary action of the dust-free paper promotes water to automatically flow to the surface to be heated and evaporated, so that the evaporation rate is increased.
Preferably, the shape of the surface of the sponge and the dust-free paper contacted with each other in the step 3) is the same.
Preferably, the sponge in the step 3) is cylindrical polyurethane sponge.
Preferably, in the step 3), a xenon lamp is adopted for illumination, the illumination distance is 6.5-8.5cm, and the illumination intensity is 0.8-6Kw/m 2. Wherein, the illumination distance refers to the distance between a xenon lamp and a carbon nano tube-dust-free paper-sponge.
Compared with the prior art, the invention has the beneficial effects that:
(1) the invention takes the carbon nano tube, the dust-free paper and the sponge as the photo-thermal conversion material, fully utilizes the heat energy, reduces the heat loss and accelerates the distillation of the seawater.
(2) The invention adopts a special structure of carbon nano tube-dust-free paper-sponge, so that the photothermal conversion material can float on the surface of seawater, and the heating of a gas-liquid interface is realized.
Drawings
FIG. 1 is a scanning electron micrograph of carbon nanotubes before sonication in example 1;
FIG. 2 is a scanning electron micrograph of the carbon nanotubes after the ultrasonication in example 1;
FIG. 3 is a graph of the mass of evaporated water over time;
FIG. 4 is a graph showing the effect of different amounts of carbon nanotubes on the efficiency of water evaporation;
fig. 5 is a graph showing the effect of different light intensities on the acceleration of seawater evaporation.
Detailed Description
The present invention is further illustrated by the following specific examples.
Example 1
(1) Adding 10mg of granular carbon nanotubes into a 100mL beaker filled with 40mL of artificial seawater, and carrying out ultrasonic crushing in a biosafer650-92 ultrasonic cell crusher to obtain carbon nanotube suspension, wherein the main parameters of the ultrasonic cell crusher are as follows: ultrasonic power 650W, ultrasonic power accuracy 75%, horn (mm)
Figure BDA0001559037750000041
Temperature 30 ℃, ultrasonic wave 5s, interval 5s, total time 60 min. Scanning electron micrographs of carbon nanotubes before and after sonication are shown in FIGS. 1 and 2.
(2) And (3) performing vacuum filtration on the carbon nanotube suspension on circular dust-free paper with the diameter of 4cm (the vacuum degree is between-0.015 and-0.02 MPa), and drying the dust-free paper at room temperature for 24 hours.
(3) Attaching the dried dust-free paper with 10mg of attached carbon nanotubes to the surface of a cylindrical polyurethane sponge (bottom diameter is 4cm, thickness is 2cm) soaked in water, floating the carbon nanotube-dust-free paper-sponge combination on the water surface of a 50ml beaker (diameter is 4cm) filled with artificial seawater, placing the beaker on an electronic balance, keeping the surface of the combination 7.5cm away from a light source, and keeping the illumination intensity of the surface of the combination at 0.8Kw/m2And the light source vertically irradiates the combined surface and the surface of the water body. The irradiation was carried out for 2h and the change in mass due to water evaporation during the irradiation was recorded. The ambient temperature is 25 ℃, the humidity is 40%, and the artificial seawater temperature is 25 ℃.
Comparative example 1
Placing 50ml beaker (diameter 4cm) containing artificial seawater on electronic balance, and keeping the distance between water surface and light source at 7.5cm (the illumination intensity of water surface at this position is 0.8 Kw/m)2) The light source irradiates the surface of the water body vertically. The irradiation was carried out for 2h and the change in mass due to water evaporation during the irradiation was recorded. The ambient temperature is 25 ℃, the humidity is 40%, and the initial temperature of the artificial seawater is 25 ℃.
Comparative example 2
Attaching a dust-free paper without carbon nanotube adhesion to the surface of a cylindrical polyurethane sponge (bottom surface diameter 4cm, thickness 2cm) soaked in water, floating the sponge-dust-free paper combination on the water surface of a 50ml beaker (diameter 4cm) filled with artificial seawater, placing the beaker on an electronic balance, and keeping the surface of the combination 7.5cm away from a light source and the illumination intensity of the surface of the combination at 0.8Kw/m2And the light source vertically irradiates the combined surface and the surface of the water body. The irradiation was carried out for 2h and the change in mass due to water evaporation during the irradiation was recorded. The ambient temperature is 25 ℃, the humidity is 40%, and the artificial seawater temperature is 25 ℃.
Performance test 1
Comparing the mass of the evaporated water with time in example 1, comparative example 1 and comparative example 2, respectively, as can be seen from FIG. 3, when the xenon lamp was irradiated for 2 hours, pure water, a combination of sponge and dust-free paper floating on the surface of pure water, and a combination of sponge, dust-free paper and 10mg of carbon nanotube floating on the surface of pure water evaporated waterThe masses were 1.180g, 1.400g and 2.946g, respectively, i.e. 0.940kgm-2、1.114kgm-2、2.346kgm-2The water evaporation rate is 0.470kgm respectively-2h-1、0.557kgm-2h-1And 1.173kgm-2h-1. The evaporation rate can be seen to promote the evaporation of water when only sponge and dust-free paper are used, but the evaporation rate of water is improved more when the photothermal conversion material carbon nanotube is added, and the evaporation rate can reach 2.5 times of that of pure water.
Examples 2 to 6
(1) Respectively adding 5, 7.5, 10, 15 and 20mg of granular carbon nanotubes into 5 100mL beakers filled with 40mL of artificial seawater, and carrying out ultrasonic crushing in a biosafer650-92 ultrasonic cell crusher to obtain a carbon nanotube suspension, wherein the main parameters of the ultrasonic cell crusher are as follows: ultrasonic power 650W, ultrasonic power accuracy 75%, horn (mm)
Figure BDA0001559037750000061
Temperature 30 ℃, ultrasonic wave 5s, interval 5s, total time 60 min.
(2) And (3) performing vacuum filtration on the carbon nanotube suspension on circular dust-free paper with the diameter of 4cm (the vacuum degree is between-0.015 and-0.02 MPa), and drying the dust-free paper at room temperature for 24 hours.
(3) Attaching the dried dust-free paper with attached carbon nanotubes to the surface of a cylindrical polyurethane sponge (bottom surface diameter is 4cm, thickness is 2cm) soaked in water, floating the sponge-dust-free paper-carbon nanotube combination on the water surface of a 50ml beaker (diameter is 4cm) filled with artificial seawater, placing the beaker on an electronic balance, keeping the distance between the combined surface and a light source to be 7.5cm, and keeping the illumination intensity of the combined surface to be 0.8Kw/m2And the light source vertically irradiates the combined surface and the surface of the water body. The irradiation was carried out for 2h and the change in mass due to water evaporation during the irradiation was recorded. The ambient temperature is 25 ℃, the humidity is 40%, and the artificial seawater temperature is 25 ℃.
Performance test 2
Comparing the mass change of the evaporated water in examples 2 to 6, it can be seen from fig. 4 that sponge + dust-free paper +5mg carbon nanotube combination was floated on the surface of pure water and sponge + dust-free paper +7 was floated on the surface of pure water when the xenon lamp was used for 2 hours of irradiation.The evaporation mass of the water of the combination of 5mg of carbon nanotubes, the combination of sponge, dust-free paper and 10mg of carbon nanotubes floating on the surface of pure water, the combination of sponge, dust-free paper and 15mg of carbon nanotubes floating on the surface of pure water and the combination of sponge, dust-free paper and 20mg of carbon nanotubes floating on the surface of pure water are 2.843g, 2.877g, 2.946g, 2.688g and 2.579g respectively, and the evaporation rate of the water is 1.131kgm-2h-1、1.145kgm-2h-1、1.173kgm-2h-1、1.07kgm-2h-1And 1.027kgm-2h-12.41, 2.44, 2.50, 2.28 and 2.185 times of the pure water evaporation rate, respectively, so that the decrease of the water evaporation rate after a certain increase with the increase of the carbon nanotube content can be obtained, which may be that the increase of the carbon nanotube content can convert more light energy into heat energy, and then the increase of the carbon nanotube content is too thick to prevent the water vapor from volatilizing and escaping, so that the water evaporation rate is decreased, and the effect is best when the carbon nanotube content is about 10 mg.
Example 7
(1) Adding 10mg of granular carbon nanotubes into a 100mL beaker filled with 40mL of artificial seawater, and carrying out ultrasonic crushing in a biosafer650-92 ultrasonic cell crusher to obtain carbon nanotube suspension, wherein the main parameters of the ultrasonic cell crusher are as follows: ultrasonic power 650W, ultrasonic power accuracy 75%, horn (mm)
Figure BDA0001559037750000071
Temperature 30 ℃, ultrasonic wave 5s, interval 5s, total time 60 min.
(2) Carrying out vacuum filtration on the carbon nanotube suspension on circular dust-free paper with the diameter of 4cm (the vacuum degree is-0.015 to-0.02 MPa), and drying the dust-free paper at room temperature for 24 hours;
(3) attaching the dried dust-free paper with 10mg of attached carbon nanotubes to the surface of a cylindrical polyurethane sponge (bottom diameter is 4cm, thickness is 2cm) soaked in water, floating the sponge-dust-free paper-carbon nanotube assembly on the water surface of a 50ml beaker (diameter is 4cm) filled with artificial seawater, placing the beaker on an electronic balance, keeping the surface of the assembly 7.5cm away from a light source, and keeping the illumination intensity of the surface of the assembly at 6Kw/m2And the light source vertically irradiates the combined surface and the surface of the water body.The irradiation was carried out for 2h and the change in mass due to water evaporation during the irradiation was recorded. The ambient temperature is 25 ℃, the humidity is 40%, and the artificial seawater temperature is 25 ℃.
Comparative example 3
Placing 50ml beaker (diameter 4cm) containing artificial seawater on electronic balance, wherein the distance between the water surface and the light source is 7.5cm, and the illumination intensity of the water surface is 6Kw/m2The light source irradiates the surface of the water body vertically. The irradiation was carried out for 2h and the change in mass due to water evaporation during the irradiation was recorded. The ambient temperature is 25 ℃, the humidity is 40%, and the artificial seawater temperature is 25 ℃.
Performance test 3
Comparing the change in the mass of the evaporated water in examples 1 and 7 and comparative examples 1 and 3, respectively, as can be seen from FIG. 5, when the xenon lamp was irradiated for 2 hours, the water evaporation mass of pure water (comparative example 3) and the combination of pure water floating sponge + dust-free paper +10mg of carbon nanotubes on the surface (example 7) were 3.46g and 12.41g, respectively, and the water evaporation rate was 1.377kgm, respectively-2h-1And 4.940kgm-2h-1. From the evaporation rate, when the sponge, the dust-free paper and the 10mg carbon nanotube can promote the obvious water evaporation rate, the evaporation rate can reach 3.59 times of that of pure water and is greatly improved compared with that of the embodiment 1, and the combination can exert the capability of accelerating the water evaporation when the light intensity is higher.

Claims (4)

1. A method for desalinating seawater based on gas-liquid interface heating is characterized by comprising the following steps:
1) dispersing carbon nanotubes in water, and performing ultrasonic treatment to obtain a carbon nanotube suspension; the feeding ratio of the carbon nano tube to the water is 10mg to 40 ml; adopting a biosafer650-92 ultrasonic cell crusher, wherein the ultrasonic power precision is 75%, the diameter of an amplitude transformer is 3mm, the ultrasonic treatment power is 600-700W, and the time is 30-60 min;
2) carrying out vacuum filtration on the carbon nanotube suspension on the dust-free paper, and then drying the dust-free paper to obtain carbon nanotube-loaded dust-free paper; the vacuum degree of vacuum filtration is-0.015 to-0.02 MPa;
3) the sponge floats on the surface of the seawater to be desalinated after the seawater to be desalinated is sucked, the dust-free paper carrying the carbon nano tubes is attached to the sponge, the shapes of the surfaces of the sponge and the dust-free paper which are in mutual contact are the same, the carbon nano tubes-dust-free paper-sponge floating on the surface of the seawater to be desalinated are obtained, and then the seawater to be desalinated is subjected to illumination distillation.
2. The method for desalinating seawater based on gas-liquid interface heating according to claim 1, wherein the dust-free paper in the step 2) is circular dust-free paper with a diameter of 3-5 cm.
3. The method for desalinating seawater based on gas-liquid interface heating according to claim 1, wherein the sponge in step 3) is cylindrical polyurethane sponge.
4. The method for desalinating seawater based on gas-liquid interface heating according to claim 1, wherein the xenon lamp is adopted for illumination in the step 3), the illumination distance is 6.5-8.5cm, and the illumination intensity is 0.8-6Kw/m2
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