CN108085788A - A kind of microwave heating prepares the device of oxidization fiber - Google Patents
A kind of microwave heating prepares the device of oxidization fiber Download PDFInfo
- Publication number
- CN108085788A CN108085788A CN201711217325.5A CN201711217325A CN108085788A CN 108085788 A CN108085788 A CN 108085788A CN 201711217325 A CN201711217325 A CN 201711217325A CN 108085788 A CN108085788 A CN 108085788A
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- microwave
- support tube
- rolling
- axis
- protective cover
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- 238000010438 heat treatment Methods 0.000 title claims abstract description 46
- 239000000835 fiber Substances 0.000 title claims abstract description 40
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 32
- 238000000576 coating method Methods 0.000 claims abstract description 23
- 239000011248 coating agent Substances 0.000 claims abstract description 22
- 239000011358 absorbing material Substances 0.000 claims abstract description 15
- 239000010425 asbestos Substances 0.000 claims abstract description 15
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 15
- 239000000463 material Substances 0.000 claims abstract description 12
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 7
- 239000010431 corundum Substances 0.000 claims abstract description 5
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052863 mullite Inorganic materials 0.000 claims abstract description 5
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 5
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 5
- 238000005096 rolling process Methods 0.000 claims description 40
- 230000001681 protective effect Effects 0.000 claims description 36
- 239000002243 precursor Substances 0.000 claims description 25
- 239000007921 spray Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 7
- 229910052799 carbon Inorganic materials 0.000 abstract description 7
- 238000005507 spraying Methods 0.000 abstract description 6
- 230000035699 permeability Effects 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 6
- 230000008569 process Effects 0.000 description 5
- TVEXGJYMHHTVKP-UHFFFAOYSA-N 6-oxabicyclo[3.2.1]oct-3-en-7-one Chemical compound C1C2C(=O)OC1C=CC2 TVEXGJYMHHTVKP-UHFFFAOYSA-N 0.000 description 4
- 238000004093 laser heating Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000005672 electromagnetic field Effects 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 241000826860 Trapezium Species 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000005674 electromagnetic induction Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000002068 genetic effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
Abstract
The present invention relates to the devices that a kind of microwave heating prepares oxidization fiber, belong to microwave heating technique technical field.The microwave heating prepares the device of oxidization fiber, including micro-wave oven, support tube and microwave absorbing coating, microwave oven internal is equipped with horizontal support tube, carrier pipe internal surface spraying microwave absorbing coating, support tube material is mullite or corundum not absorbing material, and microwave absorbing coating is ferrite or silicon carbide absorbing material.The method of the present invention is novel, clear in structure.Since absorbing material does not have very strong permeability to microwave, the energy that microwave discharges can be made more uniform；Microwave absorbing coating can dilute microwave so that material is inhaled ripple and more stablized；Support tube is wrapped up by asbestos, the energy of microwave release can be stored；By above-mentioned processing, oxidization fiber " core-skin " structure is eliminated, it is radially more uniform, volume density is improved, is laid the foundation to obtain high-performance carbon fibre.
Description
Technical field
The present invention relates to the devices that a kind of microwave heating prepares oxidization fiber, belong to microwave heating technique technical field.
Background technology
Precursor pre-oxidation process carries out between 180~280 DEG C, presently mainly using traditional heatings such as Muffle furnaces
Mode is realized.Traditional heating mode is from outward appearance to inner essence heated by radiation, convection current and conduction.Preoxidation process is double diffusion
Course, oxygen are from outward appearance to inner essence spread to fibrous inside, and internal non-carbon element micro-molecular gas product is to external diffusion.With pre-oxidation
The progress of reaction, the strand of fiber sheath have been initially formed fine and close trapezium structure, oxygen are hindered to be spread to core, makes fiber shape
Core annellated, the degree of cross linking is relatively low.Pre-oxidation is progressively carried out from fibrous external to core, the cyclisation and friendship of macromolecular chain
Connection effect makes oxidization fiber cortex fibril be initially formed fine and close netted trapezium structure, hinders the further diffusion of oxygen, occurs
The oxidation of oxidization fiber cortex is fully or even excessive, and core pre-oxidizes deficiency, thus forms skin-core structure.Traditional heating pre-oxidizes
When carbon fiber preparation process in take longest step, easily there is " core-skin " structure, and carbonisation can be genetic to so that is difficult
To obtain high performance carbon fiber.
Microwave heating has the advantages that following three：First, homogeneous heating.Electric furnace process heating is to pass to object by heat transfer
Inside, be easy to cause the half-cooked phenomenon of " outer burnt in not yet done ".The characteristics of microwave heating is maximum is that heat is in heating object
What inside generated, heat source comes from interior of articles, homogeneous heating.Mainly since electromagnetic wave has substance very strong penetration,
Penetration depth belongs to the same order of magnitude with electromagnetic wave free space wavelength, and the diameter of fiber is just in the range of this.So
Electromagnetism wave energy snap realizes homogeneous heating in the table of fiber whole cross section.Secondly, speed is fast.General heating means
It is the environment heated around heating object, heats object by the radiation of heat or the convection current of heating air.This heating
Mode efficiency is low, the time is long.Microwave is electromagnetic wave of the frequency range from 300MHz to 300GHz.Electromagnetic field is to the work of dielectric
With being that the polarization of substance causes object to generate heat the hysteresis effect of electric field.Electromagnetic field is electromagnetic induction to the effect of conducting medium,
Under the action of electromagnetic induction, fibrous inside will generate vortex, since fiber has certain resistance, so being led when flowing through
Heat is converted into during body fiber.Their common feature is the capacity of heat transmission that heating effect is not only restricted to substance, is solely dependent upon
The electrical property of substance and the parameter of additional electromagnetic field.Since the path of heat transfer is reduced, compared with conventional heating, microwave heating is
More rapidly with energy saving heating means.Again, Instantaneous Control.General heating means, heating or change furnace temperature are, it is necessary to the time
It is long.Microwave heating can realize the adjustment to microwave power in a few seconds, you can run well, and adjust microwave output work
Rate, material heating state immediately inertialess with change, realize heating immediately and adjust immediately, convenient for automation and serialization
Production.Therefore, PAN fiber preoxidation process can effectively avoid the deficiency of electric furnace process heating using microwave heating.
Since the dielectric constant of precursor is low, and fibre diameter is meticulous, it is difficult to efficient absorption microwave, so microwave energy utilizes
Rate is too low, and fiber radial structure is difficult to Effective Regulation.There are following for precursor pre-oxidation for current microwave heating equipment
Shortcoming：First, energy expenditure is big, can not reuse；2nd, energy can not dilute scattered, cause material uneven heating even；3rd, set
Standby closing can not carry out interrupted transmission heating to material.It is necessary that a kind of new-type add is provided in order to overcome these shortcomings
Thermal, and heating equipment is improved, realize the deposit of thermal energy, the dilution to energy changes heat-supplying mode and control
The mode of heating of precursor.
The content of the invention
For the above-mentioned prior art there are the problem of and deficiency, the present invention dress that a kind of microwave heating prepares oxidization fiber is provided
It puts.The device changes oxidization fiber mode of heating, promotes the efficiency of heating surface and capacity usage ratio, the present invention is by the following technical programs
It realizes.
A kind of microwave heating prepares the device of oxidization fiber, and including micro-wave oven, support tube and microwave absorbing coating, microwave oven internal is set
There is horizontal support tube, carrier pipe internal surface spraying microwave absorbing coating, support tube material is mullite or corundum not absorbing material, is inhaled
Ripple coating is ferrite or silicon carbide absorbing material.
Further include the first protective cover, asbestos, filament mouth, first axis of rolling, second axis of rolling, into silk mouth and second protect
Cover, the carrier tube outer surface are equipped with asbestos, and support tube is prevented with being respectively equipped with the second protective cover and first on micro-wave oven contact surface
Shield, the second protective cover and the first protective cover centre position are respectively equipped with into silk mouth and filament mouth, and precursor into silk mouth by passing through
Support tube comes out from filament mouth, and precursor, which is located at into silk mouth one end, connects second axis of rolling, positioned at the first rolling of filament mouth one end connection
Moving axis.
Thermocouple is further included, the thermocouple is inserted at the top of micro-wave oven inside support tube.
Second axis of rolling and the equal external connection power device of first axis of rolling.
The operation principle that the microwave heating prepares the device of oxidization fiber is：
Precursor be located at into silk mouth one end connect second axis of rolling, positioned at filament mouth one end connect first axis of rolling, precursor by into
Silk mouth comes out through support tube from filament mouth, under the microwave pre-oxidation effect of the present apparatus, constantly has precursor to enter support tube
Middle progress microwave pre-oxidation.
The beneficial effects of the invention are as follows：The method of the present invention is novel, clear in structure.Since absorbing material does not have very microwave
Strong permeability can make the energy that microwave discharges more uniform；Microwave absorbing coating can dilute microwave so that material inhales ripple more
Stablize；Support tube is wrapped up by asbestos, the energy of microwave release can be stored；By above-mentioned processing, oxidization fiber " core-skin " is eliminated
Structure, it is radially more uniform, volume density is improved, is laid the foundation to obtain high-performance carbon fibre.
Description of the drawings
Fig. 1 is apparatus of the present invention structure diagram；
Fig. 2 is cross-sectional view of the present invention.
In figure：1- thermocouples, 2- micro-wave ovens, the first protective covers of 3-, 4- asbestos, 5- support tubes, 6- microwave absorbing coatings, 7- wire vents
Mouthful, first axis of rolling of 8-, second axis of rolling of 9-, 10- is into silk mouth, 11- precursor, the second protective covers of 12-.
Specific embodiment
With reference to the accompanying drawings and detailed description, the invention will be further described.
Embodiment 1
As shown in Fig. 1 to 2, which prepares the device of oxidization fiber, micro- including micro-wave oven 2, support tube 5 and microwave absorbing coating 6
Ripple stove 2 is internally provided with horizontal support tube 5, and 5 inner surface of support tube spraying microwave absorbing coating 6,5 material of support tube is mullite
（3Al2O3•2SiO2, diameter 100mm, thickness 20mm）Not absorbing material, microwave absorbing coating 6 be ferrite, thickness 1mm.
Wherein further include the first protective cover 3, asbestos 4, filament mouth 7, first axis of rolling 8, second axis of rolling 9, into silk mouth 10
With the second protective cover 12,5 outer surface of support tube is equipped with asbestos 4, and the is respectively equipped on support tube 5 and 2 contact surface of micro-wave oven
Two protective covers 12 and the first protective cover 3, the second protective cover 12 and 3 centre position of the first protective cover are respectively equipped with into silk mouth 10 and go out
Silk mouth 7, for precursor 11 by being come out into silk mouth 10 through support tube 5 from filament mouth 7, precursor 11, which is located at into 10 one end of silk mouth, connects the
Two axis of rolling 9 connect first axis of rolling 8 positioned at 7 one end of filament mouth；Thermocouple 1 is further included, the thermocouple 1 is pushed up from micro-wave oven 2
Portion is inserted into inside support tube 5.8 equal external connection power device of second axis of rolling 9 and first axis of rolling.
Same precursor 11 is placed in the existing micro-wave oven 2 of identical microwave power and pre-oxidizes 1h, when the present apparatus shortens
Between 30min, promoted 50% efficiency.Existing apparatus confined space heats, and be easy to cause " core-skin " structure, precursor is carbonized and is broken.
And the present apparatus realizes laser heating under applied external force, can eliminate oxidization fiber " core-skin " structure, and it is radially more uniform, it improves
Volume density lays the foundation to obtain high-performance carbon fibre.
Embodiment 2
As shown in Fig. 1 to 2, which prepares the device of oxidization fiber, micro- including micro-wave oven 2, support tube 5 and microwave absorbing coating 6
Ripple stove 2 is internally provided with horizontal support tube 5, and 5 inner surface of support tube spraying microwave absorbing coating 6,5 material of support tube is mullite
（3Al2O3•2SiO2, diameter 100mm, thickness 20mm）Not absorbing material, microwave absorbing coating 6 be silicon carbide absorbing material, thickness 2mm.
Wherein further include the first protective cover 3, asbestos 4, filament mouth 7, first axis of rolling 8, second axis of rolling 9, into silk mouth 10
With the second protective cover 12,5 outer surface of support tube is equipped with asbestos 4, and the is respectively equipped on support tube 5 and 2 contact surface of micro-wave oven
Two protective covers 12 and the first protective cover 3, the second protective cover 12 and 3 centre position of the first protective cover are respectively equipped with into silk mouth 10 and go out
Silk mouth 7, for precursor 11 by being come out into silk mouth 10 through support tube 5 from filament mouth 7, precursor 11, which is located at into 10 one end of silk mouth, connects the
Two axis of rolling 9 connect first axis of rolling 8 positioned at 7 one end of filament mouth；Thermocouple 1 is further included, the thermocouple 1 is pushed up from micro-wave oven 2
Portion is inserted into inside support tube 5.8 equal external connection power device of second axis of rolling 9 and first axis of rolling.
Same precursor 11 is placed on to the effect that 1h is pre-oxidized in the existing micro-wave oven 2 of identical microwave power and is reached,
The present apparatus shortens time 30min, promotes 50% efficiency.Existing apparatus confined space heats, and be easy to cause " core-skin " structure, former
Silk is carbonized and is broken.And the present apparatus realizes laser heating under applied external force, can eliminate oxidization fiber " core-skin " structure, radially
More uniformly, volume density is improved, is laid the foundation to obtain high-performance carbon fibre.
Embodiment 3
As shown in Fig. 1 to 2, which prepares the device of oxidization fiber, micro- including micro-wave oven 2, support tube 5 and microwave absorbing coating 6
Ripple stove 2 is internally provided with horizontal support tube 5, and 5 inner surface of support tube spraying microwave absorbing coating 6,5 material of support tube is corundum（Al2O3,
Diameter 100mm, thickness 20mm）Not absorbing material, microwave absorbing coating 6 be ferrite wave-absorbing material, thickness 3mm.
Wherein further include the first protective cover 3, asbestos 4, filament mouth 7, first axis of rolling 8, second axis of rolling 9, into silk mouth 10
With the second protective cover 12,5 outer surface of support tube is equipped with asbestos 4, and the is respectively equipped on support tube 5 and 2 contact surface of micro-wave oven
Two protective covers 12 and the first protective cover 3, the second protective cover 12 and 3 centre position of the first protective cover are respectively equipped with into silk mouth 10 and go out
Silk mouth 7, for precursor 11 by being come out into silk mouth 10 through support tube 5 from filament mouth 7, precursor 11, which is located at into 10 one end of silk mouth, connects the
Two axis of rolling 9 connect first axis of rolling 8 positioned at 7 one end of filament mouth；Thermocouple 1 is further included, the thermocouple 1 is pushed up from micro-wave oven 2
Portion is inserted into inside support tube 5.8 equal external connection power device of second axis of rolling 9 and first axis of rolling.
Same precursor 11 is placed on to the effect that 1h is pre-oxidized in the existing micro-wave oven 2 of identical microwave power and is reached,
The present apparatus shortens time 30min, promotes 50% efficiency.Existing apparatus confined space heats, and be easy to cause " core-skin " structure, former
Silk is carbonized and is broken.And the present apparatus realizes laser heating under applied external force, can eliminate oxidization fiber " core-skin " structure, radially
More uniformly, volume density is improved, is laid the foundation to obtain high-performance carbon fibre.
Embodiment 4
As shown in Fig. 1 to 2, which prepares the device of oxidization fiber, micro- including micro-wave oven 2, support tube 5 and microwave absorbing coating 6
Ripple stove 2 is internally provided with horizontal support tube 5, and 5 inner surface of support tube spraying microwave absorbing coating 6,5 material of support tube is corundum（Al2O3,
Diameter 100mm, thickness 20mm）Not absorbing material, microwave absorbing coating 6 be silicon carbide absorbing material, thickness 5mm.
Wherein further include the first protective cover 3, asbestos 4, filament mouth 7, first axis of rolling 8, second axis of rolling 9, into silk mouth 10
With the second protective cover 12,5 outer surface of support tube is equipped with asbestos 4, and the is respectively equipped on support tube 5 and 2 contact surface of micro-wave oven
Two protective covers 12 and the first protective cover 3, the second protective cover 12 and 3 centre position of the first protective cover are respectively equipped with into silk mouth 10 and go out
Silk mouth 7, for precursor 11 by being come out into silk mouth 10 through support tube 5 from filament mouth 7, precursor 11, which is located at into 10 one end of silk mouth, connects the
Two axis of rolling 9 connect first axis of rolling 8 positioned at 7 one end of filament mouth；Thermocouple 1 is further included, the thermocouple 1 is pushed up from micro-wave oven 2
Portion is inserted into inside support tube 5.8 equal external connection power device of second axis of rolling 9 and first axis of rolling.
Same precursor 11 is placed on to the effect that 1h is pre-oxidized in the existing micro-wave oven 2 of identical microwave power and is reached,
The present apparatus shortens time 30min, promotes 50% efficiency.Existing apparatus confined space heats, and be easy to cause " core-skin " structure, former
Silk is carbonized and is broken.And the present apparatus realizes laser heating under applied external force, can eliminate oxidization fiber " core-skin " structure, radially
More uniformly, volume density is improved, is laid the foundation to obtain high-performance carbon fibre.
The specific embodiment of the present invention is explained in detail above in association with attached drawing, but the present invention is not limited to above-mentioned
Embodiment, within the knowledge of a person skilled in the art, can also be before present inventive concept not be departed from
Put that various changes can be made.
Claims (4)
1. a kind of microwave heating prepares the device of oxidization fiber, it is characterised in that：Including micro-wave oven（2）, support tube（5）It is applied with ripple is inhaled
Layer（6）, micro-wave oven（2）It is internally provided with horizontal support tube（5）, support tube（5）Inner surface sprays microwave absorbing coating（6）, support tube
（5）Material is mullite or corundum not absorbing material, microwave absorbing coating（6）For ferrite or silicon carbide absorbing material.
2. microwave heating according to claim 1 prepares the device of oxidization fiber, it is characterised in that：Further include the first protective cover
（3）, asbestos（4）, filament mouth（7）, first axis of rolling（8）, second axis of rolling（9）, into silk mouth（10）With the second protective cover（12）,
The support tube（5）Outer surface is equipped with asbestos（4）, support tube（5）With micro-wave oven（2）The second protective cover is respectively equipped on contact surface
（12）With the first protective cover（3）, the second protective cover（12）With the first protective cover（3）Centre position is respectively equipped with into silk mouth（10）With
Filament mouth（7）, precursor（11）By into silk mouth（10）Through support tube（5）From filament mouth（7）Out, precursor（11）Positioned at into silk
Mouthful（10）One end connects second axis of rolling（9）, positioned at filament mouth（7）One end connects first axis of rolling（8）.
3. microwave heating according to claim 1 or 2 prepares the device of oxidization fiber, it is characterised in that：Further include thermocouple
（1）, the thermocouple（1）From micro-wave oven（2）Top is inserted into support tube（5）It is internal.
4. microwave heating according to claim 2 prepares the device of oxidization fiber, it is characterised in that：Second axis of rolling
（9）With first axis of rolling（8）Equal external connection power device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711217325.5A CN108085788A (en) | 2017-11-28 | 2017-11-28 | A kind of microwave heating prepares the device of oxidization fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711217325.5A CN108085788A (en) | 2017-11-28 | 2017-11-28 | A kind of microwave heating prepares the device of oxidization fiber |
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| Publication Number | Publication Date |
|---|---|
| CN108085788A true CN108085788A (en) | 2018-05-29 |
Family
ID=62172366
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711217325.5A Pending CN108085788A (en) | 2017-11-28 | 2017-11-28 | A kind of microwave heating prepares the device of oxidization fiber |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006101084A1 (en) * | 2005-03-23 | 2006-09-28 | Bridgestone Corporation | Carbon fiber and processes for (continuous) production thereof, and catalyst structures, electrodes for solid polymer fuel cells, and solid polymer fuel cells, made by using the carbon fiber |
| CN1964584A (en) * | 2005-11-09 | 2007-05-16 | 刘秋雷 | A microwave heating device |
| CN202830266U (en) * | 2012-07-12 | 2013-03-27 | 永虹科技股份有限公司 | Manufacture device of high-module graphite fibers |
| CN203212727U (en) * | 2013-03-19 | 2013-09-25 | 北京中丽制机工程技术有限公司 | Dual-purpose filament yarn drafting and winding device |
-
2017
- 2017-11-28 CN CN201711217325.5A patent/CN108085788A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006101084A1 (en) * | 2005-03-23 | 2006-09-28 | Bridgestone Corporation | Carbon fiber and processes for (continuous) production thereof, and catalyst structures, electrodes for solid polymer fuel cells, and solid polymer fuel cells, made by using the carbon fiber |
| CN1964584A (en) * | 2005-11-09 | 2007-05-16 | 刘秋雷 | A microwave heating device |
| CN202830266U (en) * | 2012-07-12 | 2013-03-27 | 永虹科技股份有限公司 | Manufacture device of high-module graphite fibers |
| CN203212727U (en) * | 2013-03-19 | 2013-09-25 | 北京中丽制机工程技术有限公司 | Dual-purpose filament yarn drafting and winding device |
Non-Patent Citations (2)
| Title |
|---|
| 张春红等编著: "《高分子材料》", 28 February 2016 * |
| 张智清等编著: "《商品知识》", 31 July 2002 * |
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Application publication date: 20180529 |
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