CN108022938A - A kind of manufacture method of semiconductor devices - Google Patents

A kind of manufacture method of semiconductor devices Download PDF

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Publication number
CN108022938A
CN108022938A CN201610927732.4A CN201610927732A CN108022938A CN 108022938 A CN108022938 A CN 108022938A CN 201610927732 A CN201610927732 A CN 201610927732A CN 108022938 A CN108022938 A CN 108022938A
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CN
China
Prior art keywords
wafer
method described
silicon oxide
oxide layer
etch
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610927732.4A
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Chinese (zh)
Inventor
张先明
詹扬
丁敬秀
李秀军
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Semiconductor Manufacturing International Shanghai Corp
Semiconductor Manufacturing International Beijing Corp
Original Assignee
Semiconductor Manufacturing International Shanghai Corp
Semiconductor Manufacturing International Beijing Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Semiconductor Manufacturing International Shanghai Corp, Semiconductor Manufacturing International Beijing Corp filed Critical Semiconductor Manufacturing International Shanghai Corp
Priority to CN201610927732.4A priority Critical patent/CN108022938A/en
Publication of CN108022938A publication Critical patent/CN108022938A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14683Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14601Structural or functional details thereof
    • H01L27/1464Back illuminated imager structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/14Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
    • H01L27/144Devices controlled by radiation
    • H01L27/146Imager structures
    • H01L27/14683Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
    • H01L27/14687Wafer level processing

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Electromagnetism (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Weting (AREA)

Abstract

The present invention provides a kind of manufacture method of semiconductor devices, the described method comprises the following steps:Wafer to be etched is provided, local laser annealing is carried out to the wafer, to form hot silicon oxide layer on the surface of the central area of the wafer;Spin etch is carried out to the wafer.Method using the present invention, compensates the total thickness variations of wafer, improves the performance of total thickness variations;And distributor need not be moved with 85% more than device wafers, expand process window;So as to also avoid the problem that the chuck damage thus brought, it is possible to achieve produce in enormous quantities.

Description

A kind of manufacture method of semiconductor devices
Technical field
The present invention relates to technical field of semiconductors, in particular to a kind of manufacture method of semiconductor devices.
Background technology
CIS (CMOS Image Sensor, cmos image sensor) device plays more next in our daily life More important role, it becomes in a variety of digital products such as mobile phone, laptop, digital camera, DV Essential element.And as the development of technology, people are also higher and higher to the quality requirement of display picture in digital product.Usually In the case of, imaging sensor is above illumination (Front Side Illumination, abbreviation FSI), photosensitive layer, metal layer, Jie Other optical elements such as electric layer and lenticule are set on a silicon substrate, and light reaches photosensitive through lenticule, metal layer, dielectric layer Layer.Due to the refraction of the obstruction and light of metal layer and dielectric layer, reflection etc., so as to get the light total amount up to photosensitive layer is greatly reduced, Such result is reduction of the sensitivity of imaging sensor.Higher sensitivity in order to obtain, backside illumination (Back Side Illumination, abbreviation BSI) technology is by development and application.BSI imaging sensors can provide higher sensing area ratio (fill Factor) and than relatively low destruction interference (destructive interference), its substrate is very thin, lens jacket, Photosensitive layer and metal layer, dielectric layer respectively on opposite two surfaces of silicon substrate, therefore by the substrate back side illuminaton into The light come directly reaches photosensitive layer by lenticule, avoids the obstruction of metal layer and dielectric layer, and less light is depleted, So that imaging sensor has higher sensitivity.
In the prior art, limited by chemical mechanical grinding and rotary wet-etching technology process, ground in chemical machinery After mill and wet method rotation etching, there are the total thickness variations of crystal round fringes in back-illuminated cmos image sensors (BSI CIS) The problem of (total thickness variation, TTV) is big." total thickness variations " are defined as the thick and most of wafer Absolute thickness between thin section point is poor.Because BSI imaging sensors use photodetector for backside-illuminated formula, if wafer thickness is uneven, Light incidence process is uneven, necessarily affects the photoelectric effect of BSI imaging sensors.I.e. total thickness variations conference influences the suction of light Receive, and cause the production loss of crystal round fringes, it is therefore desirable to which preceding working procedure and/or later process compensate it.Rotating , it is necessary to which distributor is moved to 85% more than wafer in formula wet etching, such as 95%, to make up the etching of crystal round fringes, and divide The maximum moving distance that orchestration allows is 85%;And in moving process, the chemical substance splashed backward passes through N2Hole enters, Cause chuck to damage, and then lead to not produce in enormous quantities.
It is an object of the invention to provide a kind of manufacture method of semiconductor devices, to solve above-mentioned technical problem.
The content of the invention
A series of concept of reduced forms is introduced in Summary, this will in specific embodiment part into One step describes in detail.The Summary of the present invention is not meant to attempt to limit technical solution claimed Key feature and essential features, do not mean that the protection domain for attempting to determine technical solution claimed more.
In view of the deficiencies of the prior art, the present invention provides a kind of manufacture method of semiconductor devices, the described method includes:Carry For wafer to be etched, local laser annealing is carried out to the wafer, to form heat on the surface of the central area of the wafer Silicon oxide layer;Spin etch is carried out to the wafer.
Further, the etchant that the spin etch uses is tetramethylammonium hydroxide.
Further, it is additionally included in the edge etch step performed after the local laser annealing.
Further, the edge etch step carries out the fringe region of the wafer using the hot silicon oxide layer as mask Etching.
Further, the etchant that the edge etch step uses is tetramethylammonium hydroxide.
Further, the thickness that the edge etch step etching removes is 0-1 microns.
Further, the step of carrying out local laser annealing to the wafer includes the use of the edge of wafer described in masked Region, and the step of irradiate the wafer using laser.
Further, the wave-length coverage of laser used is in the local laser annealing:200-350nm.
Further, the thickness of the hot silicon oxide layer is 5-10nm.
Further, the width for not forming the fringe region of the hot silicon oxide layer on the wafer is 3-8mm.
Further, the step of removing the hot silicon oxide layer is further included before spin etch is carried out to the wafer.
In conclusion the method according to the invention, compensates the total thickness variations of wafer, gross thickness change is improved The performance of change;And distributor need not be moved with 85% more than device wafers, expand process window;So as to also avoid thus The problem of chuck damage brought, it is possible to achieve produce in enormous quantities.
Brief description of the drawings
The drawings below of the present invention is used to understand the present invention in this as the part of the present invention.Shown in the drawings of this hair Bright embodiment and its description, principle used to explain the present invention.
In attached drawing:
Fig. 1 is the technical process schematic diagram of the semiconductor devices of the present invention.
The schematic cross section that the step of Fig. 2 is and is implemented successively according to the method for the exemplary embodiment of the present invention obtains respectively Figure.
Embodiment
In the following description, a large amount of concrete details are given in order to provide more thorough understanding of the invention.So And it is obvious to the skilled person that the present invention may not need one or more of these details and be able to Implement.In other examples, in order to avoid with the present invention obscure, for some technical characteristics well known in the art not into Row description.
In order to thoroughly understand the present invention, detailed step will be proposed in following description, to explain proposition of the present invention Semiconductor devices manufacture method.Obviously, execution of the invention is not limited to the technical staff of semiconductor applications and is familiar with Specific details.Presently preferred embodiments of the present invention is described in detail as follows, but in addition to these detailed descriptions, the present invention can be with With other embodiment.
It should be appreciated that when the term " comprising " and/or " including " is used in this specification, it is indicated described in presence Feature, entirety, step, operation, element and/or component, but do not preclude the presence or addition of other one or more features, entirety, Step, operation, element, component and/or combinations thereof.
The manufacture method of semiconductor devices according to prior art, by chemical mechanical grinding and rotary wet-etching technology The limitation of process, back-illuminated cmos image sensors occur crystal round fringes total thickness variations it is big the problem of, it is necessary to preceding working procedure And/or later process compensates it.In rotary wet etching, the linear velocity of crystal round fringes is high, wafer and etching liquid Time of contact it is short, etch period is short, and the etching rate of crystal round fringes is low, causes the TTV of wafer to be more than 0.3um, and desired TTV Less than 0.2um.Therefore, in rotary wet etching, it is necessary to distributor is moved to 85% more than wafer, such as 95%, come more The etching of crystal round fringes is mended, and the maximum moving distance that distributor allows is 85%;And in moving process, splash backward Chemical substance passes through N2Hole enters, and causes chuck to damage, and then lead to not produce in enormous quantities.
Presence in view of the above problems, the present invention propose a kind of manufacture method of semiconductor devices, as shown in Figure 1, its Including following key step:
In step S101, there is provided wafer to be etched, carries out local laser annealing, with the wafer to the wafer Hot silicon oxide layer is formed on the surface of central area;
In step s 102, spin etch is carried out to the wafer.
Further, the etchant that the spin etch uses is tetramethylammonium hydroxide.
Further, it is additionally included in the edge etch step performed after the local laser annealing.
Further, the edge etch step carries out the fringe region of the wafer using the hot silicon oxide layer as mask Etching.
Further, the etchant that the edge etch step uses is tetramethylammonium hydroxide.
Further, the step of carrying out local laser annealing to the wafer includes the use of the edge of wafer described in masked Region, and the step of irradiate the wafer using laser.
Further, the step of removing the hot silicon oxide layer is further included before spin etch is carried out to the wafer.
Manufacturing method according to the invention, compensates the total thickness variations of wafer, improves total thickness variations Performance;And distributor need not be moved with 85% more than device wafers, expand process window;So as to also avoid thus bringing Chuck damage the problem of, it is possible to achieve produce in enormous quantities.
Exemplary embodiment
With reference to Fig. 2A-Fig. 2 G, the step of method according to an exemplary embodiment of the present invention is implemented successively point illustrated therein is The schematic cross sectional view not obtained.
First, there is provided support wafer 200 and device wafers 201, and the device wafers 201 are bonded to the support crystalline substance On the surface of circle 200, its bonded interface is 202, as shown in Figure 2 A.
The device wafers are Silicon Wafer.In subsequent technique, support wafer provides mechanical support for thin device wafers, Device wafers are made not to be damaged.Device wafers and support wafer are combined, and are realized and interconnected by Si-O keys, the support wafer Silicon oxide layer of the bonding face formed with thermal oxide growth.
The bonding technology is thermal bonding, and during the thermal bonding, the bonding pressure of application is 1-10N, bonding time For 10-60s.Before two wafers are bonded, the wafer for being intended to bonding carries out wet clean process, attached to remove crystal column surface as far as possible The particle, impurity, chemical pollutant etc., to obtain preferably bonding interface, meet rigors of the bonding conditions to surface. The cleaning step carries out infiltration cleaning using deionized water (DI water) to device wafers, is then spin-dried for.As one A example, the rotating speed of the spinning step is 1000-3500rpm, time 1-5min.Above-mentioned process conditions are to illustrate Bright purpose, those skilled in the art can be adjusted as the case may be.
Next, the device wafers 201 are ground, to remove surface damage layer, as shown in Figure 2 B.Institute after grinding The thickness for stating device wafers is 1-10um.Ginding process used can be that mechanical milling method, chemical grinding method or chemical machinery are ground Mill method.The processing step of above-mentioned grinding has been known to those skilled in the art, and details are not described herein.
Then, chemical mechanical grinding step is performed to the device wafers 201, to improve the rough surface of device wafers Degree, as shown in Figure 2 C.After performing chemical mechanical grinding, the thickness of the device wafers is 1-7um.The numerical value only as an example, Can suitably it be adjusted according to specific device.The technical process of above-mentioned chemical mechanical grinding is the prior art, herein no longer Repeat.
Then, local laser annealing is carried out to the device wafers 201, with the central area of the device wafers 201 Surface on form hot silicon oxide layer 203, as shown in Figure 2 D.
The step of carrying out local laser annealing to the device wafers 201 includes the use of mask 204 and covers the wafer 201 Fringe region, and irradiate the wafer using laser.The fringe region of the hot silicon oxide layer is not formed on the wafer Width is 3-8mm.Therefore, in laser annealing, only the uncovered area of device wafers is exposed under laser.In atmosphere or In oxygen atmosphere, under the action of strong UV laser pulses, the oxide that thickness is about 40nm is produced, hot Si oxide Formation is attributed to absorption of the silicon to oxygen during surface melting.In the melting of recrystallization zone and again in process of setting, silicon leads to The oxygen of capture absorption is crossed, Quick Oxidation occurs, forms hot silicon oxide layer.Make the technique depth of laser annealing controllable, it is necessary to Laser with 200-350nm, therefore, the wave-length coverage of laser used is:200-350nm.After local laser annealing, the heat The thickness of silicon oxide layer is 5-10nm.Above-mentioned numerical value according to specific device only as an example, can suitably be adjusted.
Then, rotation etching is carried out to the edge of the device wafers 201, as shown in Figure 2 E.The edge etch is with institute Hot silicon oxide layer 203 is stated to be etched the fringe region of the device wafers 201 for mask.The edge etch step uses Etchant be tetramethylammonium hydroxide (TMAH), TMAH etching liquids are sprayed in the device wafers, by rotation make institute Etching liquid is stated to be uniformly distributed.TMAH is selected as wet etching liquid, this is because, first, not metal ion in TMAH will not Because foreign metal ion causes damage device wafers, secondly TMAH has the corrosion rate close with KOH and selection ratio, rotten Erosion surface effect is good, and last TMAH is nontoxic and pollution-free, easy to operate.Preferably, the concentration of TMAH is 5%-25%.TMAH is wet When method etches no longer because crystal orientation is different and etch rate etc., the surface obtained after TMAH wet etchings be it is smooth, it is each Region etch speed is identical, improves the reliability of device.
The thickness that the edge etch step etching removes is 0-1 microns, that is, after etching, the thickness of the device wafers 201 Spend for 1-6um.Numerical value according to specific device only as an example, can suitably be adjusted.Due in previous step, in device Part crystal circle center forms hot silicon oxide layer, in this step, using edge of the hot silicon oxide layer as mask to the wafer Region is etched.TMAH optionally etched edge silicon without etch center hot silicon oxide layer, therefore etch after device The edge of wafer is thinner than center, so as to be compensated to the TTV of device wafers.
Then, the device wafers are cleaned with hydrofluoric acid, to remove hot silicon oxide layer 203, as shown in Figure 2 F.It is excellent The hf etching liquid for selecting concentration to be 5%-10% performs etching.Certainly, can also use well known to those skilled in the art any Etching technics performs etching.
Then, spin etch is carried out to the device wafers 201, as shown in Figure 2 G.The etching that the spin etch uses Agent is TMAH.The thickness that the spin etch step etching removes is 0-1 microns, and after etching, the thickness of device wafers is 1- 5um.Numerical value according to specific device only as an example, can suitably be adjusted.In rotary wet etching, crystal round fringes Linear velocity it is high, the time of contact of wafer and etching liquid is short, etch period is short, and the etching rate of crystal round fringes is low, in view of above Technical process compensates TTV, and TTV is less than 0.2um after this step, meets the requirements, and improves TTV performances. And distributor need not be moved with 85% more than device wafers, expand process window.So as to it also avoid in moving process, The chemical substance splashed backward passes through N2Hole enters, the problem of causing chuck to damage, it is possible to achieve produces in enormous quantities.
Finally, ion implanting and laser annealing step are performed to the device wafers.In the ion implanting, injection from Son is boron ion.The purpose for performing ion implanting is to form doped layer.Perform annealing steps purpose be activation injection boron from Son.The energy of the ion implanting is 20-30KeV.The depth of the ion implanting reaches 700-1000 angstroms.In order to make below Laser annealing can allow boron atom to activate completely, and laser annealing energy demand is sufficiently large, be preferably greater than 2.0J/cm2.Above-mentioned number Value according to specific device only as an example, can suitably be adjusted.Formed after laser annealing in device wafers extra Component, such as, metal grate, colour filter, lenticule etc., are then cut saw and are separated into back-illuminated cmos image sensors core Piece.Specific technical process is with reference to the prior art, and details are not described herein.
In conclusion manufacturing method according to the invention, compensates the total thickness variations of wafer, improves total thickness Spend the performance of change;And distributor need not be moved with 85% more than device wafers, expand process window;So as to also avoid Thus the problem of chuck damage brought, it is possible to achieve produce in enormous quantities.
The present invention is illustrated by above-described embodiment, but it is to be understood that, above-described embodiment is only intended to Citing and the purpose of explanation, and be not intended to limit the invention in the range of described embodiment.In addition people in the art Member is it is understood that the invention is not limited in above-described embodiment, teaching according to the present invention can also be made more kinds of Variants and modifications, these variants and modifications are all fallen within scope of the present invention.Protection scope of the present invention by The appended claims and its equivalent scope are defined.

Claims (11)

1. a kind of manufacture method of semiconductor devices, it is characterised in that comprise the following steps:
Wafer to be etched is provided, local laser annealing is carried out to the wafer, with the surface of the central area of the wafer Form hot silicon oxide layer;
Spin etch is carried out to the wafer.
2. according to the method described in claim 1, it is characterized in that, the etchant that the spin etch uses is tetramethyl hydrogen-oxygen Change ammonium.
3. according to the method described in claim 1, it is characterized in that, it is additionally included in the edge performed after the local laser annealing Etching step.
4. according to the method described in claim 3, it is characterized in that, the edge etch step is using the hot silicon oxide layer to cover Film is etched the fringe region of the wafer.
5. according to the method described in claim 3, it is characterized in that, the etchant that the edge etch step uses is tetramethyl Ammonium hydroxide.
6. according to the method described in claim 3, it is characterized in that, the thickness that edge etch step etching removes is 0-1 Micron.
7. according to the method described in claim 1, it is characterized in that, the step of carrying out local laser annealing to the wafer includes Using the fringe region of wafer described in masked, and the step of irradiate the wafer using laser.
8. the method according to the description of claim 7 is characterized in that the local laser annealing in laser used wave-length coverage It is:200-350nm.
9. according to the method described in claim 1, it is characterized in that, the thickness of the hot silicon oxide layer is 5-10nm.
10. according to the method described in claim 1, it is characterized in that, the side of the hot silicon oxide layer is not formed on the wafer The width in edge region is 3-8mm.
11. according to the method described in claim 1, it is characterized in that, further included before spin etch is carried out to the wafer The step of removing the hot silicon oxide layer.
CN201610927732.4A 2016-10-31 2016-10-31 A kind of manufacture method of semiconductor devices Pending CN108022938A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113097068A (en) * 2021-03-31 2021-07-09 中国科学院微电子研究所 Method for manufacturing semiconductor device
CN117524870A (en) * 2023-12-29 2024-02-06 物元半导体技术(青岛)有限公司 Wafer processing method and wafer

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5863829A (en) * 1995-08-24 1999-01-26 Komatsu Electronic Metals Co., Ltd. Process for fabricating SOI substrate
CN102044430A (en) * 2009-10-23 2011-05-04 无锡华润上华半导体有限公司 Method for polishing wafer
CN102820218A (en) * 2011-06-08 2012-12-12 中芯国际集成电路制造(上海)有限公司 Thinning method of wafer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5863829A (en) * 1995-08-24 1999-01-26 Komatsu Electronic Metals Co., Ltd. Process for fabricating SOI substrate
CN102044430A (en) * 2009-10-23 2011-05-04 无锡华润上华半导体有限公司 Method for polishing wafer
CN102820218A (en) * 2011-06-08 2012-12-12 中芯国际集成电路制造(上海)有限公司 Thinning method of wafer

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113097068A (en) * 2021-03-31 2021-07-09 中国科学院微电子研究所 Method for manufacturing semiconductor device
CN117524870A (en) * 2023-12-29 2024-02-06 物元半导体技术(青岛)有限公司 Wafer processing method and wafer

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Application publication date: 20180511