CN108017288A - A kind of glass plate of the ink layer containing glare and preparation method thereof - Google Patents

A kind of glass plate of the ink layer containing glare and preparation method thereof Download PDF

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Publication number
CN108017288A
CN108017288A CN201610966778.7A CN201610966778A CN108017288A CN 108017288 A CN108017288 A CN 108017288A CN 201610966778 A CN201610966778 A CN 201610966778A CN 108017288 A CN108017288 A CN 108017288A
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China
Prior art keywords
layer
transparent photoresist
glass
glass plate
film plating
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Granted
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CN201610966778.7A
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CN108017288B (en
Inventor
周群飞
饶桥兵
周青
俞伟华
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Lens Technology Changsha Co Ltd
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Lens Technology Changsha Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • C03C17/3417Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials all coatings being oxide coatings

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention provides a kind of glass plate of the ink layer containing glare and preparation method thereof, the glass plate includes glass substrate, coated and UV exposures and thermosetting and bakes and be arranged on the transparent photoresist layer in glass substrate B faces, the film plating layer being arranged on transparent photoresist layer and the band color ink layer being arranged on film plating layer, the thickness of the transparent photoresist layer is 0.3~5 micron, the film plating layer includes three layers or more oxide sublayers, and the gross thickness of the film plating layer is 100~280nm.The transparent photoresist layer and translucent film plating layer that the present invention adds bring the ink colors of glare for glass plate, and coating process has no effect on the quality of glass product in the present invention, and transparent photoresist layer has good adhesion property and engaging force with glass baseplate and film plating layer.Therefore, the present invention successfully develops the A faces of glass panel or back-cover a kind of and shows the glass board material of glare or illusion-colour ink effect, and the glass board material also has the characteristics such as high-flatness, low roughness and high brightness.

Description

A kind of glass plate of the ink layer containing glare and preparation method thereof
Technical field
The invention belongs to the processing technique field of glass plate, and in particular to the glass plate and its system of a kind of ink layer containing glare Preparation Method.
Background technology
Glass is a kind of multi-functional oxide crystal for integrating excellent optical performance, physical property and chemical property, The glass tool of artificial has good wearability, while glass compactness makes it have larger surface tension, above-mentioned characteristic It is very suitable for the touch panel or back-cover of the electronic products such as mobile phone, wrist-watch, camera.
At present to using glass as the touch panel of material or the processing technology of back-cover, using conventional ink colorant work Skill, i.e., first in the B faces of panel or back-cover spraying (being adapted to 3D glass) or printing (being adapted to 2D glass) one layer of coloured oil Ink, then covers protectiveness ink layer on the ink of color, to form the glass product of appearance colored decoration.But this work The glass panel or back-cover color that skill obtains are dull, no metal-like, no glare effect.
Patent application CN201510114819.5 discloses a kind of preparation method of white frame in white OGS touch screen, bag Include following steps:A) cleaning touch-screen glass plate;B) in the first white ink of frame region silk-screen printing of touched panel glass plate Layer;C) in upper surface silk-screen printing the second white ink layer of the first white ink layer;D) cure;E) cleaning touch-screen glass Plate;F) painting black photoresist;G) precuring processing is carried out to black photoresist;H) expose;I) develop, form the black of frame shape Photoresist layer;J) curing process is carried out to black photoresist layer, completes the making of white frame;Sprayed using untouchable coating process Coating black photoresist, and the black photoresist layer positioned at the superiors is formed eventually through exposure imaging, avoid impurity being brought into product In;Black photoresist is not deflated substantially under high temperature plated film, and plated film film quality is greatly improved;In addition, black light antiplastering degree is low, can improve The finish of product surface;Inkjet printing energy selective dump black photoresists, save production cost.It is additionally included in this method The step of feature film plating layer is set on black photoresist layer.The setting of black photoresist is mainly used for lifting follow-up plating in this method The film quality of film.Any film layer is not provided between white ink layer and glass plate in the invention, thus can only from the A faces of glass plate See the color of the first white ink layer and the second white ink layer, that is to say, that the appearance color of its touch-screen is still slow-witted Stagnant white, without any glare effect.
With the raising that the development in glass processing field and user require, this area is it is necessary to provide one kind containing glare oil Glass plate of layer of ink and preparation method thereof.
The content of the invention
In order to enable the A faces of glass panel or back-cover (user's contact surface) shows the ink colors of glare, inventor Expect in glass substrate and with successively setting certain thickness transparent photoresist layer and translucent film plating layer between color ink layer.
Therefore, present invention firstly provides a kind of glass plate of ink layer containing glare, including glass substrate, coated and UV to expose Light and thermosetting bake and are arranged on the transparent photoresist layer in glass substrate B faces, film plating layer, the Yi Jishe being arranged on transparent photoresist layer The band color ink layer on film plating layer is put, the thickness of the transparent photoresist layer is 0.3~5 micron, and the film plating layer includes three Layer or more oxide sublayer, and the gross thickness of the film plating layer is 100~280nm.
Inventor has primarily looked at influence of the film plating layer gross thickness to sheet product, is less than in the gross thickness of film plating layer During 100nm, desired glare effect is extremely difficult to.And the gross thickness of film plating layer is when being more than 280nm, sheet product curing ink While glare is ineffective, when plated film, is also possible to produce injury to glass substrate.
In the present invention, the photoresist is also known as photoresist, it is broadly divided into opaque photoresist and transparent photoresist by transparency, Additionally translucent photoresist can be mixed by the two as needed.In the present invention, the transparent photoresist is formed after referring to curing Photoresist layer light transmittance be more than 95% photoresist, preferably its transmitance is more than 97%.And photoresist is divided into by exposure property Eurymeric photoresist and minus photoresist.Eurymeric photoresist is that it shines the part of light and can be dissolved in photoresist developer solution, the portion without shining light Photoresist developer solution will not be dissolved in by dividing.Minus photoresist is that it shines the part of light and will not be dissolved in photoresist developer solution, without shining light Part can be dissolved in photoresist developer solution.
The present inventor also once attempted to replace using the transparent material such as PU gloss oil and UV gloss oil saturating in the present invention Mingguang City hinders.But experiment is found, using PU gloss oil and UV gloss oil when transparent material, cushion that these materials are formed in itself it is saturating Light rate only up to reach 85% or so, and the light transmittance of sheet product will be finally greatly reduced in this, thus these materials are not The padded coaming being suitable as in the present invention.In addition, experiment is found, i.e., expose without UV after spraying at last and only baked through thermosetting The transparent photoresist layer arrived, its structure also with the structure of transparent photoresist layer in the present invention there are significant difference, the transparent photoresist layer Transmitance is unable to reach 97% or more.
In a kind of specific embodiment, the glass plate be electronic product display panel or back-cover, the band face The color of color ink layer is colored, black or white.
In a kind of specific embodiment, the film plating layer is set and is formed by silica and niobium pentaoxide alternating plating.
In a kind of specific embodiment, the thickness of the transparent photoresist layer is 0.5~3 micron, the film plating layer Thickness is 120~250nm.
In a kind of specific embodiment, the glass plate, which further includes, is arranged on the protectiveness oil with color ink layer Layer of ink.
In a kind of specific embodiment, the light transmittance of the transparent photoresist layer is more than 97%.
The present invention also provides a kind of preparation method of glass plate as described above, described method includes following steps:
Step a, clean the glass substrate and be coated with transparent photoresist in its B faces whole face, and pre-baked, UV is carried out to it and is exposed The transparent photoresist layer that light, optional development and thermosetting are shaped after baking,
Step b, plated film obtains the film plating layer on the transparent photoresist layer,
Step c, on the film plating layer, silk-screen or spraying ink obtain the band color ink layer,
And optional step d, silk-screen or sprayed protection ink obtain the protection on the band color ink layer Property ink layer.
In a kind of specific embodiment, pre-baked temperature is 90~120 DEG C in step a, the pre-baked time for 0.5~ 5min;The temperature that thermosetting is baked is 220~260 DEG C, and the thermosetting roasting time is 40~80min.
In a kind of specific embodiment, the light transmittance of the transparent photoresist layer obtained after step a is more than 98%, preferably More than 99%.
Specifically, because glass substrate light transmittance itself is 92% or so, and the transmitance of transparent photoresist layer may be up to 99% Or more.Therefore, it is, for example, during the light transmittance for the glass plate that detection is provided with transparent photoresist layer:Wavelength 380-480nm, light transmittance 83.527-89.991%;Wavelength 480-580nm, light transmittance 89.991-91.527%;Wavelength 580-680nm, light transmittance 91.527-91.744%;Wavelength 680-780nm, light transmittance 91.744-91.326%.
In a kind of specific embodiment, the mode that transparent photoresist is coated with the glass substrate is using ink Jet equipment sprays transparent photoresist.
The present invention is glass in glass substrate and with the transparent photoresist layer and translucent film plating layer added between color ink layer Glass plate brings the ink colors of glare, and coating process has no effect on the quality of glass product in the present invention, transparent photoresist layer with Glass baseplate and film plating layer have good adhesion property and engaging force.Therefore, the present invention successfully develops a kind of glass panel Or the A faces of back-cover show the glass board material of glare or illusion-colour ink effect, and the glass board material also has high-flatness, low The characteristic such as roughness and high brightness.
Brief description of the drawings
Fig. 1 is the structure diagram of the 2D glass panels of the ink layer containing glare in the present invention,
Fig. 2 is the structure diagram of the 2D glass back-covers of the ink layer containing glare in the present invention.
In figure:1st, glass substrate, 2, transparent photoresist layer, 3, film plating layer, 4, band color ink layer, 5, protectiveness ink layer.
Embodiment
In the present invention, the B faces of the glass substrate refer to that it not direct when in for electronic product is contacted with user Simultaneously, and A faces refer to one side for directly being contacted with user.The transparent photoresist is commercially available acquires.
In the present invention, the transparent photoresist of coating is for example completed under ink jet equipment.
In the present invention, the translucent film layer plated includes at least three layers of oxide membranous layer, in a kind of embodiment, For SiO2And Nb2O5Cross-superimposed 4~7 layers.
In a kind of specific embodiment, the protectiveness ink layer is transparent ink layer.Known in the art, When the band color ink layer 4 is set for whole face, it is not related to development step in step a, and works as 4, the band color ink layer When being provided in the subregion in B faces, need to include development step in step a or after step c.
The present invention is specifically described by following embodiments, but protection scope of the present invention is not limited in following implementations Example.
Embodiment 1
The purpose of the present embodiment is that a kind of 2D glass panels of the layer of white ink containing glare are prepared.Contain on glass panel There are white rim area and transparent visual area.Its product structure figure is shown in Fig. 1.
Step a, clean the glass substrate and be coated with transparent photoresist in its B faces whole face, and it is pre- to the transparent photoresist layer Transparent photoresist layer (2) that is roasting, being exposed using light shield, shaped in rim area after development and thermosetting are baked,
Step b, on the transparent photoresist layer (2) by viewfinder area masking plated film thus the film plating layer is obtained in rim area (3), wherein first layer SiO2Thickness is 30nm, second layer Nb2O5Thickness is 25nm, third layer SiO2Thickness is 30nm, the 4th layer Nb2O5Thickness is 25nm, layer 5 SiO2Thickness is 30nm.
Step c, on the film plating layer (3), silk-screen white ink obtains the band color ink layer (4),
The 2D glass panel products of the layer of white ink containing glare are obtained after step c.
Or another preparation method can be taken in the present embodiment, include the following steps.
Step a2, clean the glass substrate and be coated with transparent photoresist in its B faces whole face, and it is pre- to the transparent photoresist layer It is roasting, using light shield expose and (do not develop after exposure) and thermosetting bake after obtain the transparent photoresist layer (2) that whole face shapes,
Step b2, on the transparent photoresist layer (2), whole face plated film thus obtains the film plating layer (3), wherein first layer SiO2Thickness is 50nm, second layer Nb2O5Thickness is 40nm, third layer SiO2Thickness is 60nm, the 4th layer of Nb2O5Thickness is 30nm。
Step c2, on the rim area of the film plating layer (3), silk-screen white ink obtains the band color ink layer (4), And develop to the transparent photoresist layer (2), remove the transparent photoresist and film plating layer of viewfinder area.
The 2D glass panel products of the layer of white ink containing glare are obtained after step c2.
It can be obtained using one of above two method of the present invention a kind of containing glare or illusion-colour white ink layer 2D glass panels.
Embodiment 2
The purpose of the present embodiment is that a kind of 3D glass panels of black ink layer containing glare are prepared.Contain on glass panel There are dark border area and transparent visual area.
Step a, clean the glass substrate and be coated with transparent photoresist in its B faces (concave surface of 3D glass panels) whole face, and It is pre-baked to the transparent photoresist layer, baked using light shield UV exposures, development and thermosetting after the transparent light shaped in rim area Resistance layer (2),
Step b, on the transparent photoresist layer (2) by viewfinder area masking plated film thus the film plating layer is obtained in rim area (3),
Step c, whole face spray black photoresist and obtained on the film plating layer (3) through pre-baked, exposed and developed in rim area To the band color ink layer (4) formed by the black photoresist.The 3D glass of the black ink layer containing glare is obtained after step c Panel.
Embodiment 3
The purpose of the present embodiment is that a kind of 3D glass back-covers of the layer of gold ink containing glare are prepared.Comprising whole in back-cover Face gold ink layer.
Step a, clean the glass substrate and be coated with transparent photoresist in its B faces (concave surface of 3D glass back-covers) whole face, and The transparent photoresist layer that, whole face UV exposure pre-baked to the transparent photoresist layer and thermosetting are shaped after baking in its B faces whole face (2),
Step b, whole face plated film obtains the film plating layer (3) on the transparent photoresist layer (2),
Step c, on the film plating layer (3), whole face spraying gold ink obtains band color ink layer (4),
Step d, on the band color ink layer (4), the transparent protectiveness ink of silk-screen obtains the protectiveness ink layer (5), the 3D glass back plates of the layer of gold ink containing glare are obtained.
Embodiment 4
The purpose of the present embodiment is that a kind of 2D glass back-covers of the layer of ink of blue oil containing glare are prepared.Comprising whole in back-cover Face blue oil layer of ink, its product structure figure are shown in Fig. 2.
Step a, clean the glass substrate and be coated with transparent photoresist in its B faces whole face, and it is pre- to the transparent photoresist layer The transparent photoresist layer (2) that roasting, whole face UV exposures and thermosetting are shaped after baking in its B faces whole face,
Step b, whole face plated film obtains the film plating layer (3) on the transparent photoresist layer (2),
Step c, on the film plating layer (3), whole face silk-screen blue ink obtains band color ink layer (4),
Step d, spray transparent protectiveness ink on the band color ink layer (4) and obtain the protectiveness ink layer (5), the 2D glass back plates of the layer of ink of blue oil containing glare are obtained after step d.
Comparative example 1
The purpose of the present embodiment is that a kind of 2D glass panels of layer containing white ink are prepared.Containing white on glass panel Color rim area and transparent visual area.
Step m, clean the glass substrate (1) and the rim area silk-screen white ink in its B face obtains the band color Ink layer (4), and selectively on the band color ink layer (4) of the rim area silk-screen protectiveness ink layer (5) and obtain The 2D glass panel products of the layer containing white ink.The white ink layer 2D glass panels obtained in comparative example 1, which do not have, dazzles Light or fantasy coloured effect.
Comparative example 2
The purpose of the present embodiment is that a kind of 2D glass panels of the layer of white ink containing glare are prepared.Contain on glass panel There are white rim area and transparent visual area.
Other steps in this example are consistent with embodiment 1, but first layer SiO during plated film in step b2Thickness is 60nm, the Two layers of Nb2O5Thickness is 60nm, third layer SiO2Thickness is 60nm, the 4th layer of Nb2O5Thickness is 50nm, layer 5 SiO2Thickness is 60nm.The gross thickness of film plating layer is 290nm.Obtained white ink layer 2D glass panels have glare or fantasy coloured effect, but outside Sight positive effect is poorer than the appearance in embodiment 1, and the thick film that plating is set produces sheet product larger injury, so Obtained sheet product quality is unable to reach customer requirement.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the invention, for the skill of this area For art personnel, the invention may be variously modified and varied.Within the spirit and principles of the invention, that is made any repaiies Change, equivalent substitution, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of glass plate of ink layer containing glare, including glass substrate (1), coated and UV exposures and thermosetting are baked and set Transparent photoresist layer (2) in glass substrate (1) B faces, the film plating layer (3) being arranged on transparent photoresist layer (2) and it is arranged on plating Band color ink layer (4) in film layer (3), the thickness of the transparent photoresist layer (2) is 0.3~5 micron, and the film plating layer includes Three layers or more oxide sublayers, and the gross thickness of the film plating layer is 100~280nm.
2. glass plate according to claim 1, it is characterised in that the glass plate is the display panel or the back of the body of electronic product Lid, the color of the band color ink layer (4) is colored, black or white.
3. glass plate according to claim 1, it is characterised in that the film plating layer is replaced by silica and niobium pentaoxide Plating sets to be formed.
4. glass plate according to claim 1, it is characterised in that the thickness of the transparent photoresist layer (2) is 0.5~3 micron, The thickness of the film plating layer is 120~250nm.
5. glass plate according to claim 1, it is characterised in that the glass plate, which further includes, is arranged on band color ink layer (4) the protectiveness ink layer (5) on.
6. the glass plate according to any one in Claims 1 to 5, it is characterised in that the printing opacity of the transparent photoresist layer (2) Rate is more than 97%.
7. the preparation method of glass plate according to any one in claim 1~6, it is characterised in that the described method includes Following steps:
Step a, clean the glass substrate and be coated with transparent photoresist in its B faces whole face, and pre-baked, UV exposures are carried out to it, can The transparent photoresist layer (2) that the development and thermosetting of choosing are shaped after baking,
Step b, plated film obtains the film plating layer (3) on the transparent photoresist layer (2),
Step c, on the film plating layer (3), silk-screen or spraying ink obtain the band color ink layer (4),
And optional step d, silk-screen or sprayed protection ink obtain the protectiveness on the band color ink layer (4) Ink layer (5).
8. preparation method according to claim 7, it is characterised in that pre-baked temperature is 90~120 DEG C in step a, pre-baked Time is 0.5~5min;The temperature that thermosetting is baked is 220~260 DEG C, and the thermosetting roasting time is 40~80min.
9. preparation method according to claim 7, it is characterised in that the printing opacity of the transparent photoresist layer (2) obtained after step a Rate is more than 98%, preferably more than 99%.
10. preparation method according to claim 7, it is characterised in that transparent photoresist is coated with the glass substrate Mode is to spray transparent photoresist using ink jet equipment.
CN201610966778.7A 2016-10-28 2016-10-28 Glass plate containing dazzling printing ink layer and preparation method thereof Active CN108017288B (en)

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CN108545964A (en) * 2018-06-08 2018-09-18 深圳市骏达光电股份有限公司 Mobile phone glass rear cover production method
CN111217536A (en) * 2020-01-06 2020-06-02 青岛锦绣前程节能玻璃有限公司 Colorful sunlight control coated glass and preparation method thereof
CN113630992A (en) * 2020-05-06 2021-11-09 Oppo广东移动通信有限公司 Preparation method of film-coated part, shell and electronic equipment
CN117430346A (en) * 2023-12-21 2024-01-23 浙江大华技术股份有限公司 Glass processing method, glass and image pickup device

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CN111217536A (en) * 2020-01-06 2020-06-02 青岛锦绣前程节能玻璃有限公司 Colorful sunlight control coated glass and preparation method thereof
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CN117430346A (en) * 2023-12-21 2024-01-23 浙江大华技术股份有限公司 Glass processing method, glass and image pickup device

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