CN107987919A - 一种环保高浓缩切削粉 - Google Patents

一种环保高浓缩切削粉 Download PDF

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CN107987919A
CN107987919A CN201711165034.6A CN201711165034A CN107987919A CN 107987919 A CN107987919 A CN 107987919A CN 201711165034 A CN201711165034 A CN 201711165034A CN 107987919 A CN107987919 A CN 107987919A
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周锐南
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/08—Solids

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  • Oil, Petroleum & Natural Gas (AREA)
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  • Lubricants (AREA)

Abstract

本发明涉及金属加工冷却技术领域，特别涉及一种环保高浓缩切削粉。该环保高浓缩切削粉，包括癸二酸3.5～4.5份、三乙醇胺硼酸酯1.5～3份、三异丙醇胺11～13.5份。本发明的有益效果是：生产工艺简单，卫生环保，对人体无害，便于运输，浓缩度、润滑度和抗磨度更高，生产成本低，适用范围更广。

Description

一种环保高浓缩切削粉
（一）技术领域
本发明涉及金属加工冷却技术领域，特别涉及一种环保高浓缩切削粉。
（二）背景技术
切削液是金属切削加工中重要的配套材料，使用金属切削液的目的就是降低切削力及刀具与工件之间的摩擦，及时带走切削区内产生的热量以及降低切削温度，减少刀具磨损，提高刀具耐用度，延长刀具使用寿命，从而提高生产效率，改善工件表面粗糙度，保证工件加工精度，达到最佳经济效果；切削液分为三大类：乳化油、合成切削液和微乳切削液，不同程度的含有矿物油、亚硝酸盐和重金属盐，以及对环境有害的氯、硫和磷等化合物，使用寿命短，对人体有害，易变质，在排放时对环境污染相当严重，不符合环保排放的要求；另外，现有的切削液大部分都是液体，使用比例一般是5%，用200升大桶盛装和运输，运输成本高。市场上也有一部分的粉状类切削液（兑水后为液体），但是在润滑度（PB）、抗磨度（PD）和浓缩度都比较低，达不到GB614485的国家标准，因此，市场上急需一种生产工艺简单，包装方便，高浓缩（兑水比例大），运输成本低，既节能环保，又对人体无害，同时又达到或超过GB614485的国家标准的切削粉。
（三）发明内容
本发明为了弥补现有技术的不足，提供了一种生产工艺简单、润滑度高、抗磨度高的环保高浓缩切削粉。
本发明是通过如下技术方案实现的：
一种环保高浓缩切削粉，其特征在于：按重量份数计，由以下组分组成：癸二酸3.5～4.5份、三乙醇胺硼酸酯1.5～3份、三异丙醇胺11～13.5份。
一种环保高浓缩切削粉，其特征在于：按重量份数计，还包括以下组分：三元羧酸0.1～1.5份和苯骈三氮唑0.1～1份。
先将三异丙醇胺加热溶解后过筛，冷却，造粒（直径约0.5mm左右），制成白色粉末状，再按重量比例称取以上组分，均匀混合即为成品。
其中，三元羧酸为白色粉末状固体，与三异丙醇胺常温下进行酸碱反应起到防锈作用；癸二酸为白色晶体，与三异丙醇胺常温下进行酸碱反应起到防锈和润滑的作用；三乙醇胺硼酸酯为无色透明颗粒状固体，具有防锈可抗磨能力，与羧酸类防锈剂配合，防锈效果倍增；苯骈三氮唑为白色针状固体，常温下可溶于三异丙醇胺中，可以有效抑制铜的腐蚀，对防止钢铁氧化起辅助作用。
使用时，按重量混合组分：水=1:100的比例兑入水中，稍加搅拌自然溶解，即得到环保高浓缩切削液，直接在加床加工中使用。
本发明的有益效果是：通过将各个组分按照此质量份数混合后制成的切削粉，（1）生产工艺更加简单，直接按重量比混合均匀即可，不用加热，没有液体，生产过程没有“三废”产生；（2）包装运输方便，生产成本更低，可用塑料包装袋进行包装，避免了一般使用200升铁桶的包装，包装和运输成本大大降低；（3）绿色环保，本发明使用的原料，没有亚硝酸盐、重金属盐，没有矿物油，不含氯、硫和磷等对环境不友好的物质，是绿色环保产品；（4）使用范围更广，1:100比例兑水溶解后，润滑度（PB值40千克）、抗磨度（PD值120千克）、清洗、防锈和冷却的作用超过GB614485国家标准，可广泛用于车、钻、刨、磨、锯及数控机床、加工中心的切削、磨削加工，适合铸铁、碳钢和铜等材料的加工。
（四）具体实施方式
下面通过实施例对本发明做进一步说明，但本发明范围不受此限制。
实施例一：
一种环保高浓缩切削粉，按重量份数计，由以下组分组成：三元羧酸1kg、癸二酸4kg、三乙醇胺硼酸酯3kg、三异丙醇胺11kg和苯骈三氮唑1kg。
将以上组分按比例混合后，在终端客户使用时，常温常压下兑入2000kg水中，溶解后即可使用。
实施例二：
一种环保高浓缩切削粉（用于钢铁的加工），按重量份数计，由以下组分组成：三元羧酸1kg、癸二酸4kg、三乙醇胺硼酸酯2kg和三异丙醇胺13kg。
将以上组分按比例混合后，常温常压下兑入2000kg水中混合均匀，即得。
实施例三：
一种环保高浓缩切削粉（用于铜的加工），按重量份数计，由以下组分组成：癸二酸4kg、三乙醇胺硼酸酯1.5kg、三异丙醇胺13.5kg和苯骈三氮唑1kg。
将以上组分按比例混合后，常温常压下兑入2000kg水中混合均匀，即得。
通过以上实施例得到的切削液，测试切削后得到的性能指标，详见下表：
项目 质量指标 检测方法
外观 无色透明 目测
PH值 8～9 PH广泛试纸
腐蚀试验（48h） 合格 GB/T6144
防锈试验（48h） 无锈无印 GB/T6144
润滑度PB 40 四球机试验
抗磨度PD 120 四球机试验
通过上述实施例得到的切削液，经过四球机试验得出数据，此切削液的润滑度PB值可达到40，其抗磨度PD值可达到120，远远超过传统切削液的润滑度、抗磨度和防锈程度，并且此切削液在黑色金属和有色金属中均可使用，还可应用在煤矿液压支架、机械作业和冶金行业的液压***作传动介质。

Claims (4)

1.一种环保高浓缩切削粉，其特征在于：按重量份数计，由以下组分组成：癸二酸3.5～4.5份、三乙醇胺硼酸酯1.5～3份、三异丙醇胺11～13.5份。
2.根据权利要求1所述的环保高浓缩切削粉，其特征是：按重量份数计，还包括以下组分：三元羧酸0.1～1.5份和苯骈三氮唑0.1～1份。
3.根据权利要求2所述的环保高浓缩切削粉，其特征是：按重量份数计，由以下组分组成：三元羧酸1份、癸二酸4份、三乙醇胺硼酸酯3份、三异丙醇胺11份和苯骈三氮唑1份。
4.根据权利要求1所述的环保高浓缩切削粉，其特征是：所述三乙醇胺硼酸酯为固体。
CN201711165034.6A 2017-11-21 2017-11-21 一种环保高浓缩切削粉 Pending CN107987919A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560433A (zh) * 2009-05-11 2009-10-21 启东尤希路化学工业有限公司 抗镁硬水抗镁腐蚀环境友好型水溶性切削液
CN106479654A (zh) * 2016-09-06 2017-03-08 深圳市宏达威表面处理技术有限公司 水基金属切削液
CN106867643A (zh) * 2015-12-11 2017-06-20 史晓强 一种水基润滑液

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101560433A (zh) * 2009-05-11 2009-10-21 启东尤希路化学工业有限公司 抗镁硬水抗镁腐蚀环境友好型水溶性切削液
CN106867643A (zh) * 2015-12-11 2017-06-20 史晓强 一种水基润滑液
CN106479654A (zh) * 2016-09-06 2017-03-08 深圳市宏达威表面处理技术有限公司 水基金属切削液

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
黄胜: "《经营三十六计 创业卷》", 30 April 2000 *

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Application publication date: 20180504