CN107987742A - A kind of photovoltaic module panel Protection glue band and preparation method thereof and applying method - Google Patents

A kind of photovoltaic module panel Protection glue band and preparation method thereof and applying method Download PDF

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Publication number
CN107987742A
CN107987742A CN201711239889.9A CN201711239889A CN107987742A CN 107987742 A CN107987742 A CN 107987742A CN 201711239889 A CN201711239889 A CN 201711239889A CN 107987742 A CN107987742 A CN 107987742A
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CN
China
Prior art keywords
photovoltaic module
module panel
layer
film
adhesive
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Pending
Application number
CN201711239889.9A
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Chinese (zh)
Inventor
周琪权
李晓旭
陈洪野
芋野昌三
吴小平
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Suzhou Competition Application Technology Ltd By Share Ltd
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Suzhou Competition Application Technology Ltd By Share Ltd
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Priority to CN201711239889.9A priority Critical patent/CN107987742A/en
Publication of CN107987742A publication Critical patent/CN107987742A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/322—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of solar panels
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2400/00—Presence of inorganic and organic materials
    • C09J2400/10—Presence of inorganic materials
    • C09J2400/14—Glass
    • C09J2400/143—Glass in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2427/00—Presence of halogenated polymer
    • C09J2427/006—Presence of halogenated polymer in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2467/00—Presence of polyester
    • C09J2467/006—Presence of polyester in the substrate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Photovoltaic Devices (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of photovoltaic module panel Protection glue band, including substrate layer, adhesive layer and the release layer being equipped with successively；The substrate layer is made of high water resistant alumina-bearing material film, ultra-thin glass, long-acting weather-proof antifouling film or modified PET thin-film material, and the adhesive layer is made of long-term weatherability Bao Nianjiaoshui.A kind of photovoltaic module panel of present invention Protection glue band has weatherability (soda acid, damp and hot and ultraviolet), hydrolysis, keeps being combined firm, antifouling, high printing opacity, mechanical resistant scuffing with photovoltaic module panel for a long time; it is not easy chemical attack; do not glue grieshoch; ensure washing and wipe smoothly to remove, even if can also complete to clean during natural rainwater wind.

Description

A kind of photovoltaic module panel Protection glue band and preparation method thereof and applying method
Technical field
The present invention relates to tape technology field, more particularly to a kind of photovoltaic module panel Protection glue band and preparation method thereof And applying method.
Background technology
Photovoltaic module is formed by way of panel+encapsulation+battery+encapsulation+backboard/glass, wherein panel pair Light is transparent, backboard/glass it is transparent to light or it is impermeable can be with panel is vital, and light enters group by panel Part generates electricity.The use environment of photovoltaic module is varied, and the use being included in some adverse circumstances, diffuses in atmosphere A large amount of grieshoch, be in largely acid and alkali substance, metal oxide and high-molecular compound, make element panels surface there is ash Layer, silt and sulfur-bearing in air, containing materials such as iron powders.The cleaning of photovoltaic module panel mainly passes through washing, wind and wiping Wipe etc. and to carry out, can't often be washed off clearly for the metal ion that meta-acid meta-alkali rainwater and surface have, photovoltaic panel can be reduced Glass transmission rate, if things go on like this, the decay of photovoltaic module generating efficiency are more, even result in scrapping in advance for photovoltaic module, cause Owner's massive losses.
The content of the invention
In view of above-mentioned defect existing in the prior art, the purpose of the present invention is to propose to a kind of protection of photovoltaic module panel Adhesive tape and preparation method thereof and applying method.
To achieve these goals, present invention employs following technical solution：
A kind of photovoltaic module panel Protection glue band, including substrate layer, adhesive layer and the release layer being equipped with successively；It is described Substrate layer is made of high water resistant alumina-bearing material film, ultra-thin glass, long-acting weather-proof antifouling film or modified PET thin-film material, institute Adhesive layer is stated to be made of long-term weatherability Bao Nianjiaoshui.
Further, the high water resistant alumina-bearing material film is that the THIN COMPOSITE membranous type high water resistant being made of alumina-bearing material contains aluminium Material film, in the coextruded film type high water resistant alumina-bearing material film that the direct lamination polyolefins material of aluminum containing surface is formed, by What alumina-bearing material was formed is directly coated with any of application type high water resistant alumina-bearing material film of coating, or by described compound Film-type high water resistant alumina-bearing material film, coextruded film type high water resistant alumina-bearing material film and application type high water resistant alumina-bearing material are thin The cross-mixing type high water resistant alumina-bearing material film of any two kinds of compositions in film；
The THIN COMPOSITE membranous type high water resistant alumina-bearing material film includes the layer containing aluminium core of passivation and contains aluminium core described in being arranged at The composite film layer of layer one or both sides, the composite film layer are the weatherability fluorine being pasted on the film of the layer containing aluminium core Resin film is either the weather resistant coatings being coated on the film of the layer containing aluminium core or is resistance to ultraviolet weather-proof film；Institute Weatherability fluorine resin film is stated by polyvinyl fluoride, Kynoar, ethylene-tetrafluoroethylene copolymer, polytrifluorochloroethylene, poly- four Any of vinyl fluoride or ethylene-chlorotrifluoro-ethylene copolymer or a variety of compositions；The weathering resistance coatings are by fluorocarbon resin, propylene Any of acid resin, polyester resin, polyamide, polyurethane-type resin or epoxy resin or a variety of compositions, and lead to Curing agent solidification or direct lamination are crossed to the weatherability surface；The resistance to ultraviolet weather-proof film is sub- by polyester, polyolefin, polyamides Amine or any of polyamide-based or a variety of compositions；
The coextruded film type high water resistant alumina-bearing material film includes the layer containing aluminium core of passivation and is contained by lamination in described The weatherability fluororesin layer of aluminium core layer one or both sides, or not fluorine-containing polymer resin layer；The weatherability fluororesin layer by Polyvinyl fluoride, Kynoar, ethylene-tetrafluoroethylene copolymer, polytrifluorochloroethylene, polytetrafluoroethylene (PTFE) or ethene-trifluoro chlorine Any of ethylene copolymer or a variety of compositions；The not fluorine-containing polymer resin layer by polyester, polyolefin, polyimides or Any of polyamide or a variety of compositions；
The application type high water resistant alumina-bearing material film includes the layer containing aluminium core of passivation and by containing aluminium core coated on described The weatherability fluororesin layer of layer one or both sides, or not fluorine-containing polymer resin layer；The weatherability fluororesin layer is by fluorine carbon Resin is formed, and the not fluorine-containing polymer resin layer is by acrylic resin, polyester resin, polyamide, polyurethane-type resin Or any of epoxy resin or a variety of compositions, and pass through curing agent solidification or direct lamination to containing the aluminium core layer table Face.
Further, the long-acting weather-proof antifouling film is in PVF, PVDF, ETFE, PCTFE, PTFE, ECTFE One or more of high transparency fluorine films.
Further, the modified PET film is the PET film that cure process, AG processing or AR processing are carried out on surface.
Further, the long-term weatherability Bao Nianjiaoshui is silica gel pressure sensitive adhesive, acrylate pressure sensitive adhesive or polyurethane pressure sensitive Any one in glue；The curing agent that the long-term weatherability is protected in viscose glue water is selected from epoxy hardener, platinum catalyst, isocyanide One or more in acid esters curing agent；It is purple that the ultraviolet absorber that the long-term weatherability is protected in viscose glue water is selected from salicylic acid esters Outer absorbent.
A kind of photovoltaic module panel preparation method of Protection glue band, includes the following steps：
S1：Any one raw material in silica gel pressure sensitive adhesive, acrylate pressure sensitive adhesive or polyurethane contact adhesive is taken, is used Organic solvent is mixed evenly, and obtains elite stand fat；
S2：Elite stand fat made from step S1 is taken, is added selected from epoxy hardener, platinum catalyst, isocyanate curing agent In one or more curing agent, and add be selected from salicylate type ultraviolet absorbent, made after being mixed evenly Obtain adhesive mixed liquor；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 20 μ M-50 μm, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 30 DEG C -80 DEG C, curing is not When small less than 24.
A kind of photovoltaic module panel attaching process of Protection glue band, comprises the following steps：
Step 1：Cleaning treatment is carried out to the photovoltaic module face that need to be bonded；
Step 2：The photovoltaic module panel after cleaning treatment is bonded entirely with Protection glue band using photovoltaic module panel Or segmented conformable.
Further, the step 1 specifically includes as follows：
Photovoltaic module panel front is positioned on workbench by step 1) upward, with dust collection equipment to photovoltaic module face Plate surface carries out pre- dust suction processing；
Step 2) carries out dust removal process with hairbrush to photovoltaic module panel surface；
Step 3) cleans photovoltaic module panel surface with organic solvent；
Step 4) carries out dust suction with dust collection equipment to photovoltaic module panel surface；
The step 2 specifically includes as follows：
Photovoltaic module panel is cut into several sheet material by step 1) with Protection glue band；
1st sheet material is fitted in the lower end of photovoltaic module panel by step 2), and the short side of sheet material is along photovoltaic module panel Long side is paved, and the short side of the long edge photovoltaic module panel of sheet material is paved, and tears release layer from the centre of sheet material, while use pressure roller Or scraper plate fitting, the half of adhesive layer of sheet material is affixed on photovoltaic module panel, and remove adhesive layer and photovoltaic module Bubble between panel, repeats the above method, the another half of fitting of sheet material is completed, so as to complete the fitting of the 1st sheet material；
Step 3) repeat step 2), remaining sheet material is bonded successively, until conforming to the upper end of photovoltaic module panel；
Step 4) passes through silica gel or insulating cement between the edge of sheet material and the edge of parallel adjacent photovoltaic module panel Band is sealed；
Overlapping fitting successively between adjacent each sheet material, overlapping fitting width are more than or equal to 50mm.
Further, the step 1 specifically includes as follows：
Photovoltaic module panel front is positioned on workbench by step 1) upward, with cleaning solution to photovoltaic module panel Surface carries out cleaning dedusting；
Step 2) sprays suitable water in photovoltaic module panel surface；
The step 2 specifically includes as follows：
Step 1) cuts into photovoltaic module panel and photovoltaic module panel sheet material of the same size with Protection glue；
After sheet material is torn release layer by step 2), by the long side of sheet material and the long side of the photovoltaic module panel of surface spray water Alignment tiling, upper in tiling spray suitable water, are driven out of the moisture of sheet material and photovoltaic module panel with water squeezing scraper plate again, After moisture is driven out of, room temperature stands 24-72h；
Step 3) is carried out between the edge of the edge of sheet material surrounding and photovoltaic module panel by silica gel or insulating tape Sealing.
It is a kind of according to above-mentioned any application of the photovoltaic module panel Protection glue with attaching process, for photovoltaic module Panel is bonded or is replaced with the scene of Protection glue band.
The present invention protrusion effect be：
A kind of photovoltaic module panel Protection glue band and preparation method thereof and the applying method of the present invention, has following excellent Point：
1st, a kind of photovoltaic module panel of the invention Protection glue band has weatherability (soda acid, damp and hot and ultraviolet), water-fast Solution, long-term holding are combined firm, antifouling, high printing opacity with photovoltaic module panel, mechanical resistant scratches, and are not easy chemical attack, not viscous ash Layer, ensures washing and wipes smoothly to remove, even if can also complete to clean during natural rainwater wind；
2nd, glue used in adhesive layer of the invention is high transparency, high-weatherability, and not residue glue；
3rd, photovoltaic module panel Protection glue band of the invention can be when dispatching from the factory, can also power station scene into OK, it when generated energy is decreased obviously, can at any time regularly replace, ensure that component length is new；
4th, photovoltaic module panel Protection glue of the invention band attaching process mode can be comprehensive fitting or divide Section fitting, easy to operate, fitting is convenient.
Brief description of the drawings
Fig. 1 is the structure diagram of 1-14 of the embodiment of the present invention；
In figure：1 substrate layer, 2 adhesive layers, 3 release layers.
Embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.
Embodiment 1
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of ultra-thin glass, and adhesive layer 2 is made of long-term weatherability Bao Nianjiaoshui.
Wherein, long-term weatherability Bao Nianjiaoshui is silica gel pressure sensitive adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from Epoxy hardener；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is selected from salicylate type ultraviolet absorbent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Silica gel pressure sensitive adhesive raw material is taken, is mixed evenly using organic solvent, obtains elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from epoxy hardener, and add and be selected from salicylic acid Esters ultraviolet absorber, is made adhesive mixed liquor after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 20 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 30 DEG C, when curing 24 is small.
Embodiment 2
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of long-acting weather-proof antifouling film, and adhesive layer 2 protects viscose glue by long-term weatherability Water is formed.
Wherein, long-acting weather-proof antifouling film is selected from PVF high transparency fluorine films.
Long-term weatherability Bao Nianjiaoshui is silica gel pressure sensitive adhesive；The curing agent that long-term weatherability is protected in viscose glue water is consolidated selected from epoxy Agent；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is selected from salicylate type ultraviolet absorbent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from silica gel pressure sensitive adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from epoxy hardener, and add and be selected from salicylic acid Esters ultraviolet absorber, is made adhesive mixed liquor after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 30 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 40 DEG C, when curing 36 is small.
Embodiment 3
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of long-acting weather-proof antifouling film, and adhesive layer 2 protects viscose glue by long-term weatherability Water is formed.
Wherein, long-acting weather-proof antifouling film is the high transparency fluorine film formed selected from PVF and PVDF.
Long-term weatherability Bao Nianjiaoshui is acrylate pressure sensitive adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from epoxy Curing agent and platinum catalyst；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is selected from salicylate type ultraviolet absorbent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from acrylate pressure sensitive adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from epoxy hardener and platinum catalyst, Yi Jijia Enter to be selected from salicylate type ultraviolet absorbent, adhesive mixed liquor is made after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 40 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 500 DEG C, when curing 36 is small.
Embodiment 4
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of long-acting weather-proof antifouling film, and adhesive layer 2 protects viscose glue by long-term weatherability Water is formed.
Wherein, long-acting weather-proof antifouling film is the high transparency fluorine film selected from ETFE.
Long-term weatherability Bao Nianjiaoshui is polyurethane contact adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from platinum Catalyst；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is selected from salicylate type ultraviolet absorbent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from polyurethane contact adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from platinum catalyst, and add and be selected from salicylic acid Esters ultraviolet absorber, is made adhesive mixed liquor after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 50 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 60 DEG C, when curing 50 is small.
Embodiment 5
A kind of photovoltaic module panel of the present embodiment includes the substrate layer 1,2 and of adhesive layer that are equipped with successively with Protection glue band Release layer 3；Substrate layer 1 is made of long-acting weather-proof antifouling film, and adhesive layer 2 is made of long-term weatherability Bao Nianjiaoshui.
Wherein, long-acting weather-proof antifouling film is the high transparency fluorine film selected from PCTFE.
Long-term weatherability Bao Nianjiaoshui is silica gel pressure sensitive adhesive；The curing agent that long-term weatherability is protected in viscose glue water is urged selected from platinum One or more in agent and isocyanate curing agent；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is selected from salicylic acid Esters ultraviolet absorber.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from silica gel pressure sensitive adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from platinum catalyst and isocyanate curing agent, with And add and be selected from salicylate type ultraviolet absorbent, adhesive mixed liquor is made after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 20 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 70 DEG C, when curing 72 is small.
Embodiment 6
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of long-acting weather-proof antifouling film, and adhesive layer 2 protects viscose glue by long-term weatherability Water is formed.
Wherein, long-acting weather-proof antifouling film is the high transparency fluorine film selected from PTFE.
Long-term weatherability Bao Nianjiaoshui is acrylate pressure sensitive adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from isocyanide Acid esters curing agent；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is selected from salicylate type ultraviolet absorbent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from acrylate pressure sensitive adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from isocyanate curing agent, and add and be selected from water Poplar esters of gallic acid ultraviolet absorber, is made adhesive mixed liquor after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 25 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 80 DEG C, when curing 30 is small.
Embodiment 7
A kind of photovoltaic module panel of the present embodiment includes the substrate layer 1,2 and of adhesive layer that are equipped with successively with Protection glue band Release layer 3；Substrate layer 1 is made of long-acting weather-proof antifouling film, and adhesive layer 2 is made of long-term weatherability Bao Nianjiaoshui.
Wherein, long-acting weather-proof antifouling film is the high transparency fluorine film selected from ECTFE.
Long-term weatherability Bao Nianjiaoshui is polyurethane contact adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from isocyanide Acid esters curing agent；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is selected from salicylate type ultraviolet absorbent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from polyurethane contact adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent in isocyanate curing agent, and add and be selected from Salicylate type ultraviolet absorbent, is made adhesive mixed liquor after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 30 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 30 DEG C, when curing 36 is small.
Embodiment 8
A kind of photovoltaic module panel of the present embodiment includes the substrate layer 1,2 and of adhesive layer that are equipped with successively with Protection glue band Release layer 3；Substrate layer 1 is made of modified PET thin-film material, and adhesive layer 2 is made of long-term weatherability Bao Nianjiaoshui.
Wherein, modified PET film is to carry out the PET film of cure process on surface.
Long-term weatherability Bao Nianjiaoshui is silica gel pressure sensitive adhesive；The curing agent that long-term weatherability is protected in viscose glue water is consolidated selected from epoxy Agent；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is selected from salicylate type ultraviolet absorbent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from silica gel pressure sensitive adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from epoxy hardener, and add and be selected from salicylic acid Esters ultraviolet absorber, is made adhesive mixed liquor after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 35 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 80 DEG C, when curing 48 is small.
Embodiment 9
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of modified PET thin-film material, and adhesive layer 2 is by long-term weatherability Bao Nianjiaoshui Form.
Wherein, modified PET film is to carry out the PET film of AG processing on surface.
Long-term weatherability Bao Nianjiaoshui is acrylate pressure sensitive adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from platinum Catalyst；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is selected from salicylate type ultraviolet absorbent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from acrylate pressure sensitive adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from platinum catalyst, and add and be selected from salicylic acid Esters ultraviolet absorber, is made adhesive mixed liquor after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 40 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 50 DEG C, when curing 48 is small.
Embodiment 10
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of modified PET thin-film material, and adhesive layer 2 is by long-term weatherability Bao Nianjiaoshui Form.
Wherein, modified PET film is to carry out the PET film of AR processing on surface.
Long-term weatherability Bao Nianjiaoshui is polyurethane contact adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from epoxy Curing agent and isocyanate curing agent；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is absorbed selected from salicylate type ultraviolet Agent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from polyurethane contact adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from epoxy hardener and isocyanate curing agent, with And add and be selected from salicylate type ultraviolet absorbent, adhesive mixed liquor is made after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 50 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 60 DEG C, when curing 72 is small.
Embodiment 11
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of high water resistant alumina-bearing material film, and adhesive layer 2 is protected viscous by long-term weatherability Glue is formed.
Wherein, high water resistant alumina-bearing material film is that the THIN COMPOSITE membranous type high water resistant alumina-bearing material being made of alumina-bearing material is thin Film, THIN COMPOSITE membranous type high water resistant alumina-bearing material film include the layer containing aluminium core of passivation and are arranged at containing aluminium core layer one or both sides Composite film layer, composite film layer are the weatherability fluorine resin film being pasted on the film of the layer containing aluminium core, or to be coated on Weather resistant coatings on the film of the layer containing aluminium core, or be resistance to ultraviolet weather-proof film；Weatherability fluorine resin film by polyvinyl fluoride, Kynoar, ethylene-tetrafluoroethylene copolymer, polytrifluorochloroethylene, polytetrafluoroethylene (PTFE) or ethylene-chlorotrifluoro-ethylene copolymer Any of or a variety of compositions；Weathering resistance coatings are by fluorocarbon resin, acrylic resin, polyester resin, polyamide, polyurethane Any of type resin or epoxy resin or a variety of compositions, and pass through curing agent solidification or direct lamination to weatherability table Face；Resistance to ultraviolet weather-proof film is by polyester, polyolefin, polyimides or any of polyamide-based or a variety of form.
Long-term weatherability Bao Nianjiaoshui is polyurethane contact adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from epoxy Curing agent and isocyanate curing agent；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is absorbed selected from salicylate type ultraviolet Agent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from polyurethane contact adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from epoxy hardener and isocyanate curing agent, with And add and be selected from salicylate type ultraviolet absorbent, adhesive mixed liquor is made after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 50 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 60 DEG C, when curing 72 is small.
Embodiment 12
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of high water resistant alumina-bearing material film, and adhesive layer 2 is protected viscous by long-term weatherability Glue is formed.
Wherein, high water resistant alumina-bearing material film is the coextruded film formed in the direct lamination polyolefins material of aluminum containing surface Type high water resistant alumina-bearing material film, coextruded film type high water resistant alumina-bearing material film include the layer containing aluminium core of passivation and pass through lamination Weatherability fluororesin layer in containing aluminium core layer one or both sides, or not fluorine-containing polymer resin layer；Weatherability fluororesin layer by Polyvinyl fluoride, Kynoar, ethylene-tetrafluoroethylene copolymer, polytrifluorochloroethylene, polytetrafluoroethylene (PTFE) or ethene-trifluoro chlorine Any of ethylene copolymer or a variety of compositions；Not fluorine-containing polymer resin layer is by polyester, polyolefin, polyimides or polyamides Any of amine or a variety of compositions.
Long-term weatherability Bao Nianjiaoshui is polyurethane contact adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from epoxy Curing agent and isocyanate curing agent；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is absorbed selected from salicylate type ultraviolet Agent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from polyurethane contact adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from epoxy hardener and isocyanate curing agent, with And add and be selected from salicylate type ultraviolet absorbent, adhesive mixed liquor is made after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 50 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 60 DEG C, when curing 72 is small.
Embodiment 13
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of high water resistant alumina-bearing material film, and adhesive layer 2 is protected viscous by long-term weatherability Glue is formed.
Wherein, high water resistant alumina-bearing material film is the application type high water resistant of the direct coating coating by being formed containing alumina-bearing material Alumina-bearing material film, application type high water resistant alumina-bearing material film include the layer containing aluminium core of passivation and by coated on layers containing aluminium core one Side or the weatherability fluororesin layer of both sides, or not fluorine-containing polymer resin layer；Weatherability fluororesin layer is made of fluorocarbon resin, Not fluorine-containing polymer resin layer is by acrylic resin, polyester resin, polyamide, polyurethane-type resin or epoxy resin Any one or more compositions, and pass through curing agent solidification or direct lamination to layer surface containing aluminium core.
Long-term weatherability Bao Nianjiaoshui is polyurethane contact adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from epoxy Curing agent and isocyanate curing agent；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is absorbed selected from salicylate type ultraviolet Agent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from polyurethane contact adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from epoxy hardener and isocyanate curing agent, with And add and be selected from salicylate type ultraviolet absorbent, adhesive mixed liquor is made after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 50 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 60 DEG C, when curing 72 is small.
Embodiment 14
A kind of photovoltaic module panel Protection glue band of the present embodiment, as shown in Figure 1, including be equipped with successively substrate layer 1, Adhesive layer 2 and release layer 3；Substrate layer 1 is made of high water resistant alumina-bearing material film, and adhesive layer 2 is protected viscous by long-term weatherability Glue is formed.
Wherein, high water resistant alumina-bearing material film is thin by the THIN COMPOSITE membranous type high water resistant alumina-bearing material in embodiment 11-13 The friendship of any two kinds of compositions in film, coextruded film type high water resistant alumina-bearing material film and application type high water resistant alumina-bearing material film Pitch mixed type high water resistant alumina-bearing material film.
Long-term weatherability Bao Nianjiaoshui is polyurethane contact adhesive；The curing agent that long-term weatherability is protected in viscose glue water is selected from epoxy Curing agent and isocyanate curing agent；The ultraviolet absorber that long-term weatherability is protected in viscose glue water is absorbed selected from salicylate type ultraviolet Agent.
A kind of photovoltaic module panel preparation method of Protection glue band of the present embodiment, includes the following steps：
S1：Take and be selected from polyurethane contact adhesive raw material, be mixed evenly using organic solvent, obtain elite stand fat；
S2：Elite stand fat made from step S1 is taken, adds the curing agent selected from epoxy hardener and isocyanate curing agent, with And add and be selected from salicylate type ultraviolet absorbent, adhesive mixed liquor is made after being mixed evenly；
S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 50 μ M, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 60 DEG C, when curing 72 is small.
A kind of attaching process for photovoltaic module panel Protection glue band that embodiment 1-14 is prepared, including to cleaning at Photovoltaic module panel after reason carries out fitting or segmented conformable entirely.
The attaching process of segmented conformable includes the following steps：
Photovoltaic module panel front is positioned on workbench by step 1) upward, with dust collection equipment to photovoltaic module face Plate surface carries out pre- dust suction processing；
Step 2) carries out dust removal process with hairbrush to photovoltaic module panel surface；
Step 3) cleans photovoltaic module panel surface with organic solvent；
Step 4) carries out dust suction with dust collection equipment to photovoltaic module panel surface；
Photovoltaic module panel is cut into several sheet material by step 5) with Protection glue band；
1st sheet material is fitted in the lower end of photovoltaic module panel by step 6), and the short side of sheet material is along photovoltaic module panel Long side is paved, and the short side of the long edge photovoltaic module panel of sheet material is paved, and tears release layer from the centre of sheet material, while use pressure roller Or scraper plate fitting, the half of adhesive layer of sheet material is affixed on photovoltaic module panel, and remove adhesive layer and photovoltaic module Bubble between panel, repeats the above method, the another half of fitting of sheet material is completed, so as to complete the fitting of the 1st sheet material；
Step 7) repeat step 6), remaining sheet material is bonded successively, until conforming to the upper end of photovoltaic module panel；
Step 8) passes through silica gel or insulating cement between the edge of sheet material and the edge of parallel adjacent photovoltaic module panel Band is sealed；Overlapping fitting successively between adjacent each sheet material, overlapping fitting width are more than or equal to 50mm.
The attaching process being bonded entirely includes the following steps：
Photovoltaic module panel front is positioned on workbench by step 1) upward, with cleaning solution to photovoltaic module panel Surface carries out cleaning dedusting；
Step 2) sprays suitable water in photovoltaic module panel surface；
Step 3) cuts into photovoltaic module panel and photovoltaic module panel sheet material of the same size with Protection glue；
After sheet material is torn release layer by step 4), by the long side of sheet material and the long side of the photovoltaic module panel of surface spray water Alignment tiling, upper in tiling spray suitable water, are driven out of the moisture of sheet material and photovoltaic module panel with water squeezing scraper plate again, After moisture is driven out of, room temperature stands 24-72h；
Step 5) is carried out between the edge of the edge of sheet material surrounding and photovoltaic module panel by silica gel or insulating tape Sealing.
Test example
The effect of the present invention can be proved by following experiment：
To the performance detection of the photovoltaic module panel Protection glue band of the present invention
1st, sample
Made by oneself by embodiment 1-14.
2nd, test method
2.1 peel off 180 ° of peeling forces of force tester test sample
(1) web-like or sheet sample are taken, product is first cut into 25mm × 300mm size 3-5 bars.
(2) mirror steel plate：150 ± 1mm of length, 50 ± 1mm of width, thickness 1.5mm-2mm.
(3) one-faced tapes：The separated type material on adhesive tape is torn, glue surface cannot contact hand or other articles, by glue surface and mirror One end connection of face steel plate, with pressure roller (2Kg) in the case of external pressure is not applied, with the speed of 300mm/min 3 times back and forth so that Glue surface comes into full contact with mirror steel plate, and sample is not allow for bubble generation with mirror steel plate bonding place.
(4) sample is tested after preparing in defined test environment after parked 20min.
(5) by 180 ° of sample free end doubling, and binding face 25mm is peeled off from test plate (panel), sample free end and sample board It is clipped in respectively on upper and lower holder, release surface should be made to be consistent with the testing machine line of force, testing machine is with 300mm/min ± 10mm/ The min rates of climb are continuously peeled off, and have automatic recording instrument to draw stripping curve.
(6) record test data and destroy interface location, be averaged.
180 ° of peeling forces of force tester test sample are peeled off after 2.2 agings
(1) sample production method is consistent with the above.
(2) hot and humid 85 ± 2 DEG C are placed on after sample and mirror steel plate post, respectively, under 85 ± 5%R.H. environment 2000h, TC (- 40 DEG C~85 DEG C 6H/cycle, 200cycle) are placed, static 2h is taken out afterwards, uses above-mentioned peel test force Method is tested.
(3) record test data and destroy interface location, be averaged.
2.3 xanthochromia test methods
(1) adhesive tape is cut into 50mm*150mm samples (fluorine coating face is upper), tests b values with color difference meter and be recorded as b1.
(2) sample is put into QUV ultraviolet ageings testing machine (fluorine coating face is upper), according to UV100KWh, takes out sample again B values are tested with color difference meter and are recorded as b2.
(3) Δ b=b2-b1 is calculated.
3rd, result of the test
Result of the test is shown in Table 1, the results showed that：Photovoltaic module panel of the present invention has good caking property with Protection glue band Energy, weatherability, color inhibition.
1 photovoltaic module of the present invention of table repair sheets band the performance test results
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (10)

  1. A kind of 1. photovoltaic module panel Protection glue band, it is characterised in that：Including be equipped with successively substrate layer, adhesive layer and from Type layer；The substrate layer is by high water resistant alumina-bearing material film, ultra-thin glass, long-acting weather-proof antifouling film or modified PET film material Material is formed, and the adhesive layer is made of long-term weatherability Bao Nianjiaoshui.
  2. A kind of 2. photovoltaic module panel Protection glue band according to claim 1, it is characterised in that：The high water resistant contains aluminium Material film is the THIN COMPOSITE membranous type high water resistant alumina-bearing material film being made of alumina-bearing material, in the direct lamination polyene of aluminum containing surface The coextruded film type high water resistant alumina-bearing material film that hydro carbons material is formed, by the painting of the direct coating coating formed containing alumina-bearing material Any of type high water resistant alumina-bearing material film is covered, or by the THIN COMPOSITE membranous type high water resistant alumina-bearing material film, co-extrusion The cross-mixing of any two kinds of compositions in film-type high water resistant alumina-bearing material film and application type high water resistant alumina-bearing material film Type high water resistant alumina-bearing material film；
    The THIN COMPOSITE membranous type high water resistant alumina-bearing material film includes the layer containing aluminium core of passivation and is arranged at the layer containing aluminium core one Side or the composite film layer of both sides, the composite film layer are the weatherability fluororesin being pasted on the film of the layer containing aluminium core Film is either the weather resistant coatings being coated on the film of the layer containing aluminium core or is resistance to ultraviolet weather-proof film；It is described resistance to Time property fluorine resin film is by polyvinyl fluoride, Kynoar, ethylene-tetrafluoroethylene copolymer, polytrifluorochloroethylene, polytetrafluoroethyl-ne Any of alkene or ethylene-chlorotrifluoro-ethylene copolymer or a variety of compositions；The weathering resistance coatings are by fluorocarbon resin, acrylic acid tree Any of fat, polyester resin, polyamide, polyurethane-type resin or epoxy resin or a variety of compositions, and by solid Agent cures or directly lamination is to the weatherability surface；The resistance to ultraviolet weather-proof film by polyester, polyolefin, polyimides or Any of polyamide-based or a variety of compositions；
    The coextruded film type high water resistant alumina-bearing material film includes the layer containing aluminium core of passivation and contains aluminium core in described by lamination The weatherability fluororesin layer of layer one or both sides, or not fluorine-containing polymer resin layer；The weatherability fluororesin layer is by poly- fluorine Ethene, Kynoar, ethylene-tetrafluoroethylene copolymer, polytrifluorochloroethylene, polytetrafluoroethylene (PTFE) or ethylene-chlorinated Any of copolymer or a variety of compositions；The not fluorine-containing polymer resin layer is by polyester, polyolefin, polyimides or polyamides Any of amine or a variety of compositions；
    The application type high water resistant alumina-bearing material film includes the layer containing aluminium core of passivation and by coated on the layer containing aluminium core one Side or the weatherability fluororesin layer of both sides, or not fluorine-containing polymer resin layer；The weatherability fluororesin layer is by fluorocarbon resin Form, the not fluorine-containing polymer resin layer is by acrylic resin, polyester resin, polyamide, polyurethane-type resin or ring Any of oxygen type resin or a variety of compositions, and pass through curing agent solidification or direct lamination to the layer surface containing aluminium core.
  3. A kind of 3. photovoltaic module panel Protection glue band according to claim 1, it is characterised in that：It is described long-acting weather-proof anti- Dirty film is one or more of high transparency fluorine films in PVF, PVDF, ETFE, PCTFE, PTFE, ECTFE.
  4. A kind of 4. photovoltaic module panel Protection glue band according to claim 1, it is characterised in that：The modified PET is thin Film is the PET film that cure process, AG processing or AR processing are carried out on surface.
  5. A kind of 5. photovoltaic module panel Protection glue band according to claim 1, it is characterised in that：The long-term weatherability Bao Nianjiaoshui is any one in silica gel pressure sensitive adhesive, acrylate pressure sensitive adhesive or polyurethane contact adhesive；The long-term weatherability is protected One or more of the curing agent in epoxy hardener, platinum catalyst, isocyanate curing agent in viscose glue water；The length The ultraviolet absorber that phase weatherability is protected in viscose glue water is selected from salicylate type ultraviolet absorbent.
  6. 6. the preparation method of any photovoltaic module panel Protection glue band according to claim 1-5, it is characterised in that Include the following steps：
    S1：Any one raw material in silica gel pressure sensitive adhesive, acrylate pressure sensitive adhesive or polyurethane contact adhesive is taken, use is organic Solvent is mixed evenly, and obtains elite stand fat；
    S2：Elite stand fat made from step S1 is taken, is added in epoxy hardener, platinum catalyst, isocyanate curing agent One or more curing agent, and add and be selected from salicylate type ultraviolet absorbent, glue is made after being mixed evenly Glutinous agent mixed liquor；
    S3：Adhesive mixed liquor made from step S2 is coated on substrate layer, the dry glue thickness for obtaining adhesive layer is 20 μm -50 μm, and the substrate layer for being coated with adhesive mixed liquor one side is bonded with release layer, is placed at 30 DEG C -80 DEG C, curing is no less than 24 it is small when.
  7. 7. a kind of attaching process of photovoltaic module panel Protection glue band, it is characterised in that comprise the following steps：
    Step 1：Cleaning treatment is carried out to the photovoltaic module face that need to be bonded；
    Step 2：The photovoltaic module panel after cleaning treatment is carried out to be bonded entirely with Protection glue band using photovoltaic module panel or is divided Section fitting.
  8. A kind of 8. attaching process of photovoltaic module panel Protection glue band according to claim 7, it is characterised in that：The step One specifically include it is as follows：
    Photovoltaic module panel front is positioned on workbench by step 1) upward, with dust collection equipment to photovoltaic module panel table Face carries out pre- dust suction processing；
    Step 2) carries out dust removal process with hairbrush to photovoltaic module panel surface；
    Step 3) cleans photovoltaic module panel surface with organic solvent；
    Step 4) carries out dust suction with dust collection equipment to photovoltaic module panel surface；
    The step 2 specifically includes as follows：
    Photovoltaic module panel is cut into several sheet material by step 1) with Protection glue band；
    1st sheet material is fitted in the lower end of photovoltaic module panel by step 2), the long side of the short side of sheet material along photovoltaic module panel Pave, the short side of the long edge photovoltaic module panel of sheet material is paved, and tears release layer from the centre of sheet material, while with pressure roller or scrape Plate is bonded, and the half of adhesive layer of sheet material is affixed on photovoltaic module panel, and remove adhesive layer and photovoltaic module panel Between bubble, repeat the above method, the another half of fitting of sheet material completed, so as to complete the fitting of the 1st sheet material；
    Step 3) repeat step 2), remaining sheet material is bonded successively, until conforming to the upper end of photovoltaic module panel；
    Step 4) between the edge of sheet material and the edge of parallel adjacent photovoltaic module panel by silica gel or insulating tape into Row sealing；
    Overlapping fitting successively between adjacent each sheet material, overlapping fitting width are more than or equal to 50mm.
  9. A kind of 9. attaching process of photovoltaic module panel Protection glue band according to claim 7, it is characterised in that：The step One specifically include it is as follows：
    Photovoltaic module panel front is positioned on workbench by step 1) upward, with cleaning solution to photovoltaic module panel surface Carry out cleaning dedusting；
    Step 2) sprays suitable water in photovoltaic module panel surface；
    The step 2 specifically includes as follows：
    Step 1) cuts into photovoltaic module panel and photovoltaic module panel sheet material of the same size with Protection glue；
    After sheet material is torn release layer by step 2), the long side of sheet material is alignd with the long side of the photovoltaic module panel of surface spray water Tiling, upper in tiling spray suitable water, drive the moisture of sheet material and photovoltaic module panel out of with water squeezing scraper plate, wait to catch up with again After going out moisture, room temperature stands 24-72h；
    Step 3) is sealed between the edge of the edge of sheet material surrounding and photovoltaic module panel by silica gel or insulating tape.
  10. 10. a kind of any application of the photovoltaic module panel Protection glue with attaching process according to claim 7-9, its It is characterized in that：It is bonded or is replaced with the scene of Protection glue band for photovoltaic module panel.
CN201711239889.9A 2017-11-30 2017-11-30 A kind of photovoltaic module panel Protection glue band and preparation method thereof and applying method Pending CN107987742A (en)

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CN111002667A (en) * 2019-12-19 2020-04-14 宁波长阳科技股份有限公司 Release film and preparation method thereof
CN111002667B (en) * 2019-12-19 2022-03-08 宁波长阳科技股份有限公司 Release film and preparation method thereof
CN111073578A (en) * 2020-01-16 2020-04-28 广东安利华新材料科技有限公司 Protective film for high-temperature manufacturing process of liquid crystal display panel and preparation method
CN116864577A (en) * 2023-08-21 2023-10-10 新源劲吾(北京)科技有限公司 Film packaging equipment for color photovoltaics and application method

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Application publication date: 20180504