CN107759090A - A kind of glaze of imitative dark fund sand marbling effect and its application - Google Patents
A kind of glaze of imitative dark fund sand marbling effect and its application Download PDFInfo
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- CN107759090A CN107759090A CN201711166511.0A CN201711166511A CN107759090A CN 107759090 A CN107759090 A CN 107759090A CN 201711166511 A CN201711166511 A CN 201711166511A CN 107759090 A CN107759090 A CN 107759090A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Finishing Walls (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Abstract
The invention discloses a kind of glaze of imitative dark fund sand marbling effect and its application, the glaze of imitative dark fund sand marbling effect protects glaze, micaceous iron oxide, ceramics print cream to form by sand crystal.Raw material type needed for the glaze of the imitative dark fund sand marbling effect of the present invention is few, and aboundresources is cheap, preparation technology is simple, workable, has broken traditional burning process, special calcining system need not be formulated, enamel frit makeing cost is relatively low, is advantageous to energy-conserving and environment-protective.The glaze application method of the imitative dark fund sand marbling effect of the present invention is simple, improve technique by adjusting glaze formula, the glaze of the imitation marble effect of different-effect can be burnt out, the rich and varied of effect increases one of beautiful scenery again to Dali stone ceramic tile in construction sanitary ceramic industry.The method of the present invention, by adjusting the composition of glaze, the various glaze of organic assembling, has obtained unexpected decorative effect.
Description
Technical field
The present invention relates to ceramic field, the more particularly to a kind of glaze and its trailing of imitative dark fund sand marbling effect.
Background technology
Dark fund sand marble is a kind of mafic abyssal intrusion rock, and color is pitch black, mainly by the of substantially equal oblique side of content
Pyroxene and basic plagioclase composition, still there is the compositions such as a small amount of olivine, magnetic iron ore in addition, and clinquant gold sand is a kind of entitled
The mineral of bronzite.And imitative dark fund sand marbling effect glaze is one kind of artistic crystallization glaze, color is black, is carried in glaze
Some golden particulate matters, it appears that seem that gold paving in small, broken bits is sprinkled upon on the stone of black, especially beautiful, it can give yours
Building forms a perfect atmosphere, kitchen, cabinet table surface especially at you, designer can be allowed to have unlimited design spirit
Sense, and him can be allowed to become a reality.
CN106396740A disclose a kind of Galaxy Black glaze porcelain for being widely portable to the art pottery or Household ceramic and
Its manufacture craft.By the effect for being implemented in combination with Galaxy Black of ground-coat enamel and cover-coat enamel, the dark fund sand glaze porcelain burnt out has black
The background color of color, the Jinsha particle covered with Gold production on black background color, the Jinsha particle are viewed as polygon under the microscope
Particle, its reflecting effect is good, compared with the background color of black, has striking contrast, has unique artistic effect；In addition, should
The ground-coat enamel and cover-coat enamel of kind dark fund sand glaze porcelain are combined closely, service life length；The making of dark fund sand glaze porcelain provided by the invention
Technique, the effect of glaze paint can be adjusted by the formula and thickness of ground-coat enamel and cover-coat enamel so that the high yield rate of dark fund sand glaze, be burnt
It is low into temperature, energy-conserving and environment-protective are realized, reduce energy consumption.The technical scheme depends critically upon the complicated glaze of its composition.Meanwhile also need
To use complicated leaching glaze technique.The decoration of porcelain effect burnt till is poor, gold sand sense deficiency, without marmorean texture.Should
Glaze layer is also softer, and wearability is poor, limits its use range.
In addition, also having, part producer have developed dark fund fancy glaze, dark fund sand throws glaze (Portoro throwing glaze), but these glaze
The ceramic tile that material production obtains, only has certain dark fund sand decorative effect, heavy feeling is not strong, muddy without natural black gold sand marble
Thick, sedate sense.Meanwhile its production process needs strict control firing temperature, and it is very big to burn till difficulty.
How good decorating effect to be prepared, the glaze of the relatively simple imitative dark fund sand marbling effect of production technology, and
It is to have technical problem to be solved using the glaze decorative porcelain.
The content of the invention
Relatively easy, easy to use imitative dark fund sand marble decorative effect is formed it is an object of the invention to provide a kind of
Glaze.
It is another object of the present invention to provide a kind of ceramic preparation with imitative dark fund sand marble decorative effect
Technique.
The technical solution used in the present invention is：
A kind of glaze of imitative dark fund sand marbling effect, glaze, micaceous iron oxide, ceramics print cream is protected to form by sand crystal, sand
Crystalline substance protection glaze：Micaceous iron oxide：Print mass ratio=100 of cream：(10~40)：(50~80).
As the further improvement of above-mentioned glaze, the material quality composition of sand crystal protection glaze is：Albite is 40~60 parts,
Quartz is 5~15 parts, and kaolin is 5~12 parts, and fluorite is 3~8 parts, and wollastonite is 10~30 parts, and di-iron trioxide is 5~25
Part.Further, consisting of：Albite is 45~55 parts, and quartz is 8~12 parts, and kaolin is 7~9 parts, fluorite 5
~7 parts, wollastonite is 15~25 parts, and di-iron trioxide is 10~20 parts.
A kind of dark fund sand marbling effect ceramic tile, including base substrate, ground glaze layer, dark fund sand fancy glaze layer, imitative is followed successively by base substrate
Dark fund sand marbling effect glaze layer, sand crystal protection glaze layer and dark fund sand throw glaze layer, wherein, imitate dark fund sand marbling effect glaze and sand
The composition of crystalline substance protection glaze layer is as described above.
A kind of production technology of dark fund sand marbling effect ceramic tile, comprises the following steps：
1) water has been sprayed on base substrate, charity ground-coat enamel, has obtained ground glaze layer；
2) dark fund sand fancy glaze stamp is used on ground glaze layer, obtains printed layer；
3) the imitative imitative dark fund sand marbling effect glaze layer of dark fund sand marbling effect glaze printing is used in printed layer；
4) charity sand crystal protects glaze in imitative dark fund sand marbling effect glaze layer, obtains sand crystal protection glaze layer；
5) glaze is thrown in sand crystal protection glaze layer charity dark fund sand, obtains dark fund sand and throw glaze layer；
6) after drying, fire, post processing obtains dark fund sand marbling effect ceramic tile；
Wherein, the composition for imitating dark fund sand marbling effect glaze and sand crystal protection glaze layer is as described above.
As the further improvement of above-mentioned production technology, dark fund sand throws glaze thickness and throws the 1.5~2.5 of glaze thickness to be common
Times.
As the further improvement of above-mentioned production technology, the material quality composition that dark fund sand throws glaze is：Potassium feldspar 40~50
Part, 3~9 parts of kaolin, quartz 2~5 parts, 0~3 part of aluminum oxide, burn 2~8 parts of talcum, zinc oxide 1~6,2~8 parts of dolomite,
10~18 parts of barium sulfate, 2~8 parts of strontium carbonate, 4~10 parts of diopside.
The beneficial effects of the invention are as follows：
Raw material type needed for the glaze of the imitative dark fund sand marbling effect of the present invention is few, and aboundresources is cheap, prepares work
Skill is simple, workable, has broken traditional burning process, it is not necessary to special calcining system is formulated, enamel frit makeing cost is relatively low,
Be advantageous to energy-conserving and environment-protective.
The glaze application method of the imitative dark fund sand marbling effect of the present invention is simple, improves work by adjusting glaze formula
Skill, can burn out the glaze of the imitation marble effect of different-effect, and the rich and varied of effect is defended to Dali stone ceramic tile in building
Raw ceramic industry increases one of beautiful scenery again.
The method of the present invention, by adjusting the composition of glaze, the various glaze of organic assembling, has obtained unexpected decoration
Effect.
Brief description of the drawings
Fig. 1 and Fig. 2 is the dark fund sand marbling effect Ceramic Tiles photo that the present invention is prepared.
Embodiment
A kind of glaze of imitative dark fund sand marbling effect, glaze, micaceous iron oxide, ceramics print cream is protected to form by sand crystal, sand
Crystalline substance protection glaze：Micaceous iron oxide：Print mass ratio=100 of cream：(10~40)：(50~80).
Ceramics print cream is ceramics print cream commonly used in the art.
It is existing that sand crystal protects glaze to use, and particularly, as the further improvement of above-mentioned glaze, sand crystal protects glaze
Material quality forms：Albite is 40~60 parts, and quartz is 5~15 parts, and kaolin is 5~12 parts, and fluorite is 3~8 parts, silicon
Lime stone is 10~30 parts, and di-iron trioxide is 5~25 parts.Further, consisting of：Albite is 45~55 parts, quartz
For 8~12 parts, kaolin is 7~9 parts, and fluorite is 5~7 parts, and wollastonite is 15~25 parts, and di-iron trioxide is 10~20 parts.
A kind of dark fund sand marbling effect ceramic tile, including base substrate, ground glaze layer, dark fund sand fancy glaze layer, imitative is followed successively by base substrate
Dark fund sand marbling effect glaze layer, sand crystal protection glaze layer and dark fund sand throw glaze layer, wherein, imitate dark fund sand marbling effect glaze and sand
The composition of crystalline substance protection glaze layer is as described above.
A kind of production technology of dark fund sand marbling effect ceramic tile, comprises the following steps：
1) water has been sprayed on base substrate, charity ground-coat enamel, has obtained ground glaze layer；
2) dark fund sand fancy glaze stamp is used on ground glaze layer, obtains printed layer；
3) the imitative imitative dark fund sand marbling effect glaze layer of dark fund sand marbling effect glaze printing is used in printed layer；
4) charity sand crystal protects glaze in imitative dark fund sand marbling effect glaze layer, obtains sand crystal protection glaze layer；
5) glaze is thrown in sand crystal protection glaze layer charity dark fund sand, obtains dark fund sand and throw glaze layer；
6) after drying, fire, post processing obtains dark fund sand marbling effect ceramic tile；
Wherein, the composition for imitating dark fund sand marbling effect glaze and sand crystal protection glaze layer is as described above.
Ground-coat enamel is ground-coat enamel commonly used in the art, no particular/special requirement.It is that existing Portoro throws glaze that dark fund sand, which throws glaze, especially
, as the further improvement of above-mentioned production technology, the material quality composition that dark fund sand throws glaze is：40~50 parts of potassium feldspar, height
3~9 parts of ridge soil, 2~5 parts of quartz, 0~3 part of aluminum oxide, 2~8 parts of talcum of burning, zinc oxide 1~6,2~8 parts of dolomite, sulfuric acid
10~18 parts of barium, 2~8 parts of strontium carbonate, 4~10 parts of diopside.
As the further improvement of above-mentioned production technology, dark fund sand throws glaze thickness and throws the 1.5~2.5 of glaze thickness to be common
Times.
With reference to embodiment, technical scheme is further illustrated.In following examples, unless otherwise instructed,
Number is mass parts.
Sand crystal protects the composition of glaze：
| Numbering | Albite/part | Quartz/part | Kaolin/part | Fluorite/part | Wollastonite/part | Fe2O3/ part |
| A | 50 | 10 | 8 | 5 | 20 | 15 |
| B | 40 | 15 | 12 | 3 | 25 | 5 |
| C | 60 | 5 | 5 | 7 | 15 | 10 |
| D | 45 | 8 | 9 | 8 | 10 | 20 |
| E | 55 | 12 | 7 | 3 | 30 | 25 |
Number in table is mass parts, is well mixed by existing method, obtains sand crystal protection glaze.
For the sake of convenient comparison, the dark fund sand used in following examples throws the material quality composition of glaze：
45 parts of potassium feldspar, 6 parts of kaolin, 3 parts of quartz, 1.53 parts of aluminum oxide, 5 parts of talcum of burning, zinc oxide 4, dolomite 5
Part, 14 parts of barium sulfate, 5 parts of strontium carbonate, 7 parts of diopside.Those skilled in the art can also select other existing as needed
Dark fund sand throws glaze.
Embodiment 1
1) preparation of dark fund sand effect glaze：Dark fund sand glaze raw material is weighed by proportioning：100 parts of sand crystal protection glaze A, mica oxygen
Change 50 parts 20 parts of iron, print of cream；Add ball grinder fully to mix, pour out stand-by, i.e., obtained dark fund sand effect glaze；
2) imitative dark fund sand marbling effect glaze, then charity are printed again on the good ground-coat enamel of charity and the base substrate of Portoro glaze layer
Sand crystal protects glaze, and last one of Portoro of charity throws glaze, drying, enter in roller kilns and fire, and dark fund sand is obtained through following process
Marbling effect Ceramic Tiles.
Embodiment 2
1) preparation of dark fund sand effect glaze：Dark fund sand glaze raw material is weighed by proportioning：100 parts of sand crystal protection glaze B, mica oxygen
Change 60 parts 30 parts of iron, print of cream；Add ball grinder fully to mix, pour out stand-by, i.e., obtained dark fund sand effect glaze,
2) imitative dark fund sand marbling effect glaze, then charity are printed again on the good ground-coat enamel of charity and the base substrate of Portoro glaze layer
Sand crystal protects glaze, and last one of Portoro of charity throws glaze, drying, enter in roller kilns and fire, and dark fund sand is obtained through following process
Marbling effect Ceramic Tiles.
Embodiment 3
1) preparation of dark fund sand effect glaze：Dark fund sand glaze raw material is weighed by proportioning：100 parts of sand crystal protection glaze C, mica oxygen
Change 70 parts 10 parts of iron, print of cream；Add ball grinder fully to mix, pour out stand-by, i.e., obtained dark fund sand effect glaze；
2) imitative dark fund sand marbling effect glaze, then charity are printed again on the good ground-coat enamel of charity and the base substrate of Portoro glaze layer
Sand crystal protects glaze, and last one of Portoro of charity throws glaze, drying, enter in roller kilns and fire, and dark fund sand is obtained through following process
Marbling effect Ceramic Tiles.
Embodiment 4
1) preparation of dark fund sand effect glaze：Dark fund sand glaze raw material is weighed by proportioning：100 parts of sand crystal protection glaze C, mica oxygen
Change 80 parts 40 parts of iron, print of cream；Add ball grinder fully to mix, pour out stand-by, i.e., obtained dark fund sand effect glaze；
2) imitative dark fund sand marbling effect glaze, then charity are printed again on the good ground-coat enamel of charity and the base substrate of Portoro glaze layer
Sand crystal protects glaze, and last one of Portoro of charity throws glaze, drying, enter in roller kilns and fire, and dark fund sand is obtained through following process
Marbling effect Ceramic Tiles.
Embodiment 5
1) preparation of dark fund sand effect glaze：Dark fund sand glaze raw material is weighed by proportioning：100 parts of sand crystal protection glaze C, mica oxygen
Change 65 parts 25 parts of iron, print of cream；Add ball grinder fully to mix, pour out stand-by, i.e., obtained dark fund sand effect glaze；
2) imitative dark fund sand marbling effect glaze, then charity are printed again on the good ground-coat enamel of charity and the base substrate of Portoro glaze layer
Sand crystal protects glaze, and last one of Portoro of charity throws glaze, drying, enter in roller kilns and fire, and dark fund sand is obtained through following process
Marbling effect Ceramic Tiles.
Fig. 1 and Fig. 2 is the dark fund sand marbling effect Ceramic Tiles photo that Example 1 and Example 2 of the present invention is prepared.
It can be seen that glaze paint black is pure, clinquant gold sand is ensconced in glaze, and gold sand Ganfeng is expired, bright and glittering, has pole
Good decorative effect.
Claims (7)
1. a kind of glaze of imitative dark fund sand marbling effect, glaze, micaceous iron oxide, ceramics print cream is protected to form by sand crystal, sand crystal
Protect glaze：Micaceous iron oxide：Print mass ratio=100 of cream：(10~40)：(50~80).
2. glaze according to claim 1, it is characterised in that：The material quality of sand crystal protection glaze, which forms, is：Albite is
40~60 parts, quartz is 5~15 parts, and kaolin is 5~12 parts, and fluorite is 3~8 parts, and wollastonite is 10~30 parts, three oxidations two
Iron is 5~25 parts.
3. glaze according to claim 1, it is characterised in that：The material quality of sand crystal protection glaze, which forms, is：Albite is
45~55 parts, quartz is 8~12 parts, and kaolin is 7~9 parts, and fluorite is 5~7 parts, and wollastonite is 15~25 parts, three oxidations two
Iron is 10~20 parts.
4. a kind of dark fund sand marbling effect ceramic tile, including base substrate, it is characterised in that：Ground glaze layer, dark fund sand are followed successively by base substrate
Fancy glaze layer, imitative dark fund sand marbling effect glaze layer, sand crystal protection glaze layer and dark fund sand throw glaze layer, wherein, imitate dark fund sand marble
Effect glaze and the composition of sand crystal protection glaze layer are as described in any one of claims 1 to 3.
5. a kind of production technology of dark fund sand marbling effect ceramic tile, comprises the following steps：
1) water has been sprayed on base substrate, charity ground-coat enamel, has obtained ground glaze layer；
2) dark fund sand fancy glaze stamp is used on ground glaze layer, obtains printed layer；
3) the imitative imitative dark fund sand marbling effect glaze layer of dark fund sand marbling effect glaze printing is used in printed layer；
4) charity sand crystal protects glaze in imitative dark fund sand marbling effect glaze layer, obtains sand crystal protection glaze layer；
5) glaze is thrown in sand crystal protection glaze layer charity dark fund sand, obtains dark fund sand and throw glaze layer；
6) after drying, fire, post processing obtains dark fund sand marbling effect ceramic tile；
Wherein, imitate dark fund sand marbling effect glaze and sand crystal protects the composition of glaze layer as described in any one of claims 1 to 3.
6. production technology according to claim 5, it is characterised in that：The material quality of dark fund sand throwing glaze, which forms, is：Potassium is grown
40~50 parts of stone, 3~9 parts of kaolin, 2~5 parts of quartz, 0~3 part of aluminum oxide, 2~8 parts of talcum of burning, zinc oxide 1~6, white clouds
2~8 parts of stone, 10~18 parts of barium sulfate, 2~8 parts of strontium carbonate, 4~10 parts of diopside.
7. the production technology according to claim 5 or 6, it is characterised in that：Dark fund sand throws glaze thickness and throws glaze thickness to be common
1.5~2.5 times.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711166511.0A CN107759090B (en) | 2017-11-21 | 2017-11-21 | Glaze material with effect of imitating black gold sand marble and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711166511.0A CN107759090B (en) | 2017-11-21 | 2017-11-21 | Glaze material with effect of imitating black gold sand marble and application thereof |
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| CN107759090A true CN107759090A (en) | 2018-03-06 |
| CN107759090B CN107759090B (en) | 2020-12-01 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108756117A (en) * | 2018-04-28 | 2018-11-06 | 南安市创培电子科技有限公司 | A kind of ceramic tile and its production technology of imitative dark fund sand marbling effect |
| CN110423140A (en) * | 2019-06-26 | 2019-11-08 | 景德镇欧神诺陶瓷有限公司 | A kind of process using inkjet printing production Portoro |
| CN111689768B (en) * | 2020-06-28 | 2021-03-19 | 广西蒙娜丽莎新材料有限公司 | Co-firing method of whole-body ink-jet black golden flower fully-polished brick and common archaized brick |
| CN115611516A (en) * | 2022-12-09 | 2023-01-17 | 佛山市道氏科技有限公司 | Colored gold sand glaze and ceramic tile thereof |
| CN115849712A (en) * | 2022-12-14 | 2023-03-28 | 贵州亚泰陶瓷有限公司 | Black golden flower ceramic tile surface treatment glaze and method |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108756117A (en) * | 2018-04-28 | 2018-11-06 | 南安市创培电子科技有限公司 | A kind of ceramic tile and its production technology of imitative dark fund sand marbling effect |
| CN110423140A (en) * | 2019-06-26 | 2019-11-08 | 景德镇欧神诺陶瓷有限公司 | A kind of process using inkjet printing production Portoro |
| CN111689768B (en) * | 2020-06-28 | 2021-03-19 | 广西蒙娜丽莎新材料有限公司 | Co-firing method of whole-body ink-jet black golden flower fully-polished brick and common archaized brick |
| CN115611516A (en) * | 2022-12-09 | 2023-01-17 | 佛山市道氏科技有限公司 | Colored gold sand glaze and ceramic tile thereof |
| CN115611516B (en) * | 2022-12-09 | 2023-10-31 | 佛山市道氏科技有限公司 | Colored gold sand glaze and ceramic tile thereof |
| CN115849712A (en) * | 2022-12-14 | 2023-03-28 | 贵州亚泰陶瓷有限公司 | Black golden flower ceramic tile surface treatment glaze and method |
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