CN107699139B - A kind of super lapping liquid composition of water base environment-friendly antirust type and preparation and application - Google Patents
A kind of super lapping liquid composition of water base environment-friendly antirust type and preparation and application Download PDFInfo
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- CN107699139B CN107699139B CN201711070836.9A CN201711070836A CN107699139B CN 107699139 B CN107699139 B CN 107699139B CN 201711070836 A CN201711070836 A CN 201711070836A CN 107699139 B CN107699139 B CN 107699139B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B1/00—Processes of grinding or polishing; Use of auxiliary equipment in connection with such processes
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/14—Nitrogen-containing compounds
- C23F11/149—Heterocyclic compounds containing nitrogen as hetero atom
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- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
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Abstract
The invention discloses a kind of water base super lapping liquid composition of environment-friendly antirust type, constitutive material is nonionic or amphoteric surfactant, anion surfactant, belongs to complexing agent, boric acid, triethanolamine, silicate or molybdate, organic boronic amide, organic long-chain acid, lubricant, abrasive material, antifoaming agent, water, pH adjusting agent.A kind of environmentally-friendly water-based rust-proof type lapping liquid for steel ball grinding provided by the invention, have both it is excellent clean, cool down, lubricating, antirust function is integrated, be widely used in lappingout and the superfinishing polishing light processing of the steel ball of the materials such as carbon steel, stainless steel.
Description
Technical field
The present invention relates to a kind of super lapping liquid compositions, more particularly to a kind of for the environmentally-friendly water-based anti-of steel ball grinding
Rust type lapping liquid composition and preparation and application.
Background technology
The lapping process of steel ball with high precision is steel ball finishing process, needs to carry out steel ball surface using super lapping liquid
Small grinding repeatedly and reparation have met higher surface smoothness and geometric accuracy requirement, the type of skill of superfinishing grinding fluid
The surface quality of steel ball and efficiency are influenced with application method most important.The usual steel ball lappingout type of skill can be divided by carrier
Oil base lapping liquid and water base lapping liquid, and water base lapping liquid is divided into as emulsification lapping liquid and pure water lapping liquid.It is increasingly tight in environmental protection
Under the trend of lattice, meet the application value and social effect of the pure water lapping liquid of more performances of steel ball high-precision surface quality requirement
It is great.
Chinese patent CN 105440954A disclose a kind of steel ball smooth grinding lapping liquid and its preparation and application,
Including 10-20 parts of bentonites of parts by weight meter, 5-9 parts of coal dust, 15-20 parts of deionized waters, 1.5-2.5 parts of starch, 0.2-0.6
The sodium metasilicate, 0.4-0.8 parts of palmitic acid and 4-8 parts of titanium dioxide of part.The patent adds swelling using water as lapping liquid carrier
The constituents such as soil, coal dust, starch, titanium dioxide play the role of chronic grinding and polishing, but without lubrication as abrasive material
Property, rust-preventing characteristic and cleaning ability.
Chinese patent CN 101747864A disclose a kind of emulsion type lapping liquid for steel ball grinding, contain 70-75%
46# machinery oil, 25-30% oelic acids, 4-6% petroleum sodium sulfonates, 1-3% sorbitan monooleates, 5-8% polyoxy second
The potassium hydroxide of alkene castor oil, 2-4% triethanolamine oleates, 1.5-3% boric acid diethanol amine and 0.5-1%, while can add
Add chromium oxide suspension as abrasive material.The patent uses machinery oil as lapping liquid carrier, although with good lubricity, preventing
Rust property, but cleaning ability is general, and steel ball surface can remain more emulsification fluid after grinding, and the cleaning for increasing steel ball surface is negative
Load, there are certain harmfulness to environment and human body for simultaneous oxidation chromium.
Chinese patent CN 101974295A disclose a kind of steel ball lapping liquid, contain tri- second oleate soaps of 8-12%, 10-
14% polyethylene glycol, 8-12% diethylene glycol (DEG)s, 0.5-1.5% glycerine, 6-7% detergents, 1.2-1.8% sodium nitrites, 0.8-
1.2% industrial sodium carbonate, the antifoaming agent of 0.8-1.2%, 55-60% water, while chrome green can be added and used as abrasive material
Process is ground in lappingout and superfinishing.The patent using sodium nitrite as antirust agent, using chrome green as abrasive material, to environment with
There are certain harmfulness for human body.
Invention content
Place against the above deficiency, the purpose of the present invention is to provide a kind of super lapping liquid of high-accuracy steel ball, collection is ground,
The functions such as cooling, cleaning, lubrication, antirust are integrated, not only meet steel ball smooth grinding and fine abrasive process high polishability
And high efficiency, and with antirust function between excellent sequence, be not necessarily to oiling antirust process, play and reduce process, shorten flow and
Cost-effective purpose, while reducing the harm to environment and human body.
Technical scheme of the present invention is summarized as follows：The water base super lapping liquid composition of environment-friendly antirust type, constitutive material each group
Point mass percent be：
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the nonionic or amophoteric surface active
Agent can natural degradation, selected from fatty alcohol polyoxyethylene ether, low bubble isomery alcohol, alkyl polyglycoside, saccharide fatty acid esters, beet
One kind in alkali, imidazoline, sulfamic acid.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the anion surfactant is can
Natural degradation, be phosphoric acid polyether ester sylvite.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the metal chelating agent are selected from ethylenediamine
One kind in four sodium of tetraacethyl or disodium ethylene diamine tetraacetate.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the silicate are sodium metasilicate, described
Molybdate is sodium molybdate.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the organic long-chain acid be selected from decanedioic acid,
One or two kinds of mixtures of isononanoic acid.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the lubricant are selected from diethylene glycol (DEG), organic
One or two kinds of mixtures of metaboric acid ester.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the abrasive material are selected from water-dispersion type nanometer
One kind in inorganic matter, organosilane-modified abrasive material.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the water-dispersion type nano-inorganic substance choosing
From nano silicon dioxide and its colloidal sol, nano aluminium oxide and its colloidal sol, nano zirconium dioxide and its colloidal sol, nano-titanium dioxide and
One kind in its colloidal sol.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the antifoaming agent are selected from organic-silicon-modified
Polyether antifoam agent.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the pH adjusting agent are monoethanolamine.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the organic boronic amide be boric acid with
The reaction product of hydramine.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the oxo solvent are dissident's glycol.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, the antirust agent be benzotriazole or
Its derivative, the antirust agent are a kind of antirust agent of non-ferrous metal.
Preferably, the super lapping liquid composition of water base environment-friendly antirust type, for achieving the above object, the present invention
Also provide a kind of preparation method of the super lapping liquid composition of water base environment-friendly antirust type, which is characterized in that include the following steps：
S1：The water for accounting for total Water 25~60% is heated to 80~140 DEG C, boric acid and three second are sequentially added by the proportioning
Hydramine reacts 0.5~2 hour；If when being reacted at temperature is more than 95 DEG C, need to be reacted in the equipment for having cooling for reflux；
S2：Be added surplus water, and cool to 60 DEG C hereinafter, by it is described proportioning add metal chelating agent, silicate or
One kind of molybdate, organic long-chain acid, antirust agent make it completely dissolved；
S3：One in anion surfactant, nonionic or amphoteric surfactant is sequentially added by the proportioning
Kind, oxo solvent, organic boronic amide, lubricant, abrasive material, antifoaming agent；
S4：It is to obtain the water base environment-friendly antirust type superfinishing to grind finally to adjust ranging from the 8.3 ± 0.2 of pH with pH adjusting agent
Liquid composition.
Preferably, the preparation method of the super lapping liquid composition of water base environment-friendly antirust type adds water in the S1
Heat reacts 0.5~1 hour to 130~140 DEG C, can prepare the high organic boronic amide of purity at this temperature, can be significantly
Increase rustless property, while the dosage of organic boronic amide in component can be reduced.
For achieving the above object, the present invention separately provides a kind of super lapping liquid composition user of water base environment-friendly antirust type
Method is used the super lapping liquid composition of water base environment-friendly antirust type with water by 3~10% directly dilution.
Preferably, in the super lapping liquid composition application method of water base environment-friendly antirust type, by the water base environmental protection
The super lapping liquid composition of rust-proof type is used with water by 5~10% directly dilutions, and antirust between the sequence of steel ball is directly affected using concentration
Time, if grinding requires antirust function between the sequence of steel ball simultaneously, 5~10% dilutions use, with raising during turnover or storage
Antirust ability.
Preferably, in the super lapping liquid composition application method of water base environment-friendly antirust type, the water is deionization
Water or desalted water, the μ s/cm of conductivity≤20.
The water base super lapping liquid composition of environment-friendly antirust type can be widely used for the lappingout of the steel ball of the materials such as carbon steel, stainless steel
With superfinishing polishing light processing, after steel ball lappingout is up to standard, oiling antirust process is further cleaned or increased without using cleaning agent, it can
Directly to carry out turnover, storage or transport between sequence, the anti-rust action of " water generation oil " is played.The super lapping liquid is cooling carry with water
The features such as body, chemical stability is good, non-hazardous to environment and human body, safe and convenient to use, have nontoxic, tasteless, low foam, can
Degradation, excellent cleaning penetrating power and antirust ability, proper lubrication extreme pressure abrasiveness, collection grinding, cooling, cleaning, lubrication and
Antirust multiple functions are integrated, and are improved surface quality of steel ball during smooth grinding and fine abrasive, are reduced Micro scratching, reach
The excellent combination of the high polishability of steel ball and high grinding efficiency；Antirust function between excellent sequence reaches oil-less rust-proofing mesh between steel ball sequence
, cleaning and antirust cost have been saved, the harm to environment is further reduced in terms of few process short route.
The present invention using water as coolant carrier, using can natural degradation nonionic surfactant, anion surface active
Agent, oxo solvent low bubble permeate emulsification, improve the cleaning ability of lapping liquid；Utilize long chain organic acid, boric acid and hydramine
Chemical reactant enhancing sodium molybdate and benzotriazole, meet the antirust requirement being had enough to meet the need between steel ball grinding process and sequence；It utilizes
The lubrication property of short chain alcohol and organic boric acid ester, provides suitable boundary lubrication and contact lubricates；Utilize nanometer abrasive, control mill
The amount of cutting and improve grinding efficiency, realize the super lapping process of steel ball to grinding, cooling, cleaning, lubrication, antirust performance requirement.
The beneficial effects of the invention are as follows：
(1) the super lapping liquid of the present invention is free of chromium oxide or chromium trioxide abrasive material, while contained mainly using water as coolant carrier
Surfactant or antirust agent all can effectively from degrade, it is non-hazardous to environment and human body；
(2) the super lapping liquid of the present invention integrates grinding, cooling, cleaning, lubrication and antirust multiple functions, reaches steel ball height
The excellent combination of polishability and high grinding efficiency；
(3) the super lapping liquid of the present invention further cleans or oiling antirust without using cleaning agent, meets and has enough to meet the need between steel ball sequence
Or storage antirust requirement.
Specific implementation mode
With reference to embodiment, the present invention is described in further detail, to enable those skilled in the art with reference to specification
Word can be implemented according to this.
Embodiment 1
The water base super lapping liquid composition of environment-friendly antirust type comprising by mass percentage：Fatty alcohol polyoxyethylene ether
0.5wt%；Phosphoric acid polyether ester sylvite 1.0wt%；Dissident glycol 2.0wt%, tetrasodium ethylenediamine tetraacetate 1.0wt%；Boric acid
4.0wt%；Triethanolamine 18.0wt%；Sodium metasilicate 2.0wt%；Organic boronic amide and diethylene glycol (DEG) amount to 6.0wt%；The last of the ten Heavenly stems two
Sour 2.8wt%；Benzotriazole 0.2wt%；Organic metaboric acid ester 9.0wt%；Nano silicon dioxide sol 15.0wt%；It is organic
Silicon-modified polyether antifoaming agent 0.005wt%；Water 38.5%；Monoethanolamine, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, includes the following steps：Weigh 125 grams of deionized waters
(ratio for accounting for total Water is 32.47%), is heated to 95 DEG C, 40 grams of boric acid is then added, 180 grams of triethanolamines are stirred to react 1
Hour；Remaining 260 grams of deionized waters are added, cool to 60 DEG C hereinafter, sequentially adding 10 grams of tetrasodium ethylenediamine tetraacetates, 20
Gram sodium metasilicate, 28 grams of decanedioic acid, 2 grams of benzotriazole are stirred to being completely dissolved；Sequentially add 10 grams of phosphoric acid polyether ester potassium
Salt, 5 grams of fatty alcohol polyoxyethylene ether, 20 grams of dissident's glycol, 60 grams of organic boronic amides, 30 grams of diethylene glycol (DEG)s, 60 grams of organic inclined boron
Acid esters, 150 grams of nano silicon dioxide sols, 0.05 gram of organosilicon modified polyether antifoaming agent；Finally with monoethanolamine tune pH=
8.5。
The application method of the water base super lapping liquid composition of environment-friendly antirust type：With water steel ball lapping process is used for by 3% dilution
In use.After steel ball grinding is up to standard, the dirts such as transfer or storage or the grinding impurity that washes with water steel ball surface between direct sequence
It contaminates object and carries out finished product packing.
Embodiment 2
The water base super lapping liquid composition of environment-friendly antirust type comprising by mass percentage：Fatty alcohol polyoxyethylene ether
0.5wt%；Phosphoric acid polyether ester sylvite 1.0wt%；Dissident's glycol 2.0wt%；Disodium ethylene diamine tetraacetate 1.0wt%；Boric acid
4.0wt%；Triethanolamine 18.0wt%；Sodium metasilicate 2.0wt%；Organic boronic amide 2.0wt%；Decanedioic acid 1.5wt%；Benzene
And triazole 0.1wt%；Organic metaboric acid ester 3.0wt%；Nano silicon dioxide sol 15.0wt%；Organosilicon modified polyether disappears
Infusion 0.005wt%；Water 49.9wt%；Monoethanolamine, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, includes the following steps：Weigh 125 grams of deionized waters
(ratio for accounting for total Water is 25.05%), is heated to 140 DEG C, then 40 grams of boric acid of addition in cooling and reflux device, 180 grams
Triethanolamine is stirred to react 0.5 hour；Remaining 374 grams of deionized waters are added, cool to 60 DEG C hereinafter, sequentially adding 10 grams
Disodium ethylene diamine tetraacetate, 20 grams of sodium metasilicates, 15 grams of decanedioic acid, 1 gram of benzotriazole are stirred to being completely dissolved；Add successively again
Enter 10 grams of phosphoric acid polyether ester sylvite, 5 grams of fatty alcohol polyoxyethylene ether, 20 grams of dissident's glycol, 20 grams of organic boronic amides, 30 grams have
Machine metaboric acid ester, 150 grams of nano silicon dioxide sols, 0.05 gram of organosilicon modified polyether antifoaming agent；Finally with monoethanolamine tune
PH=8.5.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：With water steel ball lapping process is used for by 4% dilution
In use.After steel ball grinding is up to standard, the dirts such as transfer or storage or the grinding impurity that washes with water steel ball surface between direct sequence
It contaminates object and carries out finished product packing.
Embodiment 3
The water base super lapping liquid composition of environment-friendly antirust type comprising by mass percentage：Fatty alcohol polyoxyethylene ether
0.4wt%；Phosphoric acid polyether ester sylvite 1.5wt%；Disodium ethylene diamine tetraacetate 1.0wt%；Boric acid 4.0wt%；Triethanolamine
20.0wt%；Sodium metasilicate 2.0wt%；Organic boronic amide 8.0wt%；Decanedioic acid 2.8wt%；Diethylene glycol (DEG) 6.0%；Nano oxygen
Change Aluminum sol 20.0wt%；Organosilicon modified polyether antifoaming agent 0.005wt%；Water 34.3wt%；Monoethanolamine, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, includes the following steps：Weigh 120 grams of deionized waters
(ratio for accounting for total Water is 34.99%), is heated to 80 DEG C, 40 grams of boric acid is then added, 200 grams of triethanolamines are stirred to react 1
Hour；Add remaining 223 grams of deionized waters, sequentially add 10 grams of disodium ethylene diamine tetraacetates, 20 grams of sodium metasilicates, 28 grams
Decanedioic acid, stirring is to being completely dissolved；Sequentially add 15 grams of phosphoric acid polyether ester sylvite, 4 grams of fatty alcohol polyoxyethylene ether, 80 grams have
Machine boric acid amide, 60 grams of diethylene glycol (DEG)s, 200 grams of nano alumina sols, 0.05 gram of organosilicon modified polyether antifoaming agent；It finally uses single
Ethanol amine tune pH=8.5.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：With water steel ball lapping process is used for by 5% dilution
In use.After steel ball grinding is up to standard, the dirts such as transfer or storage or the grinding impurity that washes with water steel ball surface between direct sequence
It contaminates object and carries out finished product packing.
Embodiment 4
The water base super lapping liquid composition of environment-friendly antirust type comprising by mass percentage：Alkyl polyglycoside 1.0wt%；Phosphorus
Polyether acid ester sylvite 2.0wt%；Disodium ethylene diamine tetraacetate 0.8wt%；Boric acid 3.5wt%；Triethanolamine 19.0wt%；Inclined silicon
Sour sodium 2.0wt%；Organic boronic amide 3.0wt%；Decanedioic acid 3.0wt%；Benzotriazole 0.2wt%, organic metaboric acid ester
3.0wt%；Nano alumina sol 18.0wt%；Organosilicon modified polyether antifoaming agent 0.005wt%；Water 44.5wt%；Dan Yi
Hydramine, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, includes the following steps：Weigh 160 grams of deionized waters
(ratio for accounting for total Water is 45.71%), is heated to 130 DEG C, 35 grams of boric acid is then added, 190 grams of triethanolamines are stirred to react 1
Hour；Remaining 285 grams of deionized waters are added, cool to 60 DEG C hereinafter, sequentially adding 8 grams of disodium ethylene diamine tetraacetates, 20
Gram sodium metasilicate, 30 grams of decanedioic acid, 2 grams of benzotriazole are stirred to being completely dissolved；Sequentially add 20 grams of phosphoric acid polyether ester potassium
Salt, 10 grams of alkyl polyglycosides, 30 grams of organic boronic amides, 30 grams of organic metaboric acid esters, 180 grams of nano alumina sols, 0.05 gram
Organosilicon modified polyether antifoaming agent；Finally with monoethanolamine tune pH=8.5.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：With water steel ball lapping process is used for by 6% dilution
In use.After steel ball grinding is up to standard, the dirts such as transfer or storage or the grinding impurity that washes with water steel ball surface between direct sequence
It contaminates object and carries out finished product packing.
Embodiment 5
The water base super lapping liquid composition of environment-friendly antirust type comprising by mass percentage：It lives on saccharide fatty acid esters surface
Property agent 0.2wt%；Phosphoric acid polyether ester sylvite 1.0wt%；Tetrasodium ethylenediamine tetraacetate 1.5wt%；Boric acid 3wt%；Triethanolamine
15wt%；Sodium molybdate 1wt%；Organic boronic amide 10wt%；Decanedioic acid and isononanoic acid 5wt%；Organic metaboric acid ester 8wt%；
Nano zircite colloidal sol 10wt%；Organosilicon modified polyether antifoaming agent 0.0025wt%；Water 45.3wt%；Monoethanolamine, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, includes the following steps：Weigh 200 grams of deionized waters
(ratio for accounting for total Water is 44.15%), is heated to 85 DEG C, 30 grams of boric acid is then added, 150 grams of triethanolamines are stirred to react 2
Hour；Remaining 253 grams of deionized waters are added, 15 grams of tetrasodium ethylenediamine tetraacetates, 10 grams of sodium molybdates, 20 grams of last of the ten Heavenly stems two are sequentially added
Acid, 30 grams of isononanoic acids, stirring is to being completely dissolved；Sequentially add 10 grams of phosphoric acid polyether ester sylvite, 2 grams of saccharide fatty acid esters surfaces are lived
Property agent, 100 grams of organic boronic amides, 80 grams of organic metaboric acid esters, 100 grams of nano zircite colloidal sols, 0.05 gram it is organic-silicon-modified
Polyether antifoam agent；Finally with monoethanolamine tune pH=8.5.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：With water steel ball lapping process is used for by 8% dilution
In use.After steel ball grinding is up to standard, the dirts such as transfer or storage or the grinding impurity that washes with water steel ball surface between direct sequence
It contaminates object and carries out finished product packing.
Embodiment 6
The water base super lapping liquid composition of environment-friendly antirust type comprising by mass percentage：Beet alkali surface activator
0.8wt%；Phosphoric acid polyether ester sylvite 1.5wt%；Tetrasodium ethylenediamine tetraacetate 2.0wt%；Boric acid 3.5wt%；Triethanolamine
18.0wt%；Sodium molybdate 2.0wt%；Organic boronic amide 8.0wt%；Decanedioic acid 3.0wt%；Diethylene glycol (DEG) and organic metaboric acid ester
Total 9.0wt%；Nano-titanium oxide colloidal sol 15.0wt%；Organosilicon modified polyether antifoaming agent 0.002wt%；Water 37.2wt%；
Monoethanolamine, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, includes the following steps：Weigh 125 grams of deionized waters
(ratio for accounting for total Water is 33.60%), is heated to 85 DEG C, 35 grams of boric acid is then added, 180 grams of triethanolamines are stirred to react 1
Hour；Remaining 247 grams of deionized waters are added, 20 grams of tetrasodium ethylenediamine tetraacetates, 20 grams of sodium molybdates, 10 grams of last of the ten Heavenly stems two are sequentially added
Acid, 20 grams of isononanoic acids, stirring is to being completely dissolved；Sequentially add 15 grams of phosphoric acid polyether ester sylvite, 8 grams of beet alkali surface activators,
80 grams of organic boronic amides, 60 grams of diethylene glycol (DEG)s, 30 grams of organic metaboric acid esters, 150 grams of nano-titanium oxide colloidal sols, 0.05 gram of organosilicon
Modified polyether antifoaming agent；Finally with monoethanolamine tune pH=8.5.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：With water steel ball lapping process is used for by 10% dilution
In use.After steel ball grinding is up to standard, the dirts such as transfer or storage or the grinding impurity that washes with water steel ball surface between direct sequence
It contaminates object and carries out finished product packing.
Embodiment 7
The water base super lapping liquid composition of environment-friendly antirust type comprising by mass percentage：Imidazoline surfactant
0.5wt%；Phosphoric acid polyether ester sylvite 1.2wt%；Tetrasodium ethylenediamine tetraacetate 1.8wt%；Boric acid 4.0wt%；Triethanolamine
17.0wt%；Sodium metasilicate 2.8wt%；Organic boronic amide 10.0wt%；Decanedioic acid and isononanoic acid amount to 3.0wt%；Two is sweet
Alcohol 3.0wt%；Nano-titanium oxide colloidal sol 18.0wt%；Organosilicon modified polyether antifoaming agent 0.002wt%；Water 38.7wt%；It is single
Ethanol amine, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, includes the following steps：Weigh 200 grams of deionized waters
(ratio for accounting for total Water is 51.68%), is heated to 100 DEG C, then 40 grams of boric acid of addition in cooling and reflux device, 170 grams
Triethanolamine is stirred to react 1.5 hours；Remaining 187 grams of deionized waters are added, are cooled to 60 DEG C hereinafter, sequentially adding 18 grams of second
Four sodium of ethylenediamine tetraacetic acid (EDTA), 28 grams of sodium metasilicates, 12 grams of decanedioic acid, 18 grams of isononanoic acids, stirring is to being completely dissolved；12 grams of phosphoric acid are added
Polyether ester sylvite, 5 grams of imidazoline surfactants, 100 grams of organic boronic amides, 30 grams of diethylene glycol (DEG)s, 180 grams of nano-titanium oxides are molten
Glue, 0.02 gram of organosilicon modified polyether antifoaming agent；Finally with monoethanolamine tune pH=8.5.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：With water steel ball lapping process is used for by 7% dilution
In use.After steel ball grinding is up to standard, the dirts such as transfer or storage or the grinding impurity that washes with water steel ball surface between direct sequence
It contaminates object and carries out finished product packing.
Embodiment 8
The water base super lapping liquid composition of environment-friendly antirust type comprising by mass percentage：Sulfamic acid surfactant
1.0wt%；Phosphoric acid polyether ester sylvite 1.8wt%；Disodium ethylene diamine tetraacetate 1.6wt%；Boric acid 3.5wt%；Triethanolamine
19w.0t%；Sodium molybdate 2.0wt%；Organic boronic amide 6.0wt%；Isononanoic acid 2.0wt%；Diethylene glycol (DEG) 6.0wt%；Nano oxygen
Change zirconium colloidal sol 19.0wt%；Organosilicon modified polyether antifoaming agent 0.002wt%；Water 38.1wt%；Monoethanolamine, in right amount.
The preparation method of the water base super lapping liquid composition of environment-friendly antirust type, includes the following steps：Weigh 160 grams of deionized waters
(ratio for accounting for total Water is 41.99%), is heated to 95 DEG C, 35 grams of boric acid is then added, 190 grams of triethanolamines are stirred to react
1.5 hour；Remaining 221 grams of deionized waters are added, are cooled to 60 DEG C hereinafter, sequentially adding 20 grams of sodium molybdates, 16 grams of ethylenediamines
Tetraacethyl disodium, 20 grams of isononanoic acids, stirring is to being completely dissolved；18 grams of phosphoric acid polyether ester sylvite, 10 grams of sulfamic acid surfaces are added
Activating agent, 60 grams of organic boronic amides, 60 grams of diethylene glycol (DEG)s, 190 grams of nano zircite colloidal sols, 0.02 gram of organosilicon modified polyether disappear
Infusion；Finally with monoethanolamine tune pH=8.5.
The application method of the water base super lapping liquid composition of environment-friendly antirust type：With water steel ball lapping process is used for by 10% dilution
In use.After steel ball grinding is up to standard, the dirts such as transfer or storage or the grinding impurity that washes with water steel ball surface between direct sequence
It contaminates object and carries out finished product packing.
Although the embodiments of the present invention have been disclosed as above, but its is not only in the description and the implementation listed
With it can be fully applied to various fields suitable for the present invention, for those skilled in the art, can be easily
Realize other modification, therefore without departing from the general concept defined in the claims and the equivalent scope, the present invention is simultaneously unlimited
In specific details.
Claims (19)
1. a kind of super lapping liquid composition of water base environment-friendly antirust type, the mass percent of constitutive material each component are：
Can natural degradation 0.2~1.0wt% of nonionic or amphoteric surfactant；
Can natural degradation 1.0~2.0wt% of anion surfactant；
0~2.0wt% of oxo solvent；
0.8~2.0wt% of metal chelating agent；
3.0~4.0wt% of boric acid；
15.0~20.0wt% of triethanolamine；
1.0~2.8wt% of silicate or molybdate；
2.0~10.0wt% of organic boronic amide；
1.5~5.0wt% of organic long-chain acid；
0~0.2wt% of antirust agent；
3.0~9.0wt% of lubricant；
10.0~20.0wt% of abrasive material；
0.002~0.005wt% of antifoaming agent；
Water surplus；
Appropriate pH adjusting agent.
2. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the nonionic or two
Property surfactant be selected from fatty alcohol polyoxyethylene ether, low bubble isomery alcohol, alkyl polyglycoside, saccharide fatty acid esters, glycine betaine, imidazoles
One kind in quinoline, sulfamic acid.
3. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the anionic surface
Activating agent is phosphoric acid polyether ester sylvite.
4. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the metal chelating agent
One kind in tetrasodium ethylenediamine tetraacetate or disodium ethylene diamine tetraacetate.
5. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the silicate is inclined
Sodium metasilicate, the molybdate are sodium molybdate.
6. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the organic long-chain acid
One or two kinds of mixtures selected from decanedioic acid, isononanoic acid.
7. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the lubricant is selected from
One or two kinds of mixtures of diethylene glycol (DEG), organic metaboric acid ester.
8. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the abrasive material is selected from water
One kind of distributed nano-inorganic substance, organosilane-modified abrasive material.
9. the water base super lapping liquid composition of environment-friendly antirust type as shown in claim 8, which is characterized in that the water-dispersion type is received
Rice inorganic matter is selected from nano silicon dioxide and its colloidal sol, nano aluminium oxide and its colloidal sol, nano zirconium dioxide and its colloidal sol, nanometer
One kind in titanium dioxide and its colloidal sol.
10. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the antifoaming agent is
Organosilicon modified polyether antifoaming agent.
11. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the pH adjusting agent
For monoethanolamine.
12. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the organic boronic
Amide is the reaction product of boric acid and hydramine.
13. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the oxo solvent
For dissident's glycol.
14. the super lapping liquid composition of water base environment-friendly antirust type as shown in claim 1, which is characterized in that the antirust agent is
Benzotriazole or derivatives thereof.
15. a kind of system of the super lapping liquid composition of water base environment-friendly antirust type prepared described in any one of claim 1-14
Preparation Method, which is characterized in that include the following steps：
S1：The water for accounting for total Water 25 ~ 60% is heated to 80 ~ 140 DEG C, boric acid is sequentially added by the proportioning and triethanolamine is anti-
It answers 0.5 ~ 2 hour；
S2：The water of surplus is added, and cools to 60 DEG C hereinafter, adding metal chelating agent, silicate or molybdic acid by the proportioning
One kind of salt, organic long-chain acid, antirust agent make it completely dissolved；
S3：By it is described match sequentially add in anion surfactant, nonionic or amphoteric surfactant one kind, contain
Oxygen solvent, organic boronic amide, lubricant, abrasive material, antifoaming agent；
S4：Finally ranging from the 8.3 ± 0.2 of pH is adjusted with pH adjusting agent obtain the super lapping liquid combination of water base environment-friendly antirust type
Object.
16. the preparation method of the water base super lapping liquid composition of environment-friendly antirust type as claimed in claim 15, which is characterized in that institute
It states and heats the water to 130 ~ 140 DEG C in S1.
17. a kind of water base super lapping liquid composition of environment-friendly antirust type prepared described in any one of claim 1-14 makes
With method, it is characterised in that：The water base super lapping liquid composition of environment-friendly antirust type is used with water by 3 ~ 10% directly dilutions.
18. the application method of the water base super lapping liquid composition of environment-friendly antirust type as claimed in claim 17, which is characterized in that
The water base super lapping liquid composition of environment-friendly antirust type is used with water by 5 ~ 10% directly dilutions.
19. such as the application method of the super lapping liquid composition of the water base environment-friendly antirust type of claim 17-18 any one of them,
It is characterized in that, the water is deionized water or desalted water, the μ s/cm of conductivity≤20.
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| CN109810749B (en) * | 2019-03-04 | 2021-11-05 | 富莱德科技(浙江)有限公司 | Fully synthetic cutting fluid |
| CN110257150A (en) * | 2019-07-15 | 2019-09-20 | 海门市明珠钢球有限公司 | Steel ball grinding liquid and preparation method thereof |
| CN111849601A (en) * | 2020-08-11 | 2020-10-30 | 广州洛德化工科贸有限公司 | Low-temperature antirust agent suitable for fluorine-free refrigeration industry and preparation method and application thereof |
| CN111893490A (en) * | 2020-08-14 | 2020-11-06 | 北美防锈技术（上海）有限公司 | Environment-friendly water-based antirust agent |
| CN113061480B (en) * | 2021-03-31 | 2022-09-20 | 煤炭科学技术研究院有限公司 | Protective liquid for hydraulic system and preparation method and application thereof |
| CN114106702B (en) * | 2021-12-13 | 2022-11-18 | 广东凯盟钝化防锈技术有限公司 | Stainless steel fluid rough polishing wax and preparation method thereof |
| CN114921788B (en) * | 2022-07-21 | 2022-10-25 | 山东祺裕新材料有限公司 | Antirust composition material for hot-rolled pickled plate and application method thereof |
| CN115160985A (en) * | 2022-07-29 | 2022-10-11 | 南通山口精工机电有限公司 | G3-grade steel ball grinding fluid and preparation method thereof |
| CN115948193B (en) * | 2022-12-12 | 2024-06-11 | 上海纳米技术及应用国家工程研究中心有限公司 | Super-lubrication water-based cutting fluid and preparation method thereof |
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| KR100953264B1 (en) * | 2007-12-28 | 2010-04-16 | 셰플러코리아(유) | Water-based Grinding Fluid for manufacturing Bearing and the Method thereof |
| CN102102008B (en) * | 2009-12-18 | 2014-07-23 | 安集微电子（上海）有限公司 | Water-based glass grinding fluid and using method thereof |
| CN101747864B (en) * | 2009-12-21 | 2013-03-20 | 洛阳轴研科技股份有限公司 | Method for preparing and using emulsion type lapping liquid for steel ball grinding |
| CN101974295B (en) * | 2010-09-07 | 2013-04-24 | 安徽舒城云飞工贸有限公司 | Steel ball lapping liquid |
| CN102311718B (en) * | 2011-04-26 | 2014-04-30 | 东莞市安美润滑科技有限公司 | Aqueous grinding fluid applied to super precision grinding of hard and brittle materials and application method thereof |
| CN102796596A (en) * | 2011-05-27 | 2012-11-28 | 大连力鹏润滑油有限公司 | Energy-saving environmentally-friendly complete synthetic anticorrosive grinding and turning liquid |
| CN104017636B (en) * | 2014-06-06 | 2016-07-13 | 清华大学 | A kind of complete synthesis metal grinding fluid of water solublity |
| CN104087403A (en) * | 2014-07-29 | 2014-10-08 | 马思特（上海）化学有限公司 | Enhanced grinding fluid for protecting aluminum and preparation method thereof |
| CN105440954A (en) * | 2015-11-10 | 2016-03-30 | 铜陵市明诚铸造有限责任公司 | Grinding liquid for fine grinding of steel ball and preparation and use methods for grinding liquid |
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