CN107653469A - A kind of environment-friendly type electroplates glasses production technology - Google Patents

A kind of environment-friendly type electroplates glasses production technology Download PDF

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Publication number
CN107653469A
CN107653469A CN201710859451.4A CN201710859451A CN107653469A CN 107653469 A CN107653469 A CN 107653469A CN 201710859451 A CN201710859451 A CN 201710859451A CN 107653469 A CN107653469 A CN 107653469A
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China
Prior art keywords
substrate
environment
friendly type
precooling
plating
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CN201710859451.4A
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CN107653469B (en
Inventor
王为城
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XIAMEN LIYOUNG OPTICAL HI-TEC Co Ltd
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XIAMEN LIYOUNG OPTICAL HI-TEC Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/54Electroplating of non-metallic surfaces
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Eyeglasses (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

The present invention discloses a kind of production technology of environment-friendly type plating glasses, first cleans substrate by the ultrasonic oscillation added with basic surface inorganic agent;Substrate drying after cleaning, then precooling;The substrate after precooling is electroplated through dry type again;By added ultrasonic oscillation cleaning, drying, the precooling for having acidic surface inorganic agent of the substrate after plating;Substrate surface after plating precooling is subjected to intensive treatment, obtains environment-friendly type lens blank;Solidify again through heat energy, luminous energy, obtain environment-friendly type eyeglass.The present invention can protect electrodeposited coating, do not allow electrodeposited coating to be damaged, scratch, scratch, falling layer, by erosion equivalent damage, so protect eyes will not because electrodeposited coating damages and simultaneously by the stimulation of different transmitances caused by the injury such as dizziness.The use feeling of electrodeposition-type product and attractive in appearance is kept simultaneously, so as to increase the service life of product, reduces the environment-friendly type plating glasses of the wasting of resources, there is very big application value.

Description

A kind of environment-friendly type electroplates glasses production technology
Technical field
The invention belongs to the technical field of optical material, and glasses production technology is electroplated more particularly, to a kind of environment-friendly type.
Background technology
With social development progress, growth in the living standard, people come to realise the importance with eye health.So as to promote Enter the development of sunglasses, but in general sunglasses can not slowly meet the needs of popular.
Present people not only need glasses protective spectacles healthy, it is also necessary to wear fashion.So current fashion on the market Glasses are mainly based on electrodeposition-type sunglasses.Electrodeposition-type sunglasses can not only protect our glasses health, while outward appearance is more Gorgeous, colorful, fashion, so and the current first choice of people.
But current all electrodeposition-type sunglasses have one it is obvious the defects of.Because of the characteristic of electrodeposited coating, electricity is used in people Easily damage, scratch during plating type glasses, scratch, fall layer, by erosion equivalent damage, so as to influence people using sunglasses impression and U.S. See, and then influence the service life of sunglasses, cause the waste of resource not environmentally.Because electroplating the characteristic of sunglasses, same substrate Under, have that the eyeglass of plating is lower than the lens transmission rate of no plating, and to reduce the how many influence of transmissivity different for different electrodeposited coatings. Electrodeposition-type glasses for a long time with damage, because eyes receive the stimulation of different amounts of transmissivity and refractive index, human eye can be allowed Produce dizziness;Long periods of wear has the electrodeposition-type glasses of damage, or even produces injury to glasses.
Easily damage, scratch for electrodeposition-type eyewear products, scratch, fall layer, by erosion equivalent damage, the present invention thus produce.
The content of the invention
It is an object of the invention to provide a kind of environment-friendly type to electroplate glasses production technology, in the hope of that can protect the plating of glasses Layer, do not allow electrodeposited coating damaged, scratched, scratch, fall layer, by erosion equivalent damage, further protect eyes are not had because of electrodeposited coating The inconsistent generation that defect causes transmitance and refractive index to transmit into human eye stimulates, and avoids producing human eye dizziness or even injures, The use feeling of electrodeposition-type product and attractive in appearance is further kept, so as to increase the service life of product, reduces the wasting of resources.
In order to solve the above problems, the present invention adopts the following technical scheme that:
The present invention proposes that a kind of environment-friendly type electroplates the production technology of glasses, and its step is as follows:
Step 1, substrate is cleaned by 35 DEG C of cleaning fluid ultrasonic oscillations added with surface conditioning agent;Ultrasonic surface is clear Washing lotion is by sodium hydroxide, ethanol, AES(Sodium sulfate of polyethenoxy ether of fatty alcohol)、CDEA(Cocoanut fatty acid diethanolamide) With water by weight 0.6:8:1:0.8:89.6 are formulated;
Step 2, the substrate drying after cleaning, then precooling;
Step 3, then the substrate after precooling is electroplated through dry type;
Step 4, the added 35 DEG C of cleaning fluid ultrasonic oscillations for having surface conditioning agent of the substrate after plating are cleaned, dried, pre- It is cold;Ultrasonic surface cleaning fluid by sulfosuccinic acid alkyl alcohol ether ester sodium salt, 36.5% hydrochloric acid, AES, CDEA and water by weight 0.8:0.5:0.8:0.7:97.2 are formulated;
Step 5, step 4 is electroplated to the substrate surface after precooling and carries out intensive treatment, obtains environment-friendly type lens blank;
Step 6, the environment-friendly type lens blank obtained in step 5 is solidified through heat energy, luminous energy, obtains environment-friendly type eyeglass.
The step 5, the substrate that step 4 is electroplated after precooling is put into forced fluid or selfreparing forced fluid and soaked, is entered Row intensive treatment, obtain environment-friendly type lens blank.
The step 5, pre-set the rotational time, rotating speed, acceleration of spin coater;After step 4 is electroplated into precooling Substrate be put on spin coater, then forced fluid or selfreparing forced fluid are instilled on substrate;Start spin coater, by pre-setting Rotational time, rotating speed, acceleration rotation, obtain environment-friendly type lens blank.
After such scheme, the present invention take the lead in designing a kind of glasses that can protect electrodeposited coating, do not allow electrodeposited coating by To damaging, scratch, scratch, fall layer, by erosion equivalent damage, so protect eyes will not because electrodeposited coating damages and simultaneously by it is different thoroughly Cross the injury such as dizziness caused by the stimulation of rate.The use feeling of electrodeposition-type product and attractive in appearance is kept simultaneously, so as to increase product Service life, the environment-friendly type plating glasses of the wasting of resources are reduced, there is very big application value.
Brief description of the drawings
Fig. 1 electroplates Glasses structure 1 for a kind of environment-friendly type of the present invention;
Fig. 2 electroplates Glasses structure 2 for a kind of environment-friendly type of the present invention;
Fig. 3 is the TAC substrates of the present invention;
Fig. 4 is the TAC polarisation substrates of the present invention;
The PA+TAC that Fig. 5 is the present invention is molded substrate;
The PA+TAC polarisations that Fig. 6 is the present invention are molded substrate;
The PC+TAC that Fig. 7 is the present invention is molded substrate;
The PC+TAC polarisations that Fig. 8 is the present invention are molded substrate;
The PA polarisations that Fig. 9 is the present invention are molded substrate;
The PC polarisations that Figure 10 is the present invention are molded substrate.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right below in conjunction with drawings and Examples The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only to explain the present invention, not For limiting the present invention.As long as in addition, technical characteristic involved in each embodiment of invention described below that Conflict can is not formed between this to be mutually combined.
The present invention takes the lead in providing a kind of glasses that can protect electrodeposited coating, do not allow electrodeposited coating damaged, scratched, scratch, Fall layer, by erosion equivalent damage, further protect eyes not by caused by electrodeposited coating is defective because transmitance enters the inconsistent production of human eye Raw stimulation, dizziness is produced to human eye and even injured.The use feeling of electrodeposition-type product and attractive in appearance is further kept, so as to increase The service life of product, reduce the environment-friendly type plating glasses of the wasting of resources.
A kind of environment-friendly type plating glasses of the present invention, its structure 1 have as shown in Figure 1:Substrate layer, electrodeposited coating 1, electrodeposited coating 2, Protective layer 1, protective layer 2.Wherein substrate layer can be TAC materials, PC materials or nylon material etc. according to difference in functionality is compound or note Mould the substrate layer formed;It is electrodeposited coating 1 in the one side of substrate layer;It is protective layer 1 above electrodeposited coating 1;In the another of substrate layer It is simultaneously electrodeposited coating 2;It is protective layer 2 above electrodeposited coating 2.
Further, according to product function and customer demand, a kind of environment-friendly type of the invention plating glasses, its structure 2 such as Fig. 2 It is shown with:Substrate layer, electrodeposited coating 1, protective layer 1, protective layer 2.Wherein substrate layer can be TAC materials, PC materials or nylon material Deng according to the substrate layer that difference in functionality is compound or is molded;It is electrodeposited coating 1 in the one side of substrate layer;Above electrodeposited coating 1 For protective layer 1;It is protective layer 2 in the another side of substrate layer.
Substrate of the present invention, it can be divided into as shown in Figures 3 to 10 according to differences such as function, technique, customer demands TAC substrates, TAC polarisations substrate, PC, PA injection substrate, PC, PA injection polarisation substrate and PC or PA or TAC film hybrid substrate etc..
The present invention proposes that a kind of environment-friendly type electroplates the production technology of glasses, and its step is as follows:
Step 1, substrate is cleaned by the ultrasonic oscillation added with surface conditioning agent;
35 DEG C of ultrasonic surface cleaning fluids of this step are by sodium hydroxide, ethanol, AES, CDEA and water by weight 0.6:8:1: 0.8:89.6 are formulated;
The ultrasonic surface cleaning fluid of this step can effectively remove the impurity such as the organic and inorganic, dust of substrate layer adhering on surface band, Effectively pretreatment is provided to the quality of electroplating technology.
Table 1 is the ultrasonic surface cleaning fluid of this step and the comparison of comparative example.
Drawn from upper table data, in the 1st, 2,3 group of formula ratios, its semi-finished product electroplating quality produced and plating Layer fastness inequality, only in the 4th group of formula ratio of the invention, its semi-finished product electroplating quality produced and electrodeposited coating are 's.By studying test repeatedly, the 4th group of formula ratio only proposed by the present invention is most scientific, and could obtain optimal has Beneficial effect.
Step 2, the substrate drying after cleaning, then precooling;
Step 3, then the substrate after precooling is electroplated through dry type;
Step 4, by added ultrasonic oscillation cleaning, drying, the precooling for having surface conditioning agent of the substrate after plating;
35 DEG C of ultrasonic surface cleaning fluids of this step are by sulfosuccinic acid alkyl alcohol ether ester sodium salt, 36.5% hydrochloric acid, AES, CDEA With water by weight 0.8:0.5:0.8:0.7:97.2 are formulated;
Table 2 is the ultrasonic surface cleaning fluid of this step and the comparison of comparative example.
Drawn from above table data, in the 1st group of formula ratio, its finished product produced, electrodeposited coating fastness and product Matter is good, but strengthening layer fastness and poor quality;2nd group of formula ratio, its finished product produced, electrodeposited coating fastness and quality better, But strengthening layer fastness and poor quality;3rd group of formula ratio, its finished product produced, electrodeposited coating fastness is good, but poor quality, and Strengthening layer fastness and poor quality;Only in the 4th group of formula ratio of the invention, its finished product produced, electrodeposited coating fastness and product Matter is good and strengthening layer fastness and quality might as well.By studying test repeatedly, the 4th group of formula ratio only proposed by the present invention is most Science, optimal beneficial effect could be obtained.
Step 5, step 4 is electroplated to the substrate surface after precooling and carries out intensive treatment, obtains environment-friendly type lens blank;
This step has two kinds of specific situations, and a kind of is that the substrate that step 4 is electroplated after precooling is put into forced fluid or selfreparing reinforcing Soaked in liquid, carry out intensive treatment, obtain environment-friendly type lens blank;
Another kind is the rotational time, rotating speed, acceleration for pre-setting spin coater;The substrate that step 4 is electroplated after precooling is put Enter on spin coater, then forced fluid or selfreparing forced fluid are instilled on substrate;Start spin coater, during by the rotation pre-set Between, rotating speed, acceleration rotation, obtain environment-friendly type lens blank.
Step 6, the environment-friendly type lens blank obtained in step 5 is solidified through heat energy, luminous energy, obtains environment-friendly type mirror Piece.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (3)

1. a kind of production technology of environment-friendly type plating glasses, it is characterised in that step is as follows:
Step 1, substrate is cleaned by 35 DEG C of cleaning fluid ultrasonic oscillations added with surface conditioning agent;Ultrasonic surface is clear Washing lotion is by sodium hydroxide, ethanol, AES, CDEA and water by weight 0.6:8:1:0.8:89.6 are formulated;
Step 2, the substrate drying after cleaning, then precooling;
Step 3, then the substrate after precooling is electroplated through dry type;
Step 4, the added 35 DEG C of cleaning fluid ultrasonic oscillations for having surface conditioning agent of the substrate after plating are cleaned, dried, pre- It is cold;Ultrasonic surface cleaning fluid by sulfosuccinic acid alkyl alcohol ether ester sodium salt, 36.5% hydrochloric acid, AES, CDEA and water by weight 0.8:0.5:0.8:0.7:97.2 are formulated;
Step 5, step 4 is electroplated to the substrate surface after precooling and carries out intensive treatment, obtains environment-friendly type lens blank;
Step 6, the environment-friendly type lens blank obtained in step 5 is solidified through heat energy, luminous energy, obtains environment-friendly type eyeglass.
A kind of 2. production technology of environment-friendly type plating glasses as claimed in claim 1, it is characterised in that:The step 5, will Substrate after step 4 plating precooling, which is put into forced fluid or selfreparing forced fluid, to be soaked, and is carried out intensive treatment, is obtained environment-friendly type Lens blank.
A kind of 3. production technology of environment-friendly type plating glasses as claimed in claim 1, it is characterised in that:The step 5, in advance First set the rotational time, rotating speed, acceleration of spin coater;The substrate that step 4 is electroplated after precooling is put on spin coater, then Forced fluid or selfreparing forced fluid are instilled on substrate;Start spin coater, by the rotational time, rotating speed, acceleration pre-set Degree rotation, obtains environment-friendly type lens blank.
CN201710859451.4A 2017-09-21 2017-09-21 A kind of environment-friendly type plating glasses production technology Active CN107653469B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108784931A (en) * 2018-08-19 2018-11-13 杏晖光学(厦门)有限公司 A kind of anti-scratch hardening plating protective face mask

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1126479A (en) * 1966-07-08 1968-09-05 Diversey Ltd Improvements in and relating to detergent compositions
CN1051755A (en) * 1990-08-05 1991-05-29 广西壮族自治区职业病防治研究所 Detergent for medical sheet glass
JP2006160870A (en) * 2004-12-07 2006-06-22 Kao Corp Hard surface detergent
CN101368137A (en) * 2007-08-15 2009-02-18 江苏海迅实业集团股份有限公司 Optics parts surface detergent
CN102102050A (en) * 2009-12-22 2011-06-22 江西凤凰富士能光学有限公司 Optical element cleaning agent and cleaning method thereof
CN202837719U (en) * 2012-08-14 2013-03-27 厦门立扬光学科技有限公司 Scratch-proof polarized lens
CN103984120A (en) * 2014-05-30 2014-08-13 奥特路(漳州)光学科技有限公司 Method for manufacturing blue light-resistant optical lens

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1126479A (en) * 1966-07-08 1968-09-05 Diversey Ltd Improvements in and relating to detergent compositions
CN1051755A (en) * 1990-08-05 1991-05-29 广西壮族自治区职业病防治研究所 Detergent for medical sheet glass
JP2006160870A (en) * 2004-12-07 2006-06-22 Kao Corp Hard surface detergent
CN101368137A (en) * 2007-08-15 2009-02-18 江苏海迅实业集团股份有限公司 Optics parts surface detergent
CN102102050A (en) * 2009-12-22 2011-06-22 江西凤凰富士能光学有限公司 Optical element cleaning agent and cleaning method thereof
CN202837719U (en) * 2012-08-14 2013-03-27 厦门立扬光学科技有限公司 Scratch-proof polarized lens
CN103984120A (en) * 2014-05-30 2014-08-13 奥特路(漳州)光学科技有限公司 Method for manufacturing blue light-resistant optical lens

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108784931A (en) * 2018-08-19 2018-11-13 杏晖光学(厦门)有限公司 A kind of anti-scratch hardening plating protective face mask

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