CN107653469B - A kind of environment-friendly type plating glasses production technology - Google Patents
A kind of environment-friendly type plating glasses production technology Download PDFInfo
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- CN107653469B CN107653469B CN201710859451.4A CN201710859451A CN107653469B CN 107653469 B CN107653469 B CN 107653469B CN 201710859451 A CN201710859451 A CN 201710859451A CN 107653469 B CN107653469 B CN 107653469B
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/54—Electroplating of non-metallic surfaces
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
- G02B1/14—Protective coatings, e.g. hard coatings
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Eyeglasses (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
The present invention discloses a kind of production technology of environment-friendly type plating glasses, first cleans substrate by the ultrasonic oscillation added with basic surface inorganic agent;Substrate drying after cleaning, then be pre-chilled;The substrate after pre-cooling is electroplated through dry type again;By added ultrasonic oscillation cleaning, drying, the pre-cooling for having acidic surface inorganic agent of the substrate after plating;Substrate surface after plating pre-cooling is subjected to intensive treatment, obtains environment-friendly type lens blank;Solidify again through thermal energy, luminous energy, obtains environment-friendly type eyeglass.The present invention can protect electroplated layer, do not allow electroplated layer to be damaged, scratch, scratching, falling layer, by erosion equivalent damage, and then eyes is protected not injured simultaneously by dizziness caused by the stimulation of different transmitances etc. because electroplated layer damages.The use feeling and beauty of electrodeposition-type product are kept simultaneously, to increase the service life of product, the environment-friendly type plating glasses of the wasting of resources is reduced, there is very big application value.
Description
Technical field
The invention belongs to the technical fields of optical material, and glasses production technology is electroplated more particularly, to a kind of environment-friendly type.
Background technique
With social development progress, improvement of living standard, people come to realise the importance with eye health.To promote
Into the development of sunglasses, but general sunglasses have not been able to satisfy public demand slowly.
Present people not only need glasses to protect eye health, it is also necessary to wear fashion.So current fashion on the market
Glasses are mainly based on electrodeposition-type sunglasses.Electrodeposition-type sunglasses not only can protect our eye health, while appearance is more
Gorgeous, colorful, fashion, so and the current first choice of people.
But current all electrodeposition-type sunglasses have an apparent defect.Because of the characteristic of electroplated layer, electricity is used in people
It is easy to damage when plating type glasses, scratches, scratches, falling layer, by erosion equivalent damage, to influence impression and beauty that people use sunglasses
It sees, and then influences the service life of sunglasses, cause the waste of resource not environmentally.Because the characteristic of sunglasses, same substrate is electroplated
Under, have that the eyeglass of plating is lower than the lens transmission rate not being electroplated, and to reduce the how many influence of transmissivity different for different electroplated layers.
The electrodeposition-type glasses haveing damage are worn for a long time, because eyes receive the stimulation of different amounts of transmissivity and refractive index, can allow human eye
Generate dizziness;The electrodeposition-type glasses that long periods of wear is had damage, or even injury is generated to eyes.
It is easy to damage for electrodeposition-type eyewear products, scratch, scratching, falling layer, by erosion equivalent damage, thus the present invention generates.
Summary of the invention
The purpose of the present invention is to provide a kind of environment-friendly types, and glasses production technology is electroplated, in the hope of that can protect the plating of glasses
Layer does not allow electroplated layer damaged, scratched, scratched, falls layer, by erosion equivalent damage, further protecting eyes not by because electroplated layer has
Defect causes transmitance and refractive index to transmit the inconsistent generation stimulation into human eye, avoids generating human eye dizziness even injury,
The use feeling and beauty of electrodeposition-type product are further kept, to increase the service life of product, reduces the wasting of resources.
To solve the above-mentioned problems, the present invention adopts the following technical scheme:
The present invention proposes a kind of production technology of environment-friendly type plating glasses, and its step are as follows:
Step 1 cleans substrate by 35 DEG C of cleaning solution ultrasonic oscillations added with surface treating agent;Ultrasonic wave table
Face cleaning solution is by sodium hydroxide, ethyl alcohol, AES (sodium sulfate of polyethenoxy ether of fatty alcohol), CDEA (coco-nut oil fatty acid diethanol acyl
Amine) and water be formulated by weight 0.6:8:1:0.8:89.6;
Step 2, the substrate drying after cleaning, then be pre-chilled;
Step 3, then the substrate after pre-cooling is electroplated through dry type;
Step 4 by the added 35 DEG C of cleaning solution ultrasonic oscillations cleaning for having surface treating agent of the substrate after plating, is dried
Dry, pre-cooling;Ultrasonic surface cleaning solution is pressed by sulfosuccinic acid alkyl alcohol ether ester sodium salt, 36.5% hydrochloric acid, AES, CDEA and water
Weight ratio 0.8:0.5:0.8:0.7:97.2 is formulated;
Step 5, the substrate surface after step 4 is pre-chilled carry out intensive treatment, obtain environment-friendly type lens blank;
Environment-friendly type lens blank obtained in step 5 is solidified through thermal energy, luminous energy, obtains environment-friendly type mirror by step 6
Piece.
The step 5, the substrate after step 4 is pre-chilled, which is put into forced fluid or selfreparing forced fluid, to be impregnated, and is carried out strong
Change processing, obtains environment-friendly type lens blank.
The step 5 pre-sets the rotational time, revolving speed, acceleration of spin coater;Base after step 4 is pre-chilled
Piece is put on spin coater, then forced fluid or selfreparing forced fluid are instilled on substrate;Start spin coater, by the rotation pre-set
Turn time, revolving speed, acceleration rotation, obtains environment-friendly type lens blank.
After adopting the above scheme, the present invention takes the lead in designing a kind of glasses that can protect electroplated layer, do not allow electroplated layer by
To damaging, scratch, scratch, fall layer, by erosion equivalent damage, so protect eyes will not due to electroplated layer damages simultaneously by it is different thoroughly
Cross the injury such as dizziness caused by the stimulation of rate.The use feeling and beauty for keeping electrodeposition-type product simultaneously, to increase product
Service life reduces the environment-friendly type plating glasses of the wasting of resources, has very big application value.
Detailed description of the invention
Fig. 1 is that Glasses structure 1 is electroplated in a kind of environment-friendly type of the present invention;
Fig. 2 is that Glasses structure 2 is electroplated in a kind of environment-friendly type of the present invention;
Fig. 3 is TAC substrate of the invention;
Fig. 4 is TAC polarisation substrate of the invention;
Fig. 5 is that PA+TAC of the invention is molded substrate;
Fig. 6 is that PA+TAC polarisation of the invention is molded substrate;
Fig. 7 is that PC+TAC of the invention is molded substrate;
Fig. 8 is that PC+TAC polarisation of the invention is molded substrate;
Fig. 9 is that PA polarisation of the invention is molded substrate;
Figure 10 is that PC polarisation of the invention is molded substrate.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to the accompanying drawings and embodiments, right
The present invention is further elaborated.It should be appreciated that described herein, specific examples are only used to explain the present invention, not
For limiting the present invention.As long as in addition, technical characteristic involved in the various embodiments of the present invention described below that
Not constituting conflict between this can be combined with each other.
The present invention takes the lead in providing a kind of glasses that can protect electroplated layer, electroplated layer is not allowed to be damaged, scratched, scratched,
Fall layer, by erosion equivalent damage, further protect eyes not by because electroplated layer it is defective caused by because transmitance is into the inconsistent production of human eye
Raw stimulation generates dizziness to human eye and even injures.The use feeling and beauty for further keeping electrodeposition-type product, to increase
The service life of product reduces the environment-friendly type plating glasses of the wasting of resources.
Glasses are electroplated in a kind of environment-friendly type of the invention, and structure 1 has as shown in Figure 1: substrate layer, electroplated layer 1, electroplated layer 2,
Protective layer 1, protective layer 2.Wherein substrate layer can be compound according to different function for TAC material, PC material or nylon material etc. or be infused
Substrate layer made of modeling;It is electroplated layer 1 in the one side of substrate layer;It is protective layer 1 in the upper surface of electroplated layer 1;In the another of substrate layer
It is on one side electroplated layer 2;It is protective layer 2 in the upper surface of electroplated layer 2.
Further, according to product function and customer demand, glasses, structure 2 such as Fig. 2 is electroplated in a kind of environment-friendly type of the invention
It is shown with: substrate layer, electroplated layer 1, protective layer 1, protective layer 2.Wherein substrate layer can be TAC material, PC material or nylon material
Deng according to the substrate layer that different function is compound or is molded;It is electroplated layer 1 in the one side of substrate layer;In the upper surface of electroplated layer 1
For protective layer 1;It is protective layer 2 in the another side of substrate layer.
Substrate of the present invention can be divided into as shown in Figures 3 to 10 according to differences such as function, technique, customer demands
TAC substrate, TAC polarisation substrate, PC, PA injection molding substrate, PC, PA injection molding polarisation substrate and PC or PA or TAC film hybrid substrate etc..
The present invention proposes a kind of production technology of environment-friendly type plating glasses, and its step are as follows:
Step 1 cleans substrate by the ultrasonic oscillation added with surface treating agent;
35 DEG C of ultrasonic surface cleaning solutions of this step are by sodium hydroxide, ethyl alcohol, AES, CDEA and water by weight 0.6:
8:1:0.8:89.6 being formulated;
The ultrasonic surface cleaning solution of this step can effectively remove the organic and inorganic, dust etc. of substrate layer adhering on surface band
Impurity provides effectively pretreatment to the quality of electroplating technology.
The ultrasonic surface cleaning solution of step and the comparison of comparative example thus of table 1.
It is obtained from upper table data, in the 1st, 2,3 group of formula ratios, the semi-finished product electroplating quality produced and plating
Layer fastness inequality, only in the 4th group of formula ratio of the invention, the semi-finished product electroplating quality and electroplated layer produced are
's.By studying test repeatedly, the 4th group of formula ratio only proposed by the present invention be it is most scientific, could obtain optimal has
Beneficial effect.
Step 2, the substrate drying after cleaning, then be pre-chilled;
Step 3, then the substrate after pre-cooling is electroplated through dry type;
Step 4, by added ultrasonic oscillation cleaning, drying, the pre-cooling for having surface treating agent of the substrate after plating;
35 DEG C of ultrasonic surface cleaning solutions of this step by sulfosuccinic acid alkyl alcohol ether ester sodium salt, 36.5% hydrochloric acid,
AES, CDEA and water are formulated by weight 0.8:0.5:0.8:0.7:97.2;
The ultrasonic surface cleaning solution of step and the comparison of comparative example thus of table 2.
It is obtained from above table data, in the 1st group of formula ratio, the finished product produced, electroplated layer fastness and product
Matter is good, but strengthening layer fastness and poor quality;2nd group of formula ratio, the finished product produced, electroplated layer fastness and quality are good,
But strengthening layer fastness and poor quality;3rd group of formula ratio, the finished product produced, electroplated layer fastness is good, but poor quality, and
Strengthening layer fastness and poor quality;Only in 4th group of formula ratio of the invention, the finished product produced, electroplated layer fastness and product
Matter is good and strengthening layer fastness and quality might as well.By studying test repeatedly, the 4th group of formula ratio only proposed by the present invention is most
Science, optimal beneficial effect could be obtained.
Step 5, the substrate surface after step 4 is pre-chilled carry out intensive treatment, obtain environment-friendly type lens blank;
There are two types of specific situations for this step, are put into forced fluid one is the substrate after step 4 is pre-chilled or selfreparing is strengthened
It is impregnated in liquid, carries out intensive treatment, obtain environment-friendly type lens blank;
Another kind is the rotational time, revolving speed, acceleration for pre-setting spin coater;Substrate after step 4 is pre-chilled is put
Enter on spin coater, then instills forced fluid or selfreparing forced fluid on substrate;Start spin coater, when by the rotation pre-set
Between, revolving speed, acceleration rotation, obtain environment-friendly type lens blank.
Environment-friendly type lens blank obtained in step 5 is solidified through thermal energy, luminous energy, obtains environment-friendly type mirror by step 6
Piece.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (3)
1. a kind of production technology of environment-friendly type plating glasses, it is characterised in that steps are as follows:
Step 1 cleans substrate by 35 DEG C of cleaning solution ultrasonic oscillations added with surface treating agent;Ultrasonic surface is clear
Washing lotion is formulated by sodium hydroxide, ethyl alcohol, AES, CDEA and water by weight 0.6:8:1:0.8:89.6;
Step 2, the substrate drying after cleaning, then be pre-chilled;
Step 3, then the substrate after pre-cooling is electroplated through dry type;
Step 4 by the added 35 DEG C of cleaning solution ultrasonic oscillations cleaning for having surface treating agent of the substrate after plating, is dried, pre-
It is cold;Ultrasonic surface cleaning solution by sulfosuccinic acid alkyl alcohol ether ester sodium salt, 36.5% hydrochloric acid, AES, CDEA and water by weight
0.8:0.5:0.8:0.7:97.2 is formulated;
Step 5, the substrate surface after step 4 is pre-chilled carry out intensive treatment, obtain environment-friendly type lens blank;
Environment-friendly type lens blank obtained in step 5 is solidified through thermal energy, luminous energy, obtains environment-friendly type eyeglass by step 6.
2. a kind of production technology of environment-friendly type plating glasses as described in claim 1, it is characterised in that: the step 5, it will
Substrate after step 4 pre-cooling, which is put into forced fluid or selfreparing forced fluid, to be impregnated, and is carried out intensive treatment, is obtained environment-friendly type eyeglass
Semi-finished product.
3. a kind of production technology of environment-friendly type plating glasses as described in claim 1, it is characterised in that: the step 5, in advance
First set the rotational time, revolving speed, acceleration of spin coater;Substrate after step 4 is pre-chilled is put on spin coater, then in base
On piece instills forced fluid or selfreparing forced fluid;Start spin coater, is revolved by the rotational time, revolving speed, acceleration pre-set
Turn, obtains environment-friendly type lens blank.
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CN201710859451.4A CN107653469B (en) | 2017-09-21 | 2017-09-21 | A kind of environment-friendly type plating glasses production technology |
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CN107653469B true CN107653469B (en) | 2019-03-05 |
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CN108784931A (en) * | 2018-08-19 | 2018-11-13 | 杏晖光学(厦门)有限公司 | A kind of anti-scratch hardening plating protective face mask |
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CN202837719U (en) * | 2012-08-14 | 2013-03-27 | 厦门立扬光学科技有限公司 | Scratch-proof polarized lens |
CN103984120A (en) * | 2014-05-30 | 2014-08-13 | 奥特路(漳州)光学科技有限公司 | Method for manufacturing blue light-resistant optical lens |
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Patent Citations (7)
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GB1126479A (en) * | 1966-07-08 | 1968-09-05 | Diversey Ltd | Improvements in and relating to detergent compositions |
CN1051755A (en) * | 1990-08-05 | 1991-05-29 | 广西壮族自治区职业病防治研究所 | Detergent for medical sheet glass |
JP2006160870A (en) * | 2004-12-07 | 2006-06-22 | Kao Corp | Hard surface detergent |
CN101368137A (en) * | 2007-08-15 | 2009-02-18 | 江苏海迅实业集团股份有限公司 | Optics parts surface detergent |
CN102102050A (en) * | 2009-12-22 | 2011-06-22 | 江西凤凰富士能光学有限公司 | Optical element cleaning agent and cleaning method thereof |
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