CN107558298A - 一种施胶剂及其制备方法 - Google Patents

一种施胶剂及其制备方法 Download PDF

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CN107558298A
CN107558298A CN201710825178.3A CN201710825178A CN107558298A CN 107558298 A CN107558298 A CN 107558298A CN 201710825178 A CN201710825178 A CN 201710825178A CN 107558298 A CN107558298 A CN 107558298A
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蒋坤达
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/22—Proteins
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/25—Cellulose
    • D21H17/26—Ethers thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24—Polysaccharides
    • D21H17/28—Starch
    • D21H17/29—Starch cationic
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/41—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups
    • D21H17/44—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing ionic groups cationic
    • D21H17/45—Nitrogen-containing groups
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/62—Rosin; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)
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Abstract

本发明公开了一种施胶剂及其制备方法，其中，其原料配方是由如下重量份数的各组分组成：阳离子松香胶10‑15份；硫酸铝20‑30份；阳离子淀粉5‑15份；阳离子聚丙烯酰胺2‑5 份；酪蛋白朊1‑3份；羧甲基纤维素钠20‑30份；滑石粉40‑60份。本发明公开了一种施胶剂及其制备方法，本发明的施胶剂附着率高，施胶效果好，强度高，耐久性好。

Description

一种施胶剂及其制备方法
技术领域
本发明涉及抄纸施胶领域，尤其涉及的是一种施胶剂及其制备方法。
背景技术
在造纸，抄纸过程中，经常需要用到施胶剂使纸和纸板具有抗墨、抗水、抗乳液、抗腐蚀等性能以提高平滑度、强度和施用期。现有技术中的施胶剂多种多样，但是普遍存在强度差，耐久性差，施胶效果不理想的问题。
因此，现有技术有待改进。
发明内容
本发明的目的在于提供一种施胶剂及其制备方法，本发明的施胶剂附着率高，施胶效果好，强度高，耐久性好。
本发明的技术方案如下：一种施胶剂，其中，其原料配方是由如下重量份数的各组分组成：
阳离子松香胶 10-15份；
硫酸铝 20-30份；
阳离子淀粉 5-15份；
阳离子聚丙烯酰胺 2-5份；
酪蛋白朊 1-3份；
羧甲基纤维素钠 20-30份；
滑石粉 40-60份。
所述的施胶剂，其中，其原料配方是由如下重量份数的各组分组成：
阳离子松香胶 12份；
硫酸铝 21份；
阳离子淀粉 10份；
阳离子聚丙烯酰胺 2份；
酪蛋白朊 1份；
羧甲基纤维素钠 30份；
滑石粉 45份。
所述的施胶剂的制备方法，其中，包括以下步骤：
A1、将阳离子淀粉放入羧甲基纤维素钠溶液中，搅拌20分钟；
A2、加入硫酸铝、酪蛋白朊和阳离子聚丙烯酰胺，搅拌10分钟，温度为50摄氏度；
A3、加入阳离子松香胶，继续搅拌30分钟，前15分钟搅拌温度为50摄氏度，后15分钟搅拌温度为35摄氏度，然后再次升温至55-60摄氏度保温浸泡30分钟；
A4、加入滑石粉，搅拌直至没有沉淀，得到成品。
本发明的有益效果：本发明公开了一种施胶剂及其制备方法，本发明的施胶剂附着率高，施胶效果好，强度高，耐久性好。
具体实施方式
为使本发明的目的、技术方案及优点更加清楚、明确，以下列举实施例对本发明进一步详细说明。
实施例1
本实施例的施胶剂原料配方是由如下重量份数的各组分组成：
阳离子松香胶12份；
硫酸铝21份；
阳离子淀粉10份；
阳离子聚丙烯酰胺2份；
酪蛋白朊1份；
羧甲基纤维素钠30份；
滑石粉45份。
本实施例的施胶剂的制备过程如下：
A1、将阳离子淀粉放入羧甲基纤维素钠溶液中，搅拌20分钟。
A2、加入硫酸铝、酪蛋白朊和阳离子聚丙烯酰胺，搅拌10分钟，温度为50摄氏度。
A3、加入阳离子松香胶，继续搅拌30分钟，前15分钟搅拌温度为50摄氏度，后15分钟搅拌温度为35摄氏度，然后再次升温至55-60摄氏度保温浸泡30分钟；通过巧妙的采用这种先升温、在降温、最后再升温保温的技术方式，有利于提高施胶剂的附着率和耐久性，同时对温度稳定性强。
A4、加入滑石粉，搅拌直至没有沉淀，得到成品。
本实施例得到的施胶剂附着率高，施胶效果好，强度高，耐久性好。经测试，取本实施例制备的施胶剂1g进行施胶，胶料附着率达到68%，纸张强度较不施胶提高78%。
实施例2
实施例2本实施例基本与实施例1相同，不同的是，本实施例的施胶剂原料配方是由如下重量份数的各组分组成：
阳离子松香胶10份；
硫酸铝25份；
阳离子淀粉10份；
阳离子聚丙烯酰胺4份；
酪蛋白朊2份；
羧甲基纤维素钠20份；
滑石粉45份。
本实施例提供的施胶剂比实施例1的效果更好，经测试，取本实施例制备的施胶剂1g，取本实施例制备的施胶剂1g进行施胶，胶料附着率达到72%，纸张强度较不施胶的提高86%。
应当理解的是，本发明的应用不限于上述的举例，对本领域普通技术人员来说，可以根据上述说明加以改进或变换，所有这些改进和变换都应属于本发明所附权利要求的保护范围。

Claims (2)

1.一种施胶剂，其特征在于，其原料配方是由如下重量份数的各组分组成：
阳离子松香胶10份；
硫酸铝25份；
阳离子淀粉10份；
阳离子聚丙烯酰胺4份；
酪蛋白朊2份；
羧甲基纤维素钠20份；
滑石粉45份。
2.一种如权利要求1所述的施胶剂的制备方法，其特征在于，包括以下步骤：
A1、将阳离子淀粉放入羧甲基纤维素钠溶液中，搅拌20分钟；
A2、加入硫酸铝、酪蛋白朊和阳离子聚丙烯酰胺，搅拌10分钟，温度为50摄氏度；
A3、加入阳离子松香胶，继续搅拌30分钟，前15分钟搅拌温度为50摄氏度，后15分钟搅拌温度为35摄氏度，然后再次升温至55-60摄氏度保温浸泡30分钟；
A4、加入滑石粉，搅拌直至没有沉淀，得到成品。
CN201710825178.3A 2016-01-15 2016-01-15 一种施胶剂及其制备方法 Withdrawn CN107558298A (zh)

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CN201710894976.1A Pending CN107558299A (zh) 2016-01-15 2016-01-15 高耐久性施胶剂
CN201710902530.9A Pending CN107604751A (zh) 2016-01-15 2016-01-15 用于造纸工业的高强度施胶剂的制备方法
CN201710902565.2A Pending CN107503235A (zh) 2016-01-15 2016-01-15 用于造纸工业的高强度施胶剂

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CN201710902530.9A Pending CN107604751A (zh) 2016-01-15 2016-01-15 用于造纸工业的高强度施胶剂的制备方法
CN201710902565.2A Pending CN107503235A (zh) 2016-01-15 2016-01-15 用于造纸工业的高强度施胶剂

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CN106702815A (zh) * 2016-12-09 2017-05-24 苏州艾博迈尔新材料有限公司 一种复合表面施胶剂及其制备方法
CN106638140A (zh) * 2016-12-10 2017-05-10 钦州学院 一种施胶剂及其制备方法
CN107724173A (zh) * 2017-09-18 2018-02-23 芜湖米诺环保科技有限公司 一种高强度瓦楞纸用的表面抗潮剂
CN112976740A (zh) * 2021-04-09 2021-06-18 湖北银河彩印包装有限公司 一种防潮抗挤压瓦楞纸板
CN113718550B (zh) * 2021-08-26 2022-04-22 浙江百斯特化工有限公司 一种松香施胶剂及其制备方法

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JPH07189175A (ja) * 1993-12-27 1995-07-25 Nippon P M C Kk 紙用サイズ剤及びサイジング方法
WO1997028311A1 (en) * 1996-02-02 1997-08-07 Hercules Incorporated Emulsifier system for rosin sizing agents
JP4224746B2 (ja) * 1999-08-30 2009-02-18 ハリマ化成株式会社 製紙用サイズ剤
CN101255668B (zh) * 2008-04-09 2010-12-22 广西壮族自治区化工研究院 高稳定性阳离子分散松香胶及其制备方法
CN101319026A (zh) * 2008-06-18 2008-12-10 江苏飞翔化工股份有限公司 松香施胶剂中辅助松香分散的阳离子聚合物的制备方法
CN101787662B (zh) * 2010-01-14 2011-10-19 镇江大东纸业有限公司 计算机直接制印版衬纸的生产方法
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JP5880949B2 (ja) * 2012-03-10 2016-03-09 荒川化学工業株式会社 ロジン系エマルジョン型サイズ剤、その製造方法及び紙
CN103469684A (zh) * 2012-06-09 2013-12-25 江苏五洲纸业有限公司 一种改性松香施胶剂的生产方法

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CN107503235A (zh) 2017-12-22

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