CN107435264A - 一种包含聚丙烯醇与丙烯酸的纺织用扩散剂 - Google Patents
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂 Download PDFInfo
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Abstract
本发明公开了一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,属于纺织助剂技术领域。所述扩散剂包括以下重量份的各组分:聚丙烯醇 10‑30份,丙烯酸 10‑40份,三乙烯三胺 1‑5份,双氰胺 6‑10份,石油磺酸 2‑8份,硫酸镁 1‑5份,丙二醇 10‑15份,聚乙烯吡啶 5‑13份,鞣酸 4‑10份,海藻酸钠 3‑12份。本发明具有较好的不稳定性和优良的扩散性能,染色强度高,使用效果良好。
Description
技术领域
本发明属于纺织助剂技术领域,更具体是涉及一种纺织用扩散剂。
背景技术
扩散剂就是日常所说的分散剂,它是染料加工和染料应用中不可缺少的助剂。有的扩散剂本身就兼有分散性和移染性等多种作用,既可作为染料加工用扩散剂,又可作为印染中的匀染剂。
分散染料和还原染料本身都不溶于水或微溶于水,合成出来的原染料颗粒较大,不能直接用于印染工业,需要进行研磨加工,使染料颗粒分散达到1 微米左右。扩散剂的加入量一般为原染料的1 ~ 3 倍,它可使染料粒子分散,有助于颗粒粉碎,阻止已粉碎的颗粒再重新聚集,保持染料散体的稳定性。扩散剂多数是各种类型的表面活性剂,包括阴离子型、阳离子型、非离子型、两性型和高分子型等。
离子型扩散剂在染料分散体中,由于溶解而电离,其亲油基趋向于染料,亲水基趋向于水,同时扩散剂的疏水部分或它的某些基团以表面吸附、介电子极化、氢键结合等形式与染料分子相吸附,因此在染料颗粒表面有一定排列方向的相同电子层,由于同电荷互相排斥,阻止染料粒子沉降,加之由于扩散剂的亲水性,在它的外层又形成水化分子层,阻止了染料分子的相互接近。此外,在水化分子层外,还有分散液中的正电荷,它们被吸引在分散剂的负电荷周围,形成双分子层,这样染料颗粒之间的距离被拉大,当染料颗粒距离很近时,范德华引力不能产生作用,扩散剂使染料保持悬浮和分散稳定性,纺织相互接近而聚集或凝聚。
在纺织品印染过程中使用的商品染料,要求具有较好的再分散性;在染浴中具有良好的热稳定性,粘度小,对混纺中的其他组分沾色少;染料的溶解度小;金属离子含量低等。这些性能除与染料结构有关外,也与扩散剂的品种有关。
发明内容
本发明的目的是提供一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,具有较好的不稳定性和优良的扩散性能,染色强度高,使用效果良好。
本发明的目的是通过以下技术方案实现的,一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,其特征是,所述扩散剂包括以下重量份的各组分:聚丙烯醇 10-30份,丙烯酸 10-40份,三乙烯三胺 1-5份,双氰胺 6-10份,石油磺酸 2-8份,硫酸镁 1-5份,丙二醇 10-15份,聚乙烯吡啶 5-13份,鞣酸 4-10份,海藻酸钠 3-12份。
优选的,所述分散剂包括以下重量份的各组分:聚丙烯醇 14-28份,丙烯酸 15-36份,三乙烯三胺 1.2-4.6份,双氰胺 6.6-9.4份,石油磺酸 2.6-7.6份,硫酸镁 1.3-4.4份,丙二醇 10.4-14.3份,聚乙烯吡啶 5.8-12.6份,鞣酸 4.6-9.0份,海藻酸钠 3.9-11.2份。
优选的,所述分散剂包括以下重量份的各组分:聚丙烯醇 16-25份,丙烯酸 18-34份,三乙烯三胺 1.8-4.1份,双氰胺 7.2-9.0份,石油磺酸 3.3-7.0份,硫酸镁 1.8-3.9份,丙二醇 11.2-13.8份,聚乙烯吡啶 6.6-11.8份,鞣酸 5.2-8.6份,海藻酸钠 5.8-10.7份。
优选的,所述分散剂包括以下重量份的各组分:聚丙烯醇 18-23份,丙烯酸 20-30份,三乙烯三胺 2.2-3.7份,双氰胺 8.0-8.8份,石油磺酸 3.7-6.4份,硫酸镁 2.4-3.4份,丙二醇 12.1-13.0份,聚乙烯吡啶 8.5-10.2份,鞣酸 6.9-8.3份,海藻酸钠 7.6-9.3份。
优选的,所述分散剂包括以下重量份的各组分:聚丙烯醇 20-22份,丙烯酸 24-37份,三乙烯三胺 2.8-3.4份,双氰胺 8.4-8.7份,石油磺酸 4.5-5.8份,硫酸镁 2.8-3.1份,丙二醇 12.5-12.7份,聚乙烯吡啶 9.2-10.0份,鞣酸 7.2-7.9份,海藻酸钠 8.2-9.0份。
与现有技术相比,本发明具有以下有益效果:具有较好的不稳定性和优良的扩散性能,染色强度高,使用效果良好;分散能力强,储存稳定,容易化料;对于强度和色光无影响;对分散染料和还原染料具有扩散和稳定作用,并可缩短染料研磨时间。本发明纺织扩散剂,具有砂磨速度快,分散性好的优点,而且制备工艺简单;对颜色的分散性和经时稳定性都非常好,可使染料色光鲜艳,而且着色均匀。
具体实施方式
实施例1
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,包括以下重量份的各组分:聚丙烯醇 10份,丙烯酸 40份,三乙烯三胺 1份,双氰胺 10份,石油磺酸 2份,硫酸镁 5份,丙二醇 10份,聚乙烯吡啶 13份,鞣酸 4份,海藻酸钠 12份。
实施例2
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,包括以下重量份的各组分:聚丙烯醇 30份,丙烯酸 10份,三乙烯三胺 5份,双氰胺 6份,石油磺酸 8份,硫酸镁 1份,丙二醇 15份,聚乙烯吡啶 5份,鞣酸 10份,海藻酸钠 3份。
实施例3
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,包括以下重量份的各组分:聚丙烯醇 14份,丙烯酸 36份,三乙烯三胺 1.2份,双氰胺 9.4份,石油磺酸 2.6份,硫酸镁 4.4份,丙二醇 10.4份,聚乙烯吡啶 12.6份,鞣酸 4.6份,海藻酸钠 11.2份。
实施例4
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,包括以下重量份的各组分:聚丙烯醇 28份,丙烯酸 15份,三乙烯三胺 4.6份,双氰胺 6.6份,石油磺酸 7.6份,硫酸镁 1.3份,丙二醇 14.3份,聚乙烯吡啶 5.8份,鞣酸 9.0份,海藻酸钠 3.9份。
实施例5
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,包括以下重量份的各组分:聚丙烯醇 16份,丙烯酸 34份,三乙烯三胺 1.8份,双氰胺 9.0份,石油磺酸 3.3份,硫酸镁 3.9份,丙二醇 11.2份,聚乙烯吡啶 11.8份,鞣酸 5.2份,海藻酸钠 10.7份。
实施例6
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,包括以下重量份的各组分:聚丙烯醇 25份,丙烯酸 18份,三乙烯三胺 4.1份,双氰胺 7.2份,石油磺酸 7.0份,硫酸镁 3.9份,丙二醇 13.8份,聚乙烯吡啶 6.6份,鞣酸 8.6份,海藻酸钠 5.8份。
实施例7
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,包括以下重量份的各组分:聚丙烯醇 18份,丙烯酸 30份,三乙烯三胺 2.2份,双氰胺 8.8份,石油磺酸 3.7份,硫酸镁 3.4份,丙二醇 12.1份,聚乙烯吡啶 10.2份,鞣酸 6.9份,海藻酸钠 9.3份。
实施例8
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,包括以下重量份的各组分:聚丙烯醇 23份,丙烯酸 20份,三乙烯三胺 3.7份,双氰胺 8.0份,石油磺酸 6.4份,硫酸镁 2.4份,丙二醇 13.0份,聚乙烯吡啶 8.5份,鞣酸 8.3份,海藻酸钠 7.6份。
实施例9
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,包括以下重量份的各组分:聚丙烯醇 20份,丙烯酸 37份,三乙烯三胺 2.8份,双氰胺 8.7份,石油磺酸 4.5份,硫酸镁 3.1份,丙二醇 12.5份,聚乙烯吡啶 10.0份,鞣酸 7.2份,海藻酸钠 9.0份。
实施例10
一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,包括以下重量份的各组分:聚丙烯醇 22份,丙烯酸 24份,三乙烯三胺 3.4份,双氰胺 8.4份,石油磺酸 5.8份,硫酸镁 2.8份,丙二醇 12.7份,聚乙烯吡啶 9.2份,鞣酸 7.9份,海藻酸钠 8.2份。
Claims (5)
1.一种包含聚丙烯醇与丙烯酸的纺织用扩散剂,其特征是,所述扩散剂包括以下重量份的各组分:聚丙烯醇 10-30份,丙烯酸 10-40份,三乙烯三胺 1-5份,双氰胺 6-10份,石油磺酸 2-8份,硫酸镁 1-5份,丙二醇 10-15份,聚乙烯吡啶 5-13份,鞣酸 4-10份,海藻酸钠 3-12份。
2.根据权利要求1所述的包含聚丙烯醇与丙烯酸的纺织用扩散剂,其特征是,所述分散剂包括以下重量份的各组分:聚丙烯醇 14-28份,丙烯酸 15-36份,三乙烯三胺 1.2-4.6份,双氰胺 6.6-9.4份,石油磺酸 2.6-7.6份,硫酸镁 1.3-4.4份,丙二醇 10.4-14.3份,聚乙烯吡啶 5.8-12.6份,鞣酸 4.6-9.0份,海藻酸钠 3.9-11.2份。
3.根据权利要求1所述的包含聚丙烯醇与丙烯酸的纺织用扩散剂,其特征是,所述分散剂包括以下重量份的各组分:聚丙烯醇 16-25份,丙烯酸 18-34份,三乙烯三胺 1.8-4.1份,双氰胺 7.2-9.0份,石油磺酸 3.3-7.0份,硫酸镁 1.8-3.9份,丙二醇 11.2-13.8份,聚乙烯吡啶 6.6-11.8份,鞣酸 5.2-8.6份,海藻酸钠 5.8-10.7份。
4.根据权利要求1所述的包含聚丙烯醇与丙烯酸的纺织用扩散剂,其特征是,所述分散剂包括以下重量份的各组分:聚丙烯醇 18-23份,丙烯酸 20-30份,三乙烯三胺 2.2-3.7份,双氰胺 8.0-8.8份,石油磺酸 3.7-6.4份,硫酸镁 2.4-3.4份,丙二醇 12.1-13.0份,聚乙烯吡啶 8.5-10.2份,鞣酸 6.9-8.3份,海藻酸钠 7.6-9.3份。
5.根据权利要求1所述的包含聚乙烯醇与聚乙二醇脂肪酸酯的纺织用扩散剂,其特征是,所述分散剂包括以下重量份的各组分:聚丙烯醇 20-22份,丙烯酸 24-37份,三乙烯三胺 2.8-3.4份,双氰胺 8.4-8.7份,石油磺酸 4.5-5.8份,硫酸镁 2.8-3.1份,丙二醇12.5-12.7份,聚乙烯吡啶 9.2-10.0份,鞣酸 7.2-7.9份,海藻酸钠 8.2-9.0份。
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