CN107365108A - A kind of light weight board based on waste textile and preparation method thereof - Google Patents

A kind of light weight board based on waste textile and preparation method thereof Download PDF

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Publication number
CN107365108A
CN107365108A CN201710787029.2A CN201710787029A CN107365108A CN 107365108 A CN107365108 A CN 107365108A CN 201710787029 A CN201710787029 A CN 201710787029A CN 107365108 A CN107365108 A CN 107365108A
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CN
China
Prior art keywords
parts
cotton fiber
waste textile
light weight
board based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710787029.2A
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Chinese (zh)
Inventor
笪蓉
卢永凯
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Jurong Practice Record Passenger Management Consulting Co Ltd
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Jurong Practice Record Passenger Management Consulting Co Ltd
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Priority to CN201710787029.2A priority Critical patent/CN107365108A/en
Publication of CN107365108A publication Critical patent/CN107365108A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/10Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/14Polyepoxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/40Porous or lightweight materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of light weight board based on waste textile and preparation method thereof.The sheet material includes following components:Clinker, diatomite, powder of straw, sulfonated-pheno-formoldehyde resin, epoxy resin, haydite, cotton fiber, sodium carboxymethylcellulose, grafting agent, paraffin, water reducer, waterproofing agent;The cotton fiber derives from waste textile.By in sulfonated-pheno-formoldehyde resin and epoxy resin input reactor, clinker, diatomite, powder of straw, haydite, cotton fiber are added after thawing, stir, add sodium cellulose glycolate, grafting agent, water reducer and waterproofing agent, continue to stir, master batch is extruded in input extruder, finally the paraffin of thawing is coated on master batch after roll compacting and put into ball mill, is ground.Compared with prior art, present invention materials are extensive, and cost is cheap, and gained board quality is light, rigid-tough balance is good, is easy to be stripped, and is readily transported and constructs, and has good market prospects.

Description

A kind of light weight board based on waste textile and preparation method thereof
Technical field
The present invention relates to the recycling of waste textile, specifically relates to a kind of light weight board and its system based on waste textile Preparation Method.
Background technology
With the rapid development of economy, available natural resources tapered dosage, meanwhile, the temperature of combustion of fossil fuel discharge Room gas, pollutant and the improper caused environmental pollution has become increasingly serious of disposition of solid waste.Currently, solid waste is handled The processing method of thing is mostly to fill, burn or simply reclaim, but these processing methods are cured the symptoms, not the disease.Therefore, seek renewable While new energy, the recycling of recycling or high added value to full constituent.
Application number 201610545316.8, a kind of entitled environment protection architecture sheet material, the sheet material in units of parts by weight, including Following raw material:Cement 20-40 parts, construction waste soil 3-6 parts, sulfonated-methyl brown coal 2-3 parts, haydite 1-2 parts, bentonite 1-2 parts, boron Sour magnesium 1-2 parts, paraffin 2-4 parts, sulfonated-pheno-formoldehyde resin 3-5 parts, AR glass fibre 2-3 parts, carboxymethyl cellulose 2-3 parts, subtract Aqua 0.6-1.2 parts, foaming agent 0.4-0.6 parts, foaming control agent 0.4-0.6 parts, catalyst 0.1-0.2 parts, crosslinking agent 0.3- 0.6 part, foam stabilizer 0.1-0.2 parts, glyoxal 15-25 parts, hydrogen peroxide 10-20 parts, water 200-250 parts.Plate prepared by the present invention Material has fabulous lightweight, insulation, fire prevention, high intensity, the performance of environmental protection, and its performance indications will far above country and professional standard Ask.But cost is high, be not suitable for industrialization.
The content of the invention
In view of the shortcomings of the prior art, the object of the invention provides a kind of light weight board and its system based on waste textile Preparation Method, the board cost is cheap, and quality is light, and compressive property is excellent, wear-resistant.
A kind of light weight board based on waste textile, including the following component counted in parts by weight:Clinker 15-25 parts, Diatomite 24-37 parts, powder of straw 67-84 parts, sulfonated-pheno-formoldehyde resin 22-35 parts, epoxy resin 23-38 parts, haydite 12-18 Part, cotton fiber 55-70 parts, sodium carboxymethylcellulose 23-40 parts, grafting agent 1-5 parts, paraffin 3-8 parts, water reducer 1-4 parts, waterproof Agent 1-3 parts;The cotton fiber derives from waste textile.
It is the above-mentioned light weight board based on waste textile as improved, including the following component counted in parts by weight: 20 parts of clinker, 35 parts of diatomite, 72 parts of powder of straw, 28 parts of sulfonated-pheno-formoldehyde resin, 35 parts of epoxy resin, 15 parts of haydite, cotton are fine 68 parts of dimension, 35 parts of sodium carboxymethylcellulose, 4 parts of grafting agent, paraffin 3-86 parts, 2 parts of water reducer, 1 part of waterproofing agent;The cotton fiber From waste textile.
It is that the length of the cotton fiber is 45-58mm as improved.
It is as improved, the preparation method of the cotton fiber, comprises the following steps:Step 1, waste textile is cleaned Totally, and after ultraviolet-sterilization, then put into ball mill and grind to obtain fine powder;Step 2, added into fine powder at 25-37 DEG C of protease 5-12min is digested, filtering, after deionized water is washed 3-5 times, adds cellulase degradation 1-5min, after filtering, deionized water Wash filter residue, dry cotton fiber.
It is that the weight of the protease is 0.5-5.4 times of fine powder as improved.
The preparation method of the above-mentioned light weight board based on waste textile, comprises the following steps:By sulfonated-pheno-formoldehyde resin Put into epoxy resin in reactor, clinker, diatomite, powder of straw, haydite, cotton fiber are added after thawing, is stirred, then added Enter sodium cellulose glycolate, grafting agent, water reducer and waterproofing agent, continue to stir, put into extruder and extrude master batch, will finally melt The paraffin of change is coated on master batch after roll compacting and put into ball mill, grinds.
Compared with prior art, present invention materials are extensive, and cost is cheap, and gained board quality is light, rigid-tough balance is good, It is easy to be stripped, and is readily transported and constructs, there are good market prospects.
Embodiment
The present invention is further described in detail below by specific embodiment.
Embodiment 1
A kind of light weight board based on waste textile, including the following component counted in parts by weight:15 parts of clinker, diatom 24 parts of soil, 67 parts of powder of straw, 22 parts of sulfonated-pheno-formoldehyde resin, 23 parts of epoxy resin, 12 parts of haydite, 55 parts of cotton fiber, carboxymethyl 23 parts of sodium cellulosate, 1 part of grafting agent, 3 parts of paraffin, 1 part of water reducer, waterproofing agent 1-3 parts;The cotton fiber derives from waste and old weaving Product.Wherein, the length of the cotton fiber is 45mm, the preparation method of the cotton fiber, is comprised the following steps:Step 1, will be waste and old Textile cleans up, and after ultraviolet-sterilization, then put into ball mill and grind to obtain fine powder;Step 2, fine powder weight is added into fine powder 5min is digested at 0.5 times of 25 DEG C of protease of amount, is filtered, after deionized water is washed 3 times, adds cellulase degradation 1min, after filtering, deionized water washing filter residue, dry cotton fiber.
The preparation method of the above-mentioned light weight board based on waste textile, comprises the following steps:By sulfonated-pheno-formoldehyde resin Put into epoxy resin in reactor, clinker, diatomite, powder of straw, haydite, cotton fiber are added after thawing, is stirred, then added Enter sodium cellulose glycolate, grafting agent, water reducer and waterproofing agent, continue to stir, put into extruder and extrude master batch, will finally melt The paraffin of change is coated on master batch after roll compacting and put into ball mill, grinds.
Embodiment 2
A kind of light weight board based on waste textile, including the following component counted in parts by weight:Including below by weight Measure the component of number meter:20 parts of clinker, 35 parts of diatomite, 72 parts of powder of straw, 28 parts of sulfonated-pheno-formoldehyde resin, epoxy resin 35 Part, 15 parts of haydite, 68 parts of cotton fiber, 35 parts of sodium carboxymethylcellulose, 4 parts of grafting agent, paraffin 3-86 parts, 2 parts of water reducer, waterproof 1 part of agent;The cotton fiber derives from waste textile.Wherein, the length of the cotton fiber is 50mm, the preparation of the cotton fiber Method, comprise the following steps:Step 1, waste textile is cleaned up, and after ultraviolet-sterilization, then put into ball mill and grind Obtain fine powder;Step 2, added into fine powder at 0 DEG C of the protease 3 of 2.8 times of its amount and digest 5-128min, filtered, deionization washing After washing 4 times, cellulase degradation 4min is added, after filtering, deionized water washing filter residue, dry cotton fiber.
The preparation method of the above-mentioned light weight board based on waste textile, comprises the following steps:By sulfonated-pheno-formoldehyde resin Put into epoxy resin in reactor, clinker, diatomite, powder of straw, haydite, cotton fiber are added after thawing, is stirred, then added Enter sodium cellulose glycolate, grafting agent, water reducer and waterproofing agent, continue to stir, put into extruder and extrude master batch, will finally melt The paraffin of change is coated on master batch after roll compacting and put into ball mill, grinds.
Embodiment 3
A kind of light weight board based on waste textile, including the following component counted in parts by weight:25 parts of clinker, diatom 37 parts of soil, 84 parts of powder of straw, 35 parts of sulfonated-pheno-formoldehyde resin, 38 parts of epoxy resin, 18 parts of haydite, 70 parts of cotton fiber, carboxymethyl 40 parts of sodium cellulosate, 5 parts of grafting agent, 8 parts of paraffin, 4 parts of water reducer, 3 parts of waterproofing agent;The cotton fiber derives from waste and old weaving Product.
Wherein, the length of the cotton fiber is 58mm, the preparation method of the cotton fiber, is comprised the following steps:Step 1, Waste textile is cleaned up, and after ultraviolet-sterilization, then put into ball mill and grind to obtain fine powder;Step 2, added into fine powder 12min is digested at 7 DEG C of the protease 3 of 4.8 times of its weight, is filtered, after deionized water is washed 35 times, adds cellulase degradation 5min, after filtering, deionized water washing filter residue, dry cotton fiber.
The preparation method of the above-mentioned light weight board based on waste textile, comprises the following steps:By sulfonated-pheno-formoldehyde resin Put into epoxy resin in reactor, clinker, diatomite, powder of straw, haydite, cotton fiber are added after thawing, is stirred, then added Enter sodium cellulose glycolate, grafting agent, water reducer and waterproofing agent, continue to stir, put into extruder and extrude master batch, will finally melt The paraffin of change is coated on master batch after roll compacting and put into ball mill, grinds.
Comparative example 1
A kind of light weight board based on waste textile, including the following component counted in parts by weight:Including below by weight Measure the component of number meter:20 parts of clinker, 35 parts of diatomite, 72 parts of powder of straw, 28 parts of sulfonated-pheno-formoldehyde resin, epoxy resin 35 Part, 15 parts of haydite, 35 parts of sodium carboxymethylcellulose, 4 parts of grafting agent, paraffin 3-86 parts, 2 parts of water reducer, 1 part of waterproofing agent.
The preparation method of the above-mentioned light weight board based on waste textile, comprises the following steps:By sulfonated-pheno-formoldehyde resin Put into epoxy resin in reactor, clinker, diatomite are added after thawing, powder of straw, haydite, is stirred, adds hydroxyl first Base sodium cellulosate, grafting agent, water reducer and waterproofing agent, continue to stir, put into extruder and extrude master batch, finally by the stone of thawing Wax is coated on master batch after roll compacting and put into ball mill, grinds.
Performance test is just carried out to embodiment 1-3 and the gained of comparative example 1 thistle board, the data obtained is as shown in the table.
Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1
Tensile strength/MPa 52 64 58 40
Bending strength/MPa 68 78 65 48
Water absorption rate/% 2.9 1.2 2.4 4.8
It is seen from the above data that light weight board mechanical property of the present invention is good, water absorption rate is low, from embodiment 2 and contrast Example 1 is compared, and the addition of cotton fiber is even more to improve the mechanics coefficient of sheet material, and cotton fiber derives from waste textile, and cost is low Honest and clean, market prospects are good.
In addition, the invention is not restricted to above-mentioned embodiment, as long as in without departing from the scope of the present invention, can take various Mode implements the present invention.

Claims (6)

1. a kind of light weight board based on waste textile, it is characterised in that including the following component counted in parts by weight:Clinker 15-25 parts, diatomite 24-37 parts, powder of straw 67-84 parts, sulfonated-pheno-formoldehyde resin 22-35 parts, epoxy resin 23-38 parts, pottery Grain 12-18 parts, cotton fiber 55-70 parts, sodium carboxymethylcellulose 23-40 parts, grafting agent 1-5 parts, paraffin 3-8 parts, water reducer 1-4 Part, waterproofing agent 1-3 parts;The cotton fiber derives from waste textile.
2. a kind of light weight board based on waste textile according to claim 1, it is characterised in that including below by weight Measure the component of number meter:20 parts of clinker, 35 parts of diatomite, 72 parts of powder of straw, 28 parts of sulfonated-pheno-formoldehyde resin, epoxy resin 35 Part, 15 parts of haydite, 68 parts of cotton fiber, 35 parts of sodium carboxymethylcellulose, 4 parts of grafting agent, paraffin 3-86 parts, 2 parts of water reducer, waterproof 1 part of agent;The cotton fiber derives from waste textile.
3. a kind of light weight board based on waste textile according to claim 1, it is characterised in that the cotton fiber Length is 45-58mm.
4. a kind of light weight board based on waste textile according to claim 1, it is characterised in that the cotton fiber Preparation method, comprise the following steps:Step 1, waste textile is cleaned up, and after ultraviolet-sterilization, then put into ball mill Grind to obtain fine powder;Step 2, added into fine powder at 25-37 DEG C of protease and digest 5-12min, filtered, deionized water washing 3-5 After secondary, cellulase degradation 1-5min is added, after filtering, deionized water washing filter residue, dry cotton fiber.
5. a kind of light weight board based on waste textile according to claim 4, it is characterised in that the protease Weight is 0.5-5.4 times of fine powder.
6. the preparation method based on a kind of light weight board based on waste textile described in claim 1, it is characterised in that bag Include following steps:By in sulfonated-pheno-formoldehyde resin and epoxy resin input reactor, clinker, diatomite, stalk are added after thawing Powder, haydite, cotton fiber, stir, and add sodium cellulose glycolate, grafting agent, water reducer and waterproofing agent, continue to stir, Master batch is extruded in input extruder, finally the paraffin of thawing is coated on master batch after roll compacting and put into ball mill, is ground.
CN201710787029.2A 2017-09-04 2017-09-04 A kind of light weight board based on waste textile and preparation method thereof Pending CN107365108A (en)

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CN201710787029.2A CN107365108A (en) 2017-09-04 2017-09-04 A kind of light weight board based on waste textile and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710787029.2A CN107365108A (en) 2017-09-04 2017-09-04 A kind of light weight board based on waste textile and preparation method thereof

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CN107365108A true CN107365108A (en) 2017-11-21

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110951221A (en) * 2019-12-12 2020-04-03 界首市昌隆塑业有限公司 Broken cloth foaming particles for processing polyester tiles and processing technology thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102557518A (en) * 2011-12-28 2012-07-11 成都新柯力化工科技有限公司 Interior wall coating coil and preparation method thereof
CN106746907A (en) * 2015-11-20 2017-05-31 丁安强 The composite building material processed using waste textile
CN106746906A (en) * 2015-11-20 2017-05-31 杨旭 A kind of building and ornament materials of waste textile processing

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102557518A (en) * 2011-12-28 2012-07-11 成都新柯力化工科技有限公司 Interior wall coating coil and preparation method thereof
CN106746907A (en) * 2015-11-20 2017-05-31 丁安强 The composite building material processed using waste textile
CN106746906A (en) * 2015-11-20 2017-05-31 杨旭 A kind of building and ornament materials of waste textile processing

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110951221A (en) * 2019-12-12 2020-04-03 界首市昌隆塑业有限公司 Broken cloth foaming particles for processing polyester tiles and processing technology thereof

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Application publication date: 20171121