CN107335548A - The dense effluent sub-prime substep reuse technology of vulcanized lead zinc flotation concentrate - Google Patents

The dense effluent sub-prime substep reuse technology of vulcanized lead zinc flotation concentrate Download PDF

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Publication number
CN107335548A
CN107335548A CN201710549138.0A CN201710549138A CN107335548A CN 107335548 A CN107335548 A CN 107335548A CN 201710549138 A CN201710549138 A CN 201710549138A CN 107335548 A CN107335548 A CN 107335548A
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China
Prior art keywords
lead
zinc
concentrate
dense
effluent
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CN201710549138.0A
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Chinese (zh)
Inventor
姚青峰
周长银
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Inner Mongolia Sentai Business Consulting Co Ltd
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Inner Mongolia Sentai Business Consulting Co Ltd
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Priority to CN201710549138.0A priority Critical patent/CN107335548A/en
Publication of CN107335548A publication Critical patent/CN107335548A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/001Flotation agents
    • B03D1/018Mixtures of inorganic and organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/14Flotation machines
    • B03D1/16Flotation machines with impellers; Subaeration machines

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Physical Water Treatments (AREA)

Abstract

Technological process is the water mixing after the dense effluent of vulcanized lead zinc flotation concentrate and the filtering of mine tailing ceramic machine;By the dense effluent of the lead concentrate containing plurality of heavy metal ion and floating agent and the dense effluent direct reuse of zinc concentrate to lead Beneficiation flowsheet and zinc Beneficiation flowsheet;Technical reform scheme:The dense effluent of lead concentrate adds lead system and selects vulcanized lead, will contain sulfuric acid zinc metal ion and the use of diethyldithiocarbamate floating agent in lead Beneficiation flowsheet (entering Turo pump pond);The dense effluent direct reuse of zinc concentrate, sulfuric acid copper metal ion and the use of xanthate floating agent will be contained in zinc Beneficiation flowsheet, avoiding reduces the consumption of zinc sulfate and copper sulphate medicament together with zinc sulfate and copper sulphate Ar ion mixing, reduce cost for wastewater treatment.By above technological transformation, following such advantage is obtained:1st, metal loss is reduced, 2, reduce reagent consumption, save beneficiation cost, 3, improve mineral processing index, 4, reduce cost for wastewater treatment etc..

Description

The dense effluent sub-prime substep reuse technology of vulcanized lead zinc flotation concentrate
Technical field:
The dense effluent sub-prime substep reuse technology of vulcanized lead zinc flotation concentrate belongs to bargh's mineral processing production technology Field.
Background technology:
The dense effluent of vulcanized lead zinc flotation concentrate, the scheme used both at home and abroad have:Vulcanized lead zinc flotation concentrate is dense Effluent is discharged into Tailings Dam and used, without using or being used in mixed way with tailing filtration water.Inner Mongol Zalantun City state is gloomy Mining Limited Company lead zinc-silver polymetallic ore, main valuable component Pb 1.30%, Zn 5.25%, Ag in ore 101.50g/t, lead, zinc mainly exist with galena, zinc blend form, lead zinc ratio about 1: 4, and the grade of lead zincification is 6.5% or so ore deposit, technological process are controling differential flotation process for copper flow.Each 2000 tons one phase, second phase design of day output, specific flotation Flow:Cyclone overflow pulp enters 2 XB-3000 surge tanks progress dosings and sized mixing, and the ore pulp after sizing mixing enters 4 XCF/ KYF-24 flotation devices enter quadrat roughing.Lead roughing operation concentrate is selected into 5 XCF/KYF-8 flotation devices 4 lead of progress, selected After obtain lead concentrate enter it is dense, it is dense after lead ore slurry using ceramic machine filter.Lead roughing operation mine tailing enters 9 XCF/ KYF-24 flotation devices are scanned three times, are scanned rear ore pulp and are sized mixing into 2 XB-3000 surge tanks progress dosings, are sized mixing laggard Enter 5 XCF/KYF-24 flotation devices and carry out zinc roughings, rougher concentration enter 8 XCF/KYF-8 flotation devices carry out 4 times it is selected, most After obtain zinc concentrate enter it is dense, it is dense after zinc ore slurry using ceramic machine filter.Zinc rougher tailings enters 9 XCF/KYF-24 Scanned three times, the ore pulp after scanning enters mine tailing.
The gloomy Mining Limited Company mine of Inner Mongol Zalantun City state is poor under richness on ore body to have an opencast mining of, and lead+zinc supplies Ore deposit grade is high, and design mineral processing circuit is the water after the dense effluent of vulcanized lead zinc flotation concentrate and the filtering of mine tailing ceramic machine Mixing;The dense effluent of lead concentrate containing plurality of heavy metal ion and floating agent and the dense effluent of zinc concentrate is straight Take back and use lead Beneficiation flowsheet and zinc Beneficiation flowsheet;Cause following shortcoming:1st, lead concentrate and zinc concentrate are mutually containing height.2nd, reagent consumption Amount is big, beneficiation cost increase, 3, the mineral processing index rate of recovery it is low, 4, increase cost for wastewater treatment etc..In July, 2016 production theory Index:Lead head grade 1.69%, argentiferous 218.22g/t;Lead concentrate grade 57.97%, argentiferous 7390.36g/t;Lead recovery 74.88%;The rate of recovery 73.94% of silver, zinc ore crude grade 10.52%, zinc concentrate grade 50.91%, rate of recovery 78.43%.
Technical reform scheme:The dense effluent of lead concentrate adds lead system and selects vulcanized lead, will contain sulfuric acid zinc metal ion and The use of diethyldithiocarbamate floating agent is in lead Beneficiation flowsheet (entering Turo pump pond);The dense effluent direct reuse of zinc concentrate, will contain There are sulfuric acid copper metal ion and the use of xanthate floating agent in zinc Beneficiation flowsheet, avoid zinc sulfate and copper sulphate Ar ion mixing exists Together, the consumption of zinc sulfate and copper sulphate medicament is reduced, reduces cost for wastewater treatment.
In March, 2017 production theory index after the completion of transformation:Lead head grade 1.29%, argentiferous 174.92g/t;Lead essence Ore deposit grade 52.95%, argentiferous 6991.35g/t;Lead recovery 83.48%;The rate of recovery 80.75% of silver, zinc ore crude grade 10.64%, zinc concentrate grade 50.56%, rate of recovery 86.85%.
By above technological transformation, following such advantage is obtained:1st, reduce metal loss, 2, reduce reagent consumption, save ore dressing Cost, 3, improve mineral processing index, 4, reduce cost for wastewater treatment etc..
The content of the invention:
Goal of the invention:Break through the dense effluent of vulcanization lead zinc flotation concentrate be discharged into Tailings Dam without using, use, Or it is used in mixed way with tailing filtration water;The dense effluent of lead concentrate is added into lead system and selects vulcanized lead, sulfuric acid will be contained Zinc metal ion and the use of diethyldithiocarbamate floating agent are in lead Beneficiation flowsheet (entering Turo pump pond);The dense effluent of zinc concentrate is straight Take back use, sulfuric acid copper metal ion and use of xanthate floating agent will be contained in zinc Beneficiation flowsheet, reached the raising rate of recovery with The purpose of mineral processing production index.
Technical scheme:
The dense effluent of lead concentrate adds lead system and selects vulcanized lead, will contain sulfuric acid zinc metal ion and diethyldithiocarbamate flotation Medicament use is in lead Beneficiation flowsheet (entering Turo pump pond);The dense effluent direct reuse of zinc concentrate, copper sulphate gold will be contained Belong to ion and use of xanthate floating agent in zinc Beneficiation flowsheet, avoid together with zinc sulfate and copper sulphate Ar ion mixing, reduction The consumption of zinc sulfate and copper sulphate medicament, reduce cost for wastewater treatment;Reach and reduce metal loss, reduce reagent consumption, section Beneficiation cost is saved, mineral processing index is improved, reduces the purpose of cost for wastewater treatment.

Claims (3)

1. the dense effluent sub-prime substep reuse technology of vulcanized lead zinc flotation concentrate, it is characterised in that the dense effluent of concentrate Sub-prime substep reuse technology structure composition includes:
Equipment:Pneumatic flotation cell, concentrate concentrator
Backwater place to use;The dense effluent of lead concentrate adds lead system and selects vulcanized lead, will contain sulfuric acid zinc metal ion and The use of diethyldithiocarbamate floating agent is in lead Beneficiation flowsheet (entering Turo pump pond);The dense effluent direct reuse of zinc concentrate, will contain There are sulfuric acid copper metal ion and the use of xanthate floating agent in zinc Beneficiation flowsheet.
The dense effluent process structure of lead concentrate:The dense effluent of lead concentrate adds lead system and selects vulcanized lead, will contain There are sulfuric acid zinc metal ion and the use of diethyldithiocarbamate floating agent in lead Beneficiation flowsheet (entering Turo pump pond);Bubble comprising lead system Foam flushing water, lead system health sweep water.
The dense effluent process structure of zinc concentrate:The dense effluent direct reuse of zinc concentrate, copper sulphate gold will be contained Belong to ion and the use of xanthate floating agent in zinc Beneficiation flowsheet;Flush with foam water comprising Zn system, lead system health sweep water.
2. the dense effluent technique of a kind of lead concentrate according to claim 1, it is characterised in that lead concentrate is dense excessive Flow waste water to be used alone, discord production water main links together.
3. the dense effluent technique of a kind of zinc concentrate according to claim 1, it is characterised in that zinc concentrate is dense excessive Flow waste water to be used alone, discord production water main links together.
CN201710549138.0A 2017-07-10 2017-07-10 The dense effluent sub-prime substep reuse technology of vulcanized lead zinc flotation concentrate Pending CN107335548A (en)

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CN201710549138.0A CN107335548A (en) 2017-07-10 2017-07-10 The dense effluent sub-prime substep reuse technology of vulcanized lead zinc flotation concentrate

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CN201710549138.0A CN107335548A (en) 2017-07-10 2017-07-10 The dense effluent sub-prime substep reuse technology of vulcanized lead zinc flotation concentrate

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108176515A (en) * 2017-12-21 2018-06-19 南京银茂铅锌矿业有限公司 A kind of Pb-Zn deposits ore-dressing technique method for saving clean water
CN109107773A (en) * 2018-08-17 2019-01-01 云南驰宏锌锗股份有限公司 The method for electrochemical floatation of lead sulfide mixed concentrate is recycled in a kind of high-grade Pb-Zn deposits
CN112723581A (en) * 2019-10-28 2021-04-30 奥图泰(芬兰)公司 Process water treatment method

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CN101417266A (en) * 2008-11-19 2009-04-29 湖南有色金属股份有限公司黄沙坪矿业分公司 New flotation technique of lead zinc sulphur ore
WO2014012139A1 (en) * 2012-07-17 2014-01-23 Teebee Holdings Pty Ltd Monothiophosphate containing collectors and methods
CN105642429A (en) * 2016-01-28 2016-06-08 南京泽天环保有限公司 Environment-friendly method for beneficiation by utilizing beneficiation backwater
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CN101417266A (en) * 2008-11-19 2009-04-29 湖南有色金属股份有限公司黄沙坪矿业分公司 New flotation technique of lead zinc sulphur ore
WO2014012139A1 (en) * 2012-07-17 2014-01-23 Teebee Holdings Pty Ltd Monothiophosphate containing collectors and methods
CN105642429A (en) * 2016-01-28 2016-06-08 南京泽天环保有限公司 Environment-friendly method for beneficiation by utilizing beneficiation backwater
CN106378260A (en) * 2016-09-29 2017-02-08 内蒙古东升庙矿业有限责任公司 Low-grade phyllite type lead zinc ore beneficiation method

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108176515A (en) * 2017-12-21 2018-06-19 南京银茂铅锌矿业有限公司 A kind of Pb-Zn deposits ore-dressing technique method for saving clean water
CN109107773A (en) * 2018-08-17 2019-01-01 云南驰宏锌锗股份有限公司 The method for electrochemical floatation of lead sulfide mixed concentrate is recycled in a kind of high-grade Pb-Zn deposits
CN112723581A (en) * 2019-10-28 2021-04-30 奥图泰(芬兰)公司 Process water treatment method
CN112723581B (en) * 2019-10-28 2024-03-26 美卓奥图泰芬兰有限公司 Process water treatment method

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Application publication date: 20171110