CN107254132A - A kind of stable type acrylic diamond and preparation method thereof - Google Patents
A kind of stable type acrylic diamond and preparation method thereof Download PDFInfo
- Publication number
- CN107254132A CN107254132A CN201710417936.8A CN201710417936A CN107254132A CN 107254132 A CN107254132 A CN 107254132A CN 201710417936 A CN201710417936 A CN 201710417936A CN 107254132 A CN107254132 A CN 107254132A
- Authority
- CN
- China
- Prior art keywords
- binding agent
- diamond
- stable type
- acrylic
- type acrylic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L35/02—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/162—Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
A kind of stable type acrylic diamond, by weight including following components：Neopentyl glycol dimethacrylate 80 100, binding agent 10 30, tertiary butyl perbenzoate 13, polyisobutene 23, the TSL 8330 2.1 3.2 of N phenyl 3, Fluorspar Powder 10 13, hydration zinc borate 24, rosin 34, binding agent 0.2 0.8, aluminium hydroxide 16 20.
Description
Technical field
The present invention relates to specifically related to a kind of stable type acrylic diamond and preparation method thereof.
Background technology
Molding acrylic diamond is prepared by the way that inorganic filler such as aluminium hydroxide is mixed into acrylic resinoid, this sub- gram
Power diamond has various excellent a functions and performance, such as outward appearance, soft feel, but be due to acrylic resinoid in itself
Characteristic causes product to there is certain defect.
The content of the invention
In order to solve the above problems, a kind of stable type acrylic diamond, by weight including following components：Dimethyl propylene
Olefin(e) acid DOPCP 80-100, binding agent 10-30, tertiary butyl perbenzoate 1-3, polyisobutene 2-3, N- phenyl -3- amino
Propyl trimethoxy silicane 2.1-3.2, Fluorspar Powder 10-13, hydration zinc borate 2-4, rosin 3-4, binding agent 0.2-0.8, hydrogen-oxygen
Change aluminium 16-20.
It is 3 that the binding agent, which includes weight ratio,:2:5:5 modification acrylate, ethyl propylene acid esters, epoxy acrylate
And butyl acrylate, formed in 90 DEG C of stirrings.
Also include the one or more in reinforcing agent, colouring agent, shrinking agent.
A kind of preparation method of the acrylic diamond of high printing opacity, step is as follows：Dimethacrylate is added in kneader new
Pentadiol ester, binding agent, polyisobutene, N- phenyl -3- TSL 8330s, Fluorspar Powder, hydration boric acid, rosin,
Binding agent, aluminium hydroxide, above-mentioned raw materials are mediated and obtain transparent acrylic moulding compound, acrylic moulding compound is filled into mould
In, solidify under 100-145 degrees Celsius, 20-50MPa pressure, acrylic diamond is made.
The present invention has the advantages that：This product substantially increases its stability, still exists from regardless of whether seeing outside
Real diamond is all more nearly in its performance, and the process made is simple, is particularly suitable for industrialized production.
Embodiment
Embodiment 1：A kind of stable type acrylic diamond, by weight including following components：Dimethacrylate new penta
Diol ester 80, binding agent 10, tertiary butyl perbenzoate 1, polyisobutene 2, N- phenyl -3- TSL 8330s 2.1,
Fluorspar Powder 10, hydration zinc borate 2, rosin 3, binding agent 0.2, aluminium hydroxide 16.
Embodiment 2：A kind of stable type acrylic diamond, by weight including following components：Dimethacrylate new penta
Diol ester 90, binding agent 20, tertiary butyl perbenzoate 2, polyisobutene 2.5, N- phenyl -3- TSL 8330s
2.5th, Fluorspar Powder 12, hydration zinc borate 3, rosin 3.5, binding agent 0.4, aluminium hydroxide 18.
Embodiment 3：A kind of stable type acrylic diamond, by weight including following components：Dimethacrylate new penta
Diol ester 100, binding agent 30, tertiary butyl perbenzoate 3, polyisobutene 3, N- phenyl -3- TSL 8330s
3.2nd, Fluorspar Powder 13, hydration zinc borate 4, rosin 4, binding agent 0.8, aluminium hydroxide 20, colouring agent 0.2.
It is 3 that the binding agent, which includes weight ratio,:2:5:5 modification acrylate, ethyl propylene acid esters, epoxy acrylate
And butyl acrylate, formed in 90 DEG C of stirrings.
A kind of preparation method of the acrylic diamond of high printing opacity, step is as follows：Dimethacrylate is added in kneader new
Pentadiol ester, binding agent, polyisobutene, N- phenyl -3- TSL 8330s, Fluorspar Powder, hydration boric acid, rosin,
Binding agent, aluminium hydroxide, above-mentioned raw materials are mediated and obtain transparent acrylic moulding compound, acrylic moulding compound is filled into mould
In, solidify under 100-145 degrees Celsius, 20-50MPa pressure, acrylic diamond is made.
Obviously, the above embodiment of the present invention is intended to be merely illustrative of the present example, and not to the present invention
Embodiment restriction.For those of ordinary skill in the field, it can also make on the basis of the above description
Other various forms of changes or variation.There is no need and unable to give poor example to all embodiments.And these belong to this
The obvious changes or variations that the connotation of invention is amplified out still falls within protection scope of the present invention.
Claims (4)
1. a kind of stable type acrylic diamond, by weight including following components：Neopentyl glycol dimethacrylate 80-
100th, binding agent 10-30, tertiary butyl perbenzoate 1-3, polyisobutene 2-3, N- phenyl -3- TSL 8330s
2.1-3.2, Fluorspar Powder 10-13, hydration zinc borate 2-4, rosin 3-4, binding agent 0.2-0.8, aluminium hydroxide 16-20.
2. a kind of stable type acrylic diamond according to claim 1, it is characterised in that：The binding agent includes weight ratio
For 3:2:5:5 modification acrylate, ethyl propylene acid esters, epoxy acrylate and butyl acrylate, is formed in 90 DEG C of stirrings.
3. a kind of stable type acrylic diamond according to claim 1, it is characterised in that：Also include reinforcing agent, colouring agent,
One or more in shrinking agent.
4. a kind of preparation method of the acrylic diamond of high printing opacity according to claim 1-3, it is characterised in that：Step is such as
Under：Neopentyl glycol dimethacrylate, binding agent, polyisobutene, N- phenyl -3- aminopropyl trimethoxies are added in kneader
Base silane, Fluorspar Powder, hydration boric acid, rosin, binding agent, aluminium hydroxide, above-mentioned raw materials are mediated and obtain transparent acrylic mould
Plastics, acrylic moulding compound is filled into mould, is solidified under 100-145 degrees Celsius, 20-50MPa pressure, is made sub- gram
Power diamond.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710417936.8A CN107254132A (en) | 2017-06-06 | 2017-06-06 | A kind of stable type acrylic diamond and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710417936.8A CN107254132A (en) | 2017-06-06 | 2017-06-06 | A kind of stable type acrylic diamond and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107254132A true CN107254132A (en) | 2017-10-17 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710417936.8A Pending CN107254132A (en) | 2017-06-06 | 2017-06-06 | A kind of stable type acrylic diamond and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107254132A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108003535A (en) * | 2017-12-25 | 2018-05-08 | 温州中祥光电科技发展有限公司 | A kind of high tenacity acryl plates and preparation method thereof |
| CN108059785A (en) * | 2017-12-25 | 2018-05-22 | 温州中祥光电科技发展有限公司 | A kind of high stability acryl plates and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
| CN103570275A (en) * | 2013-09-12 | 2014-02-12 | 江门市德山复合材料科技有限公司 | Pure acrylic artificial stone as well as manufacturing method thereof |
-
2017
- 2017-06-06 CN CN201710417936.8A patent/CN107254132A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
| CN103570275A (en) * | 2013-09-12 | 2014-02-12 | 江门市德山复合材料科技有限公司 | Pure acrylic artificial stone as well as manufacturing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108003535A (en) * | 2017-12-25 | 2018-05-08 | 温州中祥光电科技发展有限公司 | A kind of high tenacity acryl plates and preparation method thereof |
| CN108059785A (en) * | 2017-12-25 | 2018-05-22 | 温州中祥光电科技发展有限公司 | A kind of high stability acryl plates and preparation method thereof |
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20171017 |