CN107163467A - A kind of acrylic diamond of strong printing opacity and preparation method thereof - Google Patents
A kind of acrylic diamond of strong printing opacity and preparation method thereof Download PDFInfo
- Publication number
- CN107163467A CN107163467A CN201710417937.2A CN201710417937A CN107163467A CN 107163467 A CN107163467 A CN 107163467A CN 201710417937 A CN201710417937 A CN 201710417937A CN 107163467 A CN107163467 A CN 107163467A
- Authority
- CN
- China
- Prior art keywords
- acrylic
- printing opacity
- diamond
- binding agent
- strong printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/162—Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
A kind of acrylic diamond of strong printing opacity, by weight including following components：Epoxide number is 320 525 acrylic resin 70 80, tetradecane binary acid 6 10, polyisobutene 23, styrax 0.1 0.3, the TSL 8330 2.1 3.2 of N phenyl 3, Fluorspar Powder 10 13, hydration zinc borate 24, rosin 34, binding agent 0.2 0.8, aluminium hydroxide 16 20.
Description
Technical field
The present invention relates to specifically related to a kind of acrylic diamond of strong printing opacity and preparation method thereof.
Background technology
Molding acrylic diamond is prepared by the way that inorganic filler such as aluminium hydroxide is mixed into acrylic resinoid, this sub- gram
Power diamond has various excellent a functions and performance, such as outward appearance, soft feel, but be due to acrylic resinoid in itself
Characteristic causes product to there is certain defect.
The content of the invention
In order to solve the above problems, a kind of acrylic diamond of strong printing opacity, by weight including following components：Epoxide number
For 320-525 acrylic resin 70-80, tetradecane binary acid 6-10, polyisobutene 2-3, styrax 0.1-0.3, N- phenyl-
3- TSL 8330s 2.1-3.2, Fluorspar Powder 10-13, hydration zinc borate 2-4, rosin 3-4, binding agent 0.2-
0.8th, aluminium hydroxide 16-20.
It is 3 that the binding agent, which includes weight ratio,:2:5:5 modification acrylate, ethyl propylene acid esters, epoxy acrylate
And butyl acrylate, formed in 90 DEG C of stirrings.
Also include the one or more in reinforcing agent, colouring agent, shrinking agent.
A kind of preparation method of the acrylic diamond of strong printing opacity is as follows：It is the third of 320-525 that epoxide number is added in kneader
Olefin(e) acid resin, tetradecane binary acid, polyisobutene, styrax, N- phenyl -3- TSL 8330s, Fluorspar Powder, water
Firebrake ZB, rosin, binding agent, aluminium hydroxide are closed, above-mentioned raw materials are mediated and obtain transparent acrylic moulding compound, by acrylic mould
Filling plastic solidifies into mould under 100-145 degrees Celsius, 20-50MPa pressure, and acrylic diamond is made.
The present invention has the advantages that：This product substantially increases its translucency, still exists from regardless of whether seeing outside
Real diamond is all more nearly in its performance, and the process made is simple, is particularly suitable for industrialized production.
Embodiment
Embodiment 1：A kind of acrylic diamond of strong printing opacity, by weight including following components：Epoxide number is 320-525
Acrylic resin 70, tetradecane binary acid 6, polyisobutene 2, styrax 0.1, N- phenyl -3- aminopropyl trimethoxy silicon
Alkane 2.1, Fluorspar Powder 10, hydration zinc borate 2, rosin 3, binding agent 0.2, aluminium hydroxide 16.
Try embodiment 2：A kind of acrylic diamond of strong printing opacity, by weight including following components：Epoxide number is 320-
525 acrylic resin:75th, tetradecane binary acid 8, polyisobutene 2.5, styrax 0.2, N- phenyl -3- aminopropyl front threes
TMOS 2.5, Fluorspar Powder 11, hydration zinc borate 3, rosin 3.5, binding agent 0.6, aluminium hydroxide 18.
Embodiment 3：A kind of acrylic diamond of strong printing opacity, by weight including following components：Epoxide number is 320-525
Acrylic resin:80th, tetradecane binary acid 10, polyisobutene 3, styrax 0.3, N- phenyl -3- aminopropyl trimethoxies
Silane 3.2, Fluorspar Powder 13, hydration zinc borate 4, rosin 4, binding agent 0.8, aluminium hydroxide 20.
It is 3 that the binding agent, which includes weight ratio,:2:5:5 modification acrylate, ethyl propylene acid esters, epoxy acrylate
And butyl acrylate, formed in 90 DEG C of stirrings.
A kind of preparation method of the acrylic diamond of strong printing opacity is as follows：It is the third of 320-525 that epoxide number is added in kneader
Olefin(e) acid resin, tetradecane binary acid, polyisobutene, styrax, N- phenyl -3- TSL 8330s, Fluorspar Powder, water
Firebrake ZB, rosin, binding agent, aluminium hydroxide are closed, above-mentioned raw materials are mediated and obtain transparent acrylic moulding compound, by acrylic mould
Filling plastic solidifies into mould under 100-145 degrees Celsius, 20-50MPa pressure, and acrylic diamond is made.
Obviously, the above embodiment of the present invention is intended to be merely illustrative of the present example, and not to the present invention
Embodiment restriction.For those of ordinary skill in the field, it can also make on the basis of the above description
Other various forms of changes or variation.There is no need and unable to give poor example to all embodiments.And these belong to this
The obvious changes or variations that the connotation of invention is amplified out still falls within protection scope of the present invention.
Claims (4)
1. a kind of acrylic diamond of strong printing opacity, by weight including following components：Epoxide number is 320-525 acrylic acid tree
Fat 70-80, tetradecane binary acid 6-10, polyisobutene 2-3, styrax 0.1-0.3, N- phenyl -3- aminopropyl trimethoxies
Silane 2.1-3.2, Fluorspar Powder 10-13, hydration zinc borate 2-4, rosin 3-4, binding agent 0.2-0.8, aluminium hydroxide 16-20.
2. a kind of acrylic diamond of strong printing opacity according to claim 1, it is characterised in that：The binding agent includes weight
Than for 3:2:5:5 modification acrylate, ethyl propylene acid esters, epoxy acrylate and butyl acrylate, 90 DEG C stirring and
Into.
3. a kind of acrylic diamond of strong printing opacity according to claim 1, it is characterised in that：Also include reinforcing agent, coloring
One or more in agent, shrinking agent.
4. a kind of preparation method of the acrylic diamond of high printing opacity according to claim 1-3, it is characterised in that：Step is such as
Under：Acrylic resin, tetradecane binary acid, polyisobutene, styrax, N- benzene that epoxide number is 320-525 are added in kneader
Base -3- TSL 8330s, Fluorspar Powder, hydration zinc borate, rosin, binding agent, aluminium hydroxide, above-mentioned raw materials are pinched
Close and obtain transparent acrylic moulding compound, acrylic moulding compound is filled into mould, in 100-145 degrees Celsius, 20-50MPa
Pressure under solidify, acrylic diamond is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710417937.2A CN107163467A (en) | 2017-06-06 | 2017-06-06 | A kind of acrylic diamond of strong printing opacity and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710417937.2A CN107163467A (en) | 2017-06-06 | 2017-06-06 | A kind of acrylic diamond of strong printing opacity and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107163467A true CN107163467A (en) | 2017-09-15 |
Family
ID=59825607
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710417937.2A Pending CN107163467A (en) | 2017-06-06 | 2017-06-06 | A kind of acrylic diamond of strong printing opacity and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107163467A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333448A (en) * | 2013-07-11 | 2013-10-02 | 常熟市慧丰塑料制品有限公司 | Formula of multifunctional polymethylmethacrylate |
-
2017
- 2017-06-06 CN CN201710417937.2A patent/CN107163467A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333448A (en) * | 2013-07-11 | 2013-10-02 | 常熟市慧丰塑料制品有限公司 | Formula of multifunctional polymethylmethacrylate |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170915 |