CN107200984A - A kind of obdurability acrylic diamond and preparation method thereof - Google Patents
A kind of obdurability acrylic diamond and preparation method thereof Download PDFInfo
- Publication number
- CN107200984A CN107200984A CN201710417925.XA CN201710417925A CN107200984A CN 107200984 A CN107200984 A CN 107200984A CN 201710417925 A CN201710417925 A CN 201710417925A CN 107200984 A CN107200984 A CN 107200984A
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- compounded mix
- binding agent
- powder
- acrylic
- obdurability
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L35/02—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/162—Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
A kind of obdurability acrylic diamond, by weight including following components：Neopentyl glycol dimethacrylate 80 100, binding agent 10 30, tertiary butyl perbenzoate 13, polyisobutene 23, the TSL 8330 2.1 3.2 of N phenyl 3, Fluorspar Powder 10 13, hydration zinc borate 24, rosin 34, binding agent 0.2 0.8, compounded mix 16 20, what described compounded mix was made up of the raw material of following weight parts：Aluminium hydroxide 50 60, bone meal 46, iron ore ground-slag 10 13, wollastonite in powder 57, sodium tripolyphosphate 12, DTAC 23, eucalyptus oil 12, the preparation method of described compounded mix is by above-mentioned aluminium hydroxide, iron ore ground-slag, wollastonite in powder is mixed, calcined 34 hours at 600 800 DEG C, cooling discharging, add eucalyptus oil, it is well mixed, obtain premix, sodium tripolyphosphate is added in 15 20 times of water, it is stirring evenly and then adding into DTAC, it is 60 80 DEG C to raise temperature, with above-mentioned premix mixed grinding, drying, cross 80 100 mesh sieves, produce the compounded mix.
Description
Technical field
The present invention relates to specifically related to a kind of obdurability acrylic diamond and preparation method thereof.
Background technology
Molding acrylic diamond is prepared by the way that inorganic filler such as aluminium hydroxide is mixed into acrylic resinoid, this sub- gram
Power diamond has various excellent a functions and performance, such as outward appearance, soft feel, but be due to acrylic resinoid in itself
Characteristic causes product to there is certain defect.
The content of the invention
A kind of obdurability acrylic diamond, by weight including following components：Neopentyl glycol dimethacrylate 80-
100th, binding agent 10-30, tertiary butyl perbenzoate 1-3, polyisobutene 2-3, N- phenyl -3- TSL 8330s
2.1-3.2, Fluorspar Powder 10-13, hydration zinc borate 2-4, rosin 3-4, binding agent 0.2-0.8, compounded mix 16-20, it is described
Compounded mix is made up of the raw material of following weight parts：Aluminium hydroxide 50-60, bone meal 4-6, iron ore ground-slag 10-13, wollastonite
Powder 5-7, sodium tripolyphosphate 1-2, DTAC 2-3, eucalyptus oil 1-2, the making side of described compounded mix
Method is to mix above-mentioned aluminium hydroxide, iron ore ground-slag, wollastonite in powder, is calcined 3-4 hours at 600-800 DEG C, cooling discharging, plus
Enter eucalyptus oil, be well mixed, obtain premix, sodium tripolyphosphate is added in 15-20 times of water, dodecane is stirring evenly and then adding into
Base trimethyl ammonium chloride, rise temperature is 60-80 DEG C, and with above-mentioned premix mixed grinding, drying is crossed 80-100 mesh sieves, produced
The compounded mix.
It is 3 that the binding agent, which includes weight ratio,:2:5:5 modification acrylate, ethyl propylene acid esters, epoxy acrylate
And butyl acrylate, formed in 90 DEG C of stirrings.
Also include the one or more in reinforcing agent, colouring agent, shrinking agent.
A kind of preparation method of the acrylic diamond of high printing opacity, step is as follows：Dimethacrylate is added in kneader new
Pentadiol ester, binding agent, polyisobutene, N- phenyl -3- TSL 8330s, Fluorspar Powder, hydration boric acid, rosin,
Binding agent, compounded mix, above-mentioned raw materials are mediated and obtain transparent acrylic moulding compound, acrylic moulding compound is filled into mould
In, solidify under 100-145 degrees Celsius, 20-50MPa pressure, acrylic diamond is made.
The present invention has the advantages that：This product substantially increases its obdurability, still exists from regardless of whether seeing outside
Real diamond is all more nearly in its performance, and the process made is simple, is particularly suitable for industrialized production.
Embodiment
Embodiment 1：A kind of obdurability acrylic diamond, by weight including following components：Dimethacrylate new penta
Diol ester 80, binding agent 10, tertiary butyl perbenzoate 1, polyisobutene 2, N- phenyl -3- TSL 8330s 2.1,
Fluorspar Powder 10, hydration zinc borate 2, rosin 3, binding agent 0.2, compounded mix 16, described compounded mix is by following weight parts
Raw material composition：Aluminium hydroxide 50, bone meal 4, iron ore ground-slag 10, wollastonite in powder 5, sodium tripolyphosphate 1, trimethyl
Ammonium chloride 2, eucalyptus oil 1, the preparation method of described compounded mix are to mix above-mentioned aluminium hydroxide, iron ore ground-slag, wollastonite in powder
Close, calcined 3-4 hours at 600-800 DEG C, cooling discharging, add eucalyptus oil, be well mixed, premix obtained, by tripolyphosphate
Sodium is added in 15-20 times of water, is stirring evenly and then adding into DTAC, and rise temperature is 60-80 DEG C, and upper
Premix mixed grinding is stated, is dried, 80-100 mesh sieves is crossed, produces the compounded mix.
Embodiment 2：A kind of obdurability acrylic diamond, by weight including following components：Dimethacrylate new penta
Diol ester 90, binding agent 20, tertiary butyl perbenzoate 2, polyisobutene 2.5, N- phenyl -3- TSL 8330s
2.5th, Fluorspar Powder 12, hydration zinc borate 3, rosin 3.5, binding agent 0.4, compounded mix 18, described compounded mix is by following
The raw material composition of parts by weight：Aluminium hydroxide 55, bone meal 5, iron ore ground-slag 11, wollastonite in powder 6, sodium tripolyphosphate 1.5, dodecane
Base trimethyl ammonium chloride 2.5, eucalyptus oil 1.5, the preparation method of described compounded mix is by above-mentioned aluminium hydroxide, Iron-ore Slag
Powder, wollastonite in powder mixing, calcine 3-4 hours, cooling discharging at 600-800 DEG C, add eucalyptus oil, be well mixed, must premix
Material, sodium tripolyphosphate is added in 15-20 times of water, is stirring evenly and then adding into DTAC, raises temperature
For 60-80 DEG C, with above-mentioned premix mixed grinding, drying crosses 80-100 mesh sieves, produces the compounded mix.
Embodiment 3：A kind of obdurability acrylic diamond, by weight including following components：Dimethacrylate new penta
Diol ester 100, binding agent 30, tertiary butyl perbenzoate 3, polyisobutene 3, N- phenyl -3- TSL 8330s
3.2nd, Fluorspar Powder 13, hydration zinc borate 4, rosin 4, binding agent 0.8, colouring agent 0.5, compounded mix 20, described compounded mix
It is made up of the raw material of following weight parts：Aluminium hydroxide 60, bone meal 6, iron ore ground-slag 13, wollastonite in powder 7, sodium tripolyphosphate 2,
DTAC 3, eucalyptus oil 2, the preparation method of described compounded mix is by above-mentioned aluminium hydroxide, Iron-ore Slag
Powder, wollastonite in powder mixing, calcine 3-4 hours, cooling discharging at 600-800 DEG C, add eucalyptus oil, be well mixed, must premix
Material, sodium tripolyphosphate is added in 15-20 times of water, is stirring evenly and then adding into DTAC, raises temperature
For 60-80 DEG C, with above-mentioned premix mixed grinding, drying crosses 80-100 mesh sieves, produces the compounded mix.
It is 3 that the binding agent, which includes weight ratio,:2:5:5 modification acrylate, ethyl propylene acid esters, epoxy acrylate
And butyl acrylate, formed in 90 DEG C of stirrings.
A kind of preparation method of the acrylic diamond of high printing opacity, step is as follows：Dimethacrylate is added in kneader new
Pentadiol ester, binding agent, polyisobutene, N- phenyl -3- TSL 8330s, Fluorspar Powder, hydration boric acid, rosin,
Binding agent, compounded mix, above-mentioned raw materials are mediated and obtain transparent acrylic moulding compound, acrylic moulding compound is filled into mould
In, solidify under 100-145 degrees Celsius, 20-50MPa pressure, acrylic diamond is made.
Obviously, the above embodiment of the present invention is intended to be merely illustrative of the present example, and not to the present invention
Embodiment restriction.For those of ordinary skill in the field, it can also make on the basis of the above description
Other various forms of changes or variation.There is no need and unable to give poor example to all embodiments.And these belong to this
The obvious changes or variations that the connotation of invention is amplified out still falls within protection scope of the present invention.
Claims (4)
1. a kind of obdurability acrylic diamond, it is characterised in that：Include following components by weight：Dimethacrylate new penta
Diol ester 80-100, binding agent 10-30, tertiary butyl perbenzoate 1-3, polyisobutene 2-3, N- phenyl -3- aminopropyl front threes
TMOS 2.1-3.2, Fluorspar Powder 10-13, hydration zinc borate 2-4, rosin 3-4, binding agent 0.2-0.8, compounded mix 16-
20, what described compounded mix was made up of the raw material of following weight parts：Aluminium hydroxide 50-60, bone meal 4-6, iron ore ground-slag 10-
13rd, wollastonite in powder 5-7, sodium tripolyphosphate 1-2, DTAC 2-3, eucalyptus oil 1-2, described compounded mix
Preparation method be by above-mentioned aluminium hydroxide, iron ore ground-slag, wollastonite in powder mix, at 600-800 DEG C calcine 3-4 hours, it is cold
But discharge, add eucalyptus oil, be well mixed, obtain premix, sodium tripolyphosphate is added in 15-20 times of water, after stirring
DTAC is added, rise temperature is 60-80 DEG C, with above-mentioned premix mixed grinding, 80-100 is crossed in drying
Mesh sieve, produces the compounded mix.
2. a kind of obdurability acrylic diamond according to claim 1, it is characterised in that：The binding agent includes weight ratio
For 3:2:5:5 modification acrylate, ethyl propylene acid esters, epoxy acrylate and butyl acrylate, is formed in 90 DEG C of stirrings.
3. a kind of obdurability acrylic diamond according to claim 1, it is characterised in that：Also include reinforcing agent, colouring agent,
One or more in shrinking agent.
4. a kind of preparation method of the acrylic diamond of high printing opacity according to claim 1-3, it is characterised in that：Step is such as
Under：Neopentyl glycol dimethacrylate, binding agent, polyisobutene, N- phenyl -3- aminopropyl trimethoxies are added in kneader
Base silane, Fluorspar Powder, hydration boric acid, rosin, binding agent, compounded mix, above-mentioned raw materials are mediated and obtain transparent acrylic mould
Plastics, acrylic moulding compound is filled into mould, is solidified under 100-145 degrees Celsius, 20-50MPa pressure, is made sub- gram
Power diamond.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710417925.XA CN107200984A (en) | 2017-06-06 | 2017-06-06 | A kind of obdurability acrylic diamond and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710417925.XA CN107200984A (en) | 2017-06-06 | 2017-06-06 | A kind of obdurability acrylic diamond and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107200984A true CN107200984A (en) | 2017-09-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710417925.XA Pending CN107200984A (en) | 2017-06-06 | 2017-06-06 | A kind of obdurability acrylic diamond and preparation method thereof |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3959980A1 (en) | 2020-08-25 | 2022-03-02 | Schock GmbH | Thermosetting casting compound, moulded article made from same, and method for producing the moulded item |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
| CN103570275A (en) * | 2013-09-12 | 2014-02-12 | 江门市德山复合材料科技有限公司 | Pure acrylic artificial stone as well as manufacturing method thereof |
-
2017
- 2017-06-06 CN CN201710417925.XA patent/CN107200984A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101570413A (en) * | 2008-12-30 | 2009-11-04 | 上海新天和树脂有限公司 | Acrylic artificial stone and method for preparing same |
| CN103570275A (en) * | 2013-09-12 | 2014-02-12 | 江门市德山复合材料科技有限公司 | Pure acrylic artificial stone as well as manufacturing method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3959980A1 (en) | 2020-08-25 | 2022-03-02 | Schock GmbH | Thermosetting casting compound, moulded article made from same, and method for producing the moulded item |
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| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170926 |
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| RJ01 | Rejection of invention patent application after publication |