CN107227074A - Nano thermal insulation sound-absorbing anti-nuclear radiation coating material - Google Patents

Nano thermal insulation sound-absorbing anti-nuclear radiation coating material Download PDF

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Publication number
CN107227074A
CN107227074A CN201610170323.4A CN201610170323A CN107227074A CN 107227074 A CN107227074 A CN 107227074A CN 201610170323 A CN201610170323 A CN 201610170323A CN 107227074 A CN107227074 A CN 107227074A
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CN
China
Prior art keywords
nuclear radiation
coating material
radiation coating
thermal insulation
sound
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610170323.4A
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Chinese (zh)
Inventor
吕世宁
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Shandong Blue Union Anti-Corrosion Polytron Technologies Inc
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Shandong Blue Union Anti-Corrosion Polytron Technologies Inc
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Priority to CN201610170323.4A priority Critical patent/CN107227074A/en
Publication of CN107227074A publication Critical patent/CN107227074A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32—Radiation-absorbing paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/34—Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention have developed a kind of nano thermal insulation sound-absorbing anti-nuclear radiation coating material, and the coating material can have insulation, sound-absorbing, the whole of anti-nuclear radiation function according to demand or wherein combine.The base-material of the coating material is a kind of aqueous nanometer anti-nuclear radiation material, consisting of water-based emulsion, blanc fixe, nano-tourmaline powder, nanometer scale graphite, water and auxiliary agent dispersant, defoamer, thickener, epoxy silane coupling etc.；The nm radiation material anti-nuclear radiation ability is strong, and class coating material is firmly combined with each other, with matrix, and water paste can be made with the cooperation such as expanded perlite, expanded vermiculite, cement（Putty）, thicker nano thermal insulation sound-absorbing anti-nuclear radiation coating is manufactured in wall.

Description

Nano thermal insulation sound-absorbing anti-nuclear radiation coating material
Technical field
The present invention relates to building coating technical field, espespecially nano thermal insulation sound-absorbing anti-nuclear radiation coating material.
Background technology
The blast of the Chernobyl Plant of the former Soviet Union is with nuclear leakage to the not yet recovered from a fright of people, Fukushima, Japan nuclear power station Blast and nuclear leakage more allow the research of people's most attention anti-nuclear radiation material.Traditional radiation proof, nuclear radiation material one is inhaled A large amount of influences used to environment, the harm to human health using lead, but lead can not be underestimated, " blood lead " thing occurred repeatedly Part etc. allows the salt that people have to eye be turned to environment-friendly anti-nuclear radiation material, such as barite, blanc fixe, strontium Class, tourmaline, graphite, perlite vermiculite etc., current use research and popularization have obvious quickening, but ripe product is few.
World's main trend of energy-saving and emission-reduction, makes China make Compulsory Feature to skin insulation, the current insulation Layer uses foamed polystyrene plates mostly, and such sheet material not only combines difficulty in interior walls, external skin, ftractures, comes off, rising Drum phenomenon happens occasionally, and Shanghai big fire, and Shenyang big fire, Jinan Olympic Sports Center big fire represents the security of such material very Make people worried, the carcinogen effect on environment that more seriously such material chance high temperature and big fire are separated is very big.
Urbanization degree of progress speed, human work, production, living area high concentration, high building stands in great numbers, the vehicles are ants In groups, noise pollution makes rhythm of life more and more faster, and nervous people are difficult to bear.Current light heat insulation material has one Fixed sound-absorbing effect, but it is very undesirable, it is highly desirable to develop the sound-absorbing material that can be used in building.
The content of the invention
The present invention for prior art deficiency there is provided a kind of heat-insulating and sound-absorbing anti-nuclear radiation coating material, its insulation, sound-absorbing, Anti-nuclear radiation function admirable, formula have innovation, preparation technology it is simple, using easy construction.
To achieve these goals, technical solution of the invention is:A kind of heat-insulating and sound-absorbing anti-nuclear radiation coating material, It can be divided into anti-nuclear radiation coating material and add the aqueous of the making such as aglite, cement with the anti-nuclear radiation coating material Slurry（Putty）.
The specifications of raw materials and quality proportioning of the anti-nuclear radiation coating material of the present invention are as follows：
The mesh 30% -50% of blanc fixe 300
Nano-tourmaline powder<200nm 2%—4%
Nanometer scale graphite powder<200nm 0.3%—1%
Water-based emulsion（Phenylpropyl alcohol, pure third, fluorocarbon resin emulsion or its cooperation）
50% solid point 10% -20%
Toning mill base 3% -8%
Dispersant NNO 0.5% -3.0%
Appropriate defoamer
Thickener HE2 is appropriate
Ethylene glycol 0.2% -0.5%
Epoxy silane coupling 0.3% -0.8%
Water 40% -55%
The manufacturing process of the coating is：
Water, dispersant NNO, blanc fixe, nano-tourmaline powder, nanometer scale graphite are added into sand mill, half is sanded at a high speed small When, the slurry of releasing adds other components under high velocity agitation, finally adjusts viscosity, and packaging is finished product.
The water paste of the present invention（Putty）Constituent mass ratio and manufacturing process be：
By 100 parts above-mentioned of anti-nuclear radiation coating, the swelling perlite powder of 80 mesh, expanded vermiculite powder or its mixture 100 are added Part is mixed into uniform paste to 300 parts, No. 500 30 parts to 80 parts of cement, appropriate cement water reducing agents and water in kneader .
The present invention outstanding feature be：
The blanc fixe for thering is good barrier to act on to nuclear radiation wide spectrum electromagnetic wave, the electric polarity for having coordinated electromagnetic barrier good are used Mineral tourmaline nano powder, anti-nuclear radiation and the good nanometer scale graphite powder of sound-absorbing effect, in water paint（Putty）In more The heat-insulating and sound-absorbing effect for adding lightweight is good, and swelling perlite powder, the expanded vermiculite powder for having certain anti-nuclear radiation function pass through excellent Apolegamy conjunction has obtained excellent heat-insulating and sound-absorbing and has put nuclear radiation function.
Flexible and convenient to use, environment-friendly, material of the invention can be used in interior wall, can be used for exterior wall, aqueous slurry （Putty）Thicker soil layer can be made preferably it be incubated, isolates, puts nuclear radiation function by repeatedly brushing；The present invention makes Raw material are nontoxic, environment-friendly, fire safety.
The important breakthrough of the present invention introduces epoxy silane coupling, epoxy radicals silicone hydride in aqueous architectural coating material Coupling agent not only makes to be firmly combined between each component in coating material, can also make coating material and building basis（Wall, top Canopy, roof）Adhesion greatly reinforce, can avoid ftractureing, come off, the bad phenomenon such as hollowing.
Embodiment
The anti-nuclear radiation coating material embodiment of the present invention of table 1
Embodiment 1 Embodiment 2 Embodiment 3
The mesh of blanc fixe 300 35 40 50
Nano-tourmaline powder<200nm 4 3 2
Nanometer scale graphite powder<200nm 0.8 0.6 0.4
Water-based emulsion（Solid point 50%） 20 18 15
Toning mill base 8 5 0
Dispersant NNO 3 2 1
Defoamer In right amount In right amount In right amount
Thickener HE2 In right amount In right amount In right amount
Ethylene glycol 0.3 0.3 0.3
Epoxy silane coupling 0.8 0.6 0.4
Water 28 30 31
Preparing process is：Water, dispersant NNO, blanc fixe, nano-tourmaline powder, nanometer scale graphite powder are added into sand mill, Half an hour is sanded at a high speed, the slurry of releasing adds other components under high velocity agitation, finally adjusts viscosity, packaging is finished product.
The water paste of the present invention of table 2（Putty）Embodiment
Embodiment 4 Embodiment 5 Embodiment 6
Radiation shielding coating 100 100 100
The mesh of swelling perlite powder 80 180 100
The mesh of expanded vermiculite powder 80 180 100
Cement 500 50 50 60
Water reducer 0.5 0.5 0.6
Add epoxy silane coupling 0.5 0.7 0.8
Water In right amount In right amount In right amount
Preparing process is：Various materials are added in kneader in upper table ratio, the uniform paste for being easy to construct is mixed into .

Claims (8)

1. a kind of nano thermal insulation sound-absorbing anti-nuclear radiation coating material, can be subdivided into aqueous anti-nuclear radiation coating and water paste（It is greasy Son）, and water paste is to add lightweight feature aggregate using aqueous radiation shielding coating, cement etc. is prepared.
2. nano thermal insulation sound-absorbing anti-nuclear radiation coating material according to claim 1, it is characterised in that：It is wherein described aqueous Anti-nuclear radiation coating, is that film forming agent, blanc fixe, nano-tourmaline powder, nanometer scale graphite are that function is filled out using water-based emulsion Material, adds water in addition and auxiliary agent dispersant, defoamer, thickener, epoxy silane coupling etc. are dispersed through, grind and be made.
3. nano thermal insulation sound-absorbing anti-nuclear radiation coating material according to claim 1, it is characterised in that：It is wherein described aqueous Slurry（Putty）It is the aqueous anti-nuclear radiation coating using the present invention, coordinates lightweight function aggregate, cement and cement water reducing agent warp Kneader mixed preparing.
4. nano thermal insulation sound-absorbing anti-nuclear radiation coating material according to claim 1, it is characterised in that can be with comparison Thick coating.
5. according to claim 1 nanometer of sound-absorbing anti-nuclear radiation coating material, it is characterised in that:Excellent anti-core spoke is used The blanc fixe of the mesh of 200 mesh -300 of function is penetrated, particle diameter is less than 200nm tourmaline powder and crystalline graphite powder.
6. nano thermal insulation sound-absorbing anti-nuclear radiation coating material according to claim 1, it is characterised in that：Insulation has been used to inhale Sound performance is good and has a kind of swelling perlite powder and expanded vermiculite powder of anti-nuclear radiation function.
7. nano thermal insulation sound-absorbing anti-nuclear radiation coating material according to claim 1, it is characterised in that：Painting can be made by having used The silane coupler containing epoxy radicals being firmly combined with of membrane material each other, with matrix.
8. nano thermal insulation sound-absorbing anti-nuclear radiation coating material according to claim 1, wherein described water-based emulsion can be with Coordinated using styrene-acrylic emulsion, pure-acrylic emulsion, the one or two kinds of of fluorocarbon resin emulsion.
CN201610170323.4A 2016-03-23 2016-03-23 Nano thermal insulation sound-absorbing anti-nuclear radiation coating material Withdrawn CN107227074A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610170323.4A CN107227074A (en) 2016-03-23 2016-03-23 Nano thermal insulation sound-absorbing anti-nuclear radiation coating material

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Application Number Priority Date Filing Date Title
CN201610170323.4A CN107227074A (en) 2016-03-23 2016-03-23 Nano thermal insulation sound-absorbing anti-nuclear radiation coating material

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109928698A (en) * 2019-04-09 2019-06-25 台州普立德建筑科技有限公司 A kind of water proof building exterior wall
CN111534160A (en) * 2020-04-29 2020-08-14 湖北中科博策新材料科技有限公司 Radiation-proof water paint and production process thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101831211A (en) * 2010-05-13 2010-09-15 谢绍何 Sound-absorbing radiation protective paint and preparation method thereof
CN106928781A (en) * 2015-12-31 2017-07-07 张文知 A kind of nanometer anti-nuclear radiation coating

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101831211A (en) * 2010-05-13 2010-09-15 谢绍何 Sound-absorbing radiation protective paint and preparation method thereof
CN106928781A (en) * 2015-12-31 2017-07-07 张文知 A kind of nanometer anti-nuclear radiation coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109928698A (en) * 2019-04-09 2019-06-25 台州普立德建筑科技有限公司 A kind of water proof building exterior wall
CN111534160A (en) * 2020-04-29 2020-08-14 湖北中科博策新材料科技有限公司 Radiation-proof water paint and production process thereof

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Application publication date: 20171003

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