CN107217326A - A kind of environment-friendly antibacterial flame-retardant garment plus material - Google Patents
A kind of environment-friendly antibacterial flame-retardant garment plus material Download PDFInfo
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- CN107217326A CN107217326A CN201710522025.1A CN201710522025A CN107217326A CN 107217326 A CN107217326 A CN 107217326A CN 201710522025 A CN201710522025 A CN 201710522025A CN 107217326 A CN107217326 A CN 107217326A
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- retardant
- antibacterial flame
- environment
- fiber
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/08—Heat resistant; Fire retardant
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/30—Antimicrobial, e.g. antibacterial
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of environment-friendly antibacterial flame-retardant garment plus material, and the garment material is made into fabric body by yarn of antibacterial flame-retardant fiber, and gained fabric body is dyed and post-processes to obtain garment material finished product, and the antibacterial flame-retardant fiber includes the composition of following parts by weight:Polyacrylonitrile carbon fiber:20 ~ 30 parts, cotton fiber:5 ~ 10 parts, nanometer silver antimicrobial master batch:20 ~ 30 parts, methylcellulose:15 ~ 20 parts, chitosan:5 ~ 10 parts, stearmide:5 ~ 10 parts, fire resistance fibre:10 ~ 15 parts, water-soluble binder:5 ~ 10 parts.The garment material uses special antibacterial flame-retardant fiber, assigns fabric excellent antibacterial flame-retardant performance, and antibacterial flame-retardant fibre composition is reasonable in design, and preparation cost is low, good in economic efficiency.
Description
Technical field
The invention belongs to garment material technical field, in particular it relates to a kind of environment-friendly antibacterial flame-retardant garment plus material.
Background technology
Clothes are made with fabric, and fabric is exactly the material for making clothes.It is used as one of clothes three elements, fabric
Can not only annotate the style and characteristic of clothes, and directly left and right the color of clothes, the expression effect of moulding.Presentation is come from
The noble quality of body is perfect, soft.
Modern times are produced on the clothes of formal social life institute wear, many blended yarn weaved fabrics from high-quality.And it is pure cotton, pure
The natural fabric such as hair, pure silk, pure fiber crops has become general cloth because there is the easily natural fabric such as wrinkle, yielding, compared with
It is few to be used as high-grade clothing materials.Blended yarn weaved fabric has natural fabric sweat-absorbing breathable, it is soft comfortable the characteristics of, chemical fibre face is absorbed again
Material is solid to wear well, overhangs the advantages of well-pressed, good luster color is vivid, has substantial amounts of high-grade high-quality blended yarn weaved fabric to be developed every year
Come.
Intelligence is ground data research centre data and shown:Price of the cotton goes up to cause entirely to produce chain cost and increased, and produce chain one is
Row product has to appreciate, and has exactly expedited the emergence of the new opportunity of apparel industry fabric, and the upgrading scapegoat zein fiber of cotton, bamboo are fine
Dimension, novel plant flaxen fiber etc. come on stage with glittering appearance, and these bio-based fabrics more save water and agricultural chemicals, symbol in process of production than cotton
Close the demand of consumer or even the whole society to low-carbon environment-friendly.
For garment material, the current country is primarily present following patent document:
China Patent Publication No.:CN106835467A, discloses the preparation side that a kind of multi-functional high-elastic antibacterial flame-retardant is knitted fabric
Method, comprises the following steps:Step 1, fabric is weaved, base is woven into using PTT anti-bacterial fibres, cotton fiber and fire-retardant PTFE fiber
Cloth;Step 2, preshrinking process, pre- shrink process is carried out to fabric, forms permanent three dimensional coil crimp;Step 3, dyeing,
The technique for slowing down temperature rate using staged is dyed to fabric;Step 4, soft treatment, using containing hydrophilic silicone oil
The treatment fluid of softening agent and moisture absorbing and sweat releasing auxiliary agent carries out soft treatment to fabric;Step 5, setting process, using forming machine to base
Cloth is shaped, and shaping liquid contains hydrophilic silicone oil softening agent and moisture absorbing and sweat releasing auxiliary agent.The multi-functional high-elastic antibacterial flame-retardant of the present invention
Be knitted fabric, with anti-freeze, waterproof, windproof, fire prevention, fire-retardant, antistatic, antibacterial, moisture-inhibiting, it is light and it is anti-detect pretend etc. work(
Can, it can be widely applied to the special type protection clothes fabric such as army, fire-fighting, gas defence.However, the patent provides the system of knitting fabric
Preparation Method, complex process, but composition are simple, and fabric performance is excessive, and influence is used.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide a kind of environment-friendly antibacterial flame-retardant garment plus material, institute
Garment material is stated using special antibacterial flame-retardant fiber, assigns fabric excellent antibacterial flame-retardant performance, and antibacterial flame-retardant fiber into
Divide reasonable in design, preparation cost is low, good in economic efficiency.
To reach above-mentioned purpose, the technical scheme is that:
A kind of environment-friendly antibacterial flame-retardant garment plus material, the garment material is made into fabric body, institute by yarn of antibacterial flame-retardant fiber
Fabric body is dyed and post-process to obtain garment material finished product, the antibacterial flame-retardant fiber include following parts by weight into
Point:Polyacrylonitrile carbon fiber:20 ~ 30 parts, cotton fiber:5 ~ 10 parts, nanometer silver antimicrobial master batch:20 ~ 30 parts, methylcellulose:15~
20 parts, chitosan:5 ~ 10 parts, stearmide:5 ~ 10 parts, fire resistance fibre:10 ~ 15 parts, water-soluble binder:5 ~ 10 parts.
Further, the antibacterial flame-retardant fiber includes the composition of following parts by weight:Polyacrylonitrile carbon fiber:25 ~ 30 parts, cotton
Fiber:5 ~ 8 parts, nanometer silver antimicrobial master batch:25 ~ 30 parts, methylcellulose:15 ~ 18 parts, chitosan:7 ~ 10 parts, stearmide:7
~ 10 parts, fire resistance fibre:10 ~ 13 parts, water-soluble binder:5 ~ 8 parts.
Preferably, the antibacterial flame-retardant fiber includes the composition of following parts by weight:Polyacrylonitrile carbon fiber:25 parts, cotton is fine
Dimension:8 parts, nanometer silver antimicrobial master batch:25 parts, methylcellulose:16 parts, chitosan:7 parts, stearmide:8 parts, fire resistance fibre:
13 parts, water-soluble binder:6 parts.
Preferably, the nanometer silver antimicrobial master batch includes the composition of following parts by weight:Nano-Ag particles:20 ~ 30 parts, carry
Body:10 ~ 15 parts, polyester slice:30 ~ 40 parts, coupling agent:5 ~ 10 parts, dispersant:5 ~ 10 parts.
Preferably, the nanometer silver antimicrobial agglomerate preparation method comprises the following steps:Nano-Ag particles and carrier are reacted,
Make nano-Ag particles uniform adsorption into carrier, then with coupling agent and dispersant and being added in high-speed mixer, 180
At ~ 220 DEG C, mixer inner screw rotating speed is 200 ~ 300 revs/min, is kneaded 30 ~ 50 minutes, obtains powder, then by powder and with gathering
The extrusion of the mixed merga pass double screw extruder of ester section, shaping, pelletizing, obtain the nanometer silver antimicrobial master batch.
Preferably, the polyester slice is cut into slices for PBT.
Preferably, the carrier is particular type zeolite or SiO2。
Preferably, the dispersant is AEO, APES, aliphatic acid polyethenoxy ether
Or tristerin.
Preferably, the coupling agent is monoalkoxytitanates, monoalkoxy vinethene or many alkoxy vinyl ethers.
Preferably, the antibacterial flame-retardant fiber producing processes comprise the following steps:By polyacrylonitrile carbon fiber, cotton fiber,
Fire resistance fibre is uniformly mixed, and adds nanometer silver antimicrobial master batch, methylcellulose, chitosan, stearmide, water-soluble binder,
Stirring, blending, are added in screw extruder and carry out melt extruded, the melt fully melted is transported into spinning by melt pipe
In silk casing, 270 ~ 300 DEG C of manifold spinning temperature, 2500 ~ 3500m/min of spinning speed, afterwards from the spray orifice of spinning head
Extrude, tow carries out cooled and solidified into silk in the crosswind that temperature is 18-20 DEG C, humidity is 58 ~ 60%, is then placed in boiling water
20 ~ 25min is boiled, drying is taken out, you can obtain the antibacterial flame-retardant fiber.
The beneficial effects of the present invention are:
The garment material uses special antibacterial flame-retardant fiber, assigns fabric excellent antibacterial flame-retardant performance, and antibacterial flame-retardant
Fibre composition is reasonable in design, and preparation cost is low, good in economic efficiency.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention
Scope.
A kind of environment-friendly antibacterial flame-retardant garment plus material of the present invention, the garment material is using antibacterial flame-retardant fiber as yarn
Fabric body is made into, gained fabric body is dyed and post-processes to obtain garment material finished product, and the antibacterial flame-retardant fiber includes
The composition of following parts by weight:Polyacrylonitrile carbon fiber:20 ~ 30 parts, cotton fiber:5 ~ 10 parts, nanometer silver antimicrobial master batch:20 ~ 30 parts,
Methylcellulose:15 ~ 20 parts, chitosan:5 ~ 10 parts, stearmide:5 ~ 10 parts, fire resistance fibre:10 ~ 15 parts, water soluble adhesive
Agent:5 ~ 10 parts.
Further, the antibacterial flame-retardant fiber includes the composition of following parts by weight:Polyacrylonitrile carbon fiber:25 ~ 30 parts, cotton
Fiber:5 ~ 8 parts, nanometer silver antimicrobial master batch:25 ~ 30 parts, methylcellulose:15 ~ 18 parts, chitosan:7 ~ 10 parts, stearmide:7
~ 10 parts, fire resistance fibre:10 ~ 13 parts, water-soluble binder:5 ~ 8 parts.
Preferably, the antibacterial flame-retardant fiber includes the composition of following parts by weight:Polyacrylonitrile carbon fiber:25 parts, cotton is fine
Dimension:8 parts, nanometer silver antimicrobial master batch:25 parts, methylcellulose:16 parts, chitosan:7 parts, stearmide:8 parts, fire resistance fibre:
13 parts, water-soluble binder:6 parts.
Preferably, the nanometer silver antimicrobial master batch includes the composition of following parts by weight:Nano-Ag particles:20 ~ 30 parts, carry
Body:10 ~ 15 parts, polyester slice:30 ~ 40 parts, coupling agent:5 ~ 10 parts, dispersant:5 ~ 10 parts.
Preferably, the nanometer silver antimicrobial agglomerate preparation method comprises the following steps:Nano-Ag particles and carrier are reacted,
Make nano-Ag particles uniform adsorption into carrier, then with coupling agent and dispersant and being added in high-speed mixer, 180
At ~ 220 DEG C, mixer inner screw rotating speed is 200 ~ 300 revs/min, is kneaded 30 ~ 50 minutes, obtains powder, then by powder and with gathering
The extrusion of the mixed merga pass double screw extruder of ester section, shaping, pelletizing, obtain the nanometer silver antimicrobial master batch.
Preferably, the polyester slice is cut into slices for PBT.
Preferably, the carrier is particular type zeolite or SiO2。
Preferably, the dispersant is AEO, APES, aliphatic acid polyethenoxy ether
Or tristerin.
Preferably, the coupling agent is monoalkoxytitanates, monoalkoxy vinethene or many alkoxy vinyl ethers.
Preferably, the antibacterial flame-retardant fiber producing processes comprise the following steps:By polyacrylonitrile carbon fiber, cotton fiber,
Fire resistance fibre is uniformly mixed, and adds nanometer silver antimicrobial master batch, methylcellulose, chitosan, stearmide, water-soluble binder,
Stirring, blending, are added in screw extruder and carry out melt extruded, the melt fully melted is transported into spinning by melt pipe
In silk casing, 270 ~ 300 DEG C of manifold spinning temperature, 2500 ~ 3500m/min of spinning speed, afterwards from the spray orifice of spinning head
Extrude, tow carries out cooled and solidified into silk in the crosswind that temperature is 18-20 DEG C, humidity is 58 ~ 60%, is then placed in boiling water
20 ~ 25min is boiled, drying is taken out, you can obtain the antibacterial flame-retardant fiber.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (10)
1. a kind of environment-friendly antibacterial flame-retardant garment plus material, it is characterised in that the garment material is knitted using antibacterial flame-retardant fiber as yarn
Into fabric body, gained fabric body is dyed and post-processes to obtain garment material finished product, and the antibacterial flame-retardant fiber is included such as
The composition of lower parts by weight:Polyacrylonitrile carbon fiber:20 ~ 30 parts, cotton fiber:5 ~ 10 parts, nanometer silver antimicrobial master batch:20 ~ 30 parts, first
Base cellulose:15 ~ 20 parts, chitosan:5 ~ 10 parts, stearmide:5 ~ 10 parts, fire resistance fibre:10 ~ 15 parts, water-soluble binder:
5 ~ 10 parts.
2. a kind of environment-friendly antibacterial flame-retardant garment plus material according to claim 1, it is characterised in that the antibacterial flame-retardant fiber
Include the composition of following parts by weight:Polyacrylonitrile carbon fiber:25 ~ 30 parts, cotton fiber:5 ~ 8 parts, nanometer silver antimicrobial master batch:25~30
Part, methylcellulose:15 ~ 18 parts, chitosan:7 ~ 10 parts, stearmide:7 ~ 10 parts, fire resistance fibre:10 ~ 13 parts, water solubility is viscous
Mixture:5 ~ 8 parts.
3. a kind of environment-friendly antibacterial flame-retardant garment plus material according to claim 1, it is characterised in that the antibacterial flame-retardant fiber
Include the composition of following parts by weight:Polyacrylonitrile carbon fiber:25 parts, cotton fiber:8 parts, nanometer silver antimicrobial master batch:25 parts, methyl
Cellulose:16 parts, chitosan:7 parts, stearmide:8 parts, fire resistance fibre:13 parts, water-soluble binder:6 parts.
4. a kind of environment-friendly antibacterial flame-retardant garment plus material according to any one of claim 1 ~ 3, it is characterised in that described to receive
The silver-colored antibacterial matrices of rice include the composition of following parts by weight:Nano-Ag particles:20 ~ 30 parts, carrier:10 ~ 15 parts, polyester slice:30~
40 parts, coupling agent:5 ~ 10 parts, dispersant:5 ~ 10 parts.
5. a kind of environment-friendly antibacterial flame-retardant garment plus material according to claim 4, it is characterised in that the nanometer silver antimicrobial is female
Grain preparation method comprises the following steps:Nano-Ag particles and carrier are reacted, make nano-Ag particles uniform adsorption into carrier, then
With coupling agent and dispersant and being added in high-speed mixer, at 180 ~ 220 DEG C, mixer inner screw rotating speed is 200 ~
300 revs/min, knead 30 ~ 50 minutes, obtain powder, then merga pass double screw extruder is mixed by powder and with polyester slice
Extrusion, shaping, pelletizing, obtain the nanometer silver antimicrobial master batch.
6. a kind of environment-friendly antibacterial flame-retardant garment plus material according to claim 4, it is characterised in that the polyester slice is
PBT cuts into slices.
7. a kind of environment-friendly antibacterial flame-retardant garment plus material according to claim 4, it is characterised in that the carrier boils to be extraordinary
Stone or SiO2。
8. a kind of environment-friendly antibacterial flame-retardant garment plus material according to claim 4, it is characterised in that the dispersant is fat
Alcohol APEO, APES, aliphatic acid polyethenoxy ether or tristerin.
9. a kind of environment-friendly antibacterial flame-retardant garment plus material according to claim 4, it is characterised in that the coupling agent is single alkane
Epoxide titanate esters, monoalkoxy vinethene or many alkoxy vinyl ethers.
10. a kind of environment-friendly antibacterial flame-retardant garment plus material according to claim 1, it is characterised in that the antibacterial flame-retardant is fine
Dimension preparation method comprises the following steps:Polyacrylonitrile carbon fiber, cotton fiber, fire resistance fibre are uniformly mixed, Nano Silver is added and resists
Starter grain, methylcellulose, chitosan, stearmide, water-soluble binder, stirring, blending, are added in screw extruder
Row melt extruded, the melt fully melted is transported in spinning manifold by melt pipe, manifold spinning temperature 270 ~ 300
DEG C, 2500 ~ 3500m/min of spinning speed is extruded from the spray orifice of spinning head afterwards, tow temperature be 18-20 DEG C, humidity be
Cooled and solidified is carried out in 58 ~ 60% crosswind into silk, is then placed in boiling water and boils 20 ~ 25min, take out drying, you can obtains described
Antibacterial flame-retardant fiber.
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CN201710522025.1A CN107217326A (en) | 2017-06-30 | 2017-06-30 | A kind of environment-friendly antibacterial flame-retardant garment plus material |
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CN201710522025.1A CN107217326A (en) | 2017-06-30 | 2017-06-30 | A kind of environment-friendly antibacterial flame-retardant garment plus material |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108867035A (en) * | 2018-07-04 | 2018-11-23 | 合肥远科服装设计有限公司 | A kind of amendatory knitting fabric of flame retardant property and preparation method thereof |
CN109315861A (en) * | 2018-11-23 | 2019-02-12 | 福泉市筑梦服装有限公司 | A kind of flame-retardant garment plus material and preparation method thereof |
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CN103898630A (en) * | 2014-04-13 | 2014-07-02 | 临沂市裕成纺织有限公司 | Modified bamboo charcoal polyester fiber with health function |
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2017
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CN103898630A (en) * | 2014-04-13 | 2014-07-02 | 临沂市裕成纺织有限公司 | Modified bamboo charcoal polyester fiber with health function |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108867035A (en) * | 2018-07-04 | 2018-11-23 | 合肥远科服装设计有限公司 | A kind of amendatory knitting fabric of flame retardant property and preparation method thereof |
CN109315861A (en) * | 2018-11-23 | 2019-02-12 | 福泉市筑梦服装有限公司 | A kind of flame-retardant garment plus material and preparation method thereof |
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Application publication date: 20170929 |