CN107149877A - Treated sewage reusing film alkaline cleaner - Google Patents
Treated sewage reusing film alkaline cleaner Download PDFInfo
- Publication number
- CN107149877A CN107149877A CN201610119063.8A CN201610119063A CN107149877A CN 107149877 A CN107149877 A CN 107149877A CN 201610119063 A CN201610119063 A CN 201610119063A CN 107149877 A CN107149877 A CN 107149877A
- Authority
- CN
- China
- Prior art keywords
- acid
- salt
- sodium
- treated sewage
- phosphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/02—Membrane cleaning or sterilisation ; Membrane regeneration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
- B01D2321/16—Use of chemical agents
- B01D2321/168—Use of other chemical agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a kind of Treated sewage reusing film alkaline cleaner, it is characterised in that is prepared from by the component of following mass percent：Anion surfactant 1-15；Strong base-weak acid salt 0.1-5；Metal-chelator 3-25；Phosphate 1-15；Water surplus.The Treated sewage reusing film alkaline cleaner that the present invention is provided, the Treated sewage reusing film alkaline cleaner that cleaning performance is more preferably when being cleaned to film, clean range is wider, cleaning agent is more saved.
Description
Technical field
The present invention relates to the cleaning field of reverse osmosis membrane, in particular it relates to a kind of alkalescence cleaning of Treated sewage reusing film
Agent.
Background technology
Reverse osmosis membrane is the core parts for realizing counter-infiltration, be it is a kind of simulate biological semi-permeable film be made have one
Determine the artificial pellicle of characteristic.Typically it is made of high polymer material.Such as cellulose acetate film, aromatic series polyamides
Hydrazine film, aromatic polyamide film.The diameter of surface micropore is general between 0.5~10nm, permeability it is big
The small chemical constitution with film in itself is relevant.Some high polymer materials are good to the repellency of salt, and passing through for water is fast
Spend and bad.Some high polymer material chemical structures have more hydrophilic radical, thus the penetration speed phase of water
To very fast.Therefore a kind of reverse osmosis membrane of satisfaction should have appropriate infiltration capacity or salt rejection rate.
Treated sewage reusing ultrafiltration, nanofiltration and reverse osmosis membrane system are different from general surface water or ground water regime, film
Pollution level be far above surface water or ground water regime.And the alkaline cleaner that General System is used is hydrogen-oxygen
Change sodium, disodium ethylene diamine tetraacetate, it is impossible to meet intermediate water reuse system pollutant kind many, with serious pollution
Cleaning demand.
The content of the invention
It is contemplated that overcome drawbacks described above there is provided it is a kind of film is cleaned when cleaning performance more preferably, cleaning
The scope Treated sewage reusing film alkaline cleaner that wider, cleaning agent is more saved.
The Treated sewage reusing film alkaline cleaner that the present invention is provided, it is characterised in that by following mass percent
Component is prepared from：
Further, the Treated sewage reusing film alkaline cleaner that the present invention is provided, also with following features：I.e.,
Above-mentioned anion surfactant is selected from higher fatty acid salt of the carbon number more than 10, carbon number and is more than 10
Sulfated oil, carbon number be more than 10 higher aliphatic alcohol sulfuric ester, carbon number be more than 10 fat
Race's azochlorosulfonate acid compound, carbon number are more than the alkyl that 10 alkyl aryl sulphonic acid compound, carbon number are more than 10
One or more of mixtures in naphthalene sulfonic acids compound.
The carbon number of above-claimed cpd is usually no more than 30.
Further, the Treated sewage reusing film alkaline cleaner that the present invention is provided, also with following features：I.e.,
Above-mentioned anion surfactant be selected from stearic acid sodium salt or sylvite or ammonium salt, Oleic acid sodium salt or sylvite or ammonium salt,
Laruate sodium or sylvite or ammonium salt, triethanolamine soap, sulfated castor oil, lauryl sodium sulfate, ten
Six sodium alkyl sulfates, dioctyl succinate disulfonate acid, neopelex, sodium glycocholate, hexadecane
Base benzene sulfonate, alpha-alkene sulfonate, alpha-sulfo monocarboxylate, aliphatic acid sulfoalkyl ester, succinate
In sulfonate, alkylnaphthalene sulfonate, petroleum sulfonate, lignosulfonates, alkyl glyceryl ether sulfonate
One or more of mixtures.
Further, the Treated sewage reusing film alkaline cleaner that the present invention is provided, also with following features：I.e.,
Above-mentioned strong base-weak acid salt is selected from sodium carbonate, sodium acetate, sodium phosphate, one or more of mixed in sodium acid carbonate
Compound.
Further, the Treated sewage reusing film alkaline cleaner that the present invention is provided, also with following features：I.e.,
Above-mentioned metal-chelator is selected from ethylenediamine tetra-acetic acid and its salt, aminotriacetic acid and its salt, diethylenetriamines
Pentaacetic acid and its salt, citric acid and its salt, tartaric acid and its salt, gluconic acid and its salt, ethoxy second two
Amine triacetic acid and its salt, bicine N- and its salt, 1,2,3,4- tetracarboxylic acid cyclopentane and its salt,
2-fluoroacetic acid propylmalonic acid and its salt, 2-fluoroacetic acid base fourth lead acid and its salt, polyacrylic acid, poly- methyl-prop
One or more of mixtures in olefin(e) acid, HPMA, fumaric acid-propene sulfonic acid EVA.
Further, the Treated sewage reusing film alkaline cleaner that the present invention is provided, also with following features：I.e.,
Above-mentioned phosphate be selected from sodium pyrophosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate, sodium phosphate, aluminum sodium phosphate, partially
Sodium phosphate, polyphosphate sodium, sodium tripolyphosphate, potassium dihydrogen phosphate, dipotassium hydrogen phosphate, potassium phosphate, poly- inclined phosphorus
Sour potassium, PTPP, potassium pyrophosphate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, calcium monohydrogen phosphate, calcium phosphate,
One or more of mixtures in calcium pyrophosphate, calcium dihydrogen phosphate.
Further, the Treated sewage reusing film alkaline cleaner that the present invention is provided, also with following features：I.e.,
It is prepared from by the component of following mass percent：
Further, the Treated sewage reusing film alkaline cleaner that the present invention is provided, also with following features：I.e.,
It is prepared from by the component of following mass percent：
Further, the Treated sewage reusing film alkaline cleaner that the present invention is provided, also with following features：I.e.,
Each component is put into reactor successively, mixture is uniform at a temperature of 10-80 DEG C.
The effect of the present invention and effect：
The invention provides it is a kind of film is cleaned when, cleaning performance is more preferably, clean range is wider, cleaning
The Treated sewage reusing film alkaline cleaner that medicament is more saved.
In the present invention, it is from anion surfactant as the effect of one of component, it is on the one hand cloudy
Ionic surface active agent, special structure is such as：The anionic surface of neopelex and its similar structure
Activating agent is the detergent that a class has preferable cleaning performance to oily substance and biological pollution；On the other hand,
, can be with other groups from the surfactant of the anionic nature of backbone in the formula system of the present invention
Divide such as：Sodium carbonate, metal-chelator etc. act synergistically, and each component is dissolved each other while be more uniformly distributed,
It can also play a part of promoting respective functional effect to play.
In addition, strong base-weak acid salt in the present invention, while good resiliency can be played, with other groups
After the raw synergy of distribution, highly basic agent is substituted in traditional scheme such as：The use of sodium hydroxide, so as to reduce pair
The corrosion of a whole set of water treatment system and the process for simplifying post processing.
In addition, after phosphate in the present invention and the compounding use of metal chelating agent, synergy can be produced,
And further effectively remove sulfate, organic matter and colloid pollution in water body.
Embodiment
Embodiment one, Treated sewage reusing film alkalescence cleaning 1#
The material of following each component is put into reactor successively, mixture is uniform at a temperature of 25 DEG C：
Embodiment two, Treated sewage reusing film alkalescence cleaning 2#
The material of following each component is put into reactor successively, mixture is uniform at a temperature of 25 DEG C：
Embodiment three, Treated sewage reusing film alkalescence cleaning 3#
The material of following each component is put into reactor successively, mixture is uniform at a temperature of 25 DEG C：
Example IV, Treated sewage reusing film alkalescence cleaning 4#
The material of following each component is put into reactor successively, mixture is uniform at a temperature of 15 DEG C：
Embodiment five, Treated sewage reusing film alkalescence cleaning 5#
The material of following each component is put into reactor successively, mixture is uniform at a temperature of 35 DEG C：
Embodiment six, Treated sewage reusing film alkalescence cleaning 6#
The material of following each component is put into reactor successively, mixture is uniform at a temperature of 80 DEG C：
Embodiment seven, Treated sewage reusing film alkalescence cleaning 7#
The material of following each component is put into reactor successively, mixture is uniform at a temperature of 25 DEG C：
When being cleaned using above-mentioned cleaning agent to film, cleaning performance improves 50-150% not compared with conventional clean agent
Deng, can be suitably used for all kinds of dirty stifled situations, the 15-50% that the usage amount of cleaning agent is conventional clean agent.
Claims (9)
1. a kind of Treated sewage reusing film alkaline cleaner, it is characterised in that prepared by the component of following mass percent and
Into：
2. Treated sewage reusing film alkaline cleaner as claimed in claim 1, it is characterised in that：
The anion surfactant is selected from higher fatty acid salt of the carbon number more than 10, carbon number and is more than 10
Sulfated oil, carbon number be more than 10 higher aliphatic alcohol sulfuric ester, carbon number be more than 10 fat
Race's azochlorosulfonate acid compound, carbon number are more than the alkyl that 10 alkyl aryl sulphonic acid compound, carbon number are more than 10
One or more of mixtures in naphthalene sulfonic acids compound.
3. Treated sewage reusing film alkaline cleaner as claimed in claim 1, it is characterised in that：
The anion surfactant be selected from stearic acid sodium salt or sylvite or ammonium salt, Oleic acid sodium salt or sylvite or ammonium salt,
Laruate sodium or sylvite or ammonium salt, triethanolamine soap, sulfated castor oil, lauryl sodium sulfate, ten
Six sodium alkyl sulfates, dioctyl succinate disulfonate acid, neopelex, sodium glycocholate, hexadecane
Base benzene sulfonate, alpha-alkene sulfonate, alpha-sulfo monocarboxylate, aliphatic acid sulfoalkyl ester, succinate
In sulfonate, alkylnaphthalene sulfonate, petroleum sulfonate, lignosulfonates, alkyl glyceryl ether sulfonate
One or more of mixtures.
4. Treated sewage reusing film alkaline cleaner as claimed in claim 1, it is characterised in that：
The strong base-weak acid salt is selected from sodium carbonate, sodium acetate, sodium phosphate, one or more of mixed in sodium acid carbonate
Compound.
5. Treated sewage reusing film alkaline cleaner as claimed in claim 1, it is characterised in that：
The metal-chelator is selected from ethylenediamine tetra-acetic acid and its salt, aminotriacetic acid and its salt, diethylenetriamines
Pentaacetic acid and its salt, citric acid and its salt, tartaric acid and its salt, gluconic acid and its salt, ethoxy second two
Amine triacetic acid and its salt, bicine N- and its salt, 1,2,3,4- tetracarboxylic acid cyclopentane and its salt,
2-fluoroacetic acid propylmalonic acid and its salt, 2-fluoroacetic acid base fourth lead acid and its salt, polyacrylic acid, poly- methyl-prop
One or more of mixtures in olefin(e) acid, HPMA, fumaric acid-propene sulfonic acid EVA.
6. Treated sewage reusing film alkaline cleaner as claimed in claim 1, it is characterised in that：
The phosphate be selected from sodium pyrophosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate, sodium phosphate, aluminum sodium phosphate, partially
Sodium phosphate, polyphosphate sodium, sodium tripolyphosphate, potassium dihydrogen phosphate, dipotassium hydrogen phosphate, potassium phosphate, poly- inclined phosphorus
Sour potassium, PTPP, potassium pyrophosphate, diammonium hydrogen phosphate, ammonium dihydrogen phosphate, calcium monohydrogen phosphate, calcium phosphate,
One or more of mixtures in calcium pyrophosphate, calcium dihydrogen phosphate.
7. Treated sewage reusing film alkaline cleaner as claimed in claim 1, it is characterised in that by following quality percentage
The component of ratio is prepared from：
8. Treated sewage reusing film alkaline cleaner as claimed in claim 1, it is characterised in that by following quality percentage
The component of ratio is prepared from：
9. the preparation method of the Treated sewage reusing film alkaline cleaner as described in claim 1-8 is any, it is characterised in that：
Each component is put into reactor successively, mixture is uniform at a temperature of 10-80 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610119063.8A CN107149877A (en) | 2016-03-02 | 2016-03-02 | Treated sewage reusing film alkaline cleaner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610119063.8A CN107149877A (en) | 2016-03-02 | 2016-03-02 | Treated sewage reusing film alkaline cleaner |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107149877A true CN107149877A (en) | 2017-09-12 |
Family
ID=59792471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610119063.8A Pending CN107149877A (en) | 2016-03-02 | 2016-03-02 | Treated sewage reusing film alkaline cleaner |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107149877A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108031295A (en) * | 2017-12-15 | 2018-05-15 | 中国海洋石油集团有限公司 | A kind of Ceramic excessive filtration cleaning agents of membrane and preparation method thereof |
| CN108059313A (en) * | 2017-12-14 | 2018-05-22 | 西南石油大学 | A kind of greasy filth cleaning agent and its method for handling greasy filth |
| CN108607367A (en) * | 2018-05-14 | 2018-10-02 | 广州迪奕科环保科技有限公司 | Low vacuolar membrane cleaning agent |
| CN108854561A (en) * | 2017-11-15 | 2018-11-23 | 上海屹屹环境科技有限公司 | A kind of reverse osmosis cleaning agent |
| CN110141971A (en) * | 2018-12-11 | 2019-08-20 | 新疆水处理工程技术研究中心有限公司 | Cleaning agent and preparation method thereof for counter-infiltration system |
| CN110548406A (en) * | 2019-09-10 | 2019-12-10 | 北京首钢股份有限公司 | Reverse osmosis membrane cleaning agent for sewage and cleaning method |
| CN111547908A (en) * | 2020-05-20 | 2020-08-18 | 中国石油工程建设有限公司 | Method and device for recycling, treating and regenerating saline produced water of super-heavy oil |
| CN114059129A (en) * | 2021-11-24 | 2022-02-18 | 武汉风帆电化科技股份有限公司 | Color fixing agent for dyed aluminum and aluminum alloy anodic oxide films and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6416668B1 (en) * | 1999-09-01 | 2002-07-09 | Riad A. Al-Samadi | Water treatment process for membranes |
| CN101757857A (en) * | 2009-11-17 | 2010-06-30 | 上海丰信环保科技有限公司 | Composite cleaning agent for cleaning membrane system with organic fouling |
| CN103341325A (en) * | 2013-06-18 | 2013-10-09 | 吴章锋 | Dual-purpose film cleaning agent and its preparation method and use |
| CN105214507A (en) * | 2015-11-12 | 2016-01-06 | 师宗煤焦化工有限公司 | The cleaning method of reverse-osmosis membrane element |
-
2016
- 2016-03-02 CN CN201610119063.8A patent/CN107149877A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6416668B1 (en) * | 1999-09-01 | 2002-07-09 | Riad A. Al-Samadi | Water treatment process for membranes |
| CN101757857A (en) * | 2009-11-17 | 2010-06-30 | 上海丰信环保科技有限公司 | Composite cleaning agent for cleaning membrane system with organic fouling |
| CN103341325A (en) * | 2013-06-18 | 2013-10-09 | 吴章锋 | Dual-purpose film cleaning agent and its preparation method and use |
| CN105214507A (en) * | 2015-11-12 | 2016-01-06 | 师宗煤焦化工有限公司 | The cleaning method of reverse-osmosis membrane element |
Non-Patent Citations (4)
| Title |
|---|
| 崔维汉等: "《中国防腐蚀工程师实用技术大全 第1册》", 31 October 2001, 山西科学技术出版社 * |
| 张葆宗: "《反渗透水处理应用技术》", 31 March 2004, 中国电力出版社 * |
| 栗田工业水处理药剂手册编委会: "《水处理药剂手册》", 31 August 1991, 中国石化出版社 * |
| 王彦志等: "《中药学专业（师）45天通关》", 31 January 2014, 西安交通大学出版社 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108854561A (en) * | 2017-11-15 | 2018-11-23 | 上海屹屹环境科技有限公司 | A kind of reverse osmosis cleaning agent |
| CN108059313A (en) * | 2017-12-14 | 2018-05-22 | 西南石油大学 | A kind of greasy filth cleaning agent and its method for handling greasy filth |
| CN108059313B (en) * | 2017-12-14 | 2020-11-27 | 西南石油大学 | Oil sludge cleaning agent and method for treating oil sludge by using same |
| CN108031295A (en) * | 2017-12-15 | 2018-05-15 | 中国海洋石油集团有限公司 | A kind of Ceramic excessive filtration cleaning agents of membrane and preparation method thereof |
| CN108607367A (en) * | 2018-05-14 | 2018-10-02 | 广州迪奕科环保科技有限公司 | Low vacuolar membrane cleaning agent |
| CN110141971A (en) * | 2018-12-11 | 2019-08-20 | 新疆水处理工程技术研究中心有限公司 | Cleaning agent and preparation method thereof for counter-infiltration system |
| CN110548406A (en) * | 2019-09-10 | 2019-12-10 | 北京首钢股份有限公司 | Reverse osmosis membrane cleaning agent for sewage and cleaning method |
| CN111547908A (en) * | 2020-05-20 | 2020-08-18 | 中国石油工程建设有限公司 | Method and device for recycling, treating and regenerating saline produced water of super-heavy oil |
| CN114059129A (en) * | 2021-11-24 | 2022-02-18 | 武汉风帆电化科技股份有限公司 | Color fixing agent for dyed aluminum and aluminum alloy anodic oxide films and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107149877A (en) | Treated sewage reusing film alkaline cleaner | |
| CN105062706B (en) | Resin optical lens matched moulds glass mold high-precision ultrasound cleaning agent | |
| CN105688680B (en) | A kind of cleaning method of reverse-osmosis membrane element | |
| EP0970167B1 (en) | Surface-cleaning method | |
| Atiku et al. | Harvesting of microalgae biomass from the phycoremediation process of greywater | |
| CN105688694A (en) | High-hydrophilic compound reverse osmosis membrane and preparation method of high-hydrophilic compound reverse osmosis membrane | |
| US8338356B2 (en) | Surfactant compositions with wide pH stability | |
| CN108939926A (en) | Cleaning agents of membrane and its preparation and application | |
| CN101439268A (en) | Method for preparing high-intensity high-throughput polyvinylidene fluoride hollow fiber membrane | |
| EP2098587B1 (en) | Mixture for removing limescale, cleaning and/or disinfecting | |
| CN105413475A (en) | Cleaning agent suitable for cleaning hollow fiber nanofiltration membranes and preparation method thereof | |
| CN101514306A (en) | Fabric dirt pretreatment agent containing steady biological enzyme complex and low-activity substance and preparation method thereof | |
| CN106390770A (en) | Preparation method of dopamine composite ultrafiltration membrane | |
| CN109499382A (en) | A kind of reverse osmosis membrane cleaning combination and preparation method thereof | |
| CN107925112A (en) | Reduce method, cleanser compositions of the dirt of microbiological fuel cell and application thereof | |
| CN1086198C (en) | Multifunctional concentrated phosphorus-free liquid detergent | |
| CN103521080A (en) | Alkaline cleaning agent for depth cleaning of separating membrane and application thereof | |
| CN110964603A (en) | Low-foam environment-friendly bus outer skin cleaning agent | |
| CN105664739A (en) | Preparation method of highly hydrophilic polysulfone ultrafiltration membrane | |
| CN106145383A (en) | A kind of solid union microbial bacterial agent administered for black and odorous water | |
| CN110423653A (en) | A kind of tableware dipping powder | |
| CN106362597A (en) | Film-method reclaimed-water-reusing scaling inhibitor and preparing method thereof | |
| CN102533478B (en) | Compound dissolving and cleaning agent of calcium-containing insoluble solid and manufacturing method thereof | |
| CN107149878A (en) | Treated sewage reusing film acidic cleaner | |
| CN116272389B (en) | Composite efficient membrane cleaning agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170912 |