CN101514306A - Fabric dirt pretreatment agent containing steady biological enzyme complex and low-activity substance and preparation method thereof - Google Patents
Fabric dirt pretreatment agent containing steady biological enzyme complex and low-activity substance and preparation method thereof Download PDFInfo
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- CN101514306A CN101514306A CNA200810247469XA CN200810247469A CN101514306A CN 101514306 A CN101514306 A CN 101514306A CN A200810247469X A CNA200810247469X A CN A200810247469XA CN 200810247469 A CN200810247469 A CN 200810247469A CN 101514306 A CN101514306 A CN 101514306A
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- fatty alcohol
- polyoxyethylene ether
- pretreatment agent
- enzyme complex
- stabilate
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Abstract
The invention relates to a fabric dirt pretreatment agent containing a steady biological enzyme complex and a low-activity substance and a preparation method thereof. A product of the invention takes fatty alcohol polyoxyethylene ether (7), fatty alcohol polyoxyethylene ether (9), sodium fatty alcohol-polyoxyethyleneether sulfate (70 percent), fatty alcohol polyoxyethylene ether (JFC), polyacrylate, sodium citrate, boric acid, propylene glycol, prolease, calcium chloride, isothiazolinone, essence, and deionized water as raw materials; and the method adopts a polymer to ensure that the prolease forms a polymer complex in a system by researching biological enzyme stabilization technology, which ensures the long-term effective activity of biological enzyme, ensures that the product can achieve stronger detergency when the content of an active substance is 10 percent or so and has steady quality during the storage, and achieves the aims of saving resources and protecting environment. The product is neutral, and has unique advantages in preventing fading, reducing the damage of clothes, protecting skin, and reducing pollution.
Description
Technical field
The present invention relates to household chemicals, relate in particular to a kind of fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing and preparation method thereof.
Background technology
Various spots are stained with by clothing local regular meeting in wearing process, need handle these privileged sites emphasis that speckle with spot before normal washing, just can reach the effect of thorough cleaning.The fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing then is the articles for washing at particular requirement, the fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing has strong infiltration wetting ability, can peel off spot rapidly, reach the effect of strong dirt-removing.
The like product of prior art generally adopts the alkalescence prescription for removing the dirt of neckline cuff, and portioned product also is added with solvent, might cause the clothing part to fade.Utilize biological enzyme can remove dirt easily, but biological enzyme under liquid condition especially surfactant concentration be lower than 50% o'clock very unstable, can make the very fast decline of product detersive power, therefore, the liquid enzymatic product of prior art passes through to increase the activity of surfactant content with the stabilate enzyme mostly, but is unfavorable for saving energy and reduce the cost.
In order to overcome the existing in prior technology defective, await inventing a kind of environmental protection more, do not damage the dirt pretreatment agent of the neutrality prescription of clothing.
Summary of the invention
The object of the present invention is to provide a kind of fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing and preparation method thereof.The described fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing adds biological enzyme based on ionic surface active agent, and composite permeate agent, solubilizing agent directly use stoste, and is to the clothing not damaged, colour-fast; Spot can be thoroughly removed in local emphasis washing.
The objective of the invention is to be achieved through the following technical solutions: a kind of fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing is prepared from by its ratio of weight and number by following raw material:
Fatty alcohol-polyoxyethylene ether (7) 2～6
Fatty alcohol-polyoxyethylene ether (9) 2～6
Polyoxyethylenated alcohol sodium sulfate (70%) 3～12
Fatty alcohol-polyoxyethylene ether (JFC) 0.5～2
Proteinase-10 .1～0.5
Propylene glycol 0.05～6
Polyacrylate 2～7
Trisodium Citrate 1～5
Boric acid 0～3
Calcium chloride 0.03～0.1
Isothiazolinone 0.1～0.2
Essence 0.1～0.4
Deionized water 51～90.
A kind of described preparation method who contains the fabric dirt pretreatment agent of stabilate enzyme complex compound and low activity thing, preparation process is as follows:
A, earlier in 30～40% the placing material stills with the deionized water total amount that will add in the proportioning raw materials, be heated to 60 ℃～70 ℃, add fatty alcohol-polyoxyethylene ether (7), fatty alcohol-polyoxyethylene ether (9), polyoxyethylenated alcohol sodium sulfate (70%), fatty alcohol-polyoxyethylene ether (JFC), polyacrylate, Trisodium Citrate then while stirring successively, after treating that material all dissolves, be cooled to 35 ℃～45 ℃, obtain base-material;
B, proteolytic enzyme is dissolved, join then in the described base-material with propylene glycol;
C, again calcium chloride, isothiazolinone, essence are docile and obedient preface by its ratio of weight and number and join in the described base-material, add all the other deionized waters then, stirring back is 7.0～8.0 with the boric acid adjust pH, filter with 200 order filtering nets, obtain containing the fabric dirt pretreatment agent product of stabilate enzyme complex compound and low activity thing.
The invention has the beneficial effects as follows:
1, the detersive power that contains the fabric dirt pretreatment agent of stabilate enzyme complex compound and low activity thing of the present invention can reach the A level level of national sector standard QB1224-2007 after testing, its cost performance level that at home and abroad is in a leading position, the market value of product equal even are lower than other like product;
2, the fabric dirt pretreatment agent of stabilate enzyme complex compound and low activity thing that contains of the present invention is by research biological enzyme stabilization technique, adopt polymkeric substance to make proteolytic enzyme in system, form high-molecular complex, guaranteed that biological enzyme activity is permanently effective, make product when 10% left and right sides active matter content, can reach stronger detersive power, and the lay up period constant product quality reaches and economizes on resources, the purpose of protection environment;
3, the fabric dirt pretreatment agent good penetrability that contains stabilate enzyme complex compound and low activity thing of the present invention, can cooperate common washing liquid, washing powder to use, can remove bloodstain, milk stain, fruit juice, dish juice and the neckline on the clothing, the severe spot on the cuff easily;
4, the fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing of the present invention adopts rational formula, and it is neutral that product is, and fades preventing, reduces the clothing damage, protection skin, and reducing the pollution aspect has special advantages;
5, the biological degradation rate that contains the fabric dirt pretreatment agent of stabilate enzyme complex compound and low activity thing of the present invention reaches more than 90%, is a kind of articles for washing of environmental protection.
The invention will be further described below in conjunction with embodiment.
Embodiment
Embodiment 1: a kind of fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing is prepared from by its ratio of weight and number by following raw material:
Fatty alcohol-polyoxyethylene ether (7) 2～6
Fatty alcohol-polyoxyethylene ether (9) 2～6
Polyoxyethylenated alcohol sodium sulfate (70%) 3～12
Fatty alcohol-polyoxyethylene ether (JFC) 0.5～2
Proteinase-10 .1～0.5
Propylene glycol 0.05～6
Polyacrylate 2～7
Trisodium Citrate 1～5
Boric acid 0～3
Calcium chloride 0.03～0.1
Isothiazolinone 0.1～0.2
Essence 0.1～0.4
Deionized water 51～90.
In the above-mentioned raw materials composition:
Fatty alcohol-polyoxyethylene ether (7), fatty alcohol-polyoxyethylene ether (9) are nonionogenic tenside, and greasy dirt is had good emulsifying, solublization; Also have favorable biological degradability simultaneously, can with other kinds negatively charged ion, nonionic, the composite use of cats product, and good synergistic is arranged.
Polyoxyethylenated alcohol sodium sulfate (70%) is an anti-hard water anion surfactant preferably, the solid dirt is had good peel off, the removal effect.
Fatty alcohol-polyoxyethylene ether (JFC) has good osmosis.
Proteolytic enzyme has good removal ability to the protein spot.
Propylene glycol is used for the soluble protein enzyme.
Polyacrylate has sequestering action, and good antiredeposition ability is arranged, and can serve as a connection and make in proteolytic enzyme and the system other materials form high-molecular complexes, makes proteolytic enzyme can keep active at the environment of low surfactant for a long time.
Trisodium Citrate has good sequestering action.
Calcium chloride can the stabilize proteins enzyme, guarantees that it is in the medium-term and long-term persistent activity of product system.
Isothiazolinone has another name called triumphant pine, is a kind of sanitas, can suppress microorganism growth in product of the present invention, prevents corruption.
Boric acid is used to reconcile the pH value (product requirement pH value of the present invention is 7.0～8.0) of product.
In the present embodiment, the described fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing is prepared from by its ratio of weight and number by following raw material:
Fatty alcohol-polyoxyethylene ether (7) 2
Fatty alcohol-polyoxyethylene ether (9) 4
Polyoxyethylenated alcohol sodium sulfate (70%) 5
Fatty alcohol-polyoxyethylene ether (JFC) 2
Proteinase-10 .2
Propylene glycol 2.5
Polyacrylate 2
Trisodium Citrate 3
Boric acid 0.9
Calcium chloride 0.03
Isothiazolinone 0.1
Essence 0.1
Deionized water 78.2.
A kind of described preparation method who contains the fabric dirt pretreatment agent of stabilate enzyme complex compound and low activity thing, preparation process is as follows:
A, elder generation are with in placing of the deionized water 25kg material still, be heated to 60 ℃～70 ℃, add fatty alcohol-polyoxyethylene ether (7) 2kg, fatty alcohol-polyoxyethylene ether (9) 4kg, polyoxyethylenated alcohol sodium sulfate (70%) 5kg, fatty alcohol-polyoxyethylene ether (JFC) 2kg, polyacrylate 2kg then while stirring successively, after Trisodium Citrate 3kg treats that material all dissolves, be cooled to 35 ℃～45 ℃, obtain base-material;
B, usefulness propylene glycol 2.5kg join in the described base-material then earlier with proteinase-10 .2kg dissolving;
C, calcium chloride 30g, isothiazolinone 100g, essence 100g are joined in the described base-material again, add remaining deionized water 53.2kg then, it is 7.0～8.0 that the back that stirs adds the about 0.9kg conciliation of boric acid pH value, stirs.Filter with 200 order filtering nets, obtain containing the fabric dirt pretreatment agent product of stabilate enzyme complex compound and low activity thing.
The fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing of present embodiment is remarkably productive for containing proteinic spot.
Embodiment 2: in the present embodiment, the fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing of the present invention is prepared from by its ratio of weight and number by following raw material:
Fatty alcohol-polyoxyethylene ether (7) 6
Fatty alcohol-polyoxyethylene ether (9) 2
Polyoxyethylenated alcohol sodium sulfate (70%) 3
Fatty alcohol-polyoxyethylene ether (JFC) 1.5
Proteinase-10 .5
Propylene glycol 6
Polyacrylate 7
Trisodium Citrate 1
Boric acid 1.2
Calcium chloride 0.1
Isothiazolinone 0.2
Essence 0.2
Deionized water 71.3
The described preparation method who contains the fabric dirt pretreatment agent of stabilate enzyme complex compound and low activity thing, preparation process is as follows:
A, elder generation are with in placing of the deionized water 25kg material still, be heated to 60 ℃～70 ℃, add fatty alcohol-polyoxyethylene ether (7) 6kg, fatty alcohol-polyoxyethylene ether (9) 2kg, polyoxyethylenated alcohol sodium sulfate (70%) 3kg, fatty alcohol-polyoxyethylene ether (JFC) 1.5kg, polyacrylate 7kg then while stirring successively, after Trisodium Citrate 1kg treats that material all dissolves, be cooled to 35 ℃～45 ℃, obtain base-material;
B, usefulness propylene glycol 6kg join in the described base-material then earlier with proteinase-10 .5kg dissolving;
C, again calcium chloride 100g, isothiazolinone 200g, essence 200g are docile and obedient preface and join in the described base-material, add remaining deionized water 46.3kg then, it is 7.0～8.0 that the back that stirs adds the about 1.2kg conciliation of boric acid pH value, stirs.Filter with 200 order filtering nets, obtain containing the fabric dirt pretreatment agent product of stabilate enzyme complex compound and low activity thing.
The fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing of present embodiment is remarkably productive for containing proteinic spot.
Embodiment 3: in the present embodiment, the fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing of the present invention is prepared from by its ratio of weight and number by following raw material:
Fatty alcohol-polyoxyethylene ether (7) 2
Fatty alcohol-polyoxyethylene ether (9) 2
Polyoxyethylenated alcohol sodium sulfate (70%) 12
Fatty alcohol-polyoxyethylene ether (JFC) 1
Proteinase-10 .3
Propylene glycol 4
Polyacrylate 4
Trisodium Citrate 3
Boric acid 2
Calcium chloride 0.05
Isothiazolinone 0.1
Essence 0.4
Deionized water 69.2.
The described preparation method who contains the fabric dirt pretreatment agent of stabilate enzyme complex compound and low activity thing, preparation process is as follows:
A, elder generation are with in placing of the deionized water 25kg material still, be heated to 60 ℃～70 ℃, add fatty alcohol-polyoxyethylene ether (7) 2kg, fatty alcohol-polyoxyethylene ether (9) 2kg, polyoxyethylenated alcohol sodium sulfate (70%) 12kg, fatty alcohol-polyoxyethylene ether (JFC) 1kg, polyacrylate 4kg then while stirring successively, after Trisodium Citrate 3kg treats that material all dissolves, be cooled to 35 ℃～45 ℃, obtain base-material;
B, usefulness propylene glycol 4kg join in the described base-material then earlier with proteinase-10 .3kg dissolving;
C, again calcium chloride 50g, isothiazolinone 100g, essence 400g are docile and obedient preface and join in the described base-material, add remaining deionized water 44.2kg then, it is 7.0～8.0 that the about 2kg of back adding boric acid that stirs reconciles the pH value, stir and filter, obtain containing the fabric dirt pretreatment agent product of stabilate enzyme complex compound and low activity thing with 200 order filtering nets.
The fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing of present embodiment is remarkably productive for containing proteinic spot.
Claims (5)
1, a kind of fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing is characterized in that: be prepared from by its ratio of weight and number by following raw material:
Fatty alcohol-polyoxyethylene ether (7) 2～6
Fatty alcohol-polyoxyethylene ether (9) 2～6
Polyoxyethylenated alcohol sodium sulfate (70%) 3～12
Fatty alcohol-polyoxyethylene ether (JFC) 0.5～2
Proteinase-10 .1～0.5
Propylene glycol 0.05～6
Polyacrylate 2～7
Trisodium Citrate 1～5
Boric acid 0～3
Calcium chloride 0.03～0.1
Isothiazolinone 0.1～0.2
Essence 0.1～0.4
Deionized water 51～90.
2, the fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing according to claim 1 is characterized in that: be prepared from by its ratio of weight and number by following raw material:
Fatty alcohol-polyoxyethylene ether (7) 2
Fatty alcohol-polyoxyethylene ether (9) 4
Polyoxyethylenated alcohol sodium sulfate (70%) 5
Fatty alcohol-polyoxyethylene ether (JFC) 2
Proteinase-10 .2
Propylene glycol 2.5
Polyacrylate 2
Trisodium Citrate 3
Boric acid 0.9
Calcium chloride 0.03
Isothiazolinone 0.1
Essence 0.1
Deionized water 78.2.
3, the fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing according to claim 1 is characterized in that: be prepared from by its ratio of weight and number by following raw material:
Fatty alcohol-polyoxyethylene ether (7) 6
Fatty alcohol-polyoxyethylene ether (9) 2
Polyoxyethylenated alcohol sodium sulfate (70%) 3
Fatty alcohol-polyoxyethylene ether (JFC) 1.5
Proteinase-10 .5
Propylene glycol 6
Polyacrylate 7
Trisodium Citrate 1
Boric acid 1.2
Calcium chloride 0.1
Isothiazolinone 0.2
Essence 0.2
Deionized water 71.3.
4, the fabric dirt pretreatment agent that contains stabilate enzyme complex compound and low activity thing according to claim 1 is characterized in that: be prepared from by its ratio of weight and number by following raw material:
Fatty alcohol-polyoxyethylene ether (7) 2
Fatty alcohol-polyoxyethylene ether (9) 2
Polyoxyethylenated alcohol sodium sulfate (70%) 12
Fatty alcohol-polyoxyethylene ether (JFC) 1
Proteinase-10 .3
Propylene glycol 4
Polyacrylate 4
Trisodium Citrate 3
Boric acid 2
Calcium chloride 0.05
Isothiazolinone 0.1
Essence 0.4
Deionized water 69.2.
5, a kind of preparation method who contains the fabric dirt pretreatment agent of stabilate enzyme complex compound and low activity thing as claimed in claim 1 is characterized in that preparation process is as follows:
A, earlier in 30～40% the placing material stills with the deionized water total amount that will add in the proportioning raw materials, be heated to 60 ℃～70 ℃, add fatty alcohol-polyoxyethylene ether (7), fatty alcohol-polyoxyethylene ether (9), polyoxyethylenated alcohol sodium sulfate (70%), fatty alcohol-polyoxyethylene ether (JFC), polyacrylate, Trisodium Citrate then while stirring successively, after treating that material all dissolves, be cooled to 35 ℃～45 ℃, obtain base-material;
B, proteolytic enzyme is dissolved, join then in the described base-material with propylene glycol;
C, again calcium chloride, isothiazolinone, essence are docile and obedient preface by its ratio of weight and number and join in the described base-material, add all the other deionized waters then, stirring back is 7.0～8.0 with the boric acid adjust pH, filter with 200 order filtering nets, obtain containing the fabric dirt pretreatment agent product of stabilate enzyme complex compound and low activity thing.
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| Application Number | Priority Date | Filing Date | Title |
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| CN200810247469XA CN101514306B (en) | 2008-12-31 | 2008-12-31 | Fabric dirt pretreatment agent containing steady biological enzyme complex and low-activity substance and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810247469XA CN101514306B (en) | 2008-12-31 | 2008-12-31 | Fabric dirt pretreatment agent containing steady biological enzyme complex and low-activity substance and preparation method thereof |
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| CN101514306A true CN101514306A (en) | 2009-08-26 |
| CN101514306B CN101514306B (en) | 2010-10-13 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101857824A (en) * | 2010-04-23 | 2010-10-13 | 北京绿伞化学股份有限公司 | Detergent using sodium alcohol ether carboxylate as main raw material |
| CN102242022A (en) * | 2011-06-15 | 2011-11-16 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
| CN102533465A (en) * | 2011-12-30 | 2012-07-04 | 北京绿伞化学股份有限公司 | Low foam fabric liquid detergent and preparation method thereof |
| CN101993792B (en) * | 2009-08-27 | 2012-08-22 | 上海制皂有限公司 | High efficient laundry detergent |
| CN102766540A (en) * | 2012-07-20 | 2012-11-07 | 山西大学 | Liquid enzyme stabilizing additive and preparation method and application thereof |
| CN103436379A (en) * | 2013-08-23 | 2013-12-11 | 烟台市喜旺食品有限公司 | Disincrustant for cleaning heavy oil dirt for food processing equipment |
| CN103897875A (en) * | 2012-12-25 | 2014-07-02 | 青岛海芬海洋生物科技有限公司 | Enzyme-containing clothes pre-washing agent and preparing method thereof |
| CN105779159A (en) * | 2016-04-09 | 2016-07-20 | 福建省金鹿日化股份有限公司 | Softening clothes washing condensate ball and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3244700B2 (en) * | 1991-12-04 | 2002-01-07 | ザ、プロクター、エンド、ギャンブル、カンパニー | Liquid laundry detergent containing boric acid-diol complex that inhibits citric acid, cellulase, and proteolytic enzymes |
| CN1354245A (en) * | 2000-11-22 | 2002-06-19 | 上海白猫有限公司 | Water base type liquid clothes-washing precleaning agent containing polyenzyme |
| CN1847381A (en) * | 2006-04-30 | 2006-10-18 | 北京市航天焊接材料厂 | Green multifunctional detergent and its prepn process |
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2008
- 2008-12-31 CN CN200810247469XA patent/CN101514306B/en active Active
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101993792B (en) * | 2009-08-27 | 2012-08-22 | 上海制皂有限公司 | High efficient laundry detergent |
| CN101857824A (en) * | 2010-04-23 | 2010-10-13 | 北京绿伞化学股份有限公司 | Detergent using sodium alcohol ether carboxylate as main raw material |
| CN101857824B (en) * | 2010-04-23 | 2012-08-29 | 北京绿伞化学股份有限公司 | Detergent using sodium alcohol ether carboxylate as main raw material |
| CN102242022A (en) * | 2011-06-15 | 2011-11-16 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
| CN102242022B (en) * | 2011-06-15 | 2012-12-19 | 于文 | Environment-friendly type hyperconcentration biological enzyme liquid laundry detergent and preparation method thereof |
| CN102533465A (en) * | 2011-12-30 | 2012-07-04 | 北京绿伞化学股份有限公司 | Low foam fabric liquid detergent and preparation method thereof |
| CN102766540A (en) * | 2012-07-20 | 2012-11-07 | 山西大学 | Liquid enzyme stabilizing additive and preparation method and application thereof |
| CN103897875A (en) * | 2012-12-25 | 2014-07-02 | 青岛海芬海洋生物科技有限公司 | Enzyme-containing clothes pre-washing agent and preparing method thereof |
| CN103436379A (en) * | 2013-08-23 | 2013-12-11 | 烟台市喜旺食品有限公司 | Disincrustant for cleaning heavy oil dirt for food processing equipment |
| CN105779159A (en) * | 2016-04-09 | 2016-07-20 | 福建省金鹿日化股份有限公司 | Softening clothes washing condensate ball and preparation method thereof |
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Assignee: SHANGHAI LVSAN INVI-TECH DEVELOPMENT CO., LTD. Assignor: Beijing Lusan Chemical Co., Ltd. Contract record no.: 2012310000012 Denomination of invention: Fabric dirt pretreatment agent containing steady biological enzyme complex and low-activity substance and preparation method thereof Granted publication date: 20101013 License type: Common License Open date: 20090826 Record date: 20120119 |
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Address after: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing Patentee after: Beijing green umbrella Technology Co.,Ltd. Address before: 100094, No. 3, North Road, Yongfeng industrial base, Beijing, Haidian District Patentee before: Beijing Lvsan Chemistry Co.,Ltd. |