CN107148973B - A kind of Pesticidal combination containing Bifenazate and chlorine fluorine cyanogen insect amide - Google Patents
A kind of Pesticidal combination containing Bifenazate and chlorine fluorine cyanogen insect amide Download PDFInfo
- Publication number
- CN107148973B CN107148973B CN201610124030.2A CN201610124030A CN107148973B CN 107148973 B CN107148973 B CN 107148973B CN 201610124030 A CN201610124030 A CN 201610124030A CN 107148973 B CN107148973 B CN 107148973B
- Authority
- CN
- China
- Prior art keywords
- bifenazate
- insect amide
- pesticidal combination
- cyanogen insect
- fluorine cyanogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of Pesticidal combinations including Bifenazate and chlorine fluorine cyanogen insect amide.The present invention also provides a kind of insecticides including the Pesticidal combination.Pesticidal combination and insecticide provided by the invention are efficiently, less toxic, the lasting period is long, suitable for prevention mite pest and/or lepidoptera pest.
Description
Technical field
The present invention relates to a kind of Pesticidal combinations, more particularly, to a kind of desinsection containing Bifenazate and chlorine fluorine cyanogen insect amide
Composition.
Background technology
The resistance problem of agricultural pests is a global problem.With the continuity of Chemical Control of Harmful Insects, Pesticide use
The increase of amount and it is unscientific use pesticide, pest resistance getting worse, the pest species for generating resistance are on the increase.Especially
Cause harm serious mite class and Lepidoptera class pest to agricultural production, resistance level is higher, and resistance development speed is relatively fast.Together
When, the use pesticide of high intensity causes Residual Pesticides in Farm Produce is exceeded, environmental pollution is serious to increase with peasant's drug cost
Deng being unfavorable for agricultural sustainable development.In addition, the use of single pesticide is easier to cause drug resistance.By by different pesticide product
Kind mixture, filters out rational formula, can effectively improve practical control effect, reduces dosage, reduces cost, delays pest anti-
The generation of pharmacological property extends the service life of medicament and a kind of important means of integrated pest management.Therefore, research and development are high
Effect, low toxicity, the pesticide of environmental protection and Recompounded pesticide have positive effect to agricultural sustainable development.
Bifenazate (bifenazate) is a kind of new selective foliar spray acaricide, Central nervous conduction system
The GABA receptors of system have unique effect, right with ovicidal activity and to being knocked down active (in 48~72 hours) at the rapid of mite
Each life stage of mite is effective, and the lasting period is long.Predatory mite is influenced it is minimum, to honeybee and other beneficial insects almost without
It influences, is very suitable for the comprehensive treatment of pest.Registered crop controlling object includes apple tree red spider etc..
Chlorine fluorine cyanogen insect amide (cyhalodiamide) is the novel pesticide that Zhejiang Provincial Chemical Engineering Research Inst is voluntarily developed, tool
Just like lower structure formula (I)：
The insecticide belongs to novel phthalic amide insecticides, by activating blue Buddhist nun's alkali recipient cell Intracellular calcium release logical
Road leads to the runaway release for storing calcium ion, is few in number at present to act on insect cell orchid Buddhist nun alkali (Ryanodine)
The compound of receptor.There is wide spectrum preventive effect to lepidoptera pest, generates, be extremely suitable for existing with existing insecticide no interactions resistance
Insecticide generates the prevention of the pest of resistance.
Drug cost is higher when Bifenazate and chlorine fluorine cyanogen insect amide are used alone, and limits its popularization to a certain extent
Using, and long-term exclusive use be easy to cause pest resistance degree and is continuously increased.Therefore, by Bifenazate and chlorine fluorine cyanogen insect amide
Compounded has positive effect for efficient, less toxic, environment-protection pesticide exploitation.
Invention content
The purpose of the present invention is to provide a kind of Pesticidal combinations, have efficient, low toxicity, lasting period length, can effectively prevent
The characteristics of crops Lepidoptera class pest.
The present invention provides the following technical solutions：
A kind of Pesticidal combination for agricultural pests, the Pesticidal combination include Bifenazate and chlorine fluorine cyanogen worm acyl
Amine, and the quality proportioning of Bifenazate and chlorine fluorine cyanogen insect amide is 1~50:20~1.
Pesticidal combination provided by the invention, including Bifenazate and chlorine fluorine cyanogen insect amide.For joining in Pesticidal combination
The quality proportioning of phenylhydrazine ester and chlorine fluorine cyanogen insect amide, it is preferred that the quality proportioning of the Bifenazate and chlorine fluorine cyanogen insect amide
It is 1~10:10~1.It may further be preferable that the quality proportioning of the Bifenazate and chlorine fluorine cyanogen insect amide is 1~5:5~1.
The present invention also provides a kind of insecticides for agricultural pests, and the insecticide is by weight containing 5~90%
Above-mentioned Pesticidal combination, remaining is agriculturally acceptable carrier and auxiliary agent.As preferred embodiment, the insecticide with
Weight meter contains 5~40% Pesticidal combination.
Carrier of the present invention can be solid or liquid, and any carrier commonly used in preparation insecticides is equal
It can use.
Suitable solid carrier includes：Mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance includes
Silicates, carbonate, Sulfates and oxide-based.Silicates such as kaolin, sepiolite, nacrite cover de-
Soil, mica, vermiculite, pyrophyllite, talcum.Carbonate is for example：Calcium carbonate, dolomite.Sulfates such as ammonium sulfate, sodium sulphate,
Calcium sulfate.Oxide-based such as quick lime, magnesium lime, diatomite.Plant is for example：Citrus pulp, corncob cellulose, rice husk powder, rice husk,
Big soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class such as winnofil hydrate, winnofil, white carbon.
Inorganic salts such as potassium chloride, sodium chloride.
Liquid-carrier includes water and organic solvent.When active ingredient is suspension emulsion, organic solvent plays solubilized and antifreeze
Effect.Suitable organic solvent includes aromatic hydrocarbons, such as benzene, dimethylbenzene, toluene, alkylbenzene, alkylnaphthalene and chlorinated aromatic hydrocarbons；Chloro fat
Fat hydrocarbon, such as vinyl chloride, chloroform, dichloromethane, chloroform, carbon tetrachloride and more chloroethanes；Aliphatic hydrocarbon, such as oil evaporate
Point, hexamethylene, light mineral oil and paraffin.Alcohols such as methanol, ethyl alcohol, isopropanol, butanol, isobutanol, ethylene glycol, the third two
Alcohol, glycerine, fatty alcohol etc.；Ethers such as Propylene Glycol ether, ethohexadiol ether, petroleum ether.Ketone such as acetone, first and second
Ketone, methyl iso-butyl ketone (MIBK), cyclohexanone and isophorone, N- methyl-pyrrolidons；Special solvent also has dimethylformamide,
Dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile；Vegetable oil and methylated vegetable oils.Above-mentioned organic solvent both can be used alone, and also may be used
To be used in mixed way, can also be mixed together with water.
Auxiliary agent of the present invention can include surfactant, antifoaming agent, thickener, suspending agent and antifreezing agent as needed
One or more of, can also include other common auxiliary agents of the industry as needed.
Surfactant can be emulsifier, dispersant, stabilizer or wetting agent；Can be ionic or nonionic
's.Suitable surfactant includes：The sodium salt and calcium salt of polyacrylic acid and lignin sulfonic acid；Contain at least 12 carbon in molecule
The polycondensation product of the aliphatic acid or fatty amine and ethylene oxide and/propylene oxide of atom；Glycerine, dodecanol -1, tetradecanol -
1, the aliphatic ester of sorbierite, sucrose or pentaerythrite；And the polycondensation product of they and ethylene oxide and/or propylene oxide；It
Polycondensation product sulfate or sulfonate；In the molecule at least the alkali metal of the sulfuric acid containing 10 carbon atoms or sulfonic acid or
Alkali salt, preferably sodium salt, such as lauryl sodium sulfate, Teepol, the sodium salt of sulfonated castor oil, alkaryl
Sodium sulfonate and neopelex；The polymer of ethylene oxide, the copolymer of ethylene oxide and propylene oxide.
Emulsifier includes nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonyl phenyl of nonionic emulsifier
Vinethene, fatty alcohol polyoxyethylene ether, styryl phenyl polyoxyethylene ether, alkyl phenol formaldehyde resin polyoxyethylene ether hold hydroxyl
Base polyoxyethylene poly-oxygen propylene aether, styrylphenol formaldehyde resin Polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether.
Anionic emulsifier includes mainly calcium dodecyl benzene sulfonate, three phenethyl phenol polyoxy ether phosphate amine salts, and nonyl phenol is poly-
Ethylene oxide ether phosphate amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention includes：Acrylate homopolymer sodium salt, Malaysia acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product
Sodium salt, rosin segmented polyoxyethylene ether polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, three
Phenethyl phenol polyethenoxy ether phosphate, fatty alcohol polyoxyethylene ether phosphoric acid, one kind in p-hydroxyphenyl lignin sulfonic acid sodium salt
Or it is several.
Wetting agent of the present invention includes：Fatty alcohol polyoxyethylene ether, naphthalene sulfonate, lauryl sodium sulfate, alkyl
One or more of phenol resin polyoxyethylene ether sulfate combines.
Thickener of the present invention includes xanthans, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, Arab
Glue, gelatin, one or more of polyvinyl alcohol.Antifoaming agent of the present invention is preferably：Bubble enemy, silicone, C8~10Fat
Alcohol, C10~20Saturated fat acids and amide etc..
Pesticidal combination of the present invention can be configured to missible oil, oil suspending agent, suspension according to method generally in the art
Agent, wettable powder or water dispersible granules.
Pesticidal combination of the present invention is suitable for prevention mite pest and/or lepidoptera pest.Preferably, institute
It includes red spider to state mite pest, and the lepidoptera pest includes beet armyworm, diamondback moth, bollworm and leaf roller.The present invention
The Pesticidal combination of offer is particularly suitable for the mite pest and/or lepidoptera pest in prevention vegetables, fruit tree or cotton.
Pesticidal combination of the present invention has following advantage compared with prior art：
(1) two kinds of pesticide compositionals show excellent synergistic effect within a certain ratio range in composition, after mixing
The insecticidal effect of composition be significantly improved compared with its single dose, and have the characteristics that quick-acting is good and lasting effect length；
(2) dosage is reduced, peasant's drug cost is reduced；
(3) reasonably mixture is carried out using two kinds of pesticides mode of action different to pest, the different mechanism of action, both prolonged
The Pesticide use service life has been grown, and has delayed the generation of pest resistance to insecticide.
Specific implementation mode
With reference to specific embodiment, invention is further explained, but does not limit the invention to these tools
Body embodiment.One skilled in the art would recognize that present invention encompasses may include in Claims scope
All alternatives, improvement project and equivalent scheme.
In following embodiment, unless otherwise stated, all percentages are weight percentage.
Indoor toxicity determination test is with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/
T1154.7-2006) and initiative pesticide bioactivity evaluates SOP (insecticide volume), using infusion process.
Synergy is calculated using following methods：
Contents (%) of the toxicity index × A of mixed toxicity index (the TTI)=A of theory in mixed
Contents (%) of the toxicity index × B of+B in mixed
Co-toxicity coefficient shows there is synergistic effect if more than 120；If being less than 80, it is shown to be antagonism；It is less than if more than 80
120, it is shown to be summation action.
Embodiment 1：Chlorine fluorine cyanogen insect amide and Bifenazate mixture
Table 1, chlorine fluorine cyanogen insect amide combine increasing with Bifenazate to cotton red spider Tetranychus Cinnabarinus
Effect acts on
Table 2, chlorine fluorine cyanogen insect amide and Bifenazate act on beet armyworm Spodoptera exigua synergies
| Proportioning | LC50(mg/L) | Survey toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Bifenazate | 41.35 | 2.10 | ||
| Chlorine fluorine cyanogen insect amide | 0.87 | 100.00 | ||
| Bifenazate:Chlorine fluorine cyanogen insect amide=50:1 | 14.32 | 6.08 | 4.02 | 151.00 |
| Bifenazate:Chlorine fluorine cyanogen insect amide=20:1 | 7.61 | 11.43 | 6.77 | 168.97 |
| Bifenazate:Chlorine fluorine cyanogen insect amide=1:1 | 1.05 | 82.86 | 51.05 | 162.30 |
| Bifenazate:Chlorine fluorine cyanogen insect amide=1:10 | 0.58 | 150.00 | 91.10 | 164.65 |
| Bifenazate:Chlorine fluorine cyanogen insect amide=1:20 | 0.57 | 152.63 | 95.34 | 160.09 |
As can be seen from Table 1 and Table 2, Bifenazate and chlorine fluorine cyanogen insect amide are 1~50：The model of 20~1 (by weight)
In enclosing, co-toxicity coefficient is all higher than 120, and synergistic effect is shown as to red spider and beet armyworm.Bifenazate and chlorine fluorine cyanogen worm
Amide mixture has reasonability and feasibility.
Embodiment 2,20% Bifenazate chlorine fluorine cyanogen insect amide suspending agent
By Bifenazate 18%, chlorine fluorine cyanogen insect amide 2%, emulsifier 1601# (styrylphenol polyoxyethylene polyoxies third
Alkene ether) 10%, dispersant SOPA-270 4%, bentonite 2%, xanthans 0.1%, organic silicon defoamer 0.4%, glycerine
5% and surplus be deionized water formula, each component is crushed in advance, adds in sand mill and grinds, after high shear mixing
20% Bifenazate chlorine fluorine cyanogen insect amide suspending agent is made in allotment.
20% Bifenazate chlorine fluorine cyanogen insect amide suspending agent obtained is prevented applied to wild cabbage diamondback moth.20% biphenyl
Hydrazine ester chlorine fluorine cyanogen insect amide suspending agent is watered even spraying by 10 grams/acre in wild cabbage diamondback moth larva occurance peak, 3 after medicine
The preventive effect of it and 7 days is respectively 93.4% and 97.6%.Dispenser in the same way compares 20% Bifenazate suspending agent of single dose
(formulation rate is 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), 3 days preventive effects point after medicine
Not Wei 40.3% and 87.2%, 7 days preventive effects are respectively 45.5% and 85.3% after medicine.Bifenazate and chlorine fluorine cyanogen insect amide
Synergistic effect is apparent after mixture, and preventive effect is better than single dose.
Embodiment 3,40% Bifenazate chlorine fluorine cyanogen insect amide water-dispersible granules
By Bifenazate 35%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride
8%, polyethylene glycol 3% and surplus are kaolinic formula, are made after each component is carried out dry pulverization process, granulation, drying, screening
40% Bifenazate chlorine fluorine cyanogen insect amide water-dispersible granules.
40% Bifenazate chlorine fluorine cyanogen insect amide water-dispersible granules obtained are prevented applied to red spider.40%
Phenylhydrazine ester chlorine fluorine cyanogen insect amide water-dispersible granules are watered even spraying by 10 grams/acre in red spider occurrence in peak period, in medicine
3 days and 7 days preventive effects are respectively 95.5% river 93.4% afterwards.Dispenser in the same way, control 20% Bifenazate of single dose suspend
Agent (formulation rate is 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), 3 days preventive effects after medicine
Respectively 79.2% and 25.1%, 7 days preventive effects are respectively 81.4% and 27.9% after medicine.Bifenazate and chlorine fluorine cyanogen worm acyl
Synergistic effect is apparent after amine mixture, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose, and dosage is dropped than single dose
It is low.
Embodiment 4,70% Bifenazate chlorine fluorine cyanogen insect amide water-dispersible granules
By Bifenazate 55%, chlorine fluorine cyanogen insect amide 15%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride
8%, polyethylene glycol 3% and surplus are kaolinic formula, are made after each component is carried out dry pulverization process, granulation, drying, screening
70% Bifenazate chlorine fluorine cyanogen insect amide water-dispersible granules.
70% Bifenazate chlorine fluorine cyanogen insect amide water-dispersible granules obtained are prevented applied to Laphygma exigua Hubner.
70% Bifenazate chlorine fluorine cyanogen insect amide water-dispersible granules are watered even spraying by 10 grams/acre in low instar larvae full incidence period,
7 days and 14 days preventive effects are respectively 93.2% and 94.7% after medicine.Dispenser in the same way, control 20% Bifenazate of single dose are outstanding
Floating agent (formulation rate be 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre) are prevented for 7 days after medicine
Effect is respectively 32.5% and 85.4%, and 14 days preventive effects are respectively 33.9% and 87.9% after medicine.Bifenazate and chlorine fluorine cyanogen
Synergistic effect is apparent after insect amide mixture, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 5,40% Bifenazate chlorine fluorine cyanogen insect amide wettable powder
By Bifenazate 35%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride
8%, polyethylene glycol 3% and surplus are kaolinic formula, are made after each component is carried out dry pulverization process, granulation, drying, screening
40% Bifenazate chlorine fluorine cyanogen insect amide wettable powder.
40% Bifenazate chlorine fluorine cyanogen insect amide wettable powder obtained is prevented applied to wild cabbage diamondback moth.40%
Bifenazate chlorine fluorine cyanogen insect amide wettable powder is watered even spraying by 10 grams/acre in low instar larvae occurrence in peak period,
7 days and 14 days preventive effects are respectively 95.6% and 96.7% after medicine.Dispenser in the same way, control 20% Bifenazate of single dose are outstanding
Floating agent (formulation rate be 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre) are prevented for 7 days after medicine
Effect is respectively 31.7% and 83.5%, and 14 days preventive effects are respectively 43.7% and 82.8% after medicine.Bifenazate and chlorine fluorine cyanogen
Synergistic effect is apparent after insect amide mixture, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 6,20% Bifenazate chlorine fluorine cyanogen insect amide oil suspending agent
It is poly- by Bifenazate 15%, chlorine fluorine cyanogen insect amide 5%, castor oil polyoxyethylene ether 13%, triphenyl vinyl phenol
Ethylene oxide ether phosphate 3%, organobentonite 1% and methyl oleate are mended to 100% formula, after mixing by each component,
It is sanded to certain grain size and obtains 20% Bifenazate chlorine fluorine cyanogen insect amide oil suspending agent.
20% Bifenazate chlorine fluorine cyanogen insect amide oil suspending agent obtained is applied to cotton bollworm control.20% biphenyl hydrazine
Ester chlorine fluorine cyanogen insect amide oil suspending agent is watered even spraying by 10 grams/acre in cotton bollworm larvae occurance peak, 3 days and 7 after medicine
It preventive effect is respectively 92.7% and 93.4%.Dispenser in the same way compares 20% Bifenazate suspending agent (formulation rate of single dose
It is 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), 3 days preventive effects are respectively after medicine
46.7% and 82.5%, 7 days preventive effects are 49.6% and 85.0% after medicine.Increase after Bifenazate and chlorine fluorine cyanogen insect amide mixture
Effect effect is apparent, and preventive effect is better than single dose.
Embodiment 7,20% Bifenazate chlorine fluorine cyanogen insect amide missible oil
By Bifenazate 15%, chlorine fluorine cyanogen insect amide 5%, calcium dodecyl benzene sulfonate 6%, three phenethyl phenol polyoxyethylene
Ether 6%, NMP 8% and surplus are the formula of dimethylbenzene, and 20% Bifenazate chlorine is obtained after each component is mixed evenly
Fluorine cyanogen insect amide missible oil.
20% Bifenazate chlorine fluorine cyanogen insect amide missible oil obtained is prevented applied to apple skin worm.20% biphenyl hydrazine
Ester chlorine fluorine cyanogen insect amide missible oil is watered even spraying by 10 grams/acre in larva occurance peak, 3 days and 7 days preventive effects point after medicine
It Wei 96.9% and 98.0%.Dispenser in the same way, 20% Bifenazate suspending agent of control single dose (formulation rate is 30 grams/acre)
With 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), 3 days preventive effects are respectively 57.3% He after medicine
84.5%, 7 days preventive effects are 57.1% and 87.5% after medicine.Synergistic effect is bright after Bifenazate and chlorine fluorine cyanogen insect amide mixture
Aobvious, preventive effect is better than single dose.
Claims (9)
1. a kind of Pesticidal combination for agricultural pests, it is characterised in that the Pesticidal combination includes Bifenazate and chlorine fluorine
Cyanogen insect amide, and the quality proportioning of Bifenazate and chlorine fluorine cyanogen insect amide is 1~50:20~1.
2. the Pesticidal combination described in accordance with the claim 1 for agricultural pests, it is characterised in that the Bifenazate and chlorine
The quality proportioning of fluorine cyanogen insect amide is 1~10:10~1.
3. being used for the Pesticidal combination of agricultural pests according to claim 2, it is characterised in that the Bifenazate and chlorine
The quality proportioning of fluorine cyanogen insect amide is 1~5:5~1.
4. a kind of insecticide for agricultural pests, it is characterised in that the insecticide is by weight containing 5~90% desinsection
Composition, remaining is agriculturally acceptable carrier and auxiliary agent, and the Pesticidal combination includes Bifenazate and chlorine fluorine cyanogen worm acyl
Amine, and the quality proportioning of Bifenazate and chlorine fluorine cyanogen insect amide is 1~50:20~1.
5. being used for the insecticide of agricultural pests according to claim 4, it is characterised in that the insecticide contains by weight
There is 5~40% Pesticidal combination.
6. being used for the insecticide of agricultural pests according to claim 4, it is characterised in that the insecticide can be configured to breast
Oil, oil suspending agent, suspending agent, wettable powder or water dispersible granules.
7. a kind of purposes of Pesticidal combination for agricultural pests, it is characterised in that the Pesticidal combination is for preventing mite class
Pest and/or lepidoptera pest, the Pesticidal combination include Bifenazate and chlorine fluorine cyanogen insect amide, and Bifenazate and chlorine fluorine
The quality proportioning of cyanogen insect amide is 1~50:20~1.
8. the purposes of Pesticidal combination according to claim 7, it is characterised in that the mite pest includes red spider, institute
It includes beet armyworm, diamondback moth, bollworm and leaf roller to state lepidoptera pest.
9. the purposes of Pesticidal combination according to claim 7, it is characterised in that the Pesticidal combination is for preventing vegetable
Mite pest in dish, fruit tree or cotton and/or lepidoptera pest.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610124030.2A CN107148973B (en) | 2016-03-04 | 2016-03-04 | A kind of Pesticidal combination containing Bifenazate and chlorine fluorine cyanogen insect amide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610124030.2A CN107148973B (en) | 2016-03-04 | 2016-03-04 | A kind of Pesticidal combination containing Bifenazate and chlorine fluorine cyanogen insect amide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107148973A CN107148973A (en) | 2017-09-12 |
| CN107148973B true CN107148973B (en) | 2018-10-26 |
Family
ID=59791412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610124030.2A Active CN107148973B (en) | 2016-03-04 | 2016-03-04 | A kind of Pesticidal combination containing Bifenazate and chlorine fluorine cyanogen insect amide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107148973B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112021002077A2 (en) * | 2018-08-28 | 2022-02-01 | Upl Ltd | Innovative insecticide combinations |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007101542A1 (en) * | 2006-03-06 | 2007-09-13 | Bayer Cropscience Ag | Combinations of active ingredients with insecticidal properties |
| CN101755795A (en) * | 2009-11-17 | 2010-06-30 | 陕西汤普森生物科技有限公司 | Synergistic pesticidal composition containing hexaflumuron and flubendiamide |
| CN103039501A (en) * | 2013-01-06 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing beta cypermethrin and ZJ4042 |
| CN103931639A (en) * | 2014-03-16 | 2014-07-23 | 广东中迅农科股份有限公司 | Pesticide composition containing tolfenpyrad and bifenazate |
-
2016
- 2016-03-04 CN CN201610124030.2A patent/CN107148973B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007101542A1 (en) * | 2006-03-06 | 2007-09-13 | Bayer Cropscience Ag | Combinations of active ingredients with insecticidal properties |
| CN101755795A (en) * | 2009-11-17 | 2010-06-30 | 陕西汤普森生物科技有限公司 | Synergistic pesticidal composition containing hexaflumuron and flubendiamide |
| CN103039501A (en) * | 2013-01-06 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing beta cypermethrin and ZJ4042 |
| CN103931639A (en) * | 2014-03-16 | 2014-07-23 | 广东中迅农科股份有限公司 | Pesticide composition containing tolfenpyrad and bifenazate |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107148973A (en) | 2017-09-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103039512B (en) | Agricultural insecticidal composition containing chlorpyrifos and ZJ4042 | |
| CN103039450B (en) | Agricultural insecticidal composition containing spinosad and ZJ4042 | |
| CN103250720B (en) | A kind of containing chlorfluazuron and ZJ4042 agricultural pesticide composition | |
| CN103250727B (en) | Agricultural insecticidal composition containing indoxacarb and ZJ4042 | |
| CN103039501B (en) | Agricultural insecticidal composition containing beta cypermethrin and ZJ4042 | |
| CN107148973B (en) | A kind of Pesticidal combination containing Bifenazate and chlorine fluorine cyanogen insect amide | |
| CN104938511B (en) | A kind of Pesticidal combination containing Teflubenzuron and chlorine fluorine cyanogen insect amide | |
| CN106259343B (en) | A kind of Pesticidal combination of pyriproxyfen-containing and chlorine fluorine cyanogen insect amide | |
| CN104920412B (en) | A kind of Pesticidal combination containing flufenoxuron and chlorine fluorine cyanogen insect amide | |
| CN104145963B (en) | A kind of Pesticidal combination containing ether chrysanthemum ester and ZJ4042 | |
| CN103250701B (en) | Agricultural insecticidal composition containing chlorfenapyr and ZJ4042 | |
| CN104430415A (en) | Insecticidal composition containing spirotetramat and chlorofluorocarbon cyantraniliprole | |
| CN103053545B (en) | Agricultural pesticide combination containing pymetrozine | |
| CN104957160B (en) | A kind of Pesticidal combination containing carbosulfan and chlorine fluorine cyanogen insect amide | |
| CN104145956B (en) | A kind of Pesticidal combination containing worm hydrazides and ZJ4042 | |
| CN104472488B (en) | A kind of containing flonicamid with the Pesticidal combination of chlorine fluorine cyanogen insect amide | |
| CN104938487B (en) | A kind of Pesticidal combination containing dimehypo and chlorine fluorine cyanogen insect amide | |
| CN105191952B (en) | A kind of Pesticidal combination and its insecticide for agricultural pests | |
| CN104430475A (en) | Insecticidal composition containing clothianidin and chlorofluorocarbon cyantraniliprole | |
| CN108142427A (en) | A kind of composition containing mibemycin and chlorine fluorine cyanogen insect amide | |
| CN104365645A (en) | Insecticidal composition containing acetamiprid and cyhalodiamide | |
| CN106259424A (en) | A kind of containing metrifonate with the Pesticidal combination of chlorine fluorine cyanogen insect amide | |
| CN104351184A (en) | Nitenpyram and cyhalodiamide containing insecticide composition | |
| CN104222139A (en) | Insecticide composition containing dinotefuran and ZJ4042 | |
| CN104957172A (en) | Insecticide composition containing quinalphos and cyhalodiamide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200211 Address after: 310023 No. 926, Xixi Road, Hangzhou, Zhejiang, Xihu District Co-patentee after: Sinochem Lantian Co., Ltd. Patentee after: Zhejiang Research Institute of Chemical Industry, Ltd. Co-patentee after: Sinochem Corporation Address before: 310023 No. 926, Xixi Road, Hangzhou, Zhejiang, Xihu District Co-patentee before: Sinochem Lantian Co., Ltd. Patentee before: Zhejiang Research Institute of Chemical Industry, Ltd. |