CN103039501B - Agricultural insecticidal composition containing beta cypermethrin and ZJ4042 - Google Patents
Agricultural insecticidal composition containing beta cypermethrin and ZJ4042 Download PDFInfo
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- CN103039501B CN103039501B CN201310004961.5A CN201310004961A CN103039501B CN 103039501 B CN103039501 B CN 103039501B CN 201310004961 A CN201310004961 A CN 201310004961A CN 103039501 B CN103039501 B CN 103039501B
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Abstract
The invention discloses an insecticidal composition for agricultural insects, which contains two active ingredients: the first active ingredient is beta cypermethrin, the second active ingredient is 3-chlorine-N<1>-(2-methyl-4-heptafluoroisopropyl phenyl)-N<2>-(1-methyl-1-cyano ethyl) phthalic diamide, and the weight ratio of the first active ingredient to the second active ingredient is (1-20):(50-1). The insecticidal composition is suitable for controlling piercing-sucking mouthpart insects and lepidoptera insects, and superior to a single insecticide in quick-acting property and persistent-acting property, the use cost of the insecticide is low, and environmental protection and comprehensive control of the agricultural insects are facilitated.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of by beta-cypermethrin and the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2composite high-efficiency low-toxicity agricultural pesticide composition and the insecticide thereof forming of-(1-methyl isophthalic acid-cyano ethyl) phthalic amide.
Background technology
The resistance problem of pest is a global problem.Along with Chemical Control of Harmful Insects increase and the non-science of continuity, agricultural chemicals usage amount use agricultural chemicals, pest resistance is day by day serious, the pest species that produces resistance is on the increase.The Lepidoptera class pest of particularly causing harm serious to agricultural production, resistance level is higher, and resistance development speed is relatively very fast.Meanwhile, high-intensity use agricultural chemicals, causes that Practice for Pesticide Residue in Agricultural Products exceeds standard, environmental pollution and the increase of peasant's drug cost etc., is unfavorable for agricultural sustainable development.Therefore, the pesticide of efficient, the low toxicity of research and development, environmental protection has positive effect to agricultural sustainable development.
Beta-cypermethrin Beta cypermethrin, chemical name: 2,2-dimethyl-3-(2,2-dichloroethylene) cyclopropane-carboxylic acid-alpha-cyano-(3-phenoxy group)-benzyl ester, molecular formula C
22h
19cl
2nO
3, be a kind of pyrethroid insecticides, biologically active is higher, is the efficient isomer of cypermethrin, has and tags and stomach poison function.Insecticidal spectrum is wide, the speed of knocking down is fast, and insecticidal activity is high compared with cypermethrin, is applicable to prevent and treat insect and the sanitary insect pest in the various plants such as cotton, vegetables, tea tree, forest.
The chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide (be called for short: ZJ4042), shown in structural formula following (I):
The insecticidal activity of this compound and the fipronil bisamide of recent development substantially suitable.Fipronil bisamide, English common name (flubendiamide) is researched and developed by Nihon Nihyaku Co., Ltd, chemical name is 3 iodo-N '-(2-first sulfonephthalein base-1,1-dimethyl ethyl group-N-{ 4-" 1; 2; 2,2-tetrafluoro-1-(trifluoromethyl) ethyl-o-tolyl } phthalamide, molecular formula is: C
23h
22f
7n
2o
4, belong to Novel ortho benzenedicarboxamide insecticides, activate calcium release channel in blue Buddhist nun's alkali recipient cell, cause the property out of control of storing calcium ion to discharge, be at present few in number compounds that acts on blue Buddhist nun's alkali (Ryanodine) acceptor of insect cell.Lepidoptera pest is had to wide spectrum preventive effect, produce without cross resistance with existing insecticide, be suitable for very much the control of the insect of existing insecticide generation resistance.
When beta-cypermethrin and ZJ4042 use separately, drug cost is higher, limited to a certain extent it and applied, and long-term use separately easily causes pest resistance degree constantly to increase.The mixture of different pesticide species is common methods of the agriculture resistant insect of control.Screening by formulation of pesticide, filter out rational formula, can effectively improve actual control efficiency, reduce dosage, reduce costs, delay the generation of pest resistance to insecticide, extend the service life of medicament, is the important means of integrated pest management.
Anti-the eliminating aphis of the mixture of beta-cypermethrin and ZJ4042 waited pierce-suck type implication class pest, and the Lepidoptera class pest such as prodenia litura, beet armyworm, diamond-back moth, cotton bollworm, tea geometrid there is no at present report and applies.
Summary of the invention
The object of the present invention is to provide a kind of efficient, low toxicity and lasting period are long, can effectively prevent and treat crops Lepidoptera class pest high-efficiency low-toxicity agricultural pesticide composition and insecticide thereof.
For reaching goal of the invention the technical solution used in the present invention be:
For a Pesticidal combination for pest, contain two kinds of active components, the first active component is beta-cypermethrin, second active ingredient is the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the weight ratio that described the first active component and the second activity become is 1～20:50～1.
The weight ratio that above-mentioned the first active component and the second activity become is preferably 1～10:10～1.
The present invention also provides a kind of insecticide for pest, contains by weight 5～90% above-mentioned Pesticidal combinations, and all the other are the upper acceptable carrier of agricultural and auxiliary agent.As preferred embodiment, in insecticide, preferably contain 20～70% above-mentioned Pesticidal combination, particularly preferably contain 20～40% Pesticidal combination.
Carrier of the present invention can be solid or liquid, and any carrier that is generally used for preparing insecticides all can use.
Suitable solid carrier comprises: mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance comprises silicates, carbonate, Sulfates and oxide-based.Silicates is kaolin such as, sepiolite, nacrite, imvite, mica, vermiculite, pyrophyllite, talcum.Carbonate is for example: calcium carbonate, dolomite.Sulfates is as ammonium sulfate, sodium sulphate, calcium sulphate.Oxide-based as quicklime, magnesium lime, diatomite.Plant is for example: citrus pulp, corncob cellulose, rice husk powder, rice husk, large soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class is as winnofil hydrate, winnofil, white carbon.Inorganic salts is potassium chloride such as, sodium chloride.
Liquid-carrier comprises water and organic solvent.In the time that active ingredient is aqueous emulsion or suspension emulsion, organic solvent plays solubilising and antifreeze effect.Suitable organic solvent comprises aromatic hydrocarbons, for example benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chlorinated aliphatic hydrocarbon, for example vinyl chloride, chloroform, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, for example petroleum distillate, cyclohexane, light mineral oil and paraffin.Alcohols is methyl alcohol such as, ethanol, isopropyl alcohol, butanols, isobutanol, ethylene glycol, propane diols, glycerine, fatty alcohol etc.; Ethers is Propylene Glycol ether for example, ethohexadiol ether, benzinum.Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and different fluorine that ketone, N-methyl-pyrrolidones for example; Special solvent also has dimethyl formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile; Vegetable oil and the vegetable oil that methylates.Above-mentioned organic solvent both can be used alone, but also also mix together, and can also mix together with water.
Auxiliary agent of the present invention can comprise one or more in surfactant, defoamer, thickener, suspending agent and antifreezing agent as required, can also comprise as required other auxiliary agents that the industry is conventional.
Surfactant can be emulsifier, dispersant, stabilizing agent or wetting agent; Can be ionic or nonionic.Suitable surfactant comprises: the sodium salt of polyacrylic acid and lignin sulfonic acid and calcium salt; In molecule, contain the fatty acid of at least 12 carbon atoms or fatty amine and oxirane and/polycondensation product of expoxy propane; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In molecule, at least containing the sulfuric acid of 10 carbon atoms or the alkali metal of sulfonic acid or alkali salt, is preferably sodium salt, as the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, alkylaryl sodium sulfonate and neopelex; The copolymer of polymer, oxirane and the expoxy propane of oxirane.
Emulsifier comprises nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonylphenol ether of nonionic emulsifier, fatty alcohol-polyoxyethylene ether, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether, styryl phenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.Anionic emulsifier mainly comprises calcium dodecyl benzene sulfonate, triphen ethyl phenol polyoxy ether phosphate amine salt, polyoxyethylene nonylphenol ether phosphate amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention comprises: acrylate homopolymer sodium salt, maleic acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, triphen ethyl phenol polyoxyethylene ether phosphate, fatty alcohol-polyoxyethylene ether phosphoric acid, to one or more in hydroxyphenyl lignin sulfonic acid sodium salt.
Wetting agent of the present invention comprises: fatty alcohol-polyoxyethylene ether, naphthalene sulfonate, lauryl sodium sulfate, one or more combinations in alkyl phenol resin polyoxyethylene ether sulfate.。
Thickener of the present invention comprises xanthans, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, gum Arabic, gelatin, one or more in polyvinyl alcohol.Defoamer of the present invention is preferably: bubble enemy, silicone, C
8～10fatty alcohol, C
10～20saturated fat acids and acid amides etc.
Pesticidal combination of the present invention can be configured to missible oil, aqueous emulsion, suspending agent, wetting powder or water dispersible granules according to the general method in this area.
Pesticidal combination of the present invention is specially adapted to prevent and treat pierce-suck type implication class pest and the Lepidoptera class pest in vegetables, paddy rice, cotton and tealeaves, especially prevents and treats pierce-suck type implication class pest aphid and Lepidoptera class pest prodenia litura, beet armyworm, diamond-back moth, cotton bollworm, tea geometrid.
Pesticidal combination of the present invention and insecticide thereof have following advantage compared to existing technology:
(1) in composition, two kinds of active components are composite shows good synergistic effect in certain ratio range, and the insecticidal effect of mixed composition is significantly improved compared with its single dose, and has the advantages that quick-acting is good and lasting effect is grown;
(2) reduce using dosage, reduced peasant's drug cost;
(3) utilize two kinds of active components to carry out reasonably mixture to the different mode of action of insect, the different mechanism of action, both extended agricultural chemicals service life, delay again the generation of pest resistance to insecticide.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these embodiments.One skilled in the art would recognize that the present invention contained all alternatives, improvement project and the equivalents that within the scope of claims, may comprise.
In following embodiment material prescription select can suit measures to local conditions, on result without substantial impact.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
The inventor has carried out Toxicity Determination test to beta-cypermethrin and ZJ4042 mixture.
Test is evaluated SOP(insecticide volume with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and initiative pesticide bioactivity), adopt infusion process.
Synergy adopts following method to calculate:
The content (%) of toxicity index × A of theoretical mixed toxicity index (TTI)=A in mixed
The content (%) of toxicity index × B of+B in mixed
If co-toxicity coefficient is greater than 120, showing has synergistic effect; If be less than 80, be indicated as antagonism; Be less than 120 if be greater than 80, be indicated as summation action.
Embodiment 1:ZJ4042 and beta-cypermethrin mixture
Table 1 ZJ4042 and beta-cypermethrin are to the effect of wild cabbage diamond-back moth Plutella xylostella synergy
Table 2 ZJ4042 and beta-cypermethrin are to the effect of cabbage aphid Lipaphis erysimi synergy
Can find out from result of the test table 1,2, the agricultural pesticide composition that beta-cypermethrin and ZJ4042 are composite, 1～20:30～1(by weight) scope in, co-toxicity coefficient is all greater than 120, and wild cabbage diamond-back moth and aphid are all shown as to synergistic effect.Beta-cypermethrin and ZJ4042 mixture have reasonability and feasibility.
Embodiment 2 (20% beta-cypermethrin ZJ4042 suspending agent)
Press beta-cypermethrin 18%, ZJ40422%, emulsifier 1601#(styryl phenol polyoxyethylene poly-oxygen propylene aether) 10%, dispersant SOPA-27044%, bentonite 2%, xanthans 0.1%, silicone defoaming agent 0.4%, glycerine 5%, surplus is deionized water.Above-mentioned formula is pulverized in proportion in advance, then added in sand mill and grind, after high shear mixing, allotment makes 20% beta-cypermethrin ZJ4042 suspending agent.
This embodiment 2 is applied to control wild cabbage diamond-back moth.20% beta-cypermethrin ZJ4042 suspending agent is watered even spraying by 10 grams/acre in wild cabbage diamondback moth larvae occurance peak, and after medicine, the preventive effect of 3 days, 7 days is respectively 95.2%, 96.7%.Contrast single dose 4.5% r (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 74.3%, 85.3%, and after medicine, the preventive effect of 7 days is respectively 75.6%, 86.5%.After beta-cypermethrin and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 3 (40% beta-cypermethrin ZJ4042 water-dispersible granules)
Press beta-cypermethrin 35%, ZJ40425%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus is kaolin.By above-mentioned formula, dry pulverization process, granulation, dry, screening make 40% beta-cypermethrin ZJ4042 water-dispersible granules in proportion.
This embodiment 3 is applied to control cabbage aphid.40% beta-cypermethrin ZJ4042 water-dispersible granules is watered even spraying by 10 grams/acre in cabbage aphid nymph occurrence in peak period, and after medicine, 3 days, 7 days preventive effects are respectively 93.6%, 96.7%.Contrast single dose 4.5% r (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 77.3%, 85.9%, and after medicine, the preventive effect of 7 days is respectively 78.2%, 89.2%.After beta-cypermethrin and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose, and dosage reduces than single dose.
Embodiment 4 (70% beta-cypermethrin ZJ4042 water-dispersible granules)
Press beta-cypermethrin 55%, ZJ404215%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus is kaolin.By above-mentioned formula, dry pulverization process, granulation, dry, screening make 70% beta-cypermethrin ZJ4042 water-dispersible granules in proportion.
This embodiment 4 is applied to control Laphygma exigua Hubner.70% beta-cypermethrin ZJ4042 water-dispersible granules is watered even spraying by 5 grams/acre in Laphygma exigua Hubner larva occurrence in peak period, and after medicine, 3 days, 7 days preventive effects are respectively 92.8%, 93.8%.Contrast single dose 4.5% r (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 78.0%, 77.8%, and after medicine, the preventive effect of 7 days is respectively 77.9%, 82.1%.After beta-cypermethrin and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 5 (20% beta-cypermethrin ZJ4042 oil suspending agent)
Beta-cypermethrin 15%, ZJ40425%, castor oil polyoxyethylene ether 13%, tristyrylphenol polyoxyethylene ether phosphate 3%, organobentonite 1%, methyl oleate is mended to 100%.After above-mentioned formula is mixed, sand milling is to certain particle diameter.
This embodiment 5 is applied to control cotton bollworm.20% beta-cypermethrin ZJ4042 oil suspending agent is watered even spraying by 10 grams/acre in cotton bollworm larvae occurance peak, and after medicine, 3 days, 7 days preventive effects are respectively 94.2%, 95.0%.Contrast single dose 4.5% r (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 72.9%, 83.2%, and after medicine, the preventive effect of 7 days is 77.8%, 88.7%.After beta-cypermethrin and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 6 (40% beta-cypermethrin ZJ4042 wetting powder)
Press beta-cypermethrin 35%, ZJ40425%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus is kaolin.By above-mentioned formula, dry pulverization process, granulation, dry, screening make 40% beta-cypermethrin ZJ4042 wetting powder in proportion.
This embodiment 6 is applied to control tea geometrid.40% beta-cypermethrin ZJ4042 wetting powder is watered even spraying by 10 grams/acre in tea geometrid low instar larvae occurrence in peak period, and after medicine, 3 days, 7 days preventive effects are respectively 90.7%, 91.7%.Contrast single dose 4.5% r (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 77.2%, 87.2%, and after medicine, the preventive effect of 7 days is 79.3%, 89.0%.After beta-cypermethrin and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 7 (20% beta-cypermethrin ZJ4042 missible oil)
Press beta-cypermethrin 18%, ZJ40422%, calcium dodecyl benzene sulfonate 6%, triphen ethyl phenol APEO 6%, NMP8%, surplus is dimethylbenzene.By above-mentioned formula mixing and stirring in proportion.
This embodiment 7 is applied to control wild cabbage prodenia litura.20% beta-cypermethrin ZJ4042 missible oil is watered even spraying by 10 grams/acre in wild cabbage Spodoptera litura larvae occurrence in peak period, and after medicine, 3 days, 7 days preventive effects are respectively 91.2%, 92.7%.Contrast single dose 4.5% r (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 79.2%, 79.8%, and after medicine, the preventive effect of 7 days is respectively 80.3%, 81.7%.After beta-cypermethrin and ZJ4042 mixture, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Claims (8)
1. for a Pesticidal combination for pest, it is characterized in that containing two kinds of active components, the first active component is beta-cypermethrin, and second active ingredient is the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the weight ratio that described the first active component and the second activity become is 1～20:50～1.
2. according to the Pesticidal combination for pest claimed in claim 1, it is characterized in that the weight ratio that described the first active component and the second activity become is 1～10:10～1.
3. according to the Pesticidal combination for pest claimed in claim 1, it is characterized in that described Pesticidal combination is formulated into insecticide, in described insecticide, contain 5～90% Pesticidal combination by weight, all the other are the upper acceptable carrier of agricultural and auxiliary agent.
4. according to the Pesticidal combination for pest claimed in claim 3, it is characterized in that containing in described insecticide 20～70% Pesticidal combination by weight.
5. according to the Pesticidal combination for pest claimed in claim 4, it is characterized in that containing in described insecticide 20～40% Pesticidal combination by weight.
6. according to the Pesticidal combination for pest claimed in claim 3, it is characterized in that described insecticide is missible oil, oil suspending agent, suspending agent, wetting powder or water dispersible granules.
7. according to the Pesticidal combination for pest claimed in claim 1, it is characterized in that described Pesticidal combination is for preventing and treating pierce-suck type implication class pest and the Lepidoptera class pest of vegetables, paddy rice, cotton and tealeaves.
8. according to the Pesticidal combination for pest claimed in claim 7, it is characterized in that described pierce-suck type implication class pest is aphid, described Lepidoptera class pest is prodenia litura, beet armyworm, diamond-back moth, cotton bollworm, tea geometrid.
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| CN105307491B (en) * | 2013-04-19 | 2017-11-14 | 拜耳作物科学股份公司 | Active agent combinations with insecticidal properties |
| US9549551B2 (en) * | 2013-04-19 | 2017-01-24 | Bayer Cropscience Aktiengesellschaft | Active compound combinations having insecticidal properties |
| JP2016521268A (en) * | 2013-04-19 | 2016-07-21 | バイエル・クロップサイエンス・アクチェンゲゼルシャフト | Combination of active compounds with insecticidal properties |
| CN107494586A (en) * | 2014-10-16 | 2017-12-22 | 江苏龙灯化学有限公司 | A kind of Pesticidal combination |
| CN107148973B (en) * | 2016-03-04 | 2018-10-26 | 浙江省化工研究院有限公司 | A kind of Pesticidal combination containing Bifenazate and chlorine fluorine cyanogen insect amide |
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| CN1556806A (en) * | 2001-09-21 | 2004-12-22 | �Ű˾ | Arthropodicidal anthranilamides |
| CN101703050A (en) * | 2009-11-18 | 2010-05-12 | 青岛奥迪斯生物科技有限公司 | Insecticidal composite containing chlorantraniliprole and organic phosphorus |
| WO2012034472A1 (en) * | 2010-09-13 | 2012-03-22 | 中化蓝天集团有限公司 | Cyano benzenedicarboxamide compounds, preparing methods and as agricultural insecticides uses thereof |
| CN102696601A (en) * | 2012-05-10 | 2012-10-03 | 安徽华星化工股份有限公司 | Insecticidal composition containing flubendiamide |
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2013
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1556806A (en) * | 2001-09-21 | 2004-12-22 | �Ű˾ | Arthropodicidal anthranilamides |
| CN101703050A (en) * | 2009-11-18 | 2010-05-12 | 青岛奥迪斯生物科技有限公司 | Insecticidal composite containing chlorantraniliprole and organic phosphorus |
| WO2012034472A1 (en) * | 2010-09-13 | 2012-03-22 | 中化蓝天集团有限公司 | Cyano benzenedicarboxamide compounds, preparing methods and as agricultural insecticides uses thereof |
| CN102696601A (en) * | 2012-05-10 | 2012-10-03 | 安徽华星化工股份有限公司 | Insecticidal composition containing flubendiamide |
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