CN103250701B - Agricultural insecticidal composition containing chlorfenapyr and ZJ4042 - Google Patents
Agricultural insecticidal composition containing chlorfenapyr and ZJ4042 Download PDFInfo
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- CN103250701B CN103250701B CN201310159740.5A CN201310159740A CN103250701B CN 103250701 B CN103250701 B CN 103250701B CN 201310159740 A CN201310159740 A CN 201310159740A CN 103250701 B CN103250701 B CN 103250701B
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Abstract
The invention discloses an agricultural insecticidal composition containing two active ingredients, namely chlorfenapyr and 3-chloro-N1-(2-methyl-4-heptafluoroisopropyl phenyl)-N2-(1-methyl-1-cyanoethyl)phthalimide which are in the weight ratio of (1-50): (20-1). The insecticidal composition disclosed by the invention is suitable for preventing and treating destructive insects, such as spodoptera litura, beet armyworm, cabbage caterpillar, diamondback moth and cotton bollworm, of crops. According to the agricultural insecticidal composition, the quick acting performance and effect lasting performance are better than those of single agents, and the dosage and medicating cost of insecticide are reduced, so that the environmental protection and comprehensive treatment on agricultural insects are facilitated.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of by capillary and the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2composite higher effective and lower toxic pesticide composition and the insecticide thereof forming of-(1-methyl isophthalic acid-cyano ethyl) phthalic amide.
Background technology
The resistance problem of pest is a global problem.Along with the continuity of Chemical Control of Harmful Insects,, the increase of agricultural chemicals usage amount and non-science are used agricultural chemicals, pest resistance is day by day serious, and the pest species that produces resistance is on the increase.The Lepidoptera class pest of particularly causing harm serious to agricultural production, resistance level is high, and resistance development speed is fast.Meanwhile, high-intensity use agricultural chemicals, causes that Practice for Pesticide Residue in Agricultural Products exceeds standard, environmental pollution and the increase of peasant's drug cost etc., is unfavorable for agricultural sustainable development.Therefore need that research and development are efficient, the pesticide of low toxicity, environmental protection.
Capillary chlorfenapyr, have another name called chlorfenapyr, eliminate, it is new pyrrole compounds, its insecticidal mechanism is to act on the mitochondria of insect bodies inner cell, by the mixed-functional oxidase in insect bodies, work, suppress adenosine diphosphate (ADP) to the conversion of adenosine triphosphate (ATP), there is stomach toxicity and action of contace poison.Capillary is strong in blade face permeability, has certain systemic action, and insecticidal spectrum is wide, preventive effect is high, holding effect is long, safety.
The chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide (test code number: ZJ4042), be the novel pesticide that develop voluntarily Zhejiang Provincial Chemical Engineering Research Inst, shown in structural formula following (I):
The insecticidal activity of ZJ4042 and the fipronil bisamide of recent development substantially suitable, has wide spectrum preventive effect to lepidoptera pest, produces without cross resistance with existing insecticide, is suitable for very much the control that existing insecticide produces the insect of resistance.
When capillary and ZJ4042 are used separately, drug cost is high, limited to a certain extent it and applied, and long-term use separately easily causes pest resistance degree constantly to increase.Being mixed of different pesticide species is the common methods of the agriculture resistant insect of control.By formulation of pesticide, screening, filter out rational formula, can effectively improve actual control efficiency, reduce dosage, reduce costs, delay the generation of pest resistance to insecticide, extend the service life of medicament, is the important means of integrated pest management.
The Lepidoptera class pests such as control prodenia litura, beet armyworm, cabbage caterpillar, diamond-back moth, cotton bollworm that are mixed of capillary and ZJ4042 there is no report and application at present.
Summary of the invention
The object of the present invention is to provide a kind of efficient, low toxicity, lasting period long, can effectively prevent and treat crops Lepidoptera class pest and low composition pesticide and the insecticide thereof of drug cost.
For reaching goal of the invention the technical solution used in the present invention, be:
For a Pesticidal combination for pest, it is characterized in that containing two kinds of active components, the first active component is capillary, second active ingredient is the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the weight ratio that described the first active component and the second activity become is 1～50:20～1.
The weight ratio that above-mentioned a kind of active component and the second activity become is preferably 1～10:10～1., 1～5:5～1 more preferably.
The present invention also provides a kind of insecticide for pest, contains by weight 5～90% above-mentioned Pesticidal combinations, and all the other are the upper acceptable carrier of agricultural and auxiliary agent.As preferred embodiment, in insecticide, preferably contain 5～40% above-mentioned Pesticidal combination.
Carrier of the present invention can be solid or liquid, and any carrier that is generally used for preparing insecticides all can be used.
Suitable solid carrier comprises: mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance comprises silicates, carbonate, Sulfates and oxide-based.Silicates is kaolin for example, sepiolite, nacrite, imvite, mica, vermiculite, pyrophyllite, talcum.Carbonate is for example: calcium carbonate, dolomite.Sulfates is as ammonium sulfate, sodium sulphate, calcium sulphate.Oxide-based as quicklime, magnesium lime, diatomite.Plant is for example: citrus pulp, corncob cellulose, rice husk powder, rice husk, large soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class is as winnofil hydrate, winnofil, white carbon.Inorganic salts is potassium chloride for example, sodium chloride.
Liquid-carrier comprises water and organic solvent.When active ingredient is aqueous emulsion or suspension emulsion, organic solvent plays solubilising and antifreeze effect.Suitable organic solvent comprises aromatic hydrocarbons, for example benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chlorinated aliphatic hydrocarbon, for example vinyl chloride, chloroform, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, for example petroleum distillate, cyclohexane, light mineral oil and paraffin.Alcohols is methyl alcohol for example, ethanol, isopropyl alcohol, butanols, isobutanol, ethylene glycol, propane diols, glycerine, fatty alcohol etc.; Ethers is Propylene Glycol ether for example, ethohexadiol ether, benzinum.Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and different fluorine that ketone, N-methyl-pyrrolidones for example; Special solvent also has dimethyl formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile; Vegetable oil and the vegetable oil that methylates.Above-mentioned organic solvent both can be used alone, but also also mix together, and can also mix together with water.
Auxiliary agent of the present invention can comprise one or more in surfactant, defoamer, thickener, suspending agent and antifreezing agent as required, can also comprise as required other auxiliary agents that the industry is conventional.
Surfactant can be emulsifier, dispersant, stabilizing agent or wetting agent; Can be ionic or nonionic.Suitable surfactant comprises: the sodium salt of polyacrylic acid and lignin sulfonic acid and calcium salt; In molecule, contain the fatty acid of at least 12 carbon atoms or fatty amine and oxirane and/polycondensation product of expoxy propane; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In molecule, at least containing the sulfuric acid of 10 carbon atoms or the alkali metal of sulfonic acid or alkali salt, is preferably sodium salt, as the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, alkylaryl sodium sulfonate and neopelex; The copolymer of the polymer of oxirane, oxirane and expoxy propane.
Emulsifier comprises nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonylphenol ether of nonionic emulsifier, fatty alcohol-polyoxyethylene ether, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether, styryl phenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.Anionic emulsifier mainly comprises calcium dodecyl benzene sulfonate, triphen ethyl phenol polyoxy ether phosphate amine salt, polyoxyethylene nonylphenol ether phosphate amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention comprises: acrylate homopolymer sodium salt, maleic acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, triphen ethyl phenol polyoxyethylene ether phosphate, fatty alcohol-polyoxyethylene ether phosphoric acid, to one or more in hydroxyphenyl lignin sulfonic acid sodium salt.
Wetting agent of the present invention comprises: fatty alcohol-polyoxyethylene ether, naphthalene sulfonate, lauryl sodium sulfate, one or more combinations in alkyl phenol resin polyoxyethylene ether sulfate.。
Thickener of the present invention comprises xanthans, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, gum Arabic, gelatin, one or more in polyvinyl alcohol.Defoamer of the present invention is preferably: bubble enemy, silicone, C
8～10fatty alcohol, C
10～20saturated fat acids and acid amides etc.
Pesticidal combination of the present invention can be configured to missible oil, suspending agent, wetting powder, oil suspending agent or water dispersible granules according to the general method in this area.
Pesticidal combination of the present invention is specially adapted to prevent and treat the Lepidoptera class pest in the plants such as fruit tree, vegetables, paddy rice or cotton, comprises prodenia litura, beet armyworm, cabbage caterpillar, diamond-back moth and cotton bollworm etc.
Pesticidal combination of the present invention has following advantage compared to existing technology:
(1) in composition, two kinds of pesticide compositionals show good synergistic effect in certain ratio range, and the insecticidal effect of mixed composition is significantly improved compared with its single dose, and have the advantages that quick-acting is good and lasting effect is long;
(2) reduce using dosage, reduced peasant's drug cost;
(3) utilize two kinds of agricultural chemicals to be reasonably mixed to the different mode of action of insect, the different mechanism of action, both extended agricultural chemicals service life, delay again the generation of pest resistance to insecticide.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these embodiments.One skilled in the art would recognize that the present invention contained all alternatives, improvement project and the equivalents that within the scope of claims, may comprise.
In following embodiment, material prescription is selected to suit measures to local conditions, on result without substantial impact.In these embodiments, unless otherwise indicated, all percentage is all weight percentage.
The inventor is mixed and has carried out Toxicity Determination test capillary and ZJ4042.
Test is evaluated SOP(insecticide volume with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and initiative pesticide bioactivity), adopt infusion process.
Synergy adopts following method to calculate:
The content (%) of toxicity index * A of theoretical mixed toxicity index (TTI)=A in mixed
The content (%) of toxicity index * B of+B in mixed
If co-toxicity coefficient is greater than 120, showing has synergistic effect; If be less than 80, be indicated as antagonism; If be greater than 80, be less than 120, be indicated as summation action.
Embodiment 1:ZJ4042 and the capillary embodiment that is mixed
Table 1 ZJ4042 and capillary are to the effect of wild cabbage diamond-back moth Plutella xylostella synergy
| Process | Proportioning | LC 50(mg/L) | Actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Capillary | - | 2.38 | 15.55 | ? | ? |
| ZJ4042 | - | 0.37 | 100.00 | ? | ? |
| Capillary: ZJ4042 | 50:20 | 0.68 | 54.41 | 39.68 | 137.14 |
| Capillary: ZJ4042 | 50:1 | 1.52 | 24.34 | 17.20 | 141.51 |
| Capillary: ZJ4042 | 20:1 | 1.32 | 28.03 | 19.57 | 143.25 |
| Capillary: ZJ4042 | 10:1 | 1.12 | 33.04 | 23.22 | 142.25 |
| Capillary: ZJ4042 | 5:1 | 0.86 | 43.02 | 29.62 | 145.24 |
| Capillary: ZJ4042 | 1:1 | 0.45 | 82.22 | 57.77 | 142.32 |
| Capillary: ZJ4042 | 1:5 | 0.31 | 119.35 | 85.92 | 138.91 |
| Capillary: ZJ4042 | 1:10 | 0.26 | 142.31 | 92.32 | 154.14 |
| Capillary: ZJ4042 | 1:20 | 0.27 | 137.04 | 95.98 | 142.78 |
Table 2 ZJ4042 and capillary are to the effect of Laphygma exigua Hubner Spodoptera exigua synergy
| Process | Proportioning | LC 50(mg/L) | Actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Capillary | - | 2.1 | 21.43 | ? | ? |
| ZJ4042 | - | 0.45 | 100.00 | ? | ? |
| Capillary: ZJ4042 | 50:20 | 0.68 | 66.18 | 43.88 | 150.82 |
| Capillary: ZJ4042 | 50:1 | 1.38 | 32.61 | 22.97 | 141.97 |
| Capillary: ZJ4042 | 20:1 | 1.25 | 36.00 | 25.17 | 143.03 |
| Capillary: ZJ4042 | 10:1 | 1.12 | 40.18 | 28.57 | 140.63 |
| Capillary: ZJ4042 | 5:1 | 0.86 | 52.33 | 34.52 | 151.56 |
| Capillary: ZJ4042 | 1:1 | 0.52 | 86.54 | 60.71 | 142.53 |
| Capillary: ZJ4042 | 1:5 | 0.37 | 121.62 | 86.90 | 139.95 |
| Capillary: ZJ4042 | 1:10 | 0.33 | 136.36 | 92.86 | 146.85 |
| Capillary: ZJ4042 | 1:20 | 0.35 | 128.57 | 96.26 | 133.57 |
From result of the test table 1,2, can find out, capillary and ZJ4042,1～50:20～1(by weight) scope in, co-toxicity coefficient is all greater than 120, and wild cabbage diamond-back moth and beet armyworm are all shown as to synergistic effect.Capillary and ZJ4042 are mixed and have reasonability and feasibility.
Embodiment 2 (20% capillary ZJ4042 suspending agent)
Press capillary 18%, ZJ40422%, emulsifier 1601#(styryl phenol polyoxyethylene poly-oxygen propylene aether) 10%, dispersant SOPA mono-27044%, bentonite 2%, xanthans 0.1%, silicone defoaming agent 0.4%, glycerine 5%, surplus is deionized water.Above-mentioned formula is pulverized in proportion in advance, then added in sand mill and grind, after high shear mixing, allotment makes 20% capillary ZJ4042 suspending agent.
This embodiment is applied to prevent and treat wild cabbage diamond-back moth.20% capillary ZJ4042 suspending agent is watered even spraying by 10 grams/acre in wild cabbage diamondback moth larvae occurance peak, and after medicine, the preventive effect of 3 days, 7 days is respectively 92.1%, 93.7%.Contrast single dose 12% capillary suspending agent (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 75.1%, 85.3%, and after medicine, the preventive effect of 7 days is respectively 76.9%, 86.5%.After capillary and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 3 (20% capillary ZJ4042 missible oil)
Press capillary 18%, ZJ40422%, calcium dodecyl benzene sulfonate 6%, triphen ethyl phenol APEO 6%, NMP8%, surplus is dimethylbenzene.By above-mentioned formula mixing and stirring in proportion.
This embodiment is applied to prevent and treat wild cabbage prodenia litura.20% capillary ZJ4042 missible oil is watered even spraying by 10 grams/acre in wild cabbage Spodoptera litura larvae occurrence in peak period, and after medicine, 3 days, 7 days preventive effects are respectively 90.2%, 95.2%.Contrast single dose 12% capillary suspending agent (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 72.3%, 85.9%, and after medicine, the preventive effect of 7 days is respectively 75.8%, 89.2%.After capillary and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose, and dosage reduces than single dose.
Embodiment 4 (70% capillary ZJ4042 water-dispersible granules)
Press capillary 55%, ZJ404215%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus is kaolin.By above-mentioned formula, dry pulverization process, granulation, dry, screening make 70% capillary ZJ4042 water-dispersible granules in proportion.
This embodiment is applied to prevent and treat Laphygma exigua Hubner.70% capillary ZJ4042 water-dispersible granules is watered even spraying by 5 grams/acre in Laphygma exigua Hubner larva occurrence in peak period, and after medicine, 3 days, 7 days preventive effects are respectively 91.7%, 93.1%.Contrast single dose 12% capillary suspending agent (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 71.9%, 77.8%, and after medicine, the preventive effect of 7 days is respectively 75.8%, 82.1%.After capillary and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose.
Embodiment 5 (20% capillary ZJ4042 oil suspending agent)
Capillary 15%, ZJ40425%, castor oil polyoxyethylene ether 13%, tristyrylphenol polyoxyethylene ether phosphate 3%, organobentonite 1%, methyl oleate is mended to 100%.After above-mentioned formula is mixed, sand milling is to certain particle diameter.
This embodiment is applied to prevent and treat cotton bollworm.20% capillary ZJ4042 oil suspending agent is watered even spraying by 10 grams/acre in cotton bollworm larvae occurance peak, and after medicine, 3 days, 7 days preventive effects are respectively 92.4%, 93.6%.Contrast single dose 12% capillary suspending agent (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 72.9%, 83.2%, and after medicine, the preventive effect of 7 days is 75.5%, 88.7%.After capillary and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose.
Embodiment 6 (40% capillary ZJ4042 wetting powder)
Press capillary 35%, ZJ40425%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus is kaolin.By above-mentioned formula, dry pulverization process, granulation, dry, screening make 40% chlopyrifos ZJ4042 wetting powder in proportion.
This embodiment is applied to prevent and treat cabbage caterpillar.40% capillary ZJ4042 wetting powder is watered even spraying by 5 grams/acre in cabbage caterpillar larva occurance peak, and after medicine, 3 days, 7 days preventive effects are respectively 93.4%, 94.7%.Contrast single dose 12% capillary suspending agent (formulation rate is 30 grams/acre), 20%ZJ4042 suspending agent (formulation rate is 10 grams/acre) are by same method dispenser, after medicine, the preventive effect of 3 days is respectively 71.2%, 75.2%, and after medicine, the preventive effect of 7 days is 73.7%, 82.4%.After capillary and ZJ4042 are mixed, synergistic effect is obvious, and preventive effect is better than single dose.
Claims (8)
1. for a Pesticidal combination for pest, it is characterized in that containing two kinds of active components, the first active component is capillary, and second active ingredient is the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the weight ratio that described the first active component and the second activity become is 1～50:20～1.
2. according to the Pesticidal combination for pest claimed in claim 1, it is characterized in that the weight ratio that described the first active component and the second activity become is 1～10:10～1.
3. according to the Pesticidal combination for pest claimed in claim 2, it is characterized in that the weight ratio that described the first active component and the second activity become is 1～5:5～1.
4. for an insecticide for pest, it is characterized in that containing by weight 5～90% Pesticidal combinations claimed in claim 1, all the other are the upper acceptable carrier of agricultural and auxiliary agent.
5. according to the insecticide for pest claimed in claim 4, it is characterized in that containing by weight 5～40% Pesticidal combinations claimed in claim 1.
6. according to the insecticide for pest claimed in claim 4, it is characterized in that described insecticide can be configured to missible oil, suspending agent, wetting powder, oil suspending agent or water dispersible granules.
7. according to the application of the Pesticidal combination one of claim 1-6 Suo Shu, it is characterized in that described Pesticidal combination is for preventing and treating Lepidoptera class pest prodenia litura, beet armyworm, cabbage caterpillar, diamond-back moth and cotton bollworm.
8. according to the application of Pesticidal combination claimed in claim 7, it is characterized in that described Pesticidal combination is for preventing and treating the Lepidoptera class pest of fruit tree, vegetables, paddy rice or cotton.
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| CN101935291A (en) * | 2010-09-13 | 2011-01-05 | 中化蓝天集团有限公司 | Cyano phthalic diamide compounds, preparation method thereof and use thereof as agricultural chemical pesticide |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
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| CN101935291A (en) * | 2010-09-13 | 2011-01-05 | 中化蓝天集团有限公司 | Cyano phthalic diamide compounds, preparation method thereof and use thereof as agricultural chemical pesticide |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
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Effective date of registration: 20200214 Address after: 310051 Binjiang District Jiangnan Road, Zhejiang, No. 96, No. Co-patentee after: Zhejiang Research Institute of Chemical Industry, Ltd. Patentee after: Sinochem Lantian Co., Ltd. Co-patentee after: Sinochem Corporation Address before: 310051 Binjiang District Jiangnan Road, Zhejiang, No. 96, No. Co-patentee before: Zhejiang Research Institute of Chemical Industry, Ltd. Patentee before: Sinochem Lantian Co., Ltd. |