CN107141082A - A kind of vegetable cultivation is with the organic slow-release fertilizer that concave convex rod is major ingredient - Google Patents
A kind of vegetable cultivation is with the organic slow-release fertilizer that concave convex rod is major ingredient Download PDFInfo
- Publication number
- CN107141082A CN107141082A CN201710372989.2A CN201710372989A CN107141082A CN 107141082 A CN107141082 A CN 107141082A CN 201710372989 A CN201710372989 A CN 201710372989A CN 107141082 A CN107141082 A CN 107141082A
- Authority
- CN
- China
- Prior art keywords
- parts
- well mixed
- room temperature
- modified
- major ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
Abstract
The invention discloses a kind of vegetable cultivation with the organic slow-release fertilizer that concave convex rod is major ingredient, its raw material includes attapulgite, chicken manure, marsh mud, furfural dregs, peanut cake, weathered coal, cotton dregs, EM bacterium, urea, potassium chloride, ammonium nitrate, ammonium molybdate, potassium sulfate, borax, manganese sulfate, zinc sulfate, potassium dihydrogen phosphate, dipotassium hydrogen phosphate, humic acid, modified sustained release agent, modified alta-mud, konjacmannan, diatomite and sepiolite.The organic slow-release fertilizer of the present invention is using attapulgite as major ingredient, with closing other nutriments, coated fertilizer, bulky material and slow-release material, abundant nutriment can be provided for vegetables, and nutriment can efficiently be discharged, the yield and quality of vegetables is improved.
Description
Technical field
The present invention relates to the technical field of fertilizer, more particularly to a kind of vegetable cultivation is with the organic slow-release that concave convex rod is major ingredient
Fertilizer.
Background technology
Concave-convex clay rod is a kind of natural non-metallic clay mineral, China from 1976 Luhe it is small it is winding first
It was found that after recessed Tu Kuang, being found that recessed Tu Kuang points in 14 provinces and regions such as Jiangsu, Anhui, Shandong, Liaoning in succession, yield and grade are equal
With Xuyi Jiangsu preferably, it is world's high-quality mineral reserve.Recessed soil is not only in works such as chemical industry, building materials, papermaking, medicine, food and silicate
Be used widely in terms of industry, it is also a kind of important Mineral Resources For Agriculture, mainly using its good adsorptivity, wet water after
Viscosity and plasticity be used in agricultural chemicals, fertilizer and soil improvement in terms of.Plantation of the single attapulgite to vegetables does not have
Important function, and single organic fertilizer and inorganic fertilizer, the plantation for vegetables does not have good effect yet, so needing badly
A kind of vegetable cultivation is designed with the organic slow-release fertilizer that concave convex rod is major ingredient to solve the problems of the prior art.
The content of the invention
To solve technical problem present in background technology, the present invention proposes that a kind of vegetable cultivation is major ingredient with concave convex rod
Organic slow-release fertilizer, using attapulgite as major ingredient, with closing other nutriments, coated fertilizer, bulky material and slow-release material,
Abundant nutriment can be provided for vegetables, and nutriment can efficiently be discharged, the yield of vegetables is improved
And quality.
A kind of vegetable cultivation proposed by the present invention is wrapped by weight with the organic slow-release fertilizer that concave convex rod is major ingredient, its raw material
Include：80-120 parts of attapulgite, 30-60 parts of chicken manure, mud 5-15 parts of marsh, 4-9 parts of furfural dregs, 5-8 parts of peanut cake, weathered coal 1-
2 parts, 3-5 parts of cotton dregs, 3-6 parts of EM bacterium, 5-8 parts of urea, 1-3 parts of potassium chloride, 1-4 parts of ammonium nitrate, 4-6 parts of ammonium molybdate, potassium sulfate
3-5 parts, 1-2 parts of borax, 1-3 parts of manganese sulfate, 3-5 parts of zinc sulfate, 1-3 parts of potassium dihydrogen phosphate, 6-8 parts of dipotassium hydrogen phosphate, humic
Sour 4-6 parts, modified 10-20 parts of sustained release agent, 15-25 parts of modified alta-mud, 1-5 parts of konjacmannan, 4-8 parts of diatomite, sea
2-6 parts of afrodite.
Preferably, the raw material of modified sustained release agent includes by weight：It is 4-8 parts of PLA, 2-5 parts of dichloromethane, phosphoric
1-4 parts of phosphorus, 3-6 parts of ethylenediamine, 4-8 parts of triethylamine, 2-5 parts of dimethyl sulfone, 1-4 parts of glutaraldehyde water solution, collagen 3-6
Part, 2-5 parts of acetic acid.
Preferably, modified sustained release agent is prepared by following technique：PLA and dichloromethane are well mixed, stirred,
Then in nitrogen protection under, heat up, insulation, be subsequently added into phosphorus pentachloride be well mixed, condensing reflux, be subsequently added into ethylenediamine and
Triethylamine is well mixed, and is stored at room temperature, and is washed after extraction, by drying precipitate after precipitation, is cooled to room temperature, is then added diformazan
Base sulfone is well mixed, stirring, is subsequently added into glutaraldehyde water solution and is well mixed, stirs at room temperature, and then deionized water will be precipitated
Separate out, add collagen and acetic acid is well mixed, stir, separate out sediment at room temperature after washing, it is then that sediment is true
Dried in empty drying box to constant weight, be cooled to room temperature and obtain being modified sustained release agent.
Preferably, modified sustained release agent is prepared by following technique：PLA and dichloromethane are well mixed, in 650-
850r/min rotating speeds stir 20-40min, then under nitrogen protection, are warming up to 35-39 DEG C, are incubated 10-20min, are subsequently added into
Phosphorus pentachloride is well mixed, condensing reflux 1-2h, is subsequently added into ethylenediamine and triethylamine is well mixed, be stored at room temperature 6-8h, extract
Washed after taking, sediment is cooled to room temperature in 35-45 DEG C of dry 10-14h after precipitation, then add dimethyl sulfone mixing equal
It is even, 10-30min is stirred in 450-650r/min rotating speeds, glutaraldehyde water solution is subsequently added into and is well mixed, at room temperature in 850-
1050r/min rotating speeds stir 2-4h, and then Precipitation is added collagen and acetic acid is well mixed, room temperature by deionized water
Under in 450-650r/min rotating speeds stir 20-40min, sediment is separated out after washing, then by sediment in 35-45 DEG C of vacuum
Dried in drying box to constant weight, be cooled to room temperature and obtain being modified sustained release agent.
Preferably, in the preparation technology of modified sustained release agent, the mass fraction of glutaraldehyde water solution is 1-3%.
Preferably, modified alta-mud is prepared by following technique：Magnesium sulfate and water are well mixed, swelling is then added
Soil, nano titanium oxide, flax fiber, PLA and potassium peroxydisulfate are well mixed, and 1-3h is stirred in 650-850r/min rotating speeds,
Then suction filtration, is washed with distilled water to neutrality, and grinding obtains modified alta-mud after drying.
Preferably, in the preparation technology of modified alta-mud, magnesium sulfate, water, bentonite, nano titanium oxide, flax fiber,
The weight ratio of PLA and potassium peroxydisulfate is 3-5：6-12：1-3：2-4：3-5：4-6：1-4.
A kind of vegetable cultivation of the present invention with the organic slow-release fertilizer that concave convex rod is major ingredient, its raw material include attapulgite,
Chicken manure, marsh mud, furfural dregs, peanut cake, weathered coal, cotton dregs, EM bacterium, urea, potassium chloride, ammonium nitrate, ammonium molybdate, potassium sulfate,
Borax, manganese sulfate, zinc sulfate, potassium dihydrogen phosphate, dipotassium hydrogen phosphate, humic acid, modified sustained release agent, modified alta-mud, konjaku are sweet
Reveal glycan, diatomite and sepiolite.Using attapulgite as major ingredient, the water imbibition soil modifier of attapulgite has been given full play to,
Using chicken manure, marsh mud, furfural dregs, peanut cake, weathered coal and cotton dregs as organic material, using EM bacterium as fermenting agent, with urea, chlorine
Change potassium, ammonium nitrate, ammonium molybdate, potassium sulfate, borax, manganese sulfate, zinc sulfate, potassium dihydrogen phosphate, dipotassium hydrogen phosphate and humic acid to make
For inorganic nutrients material, to be modified sustained release agent and konjacmannan as coated slow-release material, wherein konjacmannan is bag
Membrane material, modified sustained release agent is stirred by the way that PLA and dichloromethane are well mixed, and then under nitrogen protection, is heated up, is protected
Temperature, is subsequently added into phosphorus pentachloride and is well mixed, condensing reflux, is subsequently added into ethylenediamine and triethylamine is well mixed, be stored at room temperature,
Washed after extraction, by drying precipitate after precipitation, be cooled to room temperature, then added dimethyl sulfone and be well mixed, stirring then adds
Enter glutaraldehyde water solution to be well mixed, stir at room temperature, then Precipitation is added collagen and acetic acid is mixed by deionized water
Close uniform, stir, separate out sediment at room temperature after washing, will then be dried in sediment vacuum drying chamber to constant weight, cooling
Obtain being modified sustained release agent to room temperature, acyl chloride reaction is carried out to PLA as chloride reagent using phosphorus pentachloride, be is poly-
Carboxylic acid group in lactic acid is converted into-COCl, recycles acid chloride groups and the-NH in hexamethylene diamine2Group reacts to form acyl
Amine key, finally obtains the PLA of hexamethylene diamine graft modification.The PLA that collagen, glutaraldehyde and hexamethylene diamine are modified jointly
Hydrophily effect preferably, effectively increase the hydrophily of PLA, improve degradation property, apply to the organic slow-release of the present invention
In fertilizer so that organic slow-release fertilizer of the invention has excellent water suction sustained release performance.The diatomite and sepiolite of addition coordinate,
It is a kind of biogenic siliceous sedimentary rock using diatomite, it is mainly formed by the remains of ancient times diatom, chemistry composition
Based on silica, diatomite after purification, its surface area can reach 50-60m2/ g, micro pore volume reaches 0.6-
0.8cm3/ g, with the characteristic such as specific surface area is big, adsorptivity is strong, it is a kind of to contain Shuifu County with layer chain structure to coordinate sepiolite
Magnesium silicate clay mineral, main component is silica and magnesia, and the tubular structure and hole of sepiolite make it have ratio
The characteristics of surface area is big, adsorption capacity is good, fillibility absorbent material is used as by the cooperation of diatomite and sepiolite so that this
The organic slow-release fertilizer of invention has excellent water suction sustained release performance, can be effectively improved soil texture, it is to avoid soil hardening, and then
Effectively increase the yield of vegetables.Wherein, modified alta-mud is by the way that magnesium sulfate and water are well mixed, then add bentonite,
Nano titanium oxide, flax fiber, PLA and potassium peroxydisulfate are well mixed, stirring, then suction filtration, in being washed with distilled water to
Property, grinding obtains modified alta-mud after drying, by carrying out magnesium ion modification to bentonite, and combines nano titanium oxide and Asia
The modified filler of flaxen fiber, with PLA in the presence of potassium peroxydisulfate initiator, realizes graft modification, and obtained modification is swollen
Profit soil is applied in the organic slow-release fertilizer of the present invention so that organic slow-release fertilizer of the invention has excellent sustained release and degradability
Energy.The organic slow-release fertilizer of the present invention is using attapulgite as major ingredient, with closing other nutriments, coated fertilizer, bulky material
And slow-release material, abundant nutriment can be provided for vegetables, and nutriment can efficiently be discharged, improve
The yield and quality of vegetables.
Embodiment
The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair
It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair
In bright protection domain.
In embodiment, the parts by weight of attapulgite can for 80 parts, 85 parts, 90 parts, 95 parts, 100 parts, 105 parts,
110 parts, 115 parts, 120 parts；The parts by weight of chicken manure can be 30 parts, 35 parts, 40 parts, 45 parts, 50 parts, 55 parts, 60 parts；Marsh mud
Parts by weight can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts；The weight of furfural dregs
Part can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；The parts by weight of peanut cake
It can be 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of weathered coal can for 1 part, 1.1 parts, 1.2 parts,
1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, 2 parts；The parts by weight of cotton dregs can for 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts；The parts by weight of EM bacterium can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of urea
It can be 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of potassium chloride can for 1 part, 1.5 parts, 2 parts, 2.5
Part, 3 parts；The parts by weight of ammonium nitrate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts；The parts by weight of ammonium molybdate can
Think 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of potassium sulfate can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Borax
Parts by weight can be 1 part, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, 2 parts；
The parts by weight of manganese sulfate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The parts by weight of zinc sulfate can for 3 parts, 3.5 parts, 4
Part, 4.5 parts, 5 parts；The parts by weight of potassium dihydrogen phosphate can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The weight of dipotassium hydrogen phosphate
Part can be 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of humic acid can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；
The parts by weight of modified sustained release agent can for 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20
Part；The parts by weight of modified alta-mud can for 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts,
25 parts；The parts by weight of konjacmannan can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts；Diatomaceous parts by weight can for 4 parts,
4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of sepiolite can for 2 parts, 2.5 parts, 3 parts, 3.5
Part, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts.
Embodiment 1
A kind of vegetable cultivation proposed by the present invention is wrapped by weight with the organic slow-release fertilizer that concave convex rod is major ingredient, its raw material
Include：100 parts of attapulgite, 45 parts of chicken manure, 10 parts of marsh mud, 6.5 parts of furfural dregs, 6.5 parts of peanut cake, 1.5 parts of weathered coal, cotton dregs
4 parts, 4.5 parts of EM bacterium, 6.5 parts of urea, 2 parts of potassium chloride, 2.5 parts of ammonium nitrate, 5 parts of ammonium molybdate, 4 parts of potassium sulfate, 1.5 parts of borax,
2 parts of manganese sulfate, 4 parts of zinc sulfate, 2 parts of potassium dihydrogen phosphate, 7 parts of dipotassium hydrogen phosphate, 5 parts of humic acid, 15 parts of sustained release agent of modification, modification
20 parts of bentonite, 3 parts of konjacmannan, 6 parts of diatomite, 4 parts of sepiolite.
Modified sustained release agent is prepared by following technique：6 parts of PLAs and 3.5 parts of dichloromethane are mixed equal by weight
It is even, 30min is stirred in 750r/min rotating speeds, then under nitrogen protection, 37 DEG C is warming up to, is incubated 15min, is subsequently added into 2.5
Part mass fraction is well mixed for 2% phosphorus pentachloride, and condensing reflux 1.5h is subsequently added into 4.5 parts of ethylenediamines and 6 parts of triethylamines
It is well mixed, 7h is stored at room temperature, is washed after extraction, sediment is cooled to room temperature, Ran Houjia in 40 DEG C of dry 12h after precipitation
Enter 3.5 parts of dimethyl sulfones to be well mixed, 20min is stirred in 550r/min rotating speeds, be subsequently added into 2.5 parts of glutaraldehyde water solution mixing
Uniformly, 3h is stirred in 950r/min rotating speeds at room temperature, then Precipitation is added 4.5 parts of collagens and 3.5 by deionized water
Part acetic acid is well mixed, and is stirred 30min in 550r/min rotating speeds at room temperature, is separated out sediment after washing, then by sediment
Dried in 40 DEG C of vacuum drying chambers to constant weight, be cooled to room temperature and obtain being modified sustained release agent.
Modified alta-mud is prepared by following technique：4 parts of magnesium sulfate and 9 parts of water are well mixed by weight, then
2 parts of bentonites, 3 parts of nano titanium oxides, 4 parts of flax fibers, 5 parts of PLAs and 2.5 parts of potassium peroxydisulfates are added to be well mixed, in
750r/min rotating speeds stir 2h, then suction filtration, are washed with distilled water to neutrality, and grinding obtains modified alta-mud after drying.
Embodiment 2
A kind of vegetable cultivation proposed by the present invention is wrapped by weight with the organic slow-release fertilizer that concave convex rod is major ingredient, its raw material
Include：80 parts of attapulgite, 60 parts of chicken manure, 5 parts of marsh mud, 9 parts of furfural dregs, 5 parts of peanut cake, 2 parts of weathered coal, 3 parts of cotton dregs, EM bacterium
6 parts, 5 parts of urea, 3 parts of potassium chloride, 1 part of ammonium nitrate, 6 parts of ammonium molybdate, 3 parts of potassium sulfate, 2 parts of borax, 1 part of manganese sulfate, zinc sulfate 5
Part, 1 part of potassium dihydrogen phosphate, 8 parts of dipotassium hydrogen phosphate, 4 parts of humic acid, modified 20 parts of sustained release agent, 15 parts of modified alta-mud, konjaku are sweet
Reveal 5 parts of glycan, 4 parts of diatomite, 6 parts of sepiolite.
Modified sustained release agent is prepared by following technique：4 parts of PLAs and 5 parts of dichloromethane are mixed equal by weight
It is even, 40min is stirred in 650r/min rotating speeds, then under nitrogen protection, 35 DEG C is warming up to, is incubated 20min, is subsequently added into 1 part
Mass fraction is well mixed for 3% phosphorus pentachloride, condensing reflux 1h, is subsequently added into 6 parts of ethylenediamines and 4 parts of triethylamine mixing are equal
It is even, 8h is stored at room temperature, is washed after extraction, sediment is cooled to room temperature in 35 DEG C of dry 14h after precipitation, 2 part two is then added
Methyl sulfone is well mixed, and 10min is stirred in 650r/min rotating speeds, is subsequently added into 4 parts of glutaraldehyde water solutions and is well mixed, at room temperature
4h is stirred in 850r/min rotating speeds, then Precipitation is added 3 parts of collagens and 5 parts of acetic acid are well mixed by deionized water,
40min is stirred in 450r/min rotating speeds at room temperature, is separated out sediment after washing, then by sediment in 35 DEG C of vacuum drying chambers
Middle drying is cooled to room temperature and obtains being modified sustained release agent to constant weight.
Modified alta-mud is prepared by following technique：3 parts of magnesium sulfate and 12 parts of water are well mixed by weight, then
1 part of bentonite, 4 parts of nano titanium oxides, 3 parts of flax fibers, 6 parts of PLAs and 1 part of potassium peroxydisulfate is added to be well mixed, in
850r/min rotating speeds stir 1h, then suction filtration, are washed with distilled water to neutrality, and grinding obtains modified alta-mud after drying.
Embodiment 3
A kind of vegetable cultivation proposed by the present invention is wrapped by weight with the organic slow-release fertilizer that concave convex rod is major ingredient, its raw material
Include：120 parts of attapulgite, 30 parts of chicken manure, 15 parts of marsh mud, 4 parts of furfural dregs, 8 parts of peanut cake, 1 part of weathered coal, 5 parts of cotton dregs, EM
3 parts of bacterium, 8 parts of urea, 1 part of potassium chloride, 4 parts of ammonium nitrate, 4 parts of ammonium molybdate, 5 parts of potassium sulfate, 1 part of borax, 3 parts of manganese sulfate, sulfuric acid
3 parts of zinc, 3 parts of potassium dihydrogen phosphate, 6 parts of dipotassium hydrogen phosphate, 6 parts of humic acid, modified 10 parts of sustained release agent, 25 parts of modified alta-mud, evil spirit
1 part of taro mannosan, 8 parts of diatomite, 2 parts of sepiolite.
Modified sustained release agent is prepared by following technique：8 parts of PLAs and 2 parts of dichloromethane are mixed equal by weight
It is even, 20min is stirred in 850r/min rotating speeds, then under nitrogen protection, 39 DEG C is warming up to, is incubated 10min, is subsequently added into 4 parts
Mass fraction is well mixed for 1% phosphorus pentachloride, condensing reflux 2h, is subsequently added into 3 parts of ethylenediamines and 8 parts of triethylamine mixing are equal
It is even, 6h is stored at room temperature, is washed after extraction, sediment is cooled to room temperature in 45 DEG C of dry 10h after precipitation, 5 part two is then added
Methyl sulfone is well mixed, and 30min is stirred in 450r/min rotating speeds, is subsequently added into 1 part of glutaraldehyde water solution and is well mixed, at room temperature
2h is stirred in 1050r/min rotating speeds, then Precipitation is added 6 parts of collagens and 2 parts of acetic acid mixing are equal by deionized water
It is even, 20min is stirred in 650r/min rotating speeds at room temperature, sediment is separated out after washing, then done sediment in 45 DEG C of vacuum
Dried in dry case to constant weight, be cooled to room temperature and obtain being modified sustained release agent.
Modified alta-mud is prepared by following technique：5 parts of magnesium sulfate and 6 parts of water are well mixed by weight, then
3 parts of bentonites, 2 parts of nano titanium oxides, 5 parts of flax fibers, 4 parts of PLAs and 4 parts of potassium peroxydisulfates are added to be well mixed, in
650r/min rotating speeds stir 3h, then suction filtration, are washed with distilled water to neutrality, and grinding obtains modified alta-mud after drying.
Embodiment 4
A kind of vegetable cultivation proposed by the present invention is wrapped by weight with the organic slow-release fertilizer that concave convex rod is major ingredient, its raw material
Include：85 parts of attapulgite, 55 parts of chicken manure, 8 parts of marsh mud, 8 parts of furfural dregs, 6 parts of peanut cake, 1.8 parts of weathered coal, 3.5 parts of cotton dregs,
5 parts of EM bacterium, 6 parts of urea, 2.5 parts of potassium chloride, 2 parts of ammonium nitrate, 5.5 parts of ammonium molybdate, 3.5 parts of potassium sulfate, 1.8 parts of borax, sulfuric acid
1.5 parts of manganese, 4.5 parts of zinc sulfate, 1.5 parts of potassium dihydrogen phosphate, 7.5 parts of dipotassium hydrogen phosphate, 4.5 parts of humic acid, modified sustained release agent 18
Part, 18 parts of modified alta-mud, 4 parts of konjacmannan, 5 parts of diatomite, 5 parts of sepiolite.
Modified sustained release agent is prepared by following technique：5 parts of PLAs and 4 parts of dichloromethane are mixed equal by weight
It is even, 35min is stirred in 620r/min rotating speeds, then under nitrogen protection, 36 DEG C is warming up to, is incubated 18min, is subsequently added into 2 parts
Mass fraction is well mixed for 2.5% phosphorus pentachloride, condensing reflux 1.2h, is subsequently added into 5 parts of ethylenediamines and 5 parts of triethylamines are mixed
Close uniform, be stored at room temperature 7.5h, washed after extraction, sediment is cooled to room temperature, Ran Houjia in 38 DEG C of dry 13h after precipitation
Enter 3 parts of dimethyl sulfones to be well mixed, 15min is stirred in 620r/min rotating speeds, be subsequently added into 3 parts of glutaraldehyde water solution mixing equal
It is even, 3.5h is stirred in 880r/min rotating speeds at room temperature, then Precipitation is added 4 parts of collagens and 4 portions of vinegar by deionized water
Acid is well mixed, stirs 35min in 480r/min rotating speeds at room temperature, separates out sediment after washing, then by sediment in 38
Dried in DEG C vacuum drying chamber to constant weight, be cooled to room temperature and obtain being modified sustained release agent.
Modified alta-mud is prepared by following technique：3.5 parts of magnesium sulfate and 11 parts of water are well mixed by weight, so
1.5 parts of bentonites, 3.5 parts of nano titanium oxides, 3.5 parts of flax fibers, 5.5 parts of PLAs and 2 parts of potassium peroxydisulfates are added afterwards to mix
Close uniform, stir 1.5h in 820r/min rotating speeds, then suction filtration, be washed with distilled water to neutrality, grind and be modified after drying
Bentonite.
Embodiment 5
A kind of vegetable cultivation proposed by the present invention is wrapped by weight with the organic slow-release fertilizer that concave convex rod is major ingredient, its raw material
Include：115 parts of attapulgite, 35 parts of chicken manure, 12 parts of marsh mud, 5 parts of furfural dregs, 7 parts of peanut cake, 1.2 parts of weathered coal, cotton dregs 4.5
Part, 4 parts of EM bacterium, 7 parts of urea, 1.5 parts of potassium chloride, 3 parts of ammonium nitrate, 4.5 parts of ammonium molybdate, 4.5 parts of potassium sulfate, 1.2 parts of borax, sulphur
Sour 2.5 parts of manganese, 3.5 parts of zinc sulfate, 2.5 parts of potassium dihydrogen phosphate, 6.5 parts of dipotassium hydrogen phosphate, 5.5 parts of humic acid, modified sustained release agent
12 parts, 22 parts of modified alta-mud, 2 parts of konjacmannan, 7 parts of diatomite, 3 parts of sepiolite.
Modified sustained release agent is prepared by following technique：7 parts of PLAs and 3 parts of dichloromethane are mixed equal by weight
It is even, 25min is stirred in 830r/min rotating speeds, then under nitrogen protection, 38 DEG C is warming up to, is incubated 12min, is subsequently added into 3 parts
Mass fraction is well mixed for 1.5% phosphorus pentachloride, condensing reflux 1.8h, is subsequently added into 4 parts of ethylenediamines and 7 parts of triethylamines are mixed
Close uniform, be stored at room temperature 6.5h, washed after extraction, sediment is cooled to room temperature, Ran Houjia in 42 DEG C of dry 11h after precipitation
Enter 4 parts of dimethyl sulfones to be well mixed, 25min is stirred in 480r/min rotating speeds, be subsequently added into 2 parts of glutaraldehyde water solution mixing equal
It is even, 2.5h is stirred in 1020r/min rotating speeds at room temperature, then Precipitation is added 5 parts of collagens and 3 parts by deionized water
Acetic acid be well mixed, at room temperature in 620r/min rotating speeds stir 25min, sediment is separated out after washing, then by sediment in
Dried in 42 DEG C of vacuum drying chambers to constant weight, be cooled to room temperature and obtain being modified sustained release agent.
Modified alta-mud is prepared by following technique：4.5 parts of magnesium sulfate and 7 parts of water are well mixed by weight, so
2.5 parts of bentonites, 2.5 parts of nano titanium oxides, 4.5 parts of flax fibers, 4.5 parts of PLAs and 3 parts of potassium peroxydisulfates are added afterwards to mix
Close uniform, stir 2.5h in 680r/min rotating speeds, then suction filtration, be washed with distilled water to neutrality, grind and be modified after drying
Bentonite.
By the vegetable cultivation in embodiment 1- embodiments 5 with the organic slow-release fertilizer that concave convex rod is major ingredient in vegetable transplanting
Before, by every 15kg/667m2Amount disposably apply, contrast groups basal dressing and are topdressed according to a conventional method, and total fertilization amount is 15kg/
667m2, fertilizer is nitrogen-phosphorus-potassium compound fertilizer, wherein, nitrogenous fertilizer and potash fertilizer spread fertilizer over the fields in two times；
Yield-increasing efficiency=(experimental group yield/contrast groups yield -1) * 100%
Obtained vegetable increase production efficiency is as shown in table 1.
Table 1：
The vegetable increase production efficiency data obtained according to table 1, it is having for major ingredient with concave convex rod to obtain vegetable cultivation of the invention
Machine slow release fertilizer effectively improves the yield of vegetables.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. a kind of vegetable cultivation is with the organic slow-release fertilizer that concave convex rod is major ingredient, it is characterised in that its raw material includes by weight：
80-120 parts of attapulgite, 30-60 parts of chicken manure, mud 5-15 parts of marsh, 4-9 parts of furfural dregs, 5-8 parts of peanut cake, weathered coal 1-2
Part, 3-5 parts of cotton dregs, 3-6 parts of EM bacterium, 5-8 parts of urea, 1-3 parts of potassium chloride, 1-4 parts of ammonium nitrate, 4-6 parts of ammonium molybdate, potassium sulfate 3-
5 parts, 1-2 parts of borax, 1-3 parts of manganese sulfate, 3-5 parts of zinc sulfate, 1-3 parts of potassium dihydrogen phosphate, 6-8 parts of dipotassium hydrogen phosphate, humic acid
4-6 parts, modified 10-20 parts of sustained release agent, 15-25 parts of modified alta-mud, 1-5 parts of konjacmannan, 4-8 parts of diatomite, Hai Pao
2-6 parts of stone.
2. vegetable cultivation according to claim 1 is with the organic slow-release fertilizer that concave convex rod is major ingredient, it is characterised in that modified
The raw material of sustained release agent includes by weight：4-8 parts of PLA, 2-5 parts of dichloromethane, 1-4 parts of phosphorus pentachloride, 3-6 parts of ethylenediamine,
4-8 parts of triethylamine, 2-5 parts of dimethyl sulfone, 1-4 parts of glutaraldehyde water solution, 3-6 parts of collagen, 2-5 parts of acetic acid.
3. vegetable cultivation according to claim 1 or 2 is with the organic slow-release fertilizer that concave convex rod is major ingredient, it is characterised in that
Modified sustained release agent is prepared by following technique：PLA and dichloromethane are well mixed, stirred, is then protected in nitrogen
Under, heat up, insulation is subsequently added into phosphorus pentachloride and is well mixed, condensing reflux, be subsequently added into ethylenediamine and triethylamine mixing is equal
It is even, it is stored at room temperature, is washed after extraction, by drying precipitate after precipitation, be cooled to room temperature, then adds dimethyl sulfone mixing equal
Even, stirring is subsequently added into glutaraldehyde water solution and is well mixed, stirs at room temperature, and then Precipitation is added glue by deionized water
Former albumen and acetic acid are well mixed, and are stirred, are separated out sediment at room temperature after washing, will then be done in sediment vacuum drying chamber
It is dry to constant weight, be cooled to room temperature and obtain being modified sustained release agent.
4. vegetable cultivation according to claim any one of 1-3 is with the organic slow-release fertilizer that concave convex rod is major ingredient, its feature
It is, modified sustained release agent is prepared by following technique：PLA and dichloromethane are well mixed, turned in 650-850r/min
Speed stirring 20-40min, then under nitrogen protection, is warming up to 35-39 DEG C, is incubated 10-20min, is subsequently added into phosphorus pentachloride and mixes
Close uniform, condensing reflux 1-2h, is subsequently added into ethylenediamine and triethylamine is well mixed, is stored at room temperature 6-8h, is washed after extraction, is sunk
Sediment is cooled to room temperature in 35-45 DEG C of dry 10-14h behind shallow lake, dimethyl sulfone is then added and is well mixed, in 450-
650r/min rotating speeds stir 10-30min, are subsequently added into glutaraldehyde water solution and are well mixed, turn at room temperature in 850-1050r/min
Speed stirring 2-4h, then deionized water is by Precipitation, and addition collagen and acetic acid are well mixed, at room temperature in 450-
650r/min rotating speeds stir 20-40min, separate out sediment after washing, then by sediment in 35-45 DEG C of vacuum drying chamber
Dry to constant weight, be cooled to room temperature and obtain being modified sustained release agent.
5. vegetable cultivation according to claim any one of 1-4 is with the organic slow-release fertilizer that concave convex rod is major ingredient, its feature
It is, in the preparation technology of modified sustained release agent, the mass fraction of glutaraldehyde water solution is 1-3%.
6. vegetable cultivation according to claim any one of 1-5 is with the organic slow-release fertilizer that concave convex rod is major ingredient, its feature
It is, modified alta-mud is prepared by following technique：Magnesium sulfate and water are well mixed, bentonite, nanometer two is then added
Titanium oxide, flax fiber, PLA and potassium peroxydisulfate are well mixed, stir 1-3h in 650-850r/min rotating speeds, then suction filtration,
Neutrality is washed with distilled water to, grinding obtains modified alta-mud after drying.
7. vegetable cultivation according to claim any one of 1-6 is with the organic slow-release fertilizer that concave convex rod is major ingredient, its feature
It is, in the preparation technology of modified alta-mud, magnesium sulfate, water, bentonite, nano titanium oxide, flax fiber, PLA and mistake
The weight ratio of potassium sulfate is 3-5：6-12：1-3：2-4：3-5：4-6：1-4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710372989.2A CN107141082A (en) | 2017-05-24 | 2017-05-24 | A kind of vegetable cultivation is with the organic slow-release fertilizer that concave convex rod is major ingredient |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710372989.2A CN107141082A (en) | 2017-05-24 | 2017-05-24 | A kind of vegetable cultivation is with the organic slow-release fertilizer that concave convex rod is major ingredient |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107141082A true CN107141082A (en) | 2017-09-08 |
Family
ID=59779113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710372989.2A Pending CN107141082A (en) | 2017-05-24 | 2017-05-24 | A kind of vegetable cultivation is with the organic slow-release fertilizer that concave convex rod is major ingredient |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107141082A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107698391A (en) * | 2017-10-10 | 2018-02-16 | 苏州浔宇新材料科技有限公司 | A kind of fertilizer special for vegetable and preparation method thereof and application process |
| CN108017474A (en) * | 2018-01-23 | 2018-05-11 | 合肥仙之峰农业科技有限公司 | A kind of saline-alkali land soil conditioner |
| CN108383666A (en) * | 2018-05-25 | 2018-08-10 | 合肥慧明瀚生态农业科技有限公司 | A kind of efficient tomato slow release fertilizer and preparation method thereof |
| CN108432591A (en) * | 2018-03-22 | 2018-08-24 | 合肥雪立歆农业科技有限公司 | A kind of cultivation matrix of vegetable cultivation and preparation method thereof |
| CN109769651A (en) * | 2017-11-13 | 2019-05-21 | 江苏小潘园生态农业科技发展有限公司 | A kind of wine-growing compost |
| CN109809880A (en) * | 2017-11-21 | 2019-05-28 | 丹阳市陵口镇城墅蔬菜专业合作社 | A kind of dedicated organic Se-rich foliar fertilizer of leaf vegetables |
| CN110902821A (en) * | 2019-12-09 | 2020-03-24 | 宁波首创厨余垃圾处理有限公司 | Solid carbon source suitable for denitrification of high-concentration nitrate-nitrogen sewage and preparation method thereof |
| CN112340842A (en) * | 2020-10-09 | 2021-02-09 | 神美科技有限公司 | Preparation method of denitrification solid carbon source |
| CN113683464A (en) * | 2021-09-15 | 2021-11-23 | 深圳耐菲农业节水灌溉有限公司 | Navel orange planting fertilizer and preparation method thereof |
| CN116391604A (en) * | 2023-03-30 | 2023-07-07 | 凯盛浩丰农业有限公司 | Soilless cultivation technology for watermelons |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254024A (en) * | 2013-05-10 | 2013-08-21 | 兰州贡马工贸有限责任公司 | Attapulgite mineral powder slow-release fertilizer |
| CN104591862A (en) * | 2014-12-02 | 2015-05-06 | 林康艺 | Chitin-containing slow-release fertilizer and preparation method thereof |
| CN106588285A (en) * | 2016-11-29 | 2017-04-26 | 袁家和 | Slow release fertilizer used for rice planting and preparing method thereof |
-
2017
- 2017-05-24 CN CN201710372989.2A patent/CN107141082A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254024A (en) * | 2013-05-10 | 2013-08-21 | 兰州贡马工贸有限责任公司 | Attapulgite mineral powder slow-release fertilizer |
| CN104591862A (en) * | 2014-12-02 | 2015-05-06 | 林康艺 | Chitin-containing slow-release fertilizer and preparation method thereof |
| CN106588285A (en) * | 2016-11-29 | 2017-04-26 | 袁家和 | Slow release fertilizer used for rice planting and preparing method thereof |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107698391A (en) * | 2017-10-10 | 2018-02-16 | 苏州浔宇新材料科技有限公司 | A kind of fertilizer special for vegetable and preparation method thereof and application process |
| CN109769651A (en) * | 2017-11-13 | 2019-05-21 | 江苏小潘园生态农业科技发展有限公司 | A kind of wine-growing compost |
| CN109809880A (en) * | 2017-11-21 | 2019-05-28 | 丹阳市陵口镇城墅蔬菜专业合作社 | A kind of dedicated organic Se-rich foliar fertilizer of leaf vegetables |
| CN108017474A (en) * | 2018-01-23 | 2018-05-11 | 合肥仙之峰农业科技有限公司 | A kind of saline-alkali land soil conditioner |
| CN108432591A (en) * | 2018-03-22 | 2018-08-24 | 合肥雪立歆农业科技有限公司 | A kind of cultivation matrix of vegetable cultivation and preparation method thereof |
| CN108383666A (en) * | 2018-05-25 | 2018-08-10 | 合肥慧明瀚生态农业科技有限公司 | A kind of efficient tomato slow release fertilizer and preparation method thereof |
| CN110902821A (en) * | 2019-12-09 | 2020-03-24 | 宁波首创厨余垃圾处理有限公司 | Solid carbon source suitable for denitrification of high-concentration nitrate-nitrogen sewage and preparation method thereof |
| CN112340842A (en) * | 2020-10-09 | 2021-02-09 | 神美科技有限公司 | Preparation method of denitrification solid carbon source |
| CN113683464A (en) * | 2021-09-15 | 2021-11-23 | 深圳耐菲农业节水灌溉有限公司 | Navel orange planting fertilizer and preparation method thereof |
| CN116391604A (en) * | 2023-03-30 | 2023-07-07 | 凯盛浩丰农业有限公司 | Soilless cultivation technology for watermelons |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107141082A (en) | A kind of vegetable cultivation is with the organic slow-release fertilizer that concave convex rod is major ingredient | |
| CN106588285A (en) | Slow release fertilizer used for rice planting and preparing method thereof | |
| CN103641584A (en) | An organic fertilizer and a preparation method thereof | |
| CN104876679A (en) | Coarse biochar slow-release fertilizer and preparation method thereof | |
| CN104119168A (en) | Production method of attapulgite compressed nutrient soil | |
| CN108752130A (en) | A kind of plant raw-soil water-retaining agent and preparation method for slope greening restoration of the ecosystem | |
| CN104844366A (en) | Peanut-planting water-retaining fertilizer and preparation method thereof | |
| CN104072276B (en) | A kind of biological organic composite coated fertilizer that can activating soil and preparation method thereof | |
| CN105819963A (en) | Saline-alkali soil repairing novel fertilizer produced by taking high-silicon iron tailings as raw materials | |
| CN105541517A (en) | Soil improvement type mulberry fertilizer and preparation method thereof | |
| CN106116891A (en) | A kind of production method of attapulgite base slow-release mixing fertilizer material | |
| CN106083306A (en) | A kind of pot flowers sustained release coating fertilizer and preparation method thereof | |
| CN107903124A (en) | A kind of ecological ideas Nutrition Soil for garden landscape | |
| CN107245005A (en) | A kind of improving yield of wheat organic slow-release fertilizer resistant to lodging | |
| CN104671981A (en) | Full nutritional functional type polymer coated type strawberry fertilizer and preparation method thereof | |
| CN104130082A (en) | Low-use amount and fast-action blueberry organic fertilizer and preparation method thereof | |
| CN106835680A (en) | A kind of calcium carbonate enhancing silk fabric and preparation method thereof | |
| CN106367070A (en) | Preparation method of saline and alkaline garden soil improver | |
| CN108727112A (en) | A kind of ventilation anti-seepage sand | |
| CN104140335A (en) | Method for producing perlite compressed nutrient soil | |
| CN104072315A (en) | Biological organic composite coated slow release fertilizer containing calcium magnesium phosphate and preparation method thereof | |
| CN113692940A (en) | Ecological bag for slope greening and greening method | |
| CN106083304A (en) | A kind of for planting fruit trees selenium-rich coated slow release fertilizer and preparation method thereof | |
| CN112142523A (en) | Corn straw fiber-based water-retaining slow-release fertilizer capable of being completely degraded | |
| CN104446912A (en) | Special modified bamboo fiber coated fertilizer for acid soil strawberry and preparation method of coated fertilizer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170908 |
|
| RJ01 | Rejection of invention patent application after publication |