CN106927840B - 抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备 - Google Patents

抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备 Download PDF

Info

Publication number
CN106927840B
CN106927840B CN201710217529.2A CN201710217529A CN106927840B CN 106927840 B CN106927840 B CN 106927840B CN 201710217529 A CN201710217529 A CN 201710217529A CN 106927840 B CN106927840 B CN 106927840B
Authority
CN
China
Prior art keywords
thermal shock
shock resistant
phase
ceramic
ceramic material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201710217529.2A
Other languages
English (en)
Other versions
CN106927840A (zh
Inventor
谢建林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Material Research Institute Co ltd
Original Assignee
Shanghai Institute of Materials
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai Institute of Materials filed Critical Shanghai Institute of Materials
Priority to CN201710217529.2A priority Critical patent/CN106927840B/zh
Publication of CN106927840A publication Critical patent/CN106927840A/zh
Application granted granted Critical
Publication of CN106927840B publication Critical patent/CN106927840B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C04B35/101—Refractories from grain sized mixtures
    • C04B35/106—Refractories from grain sized mixtures containing zirconium oxide or zircon (ZrSiO4)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00—Making metallic powder or suspensions thereof
    • B22F9/02—Making metallic powder or suspensions thereof using physical processes
    • B22F9/06—Making metallic powder or suspensions thereof using physical processes starting from liquid material
    • B22F9/08—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
    • B22F9/082—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying atomising using a fluid
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/64—Burning or sintering processes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244—Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
    • C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
    • C04B2235/6567—Treatment time
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9669—Resistance against chemicals, e.g. against molten glass or molten salts
    • C04B2235/9676—Resistance against chemicals, e.g. against molten glass or molten salts against molten metals such as steel or aluminium

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

本发明涉及抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备。将含下述质量分数的原料：Al2O3 69.01％～76.00％、ZrO2 17.01％～24.13％、SiO2 5.29％～5.97％、MgO 0.05％～0.89％或Y2O3 0.05％～1.33％、TiO2 0.05％～0.19％、结合剂0.5％～1.5％混合；经90～220MPa等静压成型，在1630～1680℃温度范围高温烧结，制得抗热震复相陶瓷材料漏嘴。所述的抗热震复相陶瓷材料含有α‑氧化铝相、氧化锆相和莫来石相，适用于制成抗热震复相陶瓷漏嘴。与现有技术相比，本发明提供的抗热震复相陶瓷材料，由于含有相当数量的较低热膨胀系数莫来石相和抗侵蚀性能好、强度高的氧化锆，具有耐高温、耐熔融金属侵蚀，以及抗热震性能优越等特点；克服了传统的陶瓷漏嘴缺点，适合用于高温合金雾化制粉。

Description

抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备
技术领域
本发明涉及一种陶瓷材料，尤其是涉及抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备。
背景技术
高温合金粉末是现代金属增材制造复杂部件的重要原料，陶瓷漏嘴是雾化法制备高温合金粉末装置的关键部件之一。传统的陶瓷漏嘴，在内置1500℃熔融金属，外侧高速气流喷吹的极端环境下，很容易产生裂纹或“炸裂”，或由于耐高温、耐金属熔体侵蚀差，造成雾化制成的高温合金粉末成球性差，并可引起熔融金属从裂缝快速流出的危险。
中国专利CN106242565A公开了一种耐磨ZrO2-Al2O3复相陶瓷颗粒及其制备方法和应用，属于陶瓷复合材料制备技术领域，耐磨ZrO2-Al2O3复相陶瓷颗粒组成成分的质量分数为：10％～90％的稳定ZrO2以及10％～90％的Al2O3；采用电熔融、水冷制备得表面粗糙、粒径为0.5～7mm的高耐磨性ZrO2-Al2O3复相陶瓷颗粒，生产效率高，性能稳定，并将耐磨ZrO2-Al2O3复相陶瓷颗粒应用于制备钢铁基复合材料的增强体，能显著增强复合材料耐磨性。但是该专利中ZrO2-Al2O3复相陶瓷颗粒主要改善了材料耐磨性能，没有涉及改善陶瓷材料的抗热震性能；需要在1800℃以上电熔融、水冷制备，其制备过程能耗高；并且仅涉及0.5～7mm的ZrO2-Al2O3耐磨陶瓷颗粒，没有涉及以该材料为基体制备抗热震块体。
中国专利CN101209925B公开了一种提高氧化铝/氧化钛复相精细陶瓷材料弯曲强度和断裂韧性的方法，解决了现有Al2O3/TiO2复相陶瓷的弯曲强度、断裂韧性和硬度性能低的问题。该方法的步骤是：在球磨机中用去离子水做介质将精细氧化铝和氧化钛纳米粉体、改性剂、粘结剂聚乙烯醇混合成均匀浆料；然后喷雾干燥再造粒；随后对所得粉体进行热处理；经过热处理的粉体进行预压成型；坯料进行冷等静压成型后烧结。上述方法实现了精细陶瓷材料制备过程中陶瓷的低温快速烧结，明显降低了生产的成本，同时提高了产品的弯曲强度、断裂韧性和硬度。该专利主要改善了现有Al2O3/TiO2复相陶瓷的弯曲强度、断裂韧性和硬度性能低的问题，并有低温快速烧结的优点，同时没有涉及改善陶瓷材料的抗热震性能和高温抗侵蚀性能，特别是在1000～1500℃烧结的材料，耐高温性能不够，不适用于高温合金雾化制粉漏嘴；并且主要原料采用纳米氧化铝和纳米氧化钛粉体，成本较高。
发明内容
本发明的目的就是为了克服上述现有技术存在的缺陷而提供一种抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备。
本发明的目的可以通过以下技术方案来实现：
一种抗热震复相陶瓷材料，由含下述质量分数的原料制成：Al2O3 69.01％～76.00％、ZrO2 17.01％～24.13％、SiO2 5.29％～5.97％、MgO 0.05％～0.89％或Y2O30.05％～1.33％、TiO2 0.05％～0.19％、结合剂0.5％～1.5％。所述的结合剂为PVA、甲基纤维素或糊精中的一种或几种。所述的结合剂为PVA、甲基纤维素或糊精中的一种或几种。
原料中的Al2O3一部分形成耐高温的刚玉相基质相，其余部分与原料中含有的SiO2形成材料的莫来石相，低于所述的加入量，将会造成材料的耐高温性和机械强度下降；Al2O3加入量过多，复合材料中的刚玉相/莫来石比例过高，将会造成材料的抗热震性下降。
原料中加入的17.01％～24.13％ZrO2与材料中的氧化铝形成复合增韧基质材料，起提高材料的机械性能和抗热震性的作用，并可提高复合材料的高温抗侵蚀性能。
原料中加入的少量的MgO或Y2O3、TiO2主要是起烧结助剂和氧化锆稳定剂的作用。
进一步地，所述的抗热震复相陶瓷材料含有α－氧化铝相(刚玉相)、氧化锆相和莫来石相。氧化锆相和刚玉相在复相材料中为基质相，具有耐高温、耐腐蚀的特点。氧化锆相均匀分布在刚玉基质相中，在烧结过程中，随温度冷却，四方相氧化锆部分或全部转变成单斜氧化锆，并伴随一定的体积膨胀，在Al2O3和ZrO2晶界处产生压应力，起到复合增韧的作用。莫来石是Al2O3和SiO2在高温下生成的矿物，晶体为细针状。膨胀系数(25～1000℃)5.3×10－6/℃，具有良好的抗热震性，在本发明的材料中，针状莫来石穿插分布在基质相之间，进一步提高了本发明的复相陶瓷漏嘴的抗热震性能。
所述的抗热震复相陶瓷材料的制备方法，包括以下步骤：
1)将含下述质量分数的原料：Al2O3 69.01％～76.00％、ZrO2 17.01％～24.13％、SiO2 5.29％～5.97％、MgO 0.05％～0.89％或Y2O3 0.05％～1.33％、TiO2 0.05％～0.19％、结合剂0.5％～1.5％加水混合，加水量占原料与水总重量的4-6％；
2)将上述混合成分经90～220MPa等静压成型，在1630～1680℃温度范围高温烧结，随炉自然降温，制得抗热震复相陶瓷材料。
本发明还提供基于所述抗热震复相陶瓷材料的陶瓷漏嘴。
所述的陶瓷漏嘴的制备方法，包括以下步骤：
1)将含下述质量分数的原料：Al2O3 69.01％～76.00％、ZrO2 17.01％～24.13％、SiO2 5.29％～5.97％、MgO 0.05％～0.89％或Y2O3 0.05％～1.33％、TiO2 0.05％～0.19％、结合剂0.5％～1.5％加水混合，加水量占原料与水总重量的4-6％；
2)将上述混合成分经90～220MPa等静压成型为漏嘴，在1630～1680℃温度范围高温烧结，制得抗热震复相陶瓷漏嘴。
所述的陶瓷漏嘴主要用于高温合金雾化制粉。
本发明通过对原料与原料配比进行优化选择，并在原料选择的基础上，优化高温烧结的工艺，使得材料含有α－氧化铝相、氧化锆相和莫来石相。本发明中高温烧结的温度与时间对于材料的性能有重要影响，如果在其他温度烧结会产生不良的烧成结果，温度过低或保温时间过短，会产生欠烧，材料的机械性能降低；温度过高或保温时间过长，会产生烧结变形。
所述的抗热震复相陶瓷材料含有α－氧化铝相、氧化锆相和莫来石相，具有耐高温、耐熔融金属侵蚀，以及抗热震性能优越等特点，尤其适用于制成抗热震复相陶瓷漏嘴，因此，本发明提供了一种基于抗热震复相陶瓷材料的陶瓷漏嘴，克服了传统陶瓷漏嘴的缺点，所述的抗热震复相陶瓷漏嘴用于高温合金雾化制粉。
与现有技术相比，本发明的有益效果是：提供的抗热震复相陶瓷材料，由于含有相当数量的较低热膨胀系数莫来石相和抗侵蚀性能好、强度高的氧化锆，具有耐高温、耐熔融金属侵蚀，以及抗热震性能优越等特点；克服了传统的陶瓷漏嘴缺点，适用用于高温合金雾化制粉。
附图说明
图1：抗热震复相陶瓷漏嘴X－Ray图谱及分析结果；
图2：采用本发明陶瓷漏嘴制成的高温合金粉末SEM照片。
具体实施方式
下面结合附图和具体实施例对本发明进行详细说明。
实施例1
按比例称取含氧化钇部分稳定的氧化锆、氧化铝、氧化硅、氧化钛原料：原料的化学组分质量分数为，Al2O3 69.02％、ZrO2 23.63％、SiO2 5.80％、Y2O3 1.33％、TiO20.19％、PVA结合剂0.5％；加入5％的水，将原料混合，过筛、造粒，然后再加入到模具中，再经220MPa等静压成型，在1630℃的温度下保温3h烧成，即制得抗热震复合陶瓷漏嘴毛坯，再经机加工，使其外形尺寸达到雾化法制备高温合金粉末装置装配要求。所得复合陶瓷材料矿相分析结果见图1，应用结果和相关数据见表1。
实施例2
按比例称取含氧化镁部分稳定的氧化锆、氧化铝、氧化硅、氧化钛原料。原料的化学组分质量分数为，Al2O3 76％、ZrO2 17.36％、SiO2 5.97％、MgO 0.62％、TiO2 0.05％、糊精结合剂1.5％；加入5％的水，将原料混合，过筛、造粒，然后再加入到模具中，再经90MPa等静压成型，在1670℃的温度下保温2.5h烧成，即制得抗热震复合陶瓷漏嘴毛坯，再经机加工，使其外形尺寸达到雾化法制备高温合金粉末装置装配要求。应用结果和相关数据见表1。
实施例3
按比例称取含氧化镁部分稳定的氧化锆、氧化铝、氧化硅、氧化钛原料：原料的化学组分质量分数为：Al2O3 74.02％、ZrO2 19.30％、SiO2 5.84％、MgO 0.71％、TiO2 0.08％、甲基纤维素结合剂0.8％；加入5％的水，将原料混合，过筛、造粒，然后再加入到模具中，再经160MPa等静压成型，在1670℃的温度下保温2.5h烧成，即制得抗热震复合陶瓷漏嘴毛坯，再经机加工，使其外形尺寸达到雾化法制备高温合金粉末装置装配要求。应用结果和相关数据见表1。
实施例4
按比例称取氧化钇部分稳定的氧化锆、氧化铝、氧化硅、氧化钛原料：原料的化学组分质量分数为，Al2O3 74.55％、ZrO2 18.95％、SiO2 5.29％、Y2O3 0 1.07％、MgO 0.05％、TiO2 0.08％、PVA结合剂0.6％；加入5％的水，将原料混合，过筛、造粒，然后再加入到模具中，再经100MPa等静压成型，在1660℃的温度下保温3h烧成，即制得抗热震复合陶瓷漏嘴毛坯，再经机加工，使其外形尺寸达到雾化法制备高温合金粉末装置装配要求。应用结果和相关数据见表1。
实施例5
按比例称取氧化钇部分稳定的氧化锆和氧化镁部分稳定的氧化锆、氧化铝、氧化硅、氧化钛原料：原料的化学组分质量分数为，Al2O3 74.63％、ZrO2 18.91％、SiO2 5.50％、Y2O3 0.53％、MgO 0.35％、TiO2 0.08％、PVA结合剂0.6％；加入5％的水，将原料混合，过筛、造粒，然后再加入到模具中，再经100MPa等静压成型，在1660℃的温度下保温3h烧成，即制得抗热震复合陶瓷漏嘴毛坯，再经机加工，使其外形尺寸达到雾化法制备高温合金粉末装置装配要求。应用结果和相关数据见表1。
实施例6
按比例称取氧化镁部分稳定的氧化锆、氧化铝、氧化硅、氧化钛原料：原料的化学组分质量分数为，Al2O3 69.02％、ZrO2 24.13％、SiO2 5.80％、MgO 0.89％、TiO2 0.12％、PVA结合剂0.5％，加入5％的水，将原料混合，过筛、造粒，然后再加入到模具中，再经100MPa等静压成型，在1660℃的温度下保温3h烧成，即制得抗热震复合陶瓷漏嘴毛坯，再经机加工，使其外形尺寸达到雾化法制备高温合金粉末装置装配要求。应用结果和相关数据见表1。
表1 抗热震复合陶瓷漏嘴材料分析与应用结果
取实施例1-6制备的抗热震复合陶瓷漏嘴，在雾化法制备高温合金粉末装置装上，在上端和内侧与1500℃高温熔融合金接触，下端面及下端外侧10～70℃高速风冷条件下，进行应用和考核。结果显示，实施例1-6复合陶瓷漏嘴与高温熔融合金接触面没有出现熔融金属侵蚀，整体结构稳定，也不出现任何开裂、掉渣现象。实施例1制备的抗热震复合陶瓷漏嘴雾化制备的高温合金粉末球形度＞0.9(见图2)，实施例2-6制备的抗热震复合陶瓷漏嘴雾化制备的高温合金粉末球形度也都＞0.9。
以上实施例表明本发明的复合陶瓷漏嘴性能稳定，抗热震性好，耐火度高，雾化制备的高温合金粉末球形度好，纯度高，适用于3D打印。具有耐高温、耐熔融金属侵蚀，以及抗热震性能优越等特点；克服了传统的陶瓷漏嘴的缺点，适合用于高温合金雾化制粉，有广阔的应用前景。
上述的对实施例的描述是为便于该技术领域的普通技术人员能理解和使用发明。熟悉本领域技术的人员显然可以容易地对这些实施例做出各种修改，并把在此说明的一般原理应用到其他实施例中而不必经过创造性的劳动。因此，本发明不限于上述实施例，本领域技术人员根据本发明的揭示，不脱离本发明范畴所做出的改进和修改都应该在本发明的保护范围之内。

Claims (7)

1.一种抗热震复相陶瓷材料，其特征在于，由含下述质量分数的原料制成：Al2O369.01％～76.00％、ZrO2 17.01％～24.13％、SiO2 5.29％～5.97％、MgO 0.05％～0.89％或Y2O3 0.05％～1.33％、TiO2 0.05％～0.19％、结合剂0.5％～1.5％；
所述的抗热震复相陶瓷材料含有α－氧化铝相、氧化锆相和莫来石相，氧化锆相和刚玉相在复相材料中为基质相，氧化锆相均匀分布在刚玉基质相中；
制备方法包括以下步骤：
1)将含下述质量分数的原料：Al2O3 69.01％～76.00％、ZrO2 17.01％～24.13％、SiO25.29％～5.97％、MgO 0.05％～0.89％或Y2O3 0.05％～1.33％、TiO20.05％～0.19％、结合剂0.5％～1.5％加水混合；
2)将上述混合成分经90～220MPa等静压成型，在1630～1680℃温度范围高温烧结，制得抗热震复相陶瓷材料。
2.根据权利要求1所述的一种抗热震复相陶瓷材料，其特征在于，所述的结合剂为PVA、甲基纤维素或糊精中的一种或几种。
3.根据权利要求1所述的一种抗热震复相陶瓷材料，其特征在于，步骤1)中加水量占原料与水总重量的4-6％。
4.一种基于权利要求1-3中任一项所述抗热震复相陶瓷材料的陶瓷漏嘴。
5.一种如权利要求4所述的陶瓷漏嘴的制备方法，其特征在于，包括以下步骤：
1)将含下述质量分数的原料：Al2O3 69.01％～76.00％、ZrO2 17.01％～24.13％、SiO25.29％～5.97％、MgO 0.05％～0.89％或Y2O3 0.05％～1.33％、TiO20.05％～0.19％、结合剂0.5％～1.5％加水混合；
2)将上述混合成分经90～220MPa等静压成型为漏嘴，在1630～1680℃温度范围高温烧结，制得抗热震复相陶瓷漏嘴。
6.根据权利要求5所述的陶瓷漏嘴的制备方法，其特征在于，步骤1)中加水量占原料与水总重量的4-6％。
7.一种如权利要求4所述的陶瓷漏嘴的应用，其特征在于，所述的陶瓷漏嘴用于高温合金雾化制粉。
CN201710217529.2A 2017-04-05 2017-04-05 抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备 Active CN106927840B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710217529.2A CN106927840B (zh) 2017-04-05 2017-04-05 抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710217529.2A CN106927840B (zh) 2017-04-05 2017-04-05 抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备

Publications (2)

Publication Number Publication Date
CN106927840A CN106927840A (zh) 2017-07-07
CN106927840B true CN106927840B (zh) 2019-12-10

Family

ID=59426265

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710217529.2A Active CN106927840B (zh) 2017-04-05 2017-04-05 抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备

Country Status (1)

Country Link
CN (1) CN106927840B (zh)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113956024B (zh) * 2021-11-29 2023-02-28 上海材料研究所 一种抗热震复相陶瓷材料

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1162580A (zh) * 1996-12-23 1997-10-22 唐山市燕山产业有限公司 耐磨烧结型锆刚玉复合材料及其生产方法
CN101300207A (zh) * 2005-09-26 2008-11-05 圣戈班欧洲设计研究中心 表现出增强的抗热冲击性的烧结耐火产品

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1162580A (zh) * 1996-12-23 1997-10-22 唐山市燕山产业有限公司 耐磨烧结型锆刚玉复合材料及其生产方法
CN101300207A (zh) * 2005-09-26 2008-11-05 圣戈班欧洲设计研究中心 表现出增强的抗热冲击性的烧结耐火产品

Also Published As

Publication number Publication date
CN106927840A (zh) 2017-07-07

Similar Documents

Publication Publication Date Title
CN108367993B (zh) 经烧结的耐火锆石复合材料，其制造方法和其用途
CN110845245B (zh) 一种致密的高纯氧化锆耐火制品
JP2002145659A (ja) チタン酸アルミニウム系焼結体の製造方法
WO2013018393A1 (ja) セラミック中子およびその製造方法
JP5774135B2 (ja) ドープされた酸化クロムに基づく焼結物質
JP4944610B2 (ja) 改良された気泡発生挙動を有する焼結耐火物製品の製造を目的としたグリーン部材
CN109320213A (zh) 一种高致密度耐火陶瓷制品及其制备工艺
JP2007269605A (ja) 溶融シリカ質耐火物及びその製造方法
CN114538921B (zh) 一种玻璃相结合的大尺寸氧化锆致密烧结制品
US4461843A (en) Processes for preparing novel baddeleyite refractory articles
CN112624793A (zh) 一种氧化铝基多孔陶瓷材料的制备方法
JP2015231929A (ja) アルミナ溶融鋳造耐火物とその製造方法
CN106927840B (zh) 抗热震复相陶瓷材料及基于该材料的陶瓷漏嘴的制备
CN103771878B (zh) 一种红柱石砖的制法
CN103159484B (zh) ZrO2/SiC复合掺杂增韧Al2O3基陶瓷件的激光近净成形方法
KR101763122B1 (ko) 세라믹 코어의 제조방법, 이에 의해 제조된 세라믹 코어, 정밀주조 방법 및 이에 따라 제조된 정밀주조 제품
CN112979282A (zh) 一种氧化铝陶瓷烧结体及其制备方法和应用
KR20110132281A (ko) 고밀도 슬립-캐스트 용융 실리카 바디 제조방법
JP4822534B2 (ja) セラミックスの製造方法
CN113956024A (zh) 一种抗热震复相陶瓷材料
CN107399959B (zh) 一种利用纳米氧化物增强氧化铝-氧化镁-氧化钙系复合材料的制备方法
KR20170077972A (ko) 고강도 도자기의 제조방법
CN105016754A (zh) 玻璃供料道专用Al-99C致密氧化铝制品的制法
CN117088686B (zh) 一种改性氧化锆涂层及其制备方法
WO2014208620A1 (ja) 酸化スズ質不定形耐火物用紛体組成物、酸化スズ質不定形耐火物の製造方法、ガラス溶解炉および廃棄物溶融炉

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP01 Change in the name or title of a patent holder

Address after: 200437 No. 99, Handan Road, Shanghai, Hongkou District

Patentee after: Shanghai Material Research Institute Co.,Ltd.

Address before: 200437 No. 99, Handan Road, Shanghai, Hongkou District

Patentee before: SHANGHAI Research Institute OF MATERIALS

CP01 Change in the name or title of a patent holder