CN106866051A - A kind of construction material for having pyroelecthc properties, preparation method and building board - Google Patents
A kind of construction material for having pyroelecthc properties, preparation method and building board Download PDFInfo
- Publication number
- CN106866051A CN106866051A CN201710085051.2A CN201710085051A CN106866051A CN 106866051 A CN106866051 A CN 106866051A CN 201710085051 A CN201710085051 A CN 201710085051A CN 106866051 A CN106866051 A CN 106866051A
- Authority
- CN
- China
- Prior art keywords
- construction material
- tool
- pyroelecthc properties
- graphite
- graphite worm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/001—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/022—Carbon
- C04B14/024—Graphite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/10—Lime cements or magnesium oxide cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Civil Engineering (AREA)
- Dispersion Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention relates to a kind of construction material for having pyroelecthc properties, the construction material of the tool pyroelecthc properties includes graphite worm and land plaster or diatomite, the gross mass percentage that the graphite worm accounts for the construction material of the tool pyroelecthc properties is 5%~50%, and the density range of the graphite worm is 0.005g/cm3~0.05g/cm3.The construction material of tool pyroelecthc properties proposed by the present invention and the building board being made include the graphite worm of less content, significantly improve the thermal conductivity function of plasterboard, can be used for heat conduction, heat loss through radiation, antistatic and electromagnetic shielding field；At the same time, retain the mechanical performance of traditional building material, the demands such as actual bearer, cut-off can be met with application.
Description
Technical field
The present invention relates to building material technical field, more particularly to a kind of construction material, its preparation side for having pyroelecthc properties
Method and building board.
Background technology
Gypsum-based construction material is a kind of common and important construction material, generally include gypsum composite board, gypsum wallboard,
Plaster board and gypsum nonwoven plate etc., generally extensively using the inside finishing with building and decoration.
Traditional gypsum base or diatom earthwork materials due to relatively low thermal conductivity, therefore in building engineering field
In general be all used for heat insulator.At the same time, the electric conductivity of traditional gypsum base or diatom earthwork materials is also poor,
Therefore also often by people as the preferred of electrically insulating material.But in actual applications, it is also required to make in some special fields
The construction material with preferable thermoelectricity capability is used, for antistatic, electromagnetic shielding, heat conduction, radiating etc., and traditional gypsum,
Diatomite construction material tends not to meet this point.
It is therefore desirable to work out a kind of tool with certain heat conduction, radiating, electrostatic screen and antistatic conductive electrical property
The construction material of pyroelecthc properties, to meet the demand of actual production building.
The content of the invention
Based on this, it is an object of the invention to provide with certain heat conduction, radiating, electrostatic screen and antistatic conductive electrical property
Tool pyroelecthc properties construction material, with meet actual production building demand.
A kind of construction material for having pyroelecthc properties, it includes graphite worm and applies feed powder, and the graphite worm accounts for described
The mass percent for having the construction material of pyroelecthc properties is 5%~50%, and the density range of the graphite worm is 0.005g/
cm3~0.05g/cm3, the feed powder that applies is one kind or its combination in land plaster, pulverized limestone, diatom ooze.
The structure of the graphite worm is natural flake graphite first through chemical acid treatment again through the swollen of thermal expansion treatment generation
Swollen structure.
The mass percent that the graphite worm accounts for the construction material of the tool pyroelecthc properties is 5%~30%.
The density range of the graphite worm is 0.005g/cm3~0.03g/cm3。
The construction material of the tool pyroelecthc properties further includes binding agent, and the binding agent includes modified starch, foaming
Any one in agent, white glue with vinyl.
The mass percent that the binding agent accounts for the construction material of the tool pyroelecthc properties is 1%~5%.
A kind of preparation method of the construction material for having pyroelecthc properties, it comprises the following steps：(1) by natural flake graphite elder generation
Processed through thermal expansion again through chemical acid treatment, obtain density range for 0.005g/cm3~0.05g/cm3Graphite worm；(2) will
The graphite worm using dry-mix process be mixed and stirred for uniformly obtaining the first mixture with feed powder is applied；(3) described
Water and binding agent stirring is added to obtain the second mixture in first mixture；(4) treatment is dried to second mixture
The construction material of the tool pyroelecthc properties is obtained afterwards.
Described in step (2) in dry-mix process by the way of airflow stirring.
Water and binding agent are added in first mixture in step (3) and the second mixture is uniformly mixing to obtain.
A kind of preparation method of the construction material for having pyroelecthc properties, it comprises the following steps：(1) by natural flake graphite elder generation
Processed through thermal expansion again through chemical acid treatment, obtain density range for 0.005g/cm3~0.05g/cm3Graphite worm；(2) will
Applying feed powder adds water and binding agent to obtain jelly, and the painting feed powder is the one kind or its group in land plaster, pulverized limestone, diatom ooze
Close；(3) graphite worm is added in the jelly, stirring obtains the 3rd mixture；(4) the 3rd mixture is entered
The construction material of the tool pyroelecthc properties is obtained after row dried process.
The present invention also provides a kind of building board, and the building board is prepared from by above-mentioned construction material.
It is of the invention in the construction material of the tool pyroelecthc properties compared to prior art, using graphite worm, the graphite
The density of worm is smaller, only 0.005g/cm3~0.05g/cm3, specific surface area is big, thus in construction material, it is easier to shape
Into uniform heat conduction conductive network.In the case of with mass ratio identical shared by existing graphite particle, the tool pyroelecthc properties
Construction material conductive and heat-conductive it is better；In other words, identical heat conduction can be reached with the graphite worm of smaller scale
And the effect of shielding, while also reducing production cost, tool has an unexpected effect.In addition, described have building for pyroelecthc properties
Build material and remain original mechanical property.The building board being prepared from by the construction material of the tool pyroelecthc properties has excellent
Different heat conductivility.
In the preparation method of the construction material of tool pyroelecthc properties of the present invention, the preferential method using dry-mix process will
Graphite worm and gypsum or diatomite dry powder blend, gypsum powder coating powder is adsorbed in the surface of graphite worm, and has larger ratio
The graphite worm of surface area is easier to expose and mutually overlap to form conductive and heat-conductive networking.The preparation method is simple to operate, be easy to
Industrialized production.
Brief description of the drawings
Fig. 1 is the photo of graphite worm of the present invention.
Fig. 2 is the microphotograph of graphite worm described in Fig. 1.
Specific embodiment
For the ease of understanding the present invention, the present invention is more fully described below in conjunction with related embodiment.
This is pointed out that the present invention can be realized in many different forms, however it is not limited to embodiment described herein.Phase
Instead, there is provided the purpose of these embodiments be make to the disclosure more it is thorough comprehensively.
Unless otherwise defined, all of technologies and scientific terms used here by the article with belong to technical field of the invention
The implication that technical staff is generally understood that is identical.The term for being used in the description of the invention herein is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term as used herein " and/or " include one or more phases
The arbitrary and all of combination of the Listed Items of pass.
The present invention provides a kind of construction material for having pyroelecthc properties.The construction material of the tool pyroelecthc properties includes that graphite is compacted
Worm and painting feed powder.The mass percent that the graphite worm accounts for the construction material of the tool pyroelecthc properties is 5%~50%.Institute
The density range for stating graphite worm is 0.005g/cm3~0.05g/cm3。
The feed powder that applies is one kind or its combination in land plaster, pulverized limestone, diatom ooze.Preferably, the painting feed powder is
Land plaster or diatom ooze, painting feed powder is done with land plaster and diatom ooze, the density of construction material on the one hand can be reduced, so as to reduce right
The weight of wall is answered, on the other hand, the insulating properties of construction material and correspondence wall can be improved.
The graphite worm is natural flake graphite first through chemical acid treatment again through the expansion structure of thermal expansion treatment generation.
Specifically, preparing graphite intercalation compound by raw material of graphite, then the graphite intercalation compound is carried out into thermal expansion, obtain institute
State graphite worm.Fig. 1 and Fig. 2 is specifically referred to, the graphite worm refers to that the number of plies is 101~104Multi-layer graphene structure.
Preferably, the mass percent that the graphite worm accounts for the construction material of the tool pyroelecthc properties is 5%~30%,
The density range of the graphite worm is 0.005g/cm3~0.03g/cm3。
The construction material of the tool pyroelecthc properties can also further include binding agent.The binding agent can for modified starch,
Foaming agent, white glue with vinyl etc., specifically can be according to different application scenarios.
The present invention also provides a kind of preparation method of the construction material for having pyroelecthc properties.The preparation method includes following step
Suddenly：
(1) natural flake graphite is first processed through thermal expansion again through chemical acid treatment, obtains density range for 0.005g/
cm3~0.05g/cm3Graphite worm；
(2) graphite worm be mixed and stirred for uniformly obtaining first mixing with feed powder is applied using dry-mix process
Thing, the painting feed powder is one kind or its combination in land plaster, pulverized limestone, diatom ooze；
(3) water is added to be uniformly mixing to obtain the second mixture in first mixture；
(4) construction material for having pyroelecthc properties is obtained after treatment is dried to second mixture.
Wherein, described in step (2) in dry-mix process by the way of airflow stirring.
In step (3), binding agent can be also added, the second mixture is uniformly mixing to obtain with first mixture and water.
The present invention also provides a kind of building board.The building board is prepared from by above-mentioned construction material.
In the preparation method of the construction material of tool pyroelecthc properties of the present invention, using the method for dry-mix process by graphite
Worm mixes with feed powder is applied, and applies the surface that feed powder is adsorbed in graphite worm, and the graphite worm with large specific surface area more holds
Easily expose and mutually overlap to form conductive and heat-conductive networking.The preparation method is simple to operate, be easy to industrialized production.
The present invention also provides the preparation method of the construction material of another tool pyroelecthc properties.The preparation method includes following
Step：
(1) natural flake graphite is first processed through thermal expansion again through chemical acid treatment, obtains density range for 0.005g/
cm3~0.05g/cm3Graphite worm；
(2) will apply feed powder adds water and binding agent to obtain jelly, the painting feed powder is land plaster, pulverized limestone, diatom ooze
In one kind or its combination；
(3) graphite worm is added in the jelly, stirring obtains the 3rd mixture；
(4) construction material for having pyroelecthc properties is obtained after treatment is dried to the 3rd mixture.
As a example by the construction material of the tool pyroelecthc properties with gypsum base as raw material, below in conjunction with the tool of different materials proportioning
Construction material of pyroelecthc properties and preparation method thereof is further described to the present invention.
Embodiment 1：
A kind of preparation method of the construction material of the tool pyroelecthc properties, concretely comprises the following steps：
(1) natural flake graphite is first obtained into density for 0.005g/cm through thermal expansion treatment again through chemical acid treatment3Stone
Black worm；
(2) graphite worm and the land plaster according to certain ratio be mixed and stirred for uniformly obtaining first
Mixture, wherein the mass percent of the graphite worm is 5%, remaining is the land plaster；
Wherein, the graphite worm and the hybrid mode of the land plaster are dry-mix process, i.e., used in closed container
Airflow stirring mode mixes.
(3) water is added in first mixture and the second mixture is uniformly mixing to obtain, wherein when is stirred
Stir speed (S.S.) is controlled in 180r/min, and mixing time is 10min, wherein, the binding agent can be clay.
(4) treatment is dried to second mixture, the construction material of the tool pyroelecthc properties is obtained, in this implementation
Temperature control when treatment is dried in example is constant at 55 DEG C.
Embodiment 2：
A kind of preparation method of the construction material of the tool pyroelecthc properties, concretely comprises the following steps：
(1) natural flake graphite is first obtained into density for 0.005g/cm through thermal expansion treatment again through chemical acid treatment3Stone
Black worm；
(2) graphite worm and the land plaster according to certain ratio be mixed and stirred for uniformly obtaining first
Mixture；
Wherein, the graphite worm and the hybrid mode of the land plaster are dry-mix process, i.e., used in closed container
Airflow stirring mode mixes.
(3) water and binding agent are added in first mixture and the second mixture is uniformly mixing to obtain, wherein institute
It is 10: 84: 1 to state graphite worm, land plaster, the weight ratio of binding agent, appropriate amount of water, and when being stirred, stir speed (S.S.) control exists
180r/min, mixing time is 10min, wherein, the binding agent can be clay.
(4) treatment is dried to second mixture, the construction material of the tool pyroelecthc properties is obtained, in this implementation
Temperature control when treatment is dried in example is constant at 55 DEG C.
Embodiment 3：
A kind of preparation method of the construction material of the tool pyroelecthc properties, concretely comprises the following steps：
(1) natural flake graphite is first obtained into density for 0.005g/cm through thermal expansion treatment again through chemical acid treatment3Stone
Black worm；
(2) graphite worm and the land plaster according to certain ratio be mixed and stirred for uniformly obtaining first
Mixture, wherein, likewise, the hybrid mode that graphite worm described in the present embodiment is carried out with the land plaster is dry type mixing
Method, i.e., mixed in closed container with airflow stirring mode.
(3) water and binding agent are added in first mixture and the second mixture is uniformly mixing to obtain, wherein institute
It is 20 to state graphite worm, land plaster, the weight ratio of binding agent：75：5, appropriate amount of water, when being stirred, stir speed (S.S.) control exists
300r/min, mixing time is 25min, wherein, the binding agent can be lime-microfine silica powder.
(4) treatment is dried to second mixture, the construction material of the tool pyroelecthc properties is obtained, in this implementation
Temperature control when treatment is dried in example is constant at 70 DEG C.
Embodiment 4：
A kind of preparation method of the construction material of the tool pyroelecthc properties, concretely comprises the following steps：
(1) natural flake graphite is first obtained into density for 0.025g/cm through thermal expansion treatment again through chemical acid treatment3Stone
Black worm；
(2) graphite worm and the land plaster according to certain ratio be mixed and stirred for uniformly obtaining first
Mixture, the hybrid mode that graphite worm is carried out with the land plaster wherein described in the present embodiment is dry-mix process, that is, exist
Mixed with airflow stirring mode in closed container.
(3) water and binding agent are added in first mixture and the second mixture is uniformly mixing to obtain, wherein institute
It is 20 to state graphite worm, land plaster, the weight ratio of binding agent：75：5, appropriate amount of water, when being stirred, stir speed (S.S.) control exists
300r/min, mixing time is 25min, wherein, the binding agent can be lime-microfine silica powder.
(4) treatment is dried to second mixture, the construction material of the tool pyroelecthc properties is obtained, in this implementation
Temperature control when treatment is dried in example is constant at 70 DEG C.
Embodiment 5：
A kind of preparation method of the construction material of the tool pyroelecthc properties, concretely comprises the following steps：
(1) natural flake graphite is first obtained into density for 0.025g/cm through thermal expansion treatment again through chemical acid treatment3Stone
Black worm；
(2) graphite worm and the land plaster according to certain ratio be mixed and stirred for uniformly obtaining first
Mixture, the hybrid mode that graphite worm is carried out with the land plaster wherein described in the present embodiment is dry-mix process, that is, exist
Mixed with airflow stirring mode in closed container.
(3) water and binding agent are added in first mixture and the second mixture is uniformly mixing to obtain, wherein institute
It is 30: 65: 5 to state graphite worm, land plaster, the weight ratio of binding agent, appropriate amount of water, and when being stirred, stir speed (S.S.) control exists
300r/min, mixing time is 25min, wherein, the binding agent can be lime-microfine silica powder.
(4) treatment is dried to second mixture, the construction material of the tool pyroelecthc properties is obtained, in this implementation
Temperature control when treatment is dried in example is constant at 70 DEG C.
Construction material of the application also to the tool pyroelecthc properties of the gained of embodiment 1~5 carries out heat conductivility test.Test knot
Fruit is shown in Table 1.
Table 1
From table 1, relative to prior art, the present embodiment 1~5 includes the Building wood of the tool pyroelecthc properties of graphite worm
The heat conductivility of material has obtained larger lifting.
It is can be found that with the relevant parameter of embodiment 2 by contrasting above-described embodiment 1：The addition of binding agent, the tool heat
The heat conductivility tool of the construction material of electrical characteristics has a certain upgrade.The addition of this explanation binding agent is conducive to graphite worm to be formed
Heat conduction network.
It is can be found that with the relevant parameter of embodiment 3 by contrasting above-described embodiment 2：Change the quality percentage of binding agent
Than, the factor such as mixing speed, mixing time and drying temperature to the heat conductivility of the construction material of the tool pyroelecthc properties
Influence is smaller, and the heat conductivility of the construction material of the tool pyroelecthc properties does not almost occur obvious change.Based on this, we
The parameters such as the mass percent of above-mentioned binding agent, mixing speed, mixing time and drying temperature are fixed, by respectively
Change density of mass percent, the mass percent of the land plaster and the graphite worm of the graphite worm etc. because
Usually study the influence of its construction material heat conductivility to the tool pyroelecthc properties.
Can be learnt by contrasting the embodiment 3 and the embodiment 4：When the density for increasing the graphite worm can
To improve the thermal conductivity of the construction material of the tool pyroelecthc properties.
It is can be found that with embodiment 5 by contrasting the embodiment 4：When increase the graphite worm mass percent it
Afterwards, the heat conductivility of the construction material of the tool pyroelecthc properties has obtained further raising.
In this manual, in order to detect the capability of electromagnetic shielding of the construction material of the tool pyroelecthc properties, in magnetic field, flat
Under the various frequency ranges of face ripple and microwave, tradition is have detected without the construction material of the tool pyroelecthc properties of graphite worm and sheet
The shielding attenuation ability of the construction material of the tool pyroelecthc properties of the addition graphite worm that invention is proposed.Wherein, specific data such as table 2
Shown, table 2 is that the correspondence to electromagnetic shielding decay of the construction material of the tool pyroelecthc properties that different materials proportioning is made is closed
It is table, wherein the unit of shielding attenuation measured value is dB.
Table 2
From table 2 it can be seen that to the construction material of existing traditional tool pyroelecthc properties without the graphite worm and
Speech, after graphite worm is added, can on the whole improve the electromagnetic shielding capability of the construction material of tool pyroelecthc properties, especially
There is stronger screening ability for frequency ranges such as plane wave and microwaves.
At the same time, comparative example 1 and embodiment 2 are it is known that the mass percent of binding agent that changes, stirring speed
The factor such as degree, mixing time and drying temperature on the capability of electromagnetic shielding influence of the construction material of the tool pyroelecthc properties compared with
Small, almost there is no obvious change in the capability of electromagnetic shielding of the construction material of the tool pyroelecthc properties.
Comparative example 2, embodiment 3 and embodiment 4 are as can be seen that when the density of the graphite worm gradually increases
When, the construction material of the tool pyroelecthc properties is also gradually increasing the screening ability of magnetic field, plane wave and microwave, illustrates institute
The electromagnetic shielding capability for stating the construction material of tool pyroelecthc properties increases with the increase of the graphite worm density.
Comparative example 5, embodiment 6 and embodiment 7 it is known that when the mass fraction of the land plaster is increased,
Mass fraction equivalent to the graphite worm in the construction material of the tool pyroelecthc properties declines, the corresponding tool thermoelectricity
The construction material of characteristic is also gradually reduced to the screening ability of magnetic field, plane wave and microwave.This described land plaster quality of explanation
The increase of fraction be unfavorable for it is described tool pyroelecthc properties construction material electromagnetic shielding, reduce its to magnetic field, plane wave and
The electromagnetic shielding capability of microwave.
Compared to prior art, in the construction material of tool pyroelecthc properties of the present invention, using graphite worm, the graphite is compacted
The density of worm is smaller, only 0.005g/cm3~0.05g/cm3, specific surface area is big, thus in construction material, it is easier to formed
Thermal conductivity network.In the case of with mass ratio identical shared by existing graphite particle, the building of the tool pyroelecthc properties
Materials conductive heat-conducting effect is more preferably；In other words, identical heat conduction and shielding can be reached with the graphite worm of smaller scale
Effect, while also reducing production cost, tool has an unexpected effect.In addition, the construction material of the tool pyroelecthc properties
Remain original mechanical property.The building board being prepared from by the construction material of the tool pyroelecthc properties has excellent leading
Hot property.
Embodiment described above only expresses several embodiments of the invention, and its description is more specific and detailed, but simultaneously
Therefore the limitation to the scope of the claims of the present invention can not be interpreted as.It should be pointed out that for one of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Shield scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (12)
1. a kind of construction material for having pyroelecthc properties, it is characterised in that it includes graphite worm and applies feed powder, and the graphite is compacted
The mass percent that worm accounts for the construction material of the tool pyroelecthc properties is 5%~50%, and the density range of the graphite worm is
0.005g/cm3~0.05g/cm3, the feed powder that applies is one kind or its combination in land plaster, pulverized limestone, diatom ooze.
2. the construction material of tool pyroelecthc properties according to claim 1, it is characterised in that the structure of the graphite worm is
Natural flake graphite is first through chemical acid treatment again through the expansion structure of thermal expansion treatment generation.
3. it is according to claim 1 tool pyroelecthc properties construction material, it is characterised in that the graphite worm accounts for the tool
The mass percent of the construction material of pyroelecthc properties is 5%~30%.
4. it is according to claim 1 tool pyroelecthc properties construction material, it is characterised in that the density model of the graphite worm
It is 0.005g/cm to enclose3~0.03g/cm3。
5. it is according to claim 1 tool pyroelecthc properties construction material, it is characterised in that the building of the tool pyroelecthc properties
Material further includes binding agent, and the binding agent includes any one in modified starch, foaming agent, white glue with vinyl.
6. it is according to claim 5 tool pyroelecthc properties construction material, it is characterised in that the binding agent account for it is described tool heat
The mass percent of the construction material of electrical characteristics is 1%~5%.
7. it is a kind of have pyroelecthc properties construction material preparation method, it comprises the following steps：
(1) natural flake graphite is first processed through thermal expansion again through chemical acid treatment, obtains density range for 0.005g/cm3~
0.05g/cm3Graphite worm；
(2) graphite worm using dry-mix process be mixed and stirred for uniformly obtaining the first mixture with feed powder is applied,
The feed powder that applies is one kind or its combination in land plaster, pulverized limestone, diatom ooze；
(3) water and binding agent stirring is added to obtain the second mixture in first mixture；
(4) construction material for having pyroelecthc properties is obtained after treatment is dried to second mixture.
8. it is according to claim 7 tool pyroelecthc properties construction material preparation method, it is characterised in that in step (2)
In the dry-mix process by the way of airflow stirring.
9. it is according to claim 7 tool pyroelecthc properties construction material preparation method, it is characterised in that in step (3)
Water and binding agent are added in first mixture and the second mixture is uniformly mixing to obtain.
10. it is according to claim 7 tool pyroelecthc properties construction material preparation method, it is characterised in that the coating
Powder is one kind or its combination in land plaster, pulverized limestone, diatom ooze.
A kind of 11. preparation methods of the construction material for having pyroelecthc properties, it comprises the following steps：
(1) natural flake graphite is first processed through thermal expansion again through chemical acid treatment, obtains density range for 0.005g/cm3~
0.05g/cm3Graphite worm；
(2) will apply feed powder adds water and binding agent to obtain jelly, and the painting feed powder is in land plaster, pulverized limestone, diatom ooze
A kind of or its combination；
(3) graphite worm is added in the jelly, stirring obtains the 3rd mixture；
(4) construction material for having pyroelecthc properties is obtained after treatment is dried to the 3rd mixture.
A kind of 12. building boards, it is characterised in that building board construction material system as described in any one of claim 1~6
It is standby to form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710085051.2A CN106866051A (en) | 2017-02-16 | 2017-02-16 | A kind of construction material for having pyroelecthc properties, preparation method and building board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710085051.2A CN106866051A (en) | 2017-02-16 | 2017-02-16 | A kind of construction material for having pyroelecthc properties, preparation method and building board |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106866051A true CN106866051A (en) | 2017-06-20 |
Family
ID=59166269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710085051.2A Pending CN106866051A (en) | 2017-02-16 | 2017-02-16 | A kind of construction material for having pyroelecthc properties, preparation method and building board |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106866051A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109399979A (en) * | 2018-11-21 | 2019-03-01 | 华侨大学 | A kind of preparation method of the thermally conductive cement of foam conductive |
| CN116102310A (en) * | 2022-12-26 | 2023-05-12 | 清华大学 | Cement-based thermoelectric material and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1907905A (en) * | 2005-08-04 | 2007-02-07 | Sgl碳股份公司 | Gypsum-based building material with enhanced thermal conductivity and shielding attenuation |
| CN105000853A (en) * | 2015-05-14 | 2015-10-28 | 中国建筑材料科学研究总院 | Gypsum board with electromagnetic wave absorption function and manufacturing method thereof |
| CN106186944A (en) * | 2016-07-13 | 2016-12-07 | 西安建筑科技大学 | A kind of method improving cement-base composite material thermoelectricity capability |
-
2017
- 2017-02-16 CN CN201710085051.2A patent/CN106866051A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1907905A (en) * | 2005-08-04 | 2007-02-07 | Sgl碳股份公司 | Gypsum-based building material with enhanced thermal conductivity and shielding attenuation |
| CN105000853A (en) * | 2015-05-14 | 2015-10-28 | 中国建筑材料科学研究总院 | Gypsum board with electromagnetic wave absorption function and manufacturing method thereof |
| CN106186944A (en) * | 2016-07-13 | 2016-12-07 | 西安建筑科技大学 | A kind of method improving cement-base composite material thermoelectricity capability |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109399979A (en) * | 2018-11-21 | 2019-03-01 | 华侨大学 | A kind of preparation method of the thermally conductive cement of foam conductive |
| CN116102310A (en) * | 2022-12-26 | 2023-05-12 | 清华大学 | Cement-based thermoelectric material and preparation method and application thereof |
| CN116102310B (en) * | 2022-12-26 | 2024-05-10 | 清华大学 | Cement-based thermoelectric material and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108834389B (en) | Preparation method of bimetal organic framework derived porous carbon/multi-walled carbon nanotube nano composite wave-absorbing material | |
| Liu et al. | Microwave absorption properties of a wave-absorbing coating employing carbonyl-iron powder and carbon black | |
| CN104563316B (en) | A kind of mineral wool sound absorption board of anti-electromagnetic radiation and preparation method thereof | |
| Meng et al. | Enhanced absorbing properties of three-phase composites based on a thermoplastic-ceramic matrix (BaTiO 3+ PVDF) and carbon black nanoparticles | |
| CN108752713A (en) | One kind aligning graphene superelevation thermal conductivity composite material and preparation method | |
| Xie et al. | Electromagnetic wave absorption properties of honeycomb structured plasterboards in S and C bands | |
| CN105238179A (en) | Waterborne electromagnetic shielding coating and preparation method thereof | |
| Quan et al. | Cobalt nanoparticles embedded nitrogen-doped porous graphitized carbon composites with enhanced microwave absorption performance | |
| CN108045060B (en) | Explosion-proof broadband wave-absorbing composite material and preparation method thereof | |
| JP6801094B2 (en) | Hydrophobic type sedimentation prevention far infrared wave absorbing material and its manufacturing method, kitchen electric appliances and its manufacturing method | |
| CN102226325B (en) | A kind of far infrared carbon fiber low temperature conductive heating paper and preparation method thereof | |
| JP2019131456A (en) | Polypyrrole film-coated graphene oxide cement-based composite material and preparation method thereof | |
| CN109943018B (en) | Wave absorbing agent, wave absorbing material and respective preparation method | |
| CN114853502B (en) | Ceramic/graphene aerogel wave-absorbing material and preparation method and application thereof | |
| CN110498990B (en) | Preparation method of C @ Ni composite material and electromagnetic shielding film | |
| CN109095919B (en) | Barium titanate/cobaltosic oxide complex phase millimeter wave absorbing powder with multistage microstructure distribution and preparation method thereof | |
| CN107434389A (en) | A kind of Thistle board of anti-electromagnetic radiation and preparation method thereof | |
| CN106866051A (en) | A kind of construction material for having pyroelecthc properties, preparation method and building board | |
| CN113462357A (en) | Wave-absorbing particles and preparation method and application of composite material thereof | |
| CN103467028A (en) | Thermal-insulation mortar | |
| CN104530467A (en) | Preparation method of light bandwidth wave-absorbing material | |
| Huang et al. | Polarization genes dominated heteroatom-doped graphene aerogels toward super-efficiency microwave absorption | |
| Mu et al. | Microwave absorption properties of composite powders with low density | |
| CN103709451A (en) | Ceiling with electromagnetic wave absorption function and preparation method thereof | |
| CN107384310A (en) | A kind of CeO2/ MWCNTs composites, preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170620 |