CN106830753A - A kind of true mineral varnish of high-quality and preparation method thereof - Google Patents
A kind of true mineral varnish of high-quality and preparation method thereof Download PDFInfo
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- CN106830753A CN106830753A CN201710006353.6A CN201710006353A CN106830753A CN 106830753 A CN106830753 A CN 106830753A CN 201710006353 A CN201710006353 A CN 201710006353A CN 106830753 A CN106830753 A CN 106830753A
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- mineral varnish
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of true mineral varnish of high-quality, it is related to a kind of coating, is specifically made up of following material：Silicone acrylic emulsion, coalescents, defoamer, dispersant, thickener, curing agent, ultra-violet absorber, propane diols, aggregate, crystal whisker of hexa potassium titanate, water.True mineral varnish of the invention obtained has heatproof, water-fast, corrosion resistant, impact resistance strong, and film forming rate of drying is fast, and drop amount is small, the phenomenon such as is less prone to colours fading, turns white, come off, and stability by force, the characteristics of integrated quality is high, there is the good market competitiveness.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, and in particular to a kind of true mineral varnish of high-quality and preparation method thereof.
Background technology
True mineral varnish is that one kind exactly likes marble, granite with decorative effect, and the main natural stone-powder using shades of colour is matched somebody with somebody
System is formed.Building after true mineral varnish decoration, with natural real natural colour, gives graceful, harmonious, serious U.S.
Sense, it is adaptable to the interior/exterior decoration of all kinds of buildings, particularly on curved-surface building thing decorate, can receive it is vivid, return
Return natural effect.
But true mineral varnish most at present have the phenomenon that drop is more, application property is poor when spraying, spraying is fallen when serious
Sand up to 1/3rd or so of coating, influence construction, in addition just to occur that burst is returned after rainy day or when wetness is big white,
Discolouration phenomena, and wearability, the intensity of entirety etc. is not high, has had a strong impact on its service life.
The content of the invention
The present invention is intended to provide a kind of true mineral varnish of high-quality and preparation method thereof, obtained true mineral varnish good combination property,
Quality is high, long service life, there is good use value.
The present invention is achieved through the following technical solutions：
A kind of true mineral varnish of high-quality, is made up of the material of following weight portion：
11 ~ 14 parts of silicone acrylic emulsions, 1 ~ 1.5 part of coalescents, 0.2 ~ 0.3 part of defoamer, 1 ~ 1.5 part of dispersant, 0.5 ~ 1 part of thickening
Agent, 0.2 ~ 0.4 part of curing agent, 0.1 ~ 0.2 part of ultra-violet absorber, 0.3 ~ 0.5 part of propane diols, 63 ~ 68 parts of aggregates, 0.5 ~ 1.5
Part crystal whisker of hexa potassium titanate, 14 ~ 16 parts of water；Described aggregate is made up of the material of following weight portion：90 ~ 100 parts of natural colour sands,
0.5 ~ 1 part of sliver, 0.2 ~ 0.4 part of blacklead silica, 1 ~ 1.5 part of medical stone, 0.3 ~ 0.5 part of nano zircite.
Preferably, it is made up of the material of following weight portion：
13 parts of silicone acrylic emulsions, 1.2 parts of coalescents, 0.25 part of defoamer, 1.3 parts of dispersants, 0.8 part of thickener, 0.3 part of solidification
Agent, 0.15 part of ultra-violet absorber, 0.4 part of propane diols, 65 parts of aggregates, 1 part of crystal whisker of hexa potassium titanate, 15 parts of water；Described aggregate
It is made up of the material of following weight portion：95 parts of natural colour sands, 0.7 portion of sliver, 0.3 part of blacklead silica, 1.2 parts of medical stones, 0.4 part
Nano zircite.
Further, the coalescents are the one kind in propandiol butyl ether, propylene glycol methyl ether acetate.
Further, the defoamer is the one kind in polyoxyethylene polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether.
Further, the dispersant is the one kind in calgon, sodium pyrophosphate.
Further, the thickener is the one kind in Sodium Polyacrylate, sodium carboxymethylcellulose.
Further, the curing agent is the one kind in vinyl triamine, triethylene tetramine.
Further, the ultra-violet absorber is the one kind in Ultraviolet Absorber UV-P, ultra-violet absorber UV-O.
Further, the aggregate processing method comprises the following steps：
（1）First fully rinse standby after clean impurity to natural colour sand, sliver, blacklead silica, medical stone with clear water；
（2）By step（1）Natural colour sand, sliver, blacklead silica and medical stone after treatment are put into the phosphorus that mass fraction is 3 ~ 4%
Taken out after 10 ~ 13min of immersion treatment in acid solution, then be placed in immersion treatment 13 in the sodium hydroxide solution that mass fraction is 5 ~ 6%
Taken out after ~ 15min, be finally placed in again in modification liquid and take out standby after 25 ~ 30min of immersion treatment；Each composition in the modification liquid
Percentage by weight be：3 ~ 4% titanate coupling agents, 1.5 ~ 3% polyethylene glycol, 2 ~ 4% methyl methacrylates, 4 ~ 6% hexadecanes
Base benzene sulfonic acid sodium salt, 1 ~ 2% glycerine, 2 ~ 4% polyvinylpyrrolidones, balance of water；
（3）By step（2）Natural colour sand, sliver, blacklead silica after treatment and medical stone mixing, first take its gross mass 92 ~
95%, granular size is made after being crushed for 100 ~ 200 mesh are standby, be made after residual mass is crushed granular size for 500 ~
600 mesh are standby, mixed powder obtained after finally both are mixed standby；
（4）By nano zircite and step（3）The mixed powder of gained is well mixed to obtain final product aggregate.
A kind of preparation method of the true mineral varnish of high-quality, comprises the following steps：
（1）First coalescents, defoamer, dispersant, thickener, curing agent, ultra-violet absorber, propane diols, water are thrown jointly
It is put into agitator tank, it is standby after being stirred with 550 ~ 600 revs/min of rotating speed；
（2）Silicone acrylic emulsion is added to step（1）In agitator tank after treatment, speed of agitator is lifted to 700 ~ 750 revs/min,
It is standby after stirring；
（3）It is 60 ~ 90 μm that segment controls the length of crystal whisker of hexa potassium titanate gross mass 80 ~ 85%, the length of residuals weight is controlled to 1 ~
30 μm, step is then added to together with aggregate（2）In agitator tank after treatment, lifting speed of agitator is to 1000 ~ 1100 revs/min
Clock, appropriate adjustment viscosity after stirring.
The present invention has the advantages that：
The present invention has been carried out at rational improvement for the common use problem of existing true mineral varnish to its composition and preparation method
Reason, wherein blacklead silica, medical stone and nano zircite are with the addition of on the basis of traditional natural colour sand, sliver aggregate, effectively
Aggregate overall heatproof, corrosion resistant, water-proofing performance are improved, after being processed its surface with modification liquid, dispersion is effectively improved
Property and the compatibility with the composition such as emulsion, improve overall stability, in the preparation carry out rationally aggregate main component
Granular size classification treatment, beneficial to lifting mobility and paint vehicle film forming compactness, further improve performance；Addition
Crystal whisker of hexa potassium titanate can effectively strengthen crosslinking bond strength between each component, position, improve overall water-fast, impact resistance etc.
Performance, the classification treatment carried out to crystal whisker of hexa potassium titanate length further enhancing its filling effect.Finally in each material, method
Common mating reaction under, the obtained true mineral varnish of the present invention has heatproof, water-fast, corrosion resistant, impact resistance strong, film forming rate of drying
Hurry up, drop amount is small, the phenomenon such as be less prone to colour fading, turn white, come off, stability is strong, the characteristics of integrated quality is high, there is good city
Field competitiveness.
Specific embodiment
Embodiment 1
A kind of true mineral varnish of high-quality, is made up of the material of following weight portion：
11 parts of silicone acrylic emulsions, 1 part of coalescents, 0.2 part of defoamer, 1 part of dispersant, 0.5 part of thickener, 0.2 part of curing agent,
0.1 part of ultra-violet absorber, 0.3 part of propane diols, 63 parts of aggregates, 0.5 part of crystal whisker of hexa potassium titanate, 14 parts of water；Described aggregate by
The material of following weight portion is made：90 parts of natural colour sands, 0.5 part of sliver, 0.2 part of blacklead silica, 1 part of medical stone, 0.3 part of nanometer
Zirconium oxide.
Further, the coalescents are propandiol butyl ether.
Further, the defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether.
Further, the dispersant is calgon.
Further, the thickener is Sodium Polyacrylate.
Further, the curing agent is vinyl triamine.
Further, the ultra-violet absorber is Ultraviolet Absorber UV-P.
Further, the aggregate processing method comprises the following steps：
（1）First fully rinse standby after clean impurity to natural colour sand, sliver, blacklead silica, medical stone with clear water；
（2）By step（1）Natural colour sand, sliver, blacklead silica and medical stone after treatment are put into the phosphorus that mass fraction is 3.5%
Taken out after immersion treatment 12min in acid solution, then be placed in immersion treatment 14min in the sodium hydroxide solution that mass fraction is 5.5%
After take out, be finally placed in again in modification liquid and take out standby after immersion treatment 28min；The weight percent of each composition in the modification liquid
Than for：3.5% titanate coupling agent, 2.5% polyethylene glycol, 3% methyl methacrylate, 5% cetyl benzenesulfonic acid sodium, 1.5% the third
Triol, 3% polyvinylpyrrolidone, balance of water；
（3）By step（2）Natural colour sand, sliver, blacklead silica and medical stone mixing after treatment, first takes the 94% of its gross mass,
Granular size is made after being crushed for 100 ~ 200 mesh are standby, granular size is made after residual mass is crushed for 500 ~ 600 mesh
It is standby, mixed powder is obtained after finally both are mixed standby；
（4）By nano zircite and step（3）The mixed powder of gained is well mixed to obtain final product aggregate.
A kind of preparation method of the true mineral varnish of high-quality, comprises the following steps：
（1）First coalescents, defoamer, dispersant, thickener, curing agent, ultra-violet absorber, propane diols, water are thrown jointly
It is put into agitator tank, it is standby after being stirred with 580 revs/min of rotating speed；
（2）Silicone acrylic emulsion is added to step（1）In agitator tank after treatment, lifting speed of agitator is stirred to 720 revs/min
It is standby after uniform；
（3）It is 60 ~ 90 μm that segment controls the length of crystal whisker of hexa potassium titanate gross mass 83%, and the length of residuals weight is controlled to 1 ~ 30 μ
M, is then added to step together with aggregate（2）In agitator tank after treatment, lifting speed of agitator is stirred to 1050 revs/min
Appropriate adjustment viscosity after uniform.
Embodiment 2
A kind of true mineral varnish of high-quality, is made up of the material of following weight portion：
13 parts of silicone acrylic emulsions, 1.2 parts of coalescents, 0.25 part of defoamer, 1.3 parts of dispersants, 0.8 part of thickener, 0.3 part of solidification
Agent, 0.15 part of ultra-violet absorber, 0.4 part of propane diols, 65 parts of aggregates, 1 part of crystal whisker of hexa potassium titanate, 15 parts of water；Described aggregate
It is made up of the material of following weight portion：95 parts of natural colour sands, 0.7 portion of sliver, 0.3 part of blacklead silica, 1.2 parts of medical stones, 0.4 part
Nano zircite.Remaining method and step is with embodiment 1.
Embodiment 3
A kind of true mineral varnish of high-quality, is made up of the material of following weight portion：
14 parts of silicone acrylic emulsions, 1.5 parts of coalescents, 0.3 part of defoamer, 1.5 parts of dispersants, 1 part of thickener, 0.4 part of curing agent,
0.2 part of ultra-violet absorber, 0.5 part of propane diols, 68 parts of aggregates, 1.5 parts of crystal whisker of hexa potassium titanate, 16 parts of water；Described aggregate by
The material of following weight portion is made：100 parts of natural colour sands, 1 portion of sliver, 0.4 part of blacklead silica, 1.5 parts of medical stones, 0.5 part receive
Rice zirconium oxide.Remaining method and step is with embodiment 1.
Comparative example 1
This comparative example 1 compared with Example 1, does not contain crystal whisker of hexa potassium titanate in its composition, method and step in addition is equal
It is identical.
Comparative example 2
This comparative example 2 is compared with Example 2, complete by natural colour sand, sliver, blacklead silica and medical stone when aggregate is prepared
Portion crushes and is made granular size for 100 ~ 200 mesh, and it is 60 ~ 90 μm, side in addition to control all of crystal whisker of hexa potassium titanate length
Method step all same.
Control group
Existing commercially available true mineral varnish.
In order to contrast effect of the present invention, Quality Detection is carried out to true mineral varnish obtained in above-mentioned several ways, specifically contrast number
According to as shown in table 1 below：
Table 1
By upper table 1 as can be seen that the obtained true mineral varnish combination property of the present invention is preferable, use value is higher.
Claims (10)
1. the true mineral varnish of a kind of high-quality, it is characterised in that be made up of the material of following weight portion：
11 ~ 14 parts of silicone acrylic emulsions, 1 ~ 1.5 part of coalescents, 0.2 ~ 0.3 part of defoamer, 1 ~ 1.5 part of dispersant, 0.5 ~ 1 part of thickening
Agent, 0.2 ~ 0.4 part of curing agent, 0.1 ~ 0.2 part of ultra-violet absorber, 0.3 ~ 0.5 part of propane diols, 63 ~ 68 parts of aggregates, 0.5 ~ 1.5
Part crystal whisker of hexa potassium titanate, 14 ~ 16 parts of water；Described aggregate is made up of the material of following weight portion：90 ~ 100 parts of natural colour sands,
0.5 ~ 1 part of sliver, 0.2 ~ 0.4 part of blacklead silica, 1 ~ 1.5 part of medical stone, 0.3 ~ 0.5 part of nano zircite.
2. the true mineral varnish of a kind of high-quality according to claim 1, it is characterised in that be made up of the material of following weight portion：
13 parts of silicone acrylic emulsions, 1.2 parts of coalescents, 0.25 part of defoamer, 1.3 parts of dispersants, 0.8 part of thickener, 0.3 part of solidification
Agent, 0.15 part of ultra-violet absorber, 0.4 part of propane diols, 65 parts of aggregates, 1 part of crystal whisker of hexa potassium titanate, 15 parts of water；Described aggregate
It is made up of the material of following weight portion：95 parts of natural colour sands, 0.7 portion of sliver, 0.3 part of blacklead silica, 1.2 parts of medical stones, 0.4 part
Nano zircite.
3. the true mineral varnish of a kind of high-quality according to claim 1 and 2, it is characterised in that the coalescents are propane diols
One kind in butyl ether, propylene glycol methyl ether acetate.
4. the true mineral varnish of a kind of high-quality according to claim 1 and 2, it is characterised in that the defoamer is polyoxyethylene
One kind in polyoxy propyl alcohol amidogen ether, polypropylene glycerol aether.
5. the true mineral varnish of a kind of high-quality according to claim 1 and 2, it is characterised in that the dispersant is hexa metaphosphoric acid
One kind in sodium, sodium pyrophosphate.
6. the true mineral varnish of a kind of high-quality according to claim 1 and 2, it is characterised in that the thickener is polyacrylic acid
One kind in sodium, sodium carboxymethylcellulose.
7. the true mineral varnish of a kind of high-quality according to claim 1 and 2, it is characterised in that the curing agent is vinyl three
One kind in amine, triethylene tetramine.
8. the true mineral varnish of a kind of high-quality according to claim 1 and 2, it is characterised in that the ultra-violet absorber is purple
One kind in ultraviolet absorbers UV-P, ultra-violet absorber UV-O.
9. a kind of true mineral varnish of high-quality according to claim 1 and 2, it is characterised in that the aggregate processing method bag
Include following steps：
（1）First fully rinse standby after clean impurity to natural colour sand, sliver, blacklead silica, medical stone with clear water；
（2）By step（1）Natural colour sand, sliver, blacklead silica and medical stone after treatment are put into the phosphorus that mass fraction is 3 ~ 4%
Taken out after 10 ~ 13min of immersion treatment in acid solution, then be placed in immersion treatment 13 in the sodium hydroxide solution that mass fraction is 5 ~ 6%
Taken out after ~ 15min, be finally placed in again in modification liquid and take out standby after 25 ~ 30min of immersion treatment；Each composition in the modification liquid
Percentage by weight be：3 ~ 4% titanate coupling agents, 1.5 ~ 3% polyethylene glycol, 2 ~ 4% methyl methacrylates, 4 ~ 6% hexadecanes
Base benzene sulfonic acid sodium salt, 1 ~ 2% glycerine, 2 ~ 4% polyvinylpyrrolidones, balance of water；
（3）By step（2）Natural colour sand, sliver, blacklead silica after treatment and medical stone mixing, first take its gross mass 92 ~
95%, granular size is made after being crushed for 100 ~ 200 mesh are standby, be made after residual mass is crushed granular size for 500 ~
600 mesh are standby, mixed powder obtained after finally both are mixed standby；
（4）By nano zircite and step（3）The mixed powder of gained is well mixed to obtain final product aggregate.
10. a kind of preparation method of the true mineral varnish of high-quality as claimed in claim 1 or 2, it is characterised in that including following step
Suddenly：
（1）First coalescents, defoamer, dispersant, thickener, curing agent, ultra-violet absorber, propane diols, water are thrown jointly
It is put into agitator tank, it is standby after being stirred with 550 ~ 600 revs/min of rotating speed；
（2）Silicone acrylic emulsion is added to step（1）In agitator tank after treatment, speed of agitator is lifted to 700 ~ 750 revs/min,
It is standby after stirring；
（3）It is 60 ~ 90 μm that segment controls the length of crystal whisker of hexa potassium titanate gross mass 80 ~ 85%, the length of residuals weight is controlled to 1 ~
30 μm, step is then added to together with aggregate（2）In agitator tank after treatment, lifting speed of agitator is to 1000 ~ 1100 revs/min
Clock, appropriate adjustment viscosity after stirring.
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| CN201710006353.6A CN106830753A (en) | 2017-01-05 | 2017-01-05 | A kind of true mineral varnish of high-quality and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107652813A (en) * | 2017-09-26 | 2018-02-02 | 安徽喜宝高分子材料有限公司 | A kind of preparation method for being not easy the true mineral varnish of drop |
| CN109750807A (en) * | 2018-11-29 | 2019-05-14 | 宁波华宝石节能科技股份有限公司 | Sandstone metope and its construction method |
| CN111234675A (en) * | 2020-04-02 | 2020-06-05 | 湖南漆雕氏制造股份有限公司 | Reflective heat insulation type heat preservation stone-like coating base material |
| CN111925484A (en) * | 2020-07-01 | 2020-11-13 | 新乡市世暨涂料有限公司 | Partially crosslinked copolymer type anti-flying sand agent for stone-like paint and preparation method thereof |
| CN114292557A (en) * | 2021-12-29 | 2022-04-08 | 亚士漆(上海)有限公司 | Finishing-free real stone paint and preparation method and application thereof |
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| CN101250377A (en) * | 2008-03-04 | 2008-08-27 | 杭州森乐士涂料有限公司 | Granite stone paint and preparation method thereof |
| CN102617071A (en) * | 2012-03-23 | 2012-08-01 | 尚怀兴 | High-gloss real stone lacquer and marble simulation lacquer |
| CN103740177A (en) * | 2013-12-06 | 2014-04-23 | 青岛益群漆业集团有限公司 | Development of super weather-proof marble coating rock slice paint |
| CN105400342A (en) * | 2015-11-27 | 2016-03-16 | 宁波双人新材料有限公司 | Functional really stone paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250377A (en) * | 2008-03-04 | 2008-08-27 | 杭州森乐士涂料有限公司 | Granite stone paint and preparation method thereof |
| CN102617071A (en) * | 2012-03-23 | 2012-08-01 | 尚怀兴 | High-gloss real stone lacquer and marble simulation lacquer |
| CN103740177A (en) * | 2013-12-06 | 2014-04-23 | 青岛益群漆业集团有限公司 | Development of super weather-proof marble coating rock slice paint |
| CN105400342A (en) * | 2015-11-27 | 2016-03-16 | 宁波双人新材料有限公司 | Functional really stone paint and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107652813A (en) * | 2017-09-26 | 2018-02-02 | 安徽喜宝高分子材料有限公司 | A kind of preparation method for being not easy the true mineral varnish of drop |
| CN109750807A (en) * | 2018-11-29 | 2019-05-14 | 宁波华宝石节能科技股份有限公司 | Sandstone metope and its construction method |
| CN111234675A (en) * | 2020-04-02 | 2020-06-05 | 湖南漆雕氏制造股份有限公司 | Reflective heat insulation type heat preservation stone-like coating base material |
| CN111925484A (en) * | 2020-07-01 | 2020-11-13 | 新乡市世暨涂料有限公司 | Partially crosslinked copolymer type anti-flying sand agent for stone-like paint and preparation method thereof |
| CN114292557A (en) * | 2021-12-29 | 2022-04-08 | 亚士漆(上海)有限公司 | Finishing-free real stone paint and preparation method and application thereof |
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Application publication date: 20170613 |