CN101250377A - Granite stone paint and preparation method thereof - Google Patents
Granite stone paint and preparation method thereof Download PDFInfo
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- CN101250377A CN101250377A CNA2008100600861A CN200810060086A CN101250377A CN 101250377 A CN101250377 A CN 101250377A CN A2008100600861 A CNA2008100600861 A CN A2008100600861A CN 200810060086 A CN200810060086 A CN 200810060086A CN 101250377 A CN101250377 A CN 101250377A
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Abstract
The invention relates to a granite mineral varnish, which is prepared by raw material according to the following percentage by weight, water-based resin 10-25 parts, film forming additive 1-3 parts, propylene glycol 0.5-2 parts, mildew preventive 0.1-0.5 parts, defoaming agent 0.1-0.3 parts, color quartz sand 60-80 parts, color compound rock slices 8-30 parts and thickening agent 0.5-2 parts. The process for preparing the granite mineral varnish of the invention comprises the following steps: adding water-based resin, film forming additive, propylene glycol, mildew preventive, defoaming agent and thickening agent into a dispensing tank according to proposition, adding color quartz sand after evenly stirring, and then evenly stirring, adding color compound rock slices, and obtaining granite mineral varnish end products after evenly stirring. The granite mineral varnish has the advantages that first, excellent simulation effect, no matter near viewing or remote viewing, textures are lively, which has no difference with natural granite mineral varnish, second, excellent anti-fouling performance, third, big binding strength, fourth, excellent artificial aging (more than 800h), fifth, simple construction, only single-gun single-hole is needed, and the single gun is colorful.
Description
Technical field
The present invention relates to the chemical building material field, mainly is a kind of grouan mineral varnish and preparation method.
Background technology
Popular grouan mineral varnish has following shortcoming on the market: 1., only should see closely that sight far away then is difficult to allow the people feel that clear and definite real stone feeling feels, particularly the effect of sliver and texture.2., difficulty of construction is big, easily spraying decoration; 3., prescription is unreasonable, easily contaminated, snappiness is poor.
Summary of the invention
The present invention will solve the defective of above-mentioned prior art, and a kind of adhesion, non-fading grouan mineral varnish and preparation method are provided.
The present invention solves the technical scheme that its technical problem adopts.This grouan mineral varnish is made by the combination of following weight proportion raw material: water-base resin 10-25 part, film coalescence aid 1-3 part, propylene glycol 0.5-2 part, mould inhibitor 0.1-0.5 part, defoamer 0.1-0.3 part, colorful quartz sands 60-80 part, colored compound sliver 8-30 part, thickening material 0.5-2 part.
The combination of the compound sliver following weight of described colour proportion raw material is made: water-base resin 60-65 part, film coalescence aid 5-8 part, natural ore powder 30-35 part, mill base 1-2 part, propylene glycol 3-5 part.
Described water-base resin comprises a kind of of organic organosilicon crylic acid latex, pure-acrylic emulsion, water-borne acrylic resin or water-base fluorocarbon emulsion or several combination arbitrarily.
Described film coalescence aid comprises 2,2,4-trimethylammonium-1, the combination of 3-pentanediol mono isobutyrate or phenylcarbinol a kind of or two kinds.
The preparation method of this grouan mineral varnish of the present invention, water-base resin, film coalescence aid, propylene glycol, mould inhibitor, defoamer and thickening material are added mixer by proportioning, back adding colorful quartz sands stirs, restir is even, be added into colored compound sliver, stirring is granite and paints product.
Preparation method's step of described colorful quartz sands is as follows:
(1), with above-mentioned each raw material by the prescription add mixer successively, carry out filtration treatment after dispersed with stirring mixes;
(2), with carrying out oven dry processing first time behind the spraying machine spraying slabbing thing, temperature is controlled between 50 ℃-120 ℃;
(3), will spray flap after the oven dry and soak in solvent and more than at least five minutes, carry out oven dry processing second time after the infiltration, temperature is controlled between 50 ℃-120 ℃; Described solvent comprises methyl-silicone oil, dimethyl silicone oil, amido silicon oil, white oil, diesel oil, kerosene, 200# solvent oil, 120# solvent oil, N-BUTYL ACETATE, vinyl acetic monomer, pimelinketone, acetone, propylene glycol butyl ether or Diethylene Glycol butyl ether.
(4), be ground into big or small irregular fragment, after screening, be finished product with pulverizer.
The effect that the present invention is useful is: a, simulated effect are good, no matter closely see and far away the sight, and texture is true to nature to be as good as with natural granite stone; B, antifouling property are good; C, cohesive strength are big; D, more than the artificial ageing resistance good (800h); E, construction simply only need single rifle single hole spraying and single rifle colorful.
Embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only to be used to the present invention is described and be not used in and limit the scope of the invention.
This grouan mineral varnish is made by the combination of following weight proportion raw material: water-base resin 10-25 part, film coalescence aid 1-3 part, propylene glycol 0.5-2 part, mould inhibitor 0.1-0.5 part, defoamer 0.1-0.3 part, colorful quartz sands 60-80 part, colored compound sliver 8-30 part, thickening material 0.5-2 part.Wherein mould inhibitor, defoamer and thickening material are auxiliary agent commonly used, adopt Hangzhou rather to cause the product of synthetic materials company.
The combination of the compound sliver following weight of described colour proportion raw material is made: water-base resin 60-65 part, film coalescence aid 5-8 part, natural ore powder 30-35 part, mill base 1-2 part, propylene glycol 3-5 part; Natural ore powder itself is coloured, can add mill base 1-2 part according to client's needs and regulate color; Can also add and be used for antifreeze propylene glycol 3-5 part.
Described water-base resin comprises a kind of of organic organosilicon crylic acid latex, pure-acrylic emulsion, water-borne acrylic resin or water-base fluorocarbon emulsion or several combination arbitrarily; By weight 1-2: 1-2 preparation, when making up, the three prepares during the two combination by weight 1-2: 1-2: 1-2; Four when making up by weight 1-2: 1-2: 1-2: preparation in 1: 2.Described film coalescence aid comprises 2,2,4-trimethylammonium-1, the combination of 3-pentanediol mono isobutyrate or phenylcarbinol a kind of or two kinds, during the two combination by weight 1-2: 1-2 preparation.
The preparation method of this grouan mineral varnish, water-base resin, film coalescence aid, propylene glycol, mould inhibitor, defoamer and thickening material are added mixer by proportioning, and the back that stirs adds colorful quartz sands, and restir is even, be added into colored compound sliver, stirring is granite and paints product.
Preparation method's step of described colorful quartz sands is as follows:
(1), with above-mentioned each raw material by the prescription add mixer successively, carry out filtration treatment after dispersed with stirring mixes;
(2), with carrying out oven dry processing first time behind the spraying machine spraying slabbing thing, temperature is controlled between 50 ℃-120 ℃;
(3), will spray flap after the oven dry and soak in solvent and more than at least five minutes, carry out oven dry processing second time after the infiltration, temperature is controlled between 50 ℃-120 ℃; Described solvent comprises methyl-silicone oil, dimethyl silicone oil, amido silicon oil, white oil, diesel oil, kerosene, 200# solvent oil, 120# solvent oil, N-BUTYL ACETATE, vinyl acetic monomer, pimelinketone, acetone, propylene glycol butyl ether or Diethylene Glycol butyl ether.
(4), be ground into big or small irregular fragment, after screening, be finished product with pulverizer.
Embodiment 1: this grouan mineral varnish, make by the combination of following weight proportion raw material: 10 parts of water-base resins, 1 part of film coalescence aid, 0.5 part of propylene glycol, 0.1 part of mould inhibitor, 0.1 part of defoamer, 60 parts of colorful quartz sands, 8 parts of colored compound slivers, 0.5 part of thickening material.Wherein colored compound sliver is made by the combination of following weight proportion raw material: 60 parts of water-base resins, 6 parts of film coalescence aid, 30 parts of natural ore powders, 1 part of mill base, 3 parts of propylene glycol; Described water-base resin comprises two kinds combination of organic organosilicon crylic acid latex, pure-acrylic emulsion, water-borne acrylic resin or water-base fluorocarbon emulsion; Prepared by weight 1: 1 during the two combination; Film coalescence aid adopts 2,2,4-trimethylammonium-1, and 3-pentanediol mono isobutyrate and phenylcarbinol, the two was by weight preparation in 2: 1; Solvent during infiltration adopts kerosene.
Embodiment 2: this grouan mineral varnish, make by the combination of following weight proportion raw material: 25 parts of water-base resins, 3 parts of film coalescence aid, 2 parts of propylene glycol, 0.5 part of mould inhibitor, 0.3 part of defoamer, 80 parts of colorful quartz sands, 30 parts of colored compound slivers, 2 parts of thickening materials.Wherein colored compound sliver is made by the combination of following weight proportion raw material: 65 parts of water-base resins, 8 parts of film coalescence aid, 35 parts of natural ore powders, 2 parts of mill bases, 5 parts of propylene glycol, described water-base resin comprise three kinds combination of organic organosilicon crylic acid latex, pure-acrylic emulsion, water-borne acrylic resin or water-base fluorocarbon emulsion; When making up, the three prepares by weight 1-2: 1-2: 1-2; Film coalescence aid adopts 2,2,4-trimethylammonium-1, and the 3-pentanediol mono isobutyrate, the solvent during infiltration adopts the 200# solvent oil.
Embodiment 3: this grouan mineral varnish, make by the combination of following weight proportion raw material: 20 parts of water-base resins, 1 part of film coalescence aid, 0.5 part of propylene glycol, 0.2 part of mould inhibitor, 0.1 part of defoamer, 70 parts of colorful quartz sands, 15 parts of colored compound slivers, 0.55 part of thickening material.Wherein colored compound sliver is made by the combination of following weight proportion raw material: 60 parts of water-base resins, 6 parts of film coalescence aid, 30 parts of natural ore powders, 2 parts of mill bases, 4 parts of propylene glycol; Wherein water-base resin adopts water-borne acrylic resin, and film coalescence aid adopts 2,2,4-trimethylammonium-1, and the 3-pentanediol mono isobutyrate, the solvent during infiltration adopts N-BUTYL ACETATE.
Embodiment 4: difference from Example 1, and wherein water-base resin adopts pure-acrylic emulsion, and film coalescence aid adopts phenylcarbinol, and the solvent during infiltration adopts dimethyl silicone oil.
Embodiment 5: difference from Example 2, and wherein water-base resin adopts pure-acrylic emulsion, and film coalescence aid adopts phenylcarbinol, and the solvent during infiltration adopts dimethyl silicone oil.Wherein water-base resin adopts the organosilicon acrylic emulsion, and film coalescence aid adopts 2,2,4-trimethylammonium-1, and the 3-pentanediol mono isobutyrate, the solvent during infiltration adopts methyl-silicone oil.
Embodiment 6: difference from Example 3, and wherein water-base resin adopts water-borne acrylic resin, and film coalescence aid adopts 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate and phenylcarbinol, the two was by weight preparation in 1: 1; Solvent during infiltration adopts white oil.
Embodiment 7: difference from Example 4, and wherein water-base resin adopts water-base fluorocarbon emulsion, and film coalescence aid adopts 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate and phenylcarbinol, the two was by weight preparation in 1: 2; Solvent during infiltration adopts diesel oil.
Embodiment 8: difference from Example 5, described water-base resin comprise four kinds combination of organic organosilicon crylic acid latex, pure-acrylic emulsion, water-borne acrylic resin or water-base fluorocarbon emulsion; Four when making up by weight 1-2: 1-2: 1-2: 1-2 preparation; Solvent during infiltration adopts the 120# solvent oil.
Embodiment 9: difference from Example 1, the solvent during infiltration adopts vinyl acetic monomer.
Embodiment 10: difference from Example 2, the solvent during infiltration adopts pimelinketone.
Embodiment 11: difference from Example 3, the solvent during infiltration adopts acetone.
Embodiment 12: difference from Example 4, the solvent during infiltration adopts the propylene glycol butyl ether.
Embodiment 13: difference from Example 5, the solvent during infiltration adopts the Diethylene Glycol butyl ether.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of requirement of the present invention.
Claims (7)
1, a kind of grouan mineral varnish is characterized in that: made by the combination of following weight proportion raw material:
Water-base resin 10-25 part, film coalescence aid 1-3 part, propylene glycol 0.5-2 part, mould inhibitor 0.1-0.5 part, defoamer 0.1-0.3 part, colorful quartz sands 60-80 part, colored compound sliver 8-30 part, thickening material 0.5-2 part.
2, grouan mineral varnish according to claim 1, it is characterized in that: the combination of the compound sliver following weight of described colour proportion raw material is made: water-base resin 60-65 part, film coalescence aid 5-8 part, natural ore powder 30-35 part, mill base 1-2 part, propylene glycol 3-5 part.
3, grouan mineral varnish according to claim 1 and 2 is characterized in that: described water-base resin comprises a kind of of organic organosilicon crylic acid latex, pure-acrylic emulsion, water-borne acrylic resin or water-base fluorocarbon emulsion or several combination arbitrarily.
4, grouan mineral varnish according to claim 1 and 2, it is characterized in that: described film coalescence aid comprises 2,2,4-trimethylammonium-1, the combination of 3-pentanediol mono isobutyrate or phenylcarbinol a kind of or two kinds.
5, a kind of preparation method of grouan mineral varnish according to claim 1, it is characterized in that: water-base resin, film coalescence aid, propylene glycol, mould inhibitor, defoamer and thickening material are added mixer by proportioning, back adding colorful quartz sands stirs, restir is even, be added into colored compound sliver, stirring is granite and paints product.
6, the preparation method of grouan mineral varnish according to claim 6 is characterized in that: preparation method's step of described colorful quartz sands is as follows:
(1), with above-mentioned each raw material by the prescription add mixer successively, carry out filtration treatment after dispersed with stirring mixes;
(2), with carrying out oven dry processing first time behind the spraying machine spraying slabbing thing, temperature is controlled between 50 ℃-120 ℃;
(3), will spray flap after the oven dry and soak in solvent and more than at least five minutes, carry out oven dry processing second time after the infiltration, temperature is controlled between 50 ℃-120 ℃;
(4), be ground into big or small irregular fragment, after screening, be finished product with pulverizer.
7, the preparation method of grouan mineral varnish according to claim 7 is characterized in that: described solvent comprises methyl-silicone oil, dimethyl silicone oil, amido silicon oil, white oil, diesel oil, kerosene, 200# solvent oil, 120# solvent oil, N-BUTYL ACETATE, vinyl acetic monomer, pimelinketone, acetone, propylene glycol butyl ether or Diethylene Glycol butyl ether.
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Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101412602B (en) * | 2008-11-18 | 2010-07-21 | 唐山长虹涂料有限公司 | Stone-intimating construction coating and preparation thereof |
CN102206447A (en) * | 2011-05-16 | 2011-10-05 | 西南科技大学 | Method for preparing glimmerite sheet type granite-imitated lacquer coating |
CN102533038A (en) * | 2011-12-19 | 2012-07-04 | 河南省德嘉丽科技开发有限公司 | Natural stone paint |
CN102558973A (en) * | 2011-12-19 | 2012-07-11 | 河南省德嘉丽科技开发有限公司 | Actual granite imitation coating |
CN102674749A (en) * | 2012-02-17 | 2012-09-19 | 刘娜 | Water-based slate coating, construction process and applications thereof |
CN102747818A (en) * | 2011-04-19 | 2012-10-24 | 台湾澎记工业有限公司 | Emulational granite and manufacturing method thereof |
CN102925021A (en) * | 2012-11-13 | 2013-02-13 | 辽宁啄木鸟漆业发展有限公司 | Negative ion stone-like coatings |
CN103045040A (en) * | 2013-01-07 | 2013-04-17 | 临海市百佳涂料厂(普通合伙) | Natural rock slice paint and preparation method |
CN103131241A (en) * | 2013-02-06 | 2013-06-05 | 江苏润泰化学有限公司 | Film-forming auxiliary agent special for real-stone paint |
CN103980788A (en) * | 2014-05-15 | 2014-08-13 | 江苏科技大学 | Waterborne environment-friendly silicone-acrylic real stone exterior wall coating and preparation method thereof |
CN104031508A (en) * | 2014-06-25 | 2014-09-10 | 中山蓝海洋水性涂料有限公司 | Three-resistance type real stone paint and preparation method thereof |
CN104150811A (en) * | 2014-07-28 | 2014-11-19 | 桐乡市屠甸天虹涂料厂 | Really stone paint composite slice and preparation method thereof |
CN104371466A (en) * | 2014-11-10 | 2015-02-25 | 江西景新漆业有限公司 | Water-based colourful slice coating and preparation method thereof |
CN104402301A (en) * | 2014-11-11 | 2015-03-11 | 黄美忠 | Lightweight pottery sand stone-like paint and preparation method thereof |
CN105038601A (en) * | 2015-08-31 | 2015-11-11 | 贵州耐尔福顺成建材有限公司 | Rock slice paint and production method thereof |
CN105419542A (en) * | 2015-12-31 | 2016-03-23 | 青建集团股份公司 | Aqueous marble-imitated colorful paint and preparation construction method therefor |
CN105440827A (en) * | 2015-12-28 | 2016-03-30 | 杭州名匠建筑装饰工程有限公司 | Water-based normal-temperature-curing fluorine-silicon composite texture paint |
CN106830753A (en) * | 2017-01-05 | 2017-06-13 | 安徽柏瑞特家居装饰品有限公司 | A kind of true mineral varnish of high-quality and preparation method thereof |
CN110551431A (en) * | 2019-08-28 | 2019-12-10 | 北京莱恩斯新材料科技有限公司 | ultrathin composite rock slice stone-like paint and preparation method and application thereof |
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2008
- 2008-03-04 CN CNA2008100600861A patent/CN101250377A/en active Pending
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101412602B (en) * | 2008-11-18 | 2010-07-21 | 唐山长虹涂料有限公司 | Stone-intimating construction coating and preparation thereof |
CN102747818A (en) * | 2011-04-19 | 2012-10-24 | 台湾澎记工业有限公司 | Emulational granite and manufacturing method thereof |
CN102206447A (en) * | 2011-05-16 | 2011-10-05 | 西南科技大学 | Method for preparing glimmerite sheet type granite-imitated lacquer coating |
CN102206447B (en) * | 2011-05-16 | 2013-08-21 | 西南科技大学 | Method for preparing glimmerite sheet type granite-imitated lacquer coating |
CN102533038A (en) * | 2011-12-19 | 2012-07-04 | 河南省德嘉丽科技开发有限公司 | Natural stone paint |
CN102558973A (en) * | 2011-12-19 | 2012-07-11 | 河南省德嘉丽科技开发有限公司 | Actual granite imitation coating |
CN102674749A (en) * | 2012-02-17 | 2012-09-19 | 刘娜 | Water-based slate coating, construction process and applications thereof |
CN102925021A (en) * | 2012-11-13 | 2013-02-13 | 辽宁啄木鸟漆业发展有限公司 | Negative ion stone-like coatings |
CN103045040A (en) * | 2013-01-07 | 2013-04-17 | 临海市百佳涂料厂(普通合伙) | Natural rock slice paint and preparation method |
CN103131241A (en) * | 2013-02-06 | 2013-06-05 | 江苏润泰化学有限公司 | Film-forming auxiliary agent special for real-stone paint |
CN103980788A (en) * | 2014-05-15 | 2014-08-13 | 江苏科技大学 | Waterborne environment-friendly silicone-acrylic real stone exterior wall coating and preparation method thereof |
CN103980788B (en) * | 2014-05-15 | 2016-02-17 | 江苏科技大学 | True stone exterior coating of a kind of aqueous environment protection silicon third and preparation method thereof |
CN104031508A (en) * | 2014-06-25 | 2014-09-10 | 中山蓝海洋水性涂料有限公司 | Three-resistance type real stone paint and preparation method thereof |
CN104150811A (en) * | 2014-07-28 | 2014-11-19 | 桐乡市屠甸天虹涂料厂 | Really stone paint composite slice and preparation method thereof |
CN104371466A (en) * | 2014-11-10 | 2015-02-25 | 江西景新漆业有限公司 | Water-based colourful slice coating and preparation method thereof |
CN104402301A (en) * | 2014-11-11 | 2015-03-11 | 黄美忠 | Lightweight pottery sand stone-like paint and preparation method thereof |
CN105038601A (en) * | 2015-08-31 | 2015-11-11 | 贵州耐尔福顺成建材有限公司 | Rock slice paint and production method thereof |
CN105440827A (en) * | 2015-12-28 | 2016-03-30 | 杭州名匠建筑装饰工程有限公司 | Water-based normal-temperature-curing fluorine-silicon composite texture paint |
CN105419542A (en) * | 2015-12-31 | 2016-03-23 | 青建集团股份公司 | Aqueous marble-imitated colorful paint and preparation construction method therefor |
CN106830753A (en) * | 2017-01-05 | 2017-06-13 | 安徽柏瑞特家居装饰品有限公司 | A kind of true mineral varnish of high-quality and preparation method thereof |
CN110551431A (en) * | 2019-08-28 | 2019-12-10 | 北京莱恩斯新材料科技有限公司 | ultrathin composite rock slice stone-like paint and preparation method and application thereof |
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