CN106770541A - A kind of pocket PH combination electrode devices based on ZIGBEE wireless communication technologys - Google Patents
A kind of pocket PH combination electrode devices based on ZIGBEE wireless communication technologys Download PDFInfo
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- CN106770541A CN106770541A CN201611038382.2A CN201611038382A CN106770541A CN 106770541 A CN106770541 A CN 106770541A CN 201611038382 A CN201611038382 A CN 201611038382A CN 106770541 A CN106770541 A CN 106770541A
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/302—Electrodes, e.g. test electrodes; Half-cells pH sensitive, e.g. quinhydron, antimony or hydrogen electrodes
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- G—PHYSICS
- G08—SIGNALLING
- G08C—TRANSMISSION SYSTEMS FOR MEASURED VALUES, CONTROL OR SIMILAR SIGNALS
- G08C17/00—Arrangements for transmitting signals characterised by the use of a wireless electrical link
- G08C17/02—Arrangements for transmitting signals characterised by the use of a wireless electrical link using a radio link
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Abstract
The present invention relates to a kind of pocket PH combination electrode devices based on ZIGBEE wireless communication technologys, including power supply module, central control module, pH value acquisition module, wireless communication module, electrode maintenance module and clear water acquisition module.Wireless communication module includes zigbee modules, and the data that pH value acquisition module is collected are wirelessly transmitted to control room by the module；Electrode maintains module, including KCL supplements liquid container 21, turbidity transducer 7, KCL standard samples liquid pool 8, dredge pump 9 with electromagnetic valve, turbidity transducer 7 is used to detect the contaminated degree of standard sample liquid in KCL standard samples liquid pool 8, Central Control Module is when turbidity reaches threshold value, control of sewage disposal water pump 9 works, waste liquid in discharge KCL standard samples liquid pool 8, the electromagnetic valve positioned at KCL supplement liquid containers 21 bottom of the top of KCL standard samples liquid pool 8 is opened, and discharges KCL replenishers；The present invention can be with long term monitoring large mass of water.
Description
Technical field
The invention is related to pH value of seawater to monitor field, more particularly to the cleaning of PH combination electrodes in device and maintenance.
Background technology
Water is the precious resources of human society, is distributed Yu Haiyang, river, river, the ground that lake and underground water and glacier collectively form
In ball hydrosphere.Seawater accounts for 97.3% in estimating total Water present on the earth, and fresh water only accounts for 2.7%.Water is that the mankind depend on for existence
One of main matter, with the development of growth and the industrial and agricultural production of world population, water consumption also increasingly increasing, and due to
The life and production activity of the mankind, by a large amount of undressed sanitary sewages, industrial wastewater, and other discarded objects are often directly arranged
Enter environment water, cause ocean water pollution.Real-time monitoring to seawater quality can find out the position of polluted water body, so that right
Ocean Polluted water area is cleaned, processed, in order to avoid cause huge economic loss.
It in seawater quality monitoring process is one of most important index that pH value is, meanwhile, seawater quality monitoring is one long
Phase continuous process.In long-term monitoring process, the activity such as collection, transmitting-receiving of data can all consume substantial amounts of electric energy, monitor
The sustainable supply of device energy then faces a huge challenge.If also, existing PH combination electrodes are immersed in for a long time
In seawater, electrode front glass ball bubble surface easily by the impurity covering in seawater, blocks hydrogen ion passage, can influence to seawater
The accuracy of pH value data acquisition.Meanwhile, the PH information that traditional PH combination electrodes are collected is both needed to reach master by wired mode
Machine, reduces and uses flexibility ratio.
Existing PH combination electrodes such as are both needed to manually to be cleaned, maintain at the operation, expense when being accomplished manually the operating cost after
Power.The monitoring process of seawater quality can be brought inconvenience.And the data of seawater quality have extremely strong ageing, monitoring personnel is obtained
To time of seawater data, The faster the better.The data volume of ZigBee technology transmission is smaller, with low in energy consumption, low cost, time delay
It is short to wait good characteristic so that the working time of whole device is longer, is conducive to the long term monitoring to seawater quality.With regard to this apparently,
One kind leans on ZigBee real-time Data Transmissions, and PH that is easy to carry, can repeatedly charging and possess automatic cleaning and maintenance function is combined
Electrode assembly is particularly important.
The content of the invention
It is an object of the invention to provide a kind of easy to carry, PH that can repeatedly charge and possess automatic cleaning and maintenance function
Combination electrode device, to meet under marine environment the need for water quality long term monitoring.Technical scheme is as follows：
A kind of pocket PH combination electrode devices based on ZIGBEE wireless communication technologys, including power supply module, center control
Molding block, pH value acquisition module, wireless communication module, electrode maintenance module and clear water acquisition module, wherein,
PH value acquisition module include mechanical arm 1, be fixed on the front end of mechanical arm 1 PH combination electrodes 22, solution pool to be measured 12,
Sample introduction water pump 11, stock layout water pump 10, flush water pump 19, wherein, sample introduction water pump 11 is used to for seawater to be pumped into solution pool to be measured 12,
Stock layout water pump 10 is used for seawater discharge testing liquid pond 12；Mechanical arm 1 is used to for PH combination electrodes 22 to be placed in testing liquid pond
In 12 or raised, PH combination electrodes 22 measure pH value and transmit to central control module, under the control of central control module,
Clear water is aspirated in flush water pump suction and the PH combination electrodes 22 to raising are cleaned, and is moved through the PH combination electrodes 22 of over cleaning
Into the KCL standard samples liquid pool 8 of electrode maintenance module；
Wireless communication module includes zigbee modules, and the data that pH value acquisition module is collected are wirelessly transferred by the module
To control room；
Electrode maintains module, including the supplements of the KCL with electromagnetic valve liquid container 21, turbidity transducer 7, KCL standard samples
Liquid pool 8, dredge pump 9, turbidity transducer 7 are used to detect the contaminated degree of standard sample liquid in KCL standard samples liquid pool 8, center
When turbidity reaches threshold value, control of sewage disposal water pump 9 works control module, waste liquid in discharge KCL standard samples liquid pool 8, positioned at KCL marks
The electromagnetic valve of KCL supplement liquid containers 21 bottom of the top of quasi- sample liquid pond 8 is opened, and discharges KCL replenishers；
Clear water acquisition module includes heat conductive silica gel 16, stores seawater pond 17, stores clear water reserviors 18, liquid level gauge 13, intake pump 14, tune
Water saving pump 15 and cold plate 20, intake pump 14 are used for pumping seawater and enter storage seawater pond 17；The main body of heat conductive silica gel 16 is used as storage
The side wall in seawater pond 17, with its maritime interior waters directly contact；Heat conductive silica gel 16 is also connected with solar energy photovoltaic panel 2, for absorbing heat
Amount；The top in storage seawater pond 17 is oblique to be fixed with cold plate 20, and the seawater of evaporation is condensed into liquid by cold plate 20, and will be condensed
Liquid drain enter to store clear water reserviors 18；Liquid level gauge 13 is used to monitor water in storage clear water reserviors 18, and information of its collection is admitted to
Central Control Module, Central Control Module after clear water amount reaches max-thresholds, open, and discharges seawater, no longer by regulation water pump 15
It is evaporated condensation,；When clear water reaches minimum threshold, intake pump 14 works；
Power supply module includes charging inlet 2 and battery 4, by charging inlet 2 for battery 4 charges, it is ensured that whole system
The energy supply of system.
Brief description of the drawings
Fig. 1 is the profile of sensor device casing
Fig. 2 is the detail view that PH combination electrodes are cleaned and maintained
Fig. 3 is the theory diagram of the device
Fig. 4 is the flow chart of overall process
1st, mechanical arm；2nd, charging inlet；3rd, ZigBee communication module；4th, central control module；5th, battery；6th, foam；
7th, turbidity transducer；8th, KCL standard samples liquid pool；9th, 10,11,14,15,19, it is water pump (being not drawn into water pipe)；12nd, prepare liquid
Body pond 13, liquid level gauge；16th, heat conductive silica gel；17th, seawater pond is stored；18th, clear water reserviors are stored；20th, the cold plate that metal is made；21st, carry
The KCL supplement liquid containers of electromagnetic valve；22nd, PH combination electrodes.
Specific embodiment
Fig. 1 is the structural representation of PH combination electrode devices, and one kind is filled energy simplicity and possesses automatic cleaning and maintain work(
The PH combination electrode devices of energy, including power supply module, central control module, pH value acquisition module, wireless communication module, electrode are protected
Support module and clear water acquisition module.Specific embodiment of the invention is further described below in conjunction with accompanying drawing.
Such as Fig. 1, power supply module includes charging inlet 2 and battery 4.By charging inlet 2 for battery 4 charges, it is ensured that
The energy supply of whole system.When need to gather pH value of seawater data, it is carried to marine site to be measured by operation ship, repacking is put into sea
In seawater PH is monitored.After the completion of monitoring resultses, PH combination electrodes device is withdrawn by operation ship, be that device is carried out again
Secondary charging is in case use next time.
As shown in figure 1, pH value acquisition module includes mechanical arm 1, PH combination electrodes 22, solution pool to be measured 12, water pump 10, water
Pump 11, water pump 19.PH combination electrodes 22 are controlled to enter testing liquid pond 12 by mechanical arm 1, and water pump 11 works, and seawater enters to be measured
Liquid cell 12, measures pH value and transmits to central control module 5.Water pump 10 works, and discharges seawater.Mechanical arm 1 is by PH combination electrodes
Raise, water pump 19 works, draw clear water and rinse combination electrode.PH combination electrodes 22 are moved to KCL standard sample liquid pools by mechanical arm 1 again
In 8.Complete the maintenance to PH combination electrodes.
As shown in figure 1, communication module includes ZigBee communication module 3, the module obtains what pH value acquisition module was gathered
After pH value data, the data of collection are sent at monitoring personnel in time.Realize the real-time Data Transmission of pH value of seawater.
It is that electrode maintains module details figure, including supplement liquid container 21, the turbidity sensings of the KCL with electromagnetic valve such as Fig. 2
Device 7, KCL standard samples liquid pool 8, water pump 9.Contain the impurity such as microorganism, algae, industrial wastes in seawater, turbidity transducer 7 can inspection
The contaminated degree of the quasi- sample liquid of mark.When turbidity reaches threshold value, KCL titers have been contaminated, and must change.Water pump 9 works, and discharge is useless
Liquid.The electromagnetic valve of KCL supplement liquid containers 21 bottom is opened, and discharges KCL replenishers.Realize the renewal of KCL titers.
Such as Fig. 1, right side clear water acquisition module include heat conductive silica gel 16, store seawater pond 17, store clear water reserviors 18, liquid level gauge 13,
Water pump 14, water pump 15 and cold plate 20.Water pump 14 works, and seawater enters storage seawater pond 17.Heat conductive silica gel 16 collects the top sun
The heat and conduction that illumination bands are come are met cold plate 20 and are condensed into liquid, because cold plate 20 inclines to seawater pond 17, evaporation of seawater is stored
Tiltedly, with drainage, in the clear water inflow storage clear water reserviors 18 of condensation.Liquid level gauge 13 monitors water, and clear water amount reaches maximum threshold
After value, water pump 15 is opened, and discharges seawater, is no longer evaporated condensation, it is ensured that seawater will not be crystallized and polluted in casing.When clear
Water reaches minimum threshold, and water pump 14 works, and repeats said process.
As shown in figure 3, the device passes through charging inlet for power supply module provides electric energy, central control module control machinery arm
Running, pH value information in marine site to be measured is collected using PH combination electrodes, information is processed by central control module, and store
In data memory module；Data are collected using turbidity transducer and liquid level gauge, central control module analysis KCL standards are uploaded to
Whether sample liquid dustiness and clear water amount reach threshold value, and control water pump and electromagnetic valve to make a response in time, complete clear water
The automatic replacing of automatic data collection and KCL solution, realizes the automatic cleaning and maintenance of PH combination electrode devices.
Claims (1)
1. a kind of pocket PH combination electrode devices based on ZIGBEE wireless communication technologys, including power supply module, center control
Module, pH value acquisition module, wireless communication module, electrode maintenance module and clear water acquisition module.Wherein,
PH value acquisition module includes mechanical arm (1), is fixed on the PH combination electrodes (22), solution pool to be measured of mechanical arm (1) front end
(12), sample introduction water pump (11), stock layout water pump (10), flush water pump (19), wherein, sample introduction water pump (11) is for seawater to be pumped into
Solution pool (12) to be measured, stock layout water pump (10) by seawater for discharging testing liquid pond (12)；Mechanical arm (1) is for PH to be combined
Electrode (22) is placed in testing liquid pond (12) or is raised, and PH combination electrodes (22) measure pH value and transmit to center control mould
Block, under the control of central control module, flush water pump suction is aspirated clear water and the PH combination electrodes (22) to raising and is carried out clearly
Wash, be moved in KCL standard samples liquid pool (8) of electrode maintenance module through the PH combination electrodes (22) of over cleaning；
Wireless communication module includes zigbee modules, and the data that pH value acquisition module is collected are wirelessly transmitted to control by the module
Room processed；
Electrode maintains module, including the KCL with electromagnetic valve supplements liquid container (21), turbidity transducer (7), KCL standard samples
Liquid pool (8), dredge pump (9), turbidity transducer (7) is for detecting the contaminated journey of standard sample liquid in KCL standard samples liquid pool (8)
Degree, Central Control Module when turbidity reaches threshold value, in discharge KCL standard samples liquid pool (8) give up by control of sewage disposal water pump (9) work
Liquid, the electromagnetic valve of KCL supplements liquid container (21) bottom above KCL standard samples liquid pool (8) is opened, release KCL supplements
Liquid；
Clear water acquisition module includes heat conductive silica gel (16), stores seawater pond (17), stores clear water reserviors (18), liquid level gauge (13), intake pump
(14), regulation water pump (15) and cold plate (20), intake pump (14) enter storage seawater pond (17) for pumping seawater；Heat conductive silica gel
(16) main body as store seawater pond (17) side wall, with its maritime interior waters directly contact；Heat conductive silica gel (16) is gone back and solar energy
Volt plate (2) connection, for absorbing heat；The top of storage seawater pond (17) is oblique to be fixed with cold plate (20), and cold plate (20) will
The seawater of evaporation is condensed into liquid, and by the liquid drain of condensation enters to store clear water reserviors (18)；Liquid level gauge (13) stores for monitoring
Clear water reserviors (18) interior water, the information of its collection is admitted to Central Control Module, and Central Control Module reaches maximum in clear water amount
After threshold value, regulation water pump (15) is opened, and discharges seawater, is no longer evaporated condensation,；When clear water reaches minimum threshold, intake pump
(14) work；
Power supply module includes charging inlet (2) and battery (4), by charging inlet (2) for battery (4) charges, it is ensured that whole
The energy supply of individual system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611038382.2A CN106770541A (en) | 2016-11-11 | 2016-11-11 | A kind of pocket PH combination electrode devices based on ZIGBEE wireless communication technologys |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611038382.2A CN106770541A (en) | 2016-11-11 | 2016-11-11 | A kind of pocket PH combination electrode devices based on ZIGBEE wireless communication technologys |
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| CN106770541A true CN106770541A (en) | 2017-05-31 |
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| CN201611038382.2A Pending CN106770541A (en) | 2016-11-11 | 2016-11-11 | A kind of pocket PH combination electrode devices based on ZIGBEE wireless communication technologys |
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010086607A1 (en) * | 2009-01-28 | 2010-08-05 | Biota Guard As | Method of detecting contamination of water using living organisms |
| CN102004142A (en) * | 2010-11-24 | 2011-04-06 | 山东省科学院海洋仪器仪表研究所 | Water quality parameter measuring instrument arranged in super buoy and water quality parameter measuring method |
| GB2504981A (en) * | 2012-08-16 | 2014-02-19 | Natural Enviromental Res Council | Sensing apparatus and method for measuring algal growth |
| CN103951007A (en) * | 2014-04-02 | 2014-07-30 | 苏州市玄天环保科技有限公司 | Solar energy water purifier |
| CN104267167A (en) * | 2014-10-22 | 2015-01-07 | 中山欧麦克仪器设备有限公司 | Device for detecting PH value and other parameters of seawater of deep sea |
| CN204964493U (en) * | 2015-09-30 | 2016-01-13 | 浙江理工大学 | Wireless remote sea water quality of water environment measuring equipment |
| CN105438408A (en) * | 2015-12-29 | 2016-03-30 | 台州市航天恒通科技有限公司 | All-dimensional intelligent detection buoy |
| CN105866372A (en) * | 2016-06-22 | 2016-08-17 | 天津大学 | Ocean water quality real-time monitoring device composed of integrated sensors and communication modules |
| CN106093154A (en) * | 2016-08-04 | 2016-11-09 | 重庆和航科技股份有限公司 | The online remote supervision system of water quality pH value and method |
| CN106093124A (en) * | 2016-06-22 | 2016-11-09 | 天津大学 | A kind of integrated sensor device for ocean water quality long term monitoring |
-
2016
- 2016-11-11 CN CN201611038382.2A patent/CN106770541A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010086607A1 (en) * | 2009-01-28 | 2010-08-05 | Biota Guard As | Method of detecting contamination of water using living organisms |
| CN102004142A (en) * | 2010-11-24 | 2011-04-06 | 山东省科学院海洋仪器仪表研究所 | Water quality parameter measuring instrument arranged in super buoy and water quality parameter measuring method |
| GB2504981A (en) * | 2012-08-16 | 2014-02-19 | Natural Enviromental Res Council | Sensing apparatus and method for measuring algal growth |
| CN103951007A (en) * | 2014-04-02 | 2014-07-30 | 苏州市玄天环保科技有限公司 | Solar energy water purifier |
| CN104267167A (en) * | 2014-10-22 | 2015-01-07 | 中山欧麦克仪器设备有限公司 | Device for detecting PH value and other parameters of seawater of deep sea |
| CN204964493U (en) * | 2015-09-30 | 2016-01-13 | 浙江理工大学 | Wireless remote sea water quality of water environment measuring equipment |
| CN105438408A (en) * | 2015-12-29 | 2016-03-30 | 台州市航天恒通科技有限公司 | All-dimensional intelligent detection buoy |
| CN105866372A (en) * | 2016-06-22 | 2016-08-17 | 天津大学 | Ocean water quality real-time monitoring device composed of integrated sensors and communication modules |
| CN106093124A (en) * | 2016-06-22 | 2016-11-09 | 天津大学 | A kind of integrated sensor device for ocean water quality long term monitoring |
| CN106093154A (en) * | 2016-08-04 | 2016-11-09 | 重庆和航科技股份有限公司 | The online remote supervision system of water quality pH value and method |
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Application publication date: 20170531 |
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