CN106525941A - Bluetooth data transmission type PH combined electrode device with automatic cleaning and maintaining functions - Google Patents
Bluetooth data transmission type PH combined electrode device with automatic cleaning and maintaining functions Download PDFInfo
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- CN106525941A CN106525941A CN201610995807.2A CN201610995807A CN106525941A CN 106525941 A CN106525941 A CN 106525941A CN 201610995807 A CN201610995807 A CN 201610995807A CN 106525941 A CN106525941 A CN 106525941A
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/38—Cleaning of electrodes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N35/00—Automatic analysis not limited to methods or materials provided for in any single one of groups G01N1/00 - G01N33/00; Handling materials therefor
- G01N35/00584—Control arrangements for automatic analysers
- G01N35/0092—Scheduling
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- G—PHYSICS
- G08—SIGNALLING
- G08C—TRANSMISSION SYSTEMS FOR MEASURED VALUES, CONTROL OR SIMILAR SIGNALS
- G08C17/00—Arrangements for transmitting signals characterised by the use of a wireless electrical link
- G08C17/02—Arrangements for transmitting signals characterised by the use of a wireless electrical link using a radio link
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- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02J—CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
- H02J7/00—Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
- H02J7/34—Parallel operation in networks using both storage and other dc sources, e.g. providing buffering
- H02J7/35—Parallel operation in networks using both storage and other dc sources, e.g. providing buffering with light sensitive cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/56—Power conversion systems, e.g. maximum power point trackers
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- Health & Medical Sciences (AREA)
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- Power Engineering (AREA)
- Computer Networks & Wireless Communication (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
Abstract
The invention relates to a Bluetooth data transmission type PH combined electrode device with automatic cleaning and maintaining functions. The device comprises a power supply module, a central control module, a PH value acquisition module, a wireless communication module, an electrode maintaining module and a clear water acquisition module. The electrode maintaining module comprises a KCL replenishing liquid container 21 with an electromagnetic valve, a turbidity sensor 7, a KCL solution tank 8 and a sewage discharge pump 9. The turbidity sensor 7 is used for contamination level of standard sample solution in the KCL solution tank 8, and when turbidity reaches a threshold, the sewage discharge pump 9 starts to discharge waste liquid in the KCL solution tank 8, and the electromagnetic valve at the bottom of the KCL replenishing liquid container 21 above the KCL solution tank 8 is open to release KCL replenishing liquid. The Bluetooth data transmission type PH combined electrode device can be used for long-term monitoring of large water areas.
Description
Technical field
The invention is related to pH value of seawater monitoring field, more particularly to the cleaning of PH combination electrodes and maintenance in device.
Background technology
The resource contained in ocean is much larger than land, living species resource, mineral resources, petroleum resources, nuclear resource.Can
To say, Ocean Development Technology decides a national future economy trend and situation.The change of marine environment can be provided to ocean
The exploitation in source causes important impact, and the monitoring to seawater quality can cause change of the mankind to marine environment to be predicted, from
And reduce the risk of exploitation marine resources.
It in seawater quality monitoring process is one of most important index that pH value is, meanwhile, seawater quality monitoring is one long
Phase continuous process, if the immersion of existing PH combination electrodes long-time is in the seawater, sensitivity can be reduced, and affect to pH value of seawater
The accuracy of data acquisition.Existing PH combination electrodes such as are both needed to carry out using after to clean, maintain at operation, therefore the above-mentioned PH compound electrics
Pole cannot carry out continuous monitoring to seawater quality.Meanwhile, the PH information that traditional PH combination electrodes are collected is both needed to by having
Line mode reaches main frame, and needs to power for device by wired mode, reduces and uses flexibility ratio.
Therefore, it is a kind of to utilize solar powered technology, and possess the low-consumption wireless PH of automated cleaning and maintenance function
Monitoring of the combination electrode device to ocean water quality is extremely important.
The content of the invention
It is an object of the invention to provide a kind of PH combination electrodes device, is supervised for a long time with meeting marine environment lower sensor node
The needs of survey；Technical scheme is as follows：
A kind of bluetooth data transmission simultaneously can be cleaned and the PH combination electrode devices for maintaining automatically, including supply module, central authorities
Control module, pH value acquisition module, wireless communication module, electrode maintenance module and clear water acquisition module, wherein,
PH value acquisition module include mechanical arm 1, the PH combination electrodes 22 for being fixed on 1 front end of mechanical arm, solution pool to be measured 12,
Sample introduction water pump 11, stock layout water pump 10, flush water pump 19, wherein, sample introduction water pump 11 for sea water is pumped into solution pool to be measured 12,
Stock layout water pump 10 is for discharging testing liquid pond 12 by sea water；Mechanical arm 1 is for being placed in testing liquid pond by PH combination electrodes 22
In 12 or raised, PH combination electrodes 22 measure pH value and transmit to central control module, under the control of central control module,
Flush water pump aspirates clear water and the PH combination electrodes 22 to raising are cleaned, and the PH combination electrodes 22 through cleaning are moved to electricity
In the KCL solution pools 8 of pole maintenance module；
Wireless communication module includes bluetooth module, and the data that pH value acquisition module is collected are wirelessly transmitted to by the module
Control room；
Electrode maintains module, supplements liquid container 21, turbidity transducer 7, KCL solution pools including the KCL with electromagnetic valve
8th, dredge pump 9, turbidity transducer 7 are used for detecting the contaminated degree of standard sample liquid in KCL solution pools 8, Central Control Module
When turbidity reaches threshold value, control of sewage disposal water pump 9 works, and discharges waste liquid in KCL solution pools 8, above KCL solution pools 8
KCL supplements the electromagnetic valve of 21 bottom of liquid container and opens, and discharges KCL replenishers；
Clear water acquisition module includes heat conductive silica gel 16, stores sea water pond 17, stores clear water reserviors 18, liquidometer 13, intake pump 14, tune
Water saving pump 15 and cold plate 20, intake pump 14 are used for pumping seawater and enter storage sea water pond 17；The main body of heat conductive silica gel 16 is used as storage
The side wall in sea water pond 17, with its maritime interior waters directly contact；Heat conductive silica gel 16 is also connected with solar energy photovoltaic panel 2, for absorbing heat
Amount；The top in storage sea water pond 17 is oblique to be fixed with cold plate 20, and the sea water of evaporation is condensed into liquid by cold plate 20, and will be condensed
Liquid drain enter to store in clear water reserviors 18；Liquidometer 13 is used for monitoring the water yield in storage clear water reserviors 18, and information of its collection is admitted to
Central Control Module, Central Control Module after clear water amount reaches max-thresholds adjust water pump 15 and open, discharge sea water, no longer
It is evaporated condensation,；When clear water reaches minimum threshold, intake pump 14 works；
Supply module includes solar energy photovoltaic panel 2 and accumulator 4, and solar energy photovoltaic panel 2 absorbs luminous energy and is converted into electric energy storage
There is accumulator 4 to power for device.
Description of the drawings
Profiles of the Fig. 1 for sensor device casing
Fig. 2 is the detail view of PH combination electrodes cleaning and maintenance
Fig. 3 is the theory diagram of the device
Flow charts of the Fig. 4 for overall process
1st, mechanical arm；2nd, solar energy photovoltaic panel；3rd, bluetooth module；4th, accumulator；5th, central control module；6th, foam；7、
Turbidity transducer；8th, KCL standard samples liquid pool；9th, 10,11,14,15,19, it is water pump (being not drawn into water pipe)；12nd, testing liquid
Pond 13, liquidometer；16th, heat conductive silica gel；17th, store sea water pond；18th, clear water reserviors are stored；20th, cold plate made by metal；21st, with electricity
The KCL of magnet valve door supplements liquid container；22nd, PH combination electrodes；
Specific embodiment
Fig. 1 is the structural representation of PH combination electrode devices, a kind of PH compound electrics for possessing cleaning automatically and maintenance function
Pole device, including supply module, central control module, wireless communication module, pH value acquisition module, electrode maintenance module and clear water
Acquisition module.The specific embodiment of the present invention is further described below in conjunction with accompanying drawing.
As shown in figure 1, pH value acquisition module includes mechanical arm 1, PH combination electrodes 22, solution pool to be measured 12, water pump 10, water
Pump 11, water pump 19.PH combination electrodes 22 are controlled into testing liquid pond 12 by mechanical arm 1, and water pump 11 works, and sea water enters to be measured
Liquid cell 12, measures pH value and transmits to central control module 5.Water pump 10 works, and discharges sea water.Mechanical arm 1 is by PH combination electrodes
Raise, water pump 19 works, draw clear water and rinse combination electrode.Mechanical arm 1 moves to PH combination electrodes 22 in KCL solution pools 8 again.
As shown in figure 1, wireless communication module includes bluetooth module 3.The data that pH value acquisition module is collected pass through the mould
Block is wirelessly transmitted to operation ship control room.Bluetooth technology adopts the advanced technology such as high-speed frequency-hopping and time division multiple acess, in a spacing
Several equipment are connected from interior, and with the advantage that transmission security is good, transmission speed is fast.
Such as Fig. 2, be electrode maintenance module details figure, liquid container 21, turbidity sensing supplemented including the KCL with electromagnetic valve
Device 7, KCL solution pools 8, water pump 9.Contain the impurity such as microorganism, algae, industrial wastes in sea water, turbidity transducer 7 can detect mark
The contaminated degree of quasi- sample liquid.When turbidity reaches threshold value, KCL titers are contaminated, must be changed.Water pump 9 works, and discharges waste liquid.
KCL supplements the electromagnetic valve of 21 bottom of liquid container and opens, and discharges KCL replenishers.Realize the renewal of KCL titers.
Such as Fig. 1, right side clear water acquisition module include heat conductive silica gel 16, store sea water pond 17, store clear water reserviors 18, liquidometer 13,
Water pump 14, water pump 15 and cold plate 20.Water pump 14 works, and sea water is entered and stores sea water pond 17.Heat conductive silica gel 16 connects solar energy
Volt plate 2 absorbs heat, and evaporation of seawater is met cold plate 20 and is condensed into liquid, as cold plate 20 is inclined with angle with photovoltaic panel 2,
With drainage, the clear water of condensation is flowed into and is stored in clear water reserviors 18.Liquidometer 13 monitors the water yield, and clear water amount reaches max-thresholds
Afterwards, water pump 15 is opened, and is discharged sea water, is no longer evaporated condensation, it is ensured that sea water will not be in casing intercrystalline and pollution.Work as clear water
Minimum threshold is reached, water pump 14 works, repeat said process.
Such as Fig. 1, supply module include solar energy photovoltaic panel 2 and accumulator 4.Solar energy photovoltaic panel 2 absorbs luminous energy and is converted into
Electrical power storage is system power supply in accumulator 4, to ensure endlessly energy supply.It is powered using solar energy, Ji Nengbao
Retaining ring border, economize on resources and greatly extend the device seafaring time.
As shown in figure 3, the device is operated by central control module control machinery arm, collected using PH combination electrodes and believed
Breath, information is processed by central control module, and is stored in data memory module；Using turbidity transducer and liquid level
Collection data are collected, central control module analysis KCL standard sample liquid dustiness is uploaded to and whether clear water amount is reached threshold value, and control
Water pump and electromagnetic valve are made a response in time, complete the automatic data collection of clear water and the automatic replacing of KCL solution, realize that PH is combined
The automatic cleaning of electrode assembly and maintenance.
Claims (1)
1. a kind of bluetooth data transmission and can clean automatically and maintain PH combination electrode devices, including supply module, central authorities control
Molding block, pH value acquisition module, wireless communication module, electrode maintenance module and clear water acquisition module, wherein,
PH value acquisition module includes mechanical arm (1), the PH combination electrodes (22) for being fixed on mechanical arm (1) front end, solution pool to be measured
(12), sample introduction water pump (11), stock layout water pump (10), flush water pump (19), wherein, sample introduction water pump (11) is for sea water is pumped into
Solution pool (12) to be measured, stock layout water pump (10) for by sea water discharge testing liquid pond (12)；Mechanical arm (1) is for PH is combined
Electrode (22) is placed in testing liquid pond (12) or is raised, and PH combination electrodes (22) measure pH value and transmit to central authorities' control mould
Block, under the control of central control module, flush water pump aspirates clear water and the PH combination electrodes (22) to raising are cleaned, Jing
The PH combination electrodes (22) of over cleaning are moved in the KCL solution pools (8) of electrode maintenance module；
Wireless communication module includes bluetooth module, and the data that pH value acquisition module is collected are wirelessly transmitted to control by the module
Room；
Electrode maintains module, supplements liquid container (21), turbidity transducer (7), KCL solution pools including the KCL with electromagnetic valve
(8), dredge pump (9), turbidity transducer (7) are used for detecting the contaminated degree of standard sample liquid in KCL solution pools (8), center
When turbidity reaches threshold value, the interior waste liquid of KCL solution pools (8) is discharged in control of sewage disposal water pump (9) work to control module, molten positioned at KCL
KCL above liquid pool (8) supplements the electromagnetic valve of liquid container (21) bottom and opens, and discharges KCL replenishers；
Clear water acquisition module includes heat conductive silica gel (16), stores sea water pond (17), stores clear water reserviors (18), liquidometer (13), intake pump
(14) water pump (15) and cold plate (20), is adjusted, intake pump (14) is used for pumping seawater and enters storage sea water pond (17)；Heat conductive silica gel
(16) side wall of the main body as storage sea water pond (17), with its maritime interior waters directly contact；Heat conductive silica gel (16) is gone back and solar energy
Volt plate (2) connection, for absorbing heat；The top of storage sea water pond (17) is oblique to be fixed with cold plate (20), and cold plate (20) will
The sea water of evaporation is condensed into liquid, and the liquid drain of condensation is entered to store in clear water reserviors (18)；Liquidometer (13) is used for monitoring storage
The interior water yield of clear water reserviors (18), the information of its collection are admitted to Central Control Module, and Central Control Module reaches maximum in clear water amount
After threshold value, adjust water pump (15) and open, discharge sea water, be no longer evaporated condensation,；When clear water reaches minimum threshold, intake pump
(14) work；
Supply module includes solar energy photovoltaic panel (2) and accumulator (4), and solar energy photovoltaic panel (2) absorbs luminous energy and is converted into electric energy
It is stored in accumulator (4) to power for device.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610995807.2A CN106525941A (en) | 2016-11-11 | 2016-11-11 | Bluetooth data transmission type PH combined electrode device with automatic cleaning and maintaining functions |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610995807.2A CN106525941A (en) | 2016-11-11 | 2016-11-11 | Bluetooth data transmission type PH combined electrode device with automatic cleaning and maintaining functions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106525941A true CN106525941A (en) | 2017-03-22 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610995807.2A Pending CN106525941A (en) | 2016-11-11 | 2016-11-11 | Bluetooth data transmission type PH combined electrode device with automatic cleaning and maintaining functions |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116499525A (en) * | 2023-04-28 | 2023-07-28 | 中国科学院地质与地球物理研究所 | Portable unpolarized electrode maintenance system, device and use method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08193965A (en) * | 1995-01-17 | 1996-07-30 | Nec Corp | Sensor system for monitoring ocean environment and its controlling method |
| JPH11248696A (en) * | 1998-02-28 | 1999-09-17 | Horiba Ltd | Water quality measuring device |
| CN102004142A (en) * | 2010-11-24 | 2011-04-06 | 山东省科学院海洋仪器仪表研究所 | Water quality parameter measuring instrument arranged in super buoy and water quality parameter measuring method |
| CN103951007A (en) * | 2014-04-02 | 2014-07-30 | 苏州市玄天环保科技有限公司 | Solar energy water purifier |
| CN106093154A (en) * | 2016-08-04 | 2016-11-09 | 重庆和航科技股份有限公司 | The online remote supervision system of water quality pH value and method |
-
2016
- 2016-11-11 CN CN201610995807.2A patent/CN106525941A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08193965A (en) * | 1995-01-17 | 1996-07-30 | Nec Corp | Sensor system for monitoring ocean environment and its controlling method |
| JPH11248696A (en) * | 1998-02-28 | 1999-09-17 | Horiba Ltd | Water quality measuring device |
| CN102004142A (en) * | 2010-11-24 | 2011-04-06 | 山东省科学院海洋仪器仪表研究所 | Water quality parameter measuring instrument arranged in super buoy and water quality parameter measuring method |
| CN103951007A (en) * | 2014-04-02 | 2014-07-30 | 苏州市玄天环保科技有限公司 | Solar energy water purifier |
| CN106093154A (en) * | 2016-08-04 | 2016-11-09 | 重庆和航科技股份有限公司 | The online remote supervision system of water quality pH value and method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116499525A (en) * | 2023-04-28 | 2023-07-28 | 中国科学院地质与地球物理研究所 | Portable unpolarized electrode maintenance system, device and use method thereof |
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Application publication date: 20170322 |
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