CN106706735A - Wirelessly-charged self-cleaning PH composite electrode device based on ZIGBEE data transmission - Google Patents
Wirelessly-charged self-cleaning PH composite electrode device based on ZIGBEE data transmission Download PDFInfo
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- CN106706735A CN106706735A CN201611039679.0A CN201611039679A CN106706735A CN 106706735 A CN106706735 A CN 106706735A CN 201611039679 A CN201611039679 A CN 201611039679A CN 106706735 A CN106706735 A CN 106706735A
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- 238000004140 cleaning Methods 0.000 title claims abstract description 11
- 230000005540 biological transmission Effects 0.000 title abstract description 8
- 239000002131 composite material Substances 0.000 title abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000007788 liquid Substances 0.000 claims abstract description 48
- 238000012423 maintenance Methods 0.000 claims abstract description 13
- 238000004891 communication Methods 0.000 claims abstract description 11
- 239000010865 sewage Substances 0.000 claims abstract description 4
- 239000002699 waste material Substances 0.000 claims abstract description 4
- 238000007599 discharging Methods 0.000 claims abstract 3
- 239000013535 sea water Substances 0.000 claims description 39
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 238000012544 monitoring process Methods 0.000 claims description 10
- 239000000741 silica gel Substances 0.000 claims description 9
- 229910002027 silica gel Inorganic materials 0.000 claims description 9
- 239000013589 supplement Substances 0.000 claims description 9
- 238000012360 testing method Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 5
- 230000008020 evaporation Effects 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 238000005086 pumping Methods 0.000 claims description 3
- 239000003643 water by type Substances 0.000 claims description 2
- 230000006870 function Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 238000013480 data collection Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012806 monitoring device Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/302—Electrodes, e.g. test electrodes; Half-cells pH sensitive, e.g. quinhydron, antimony or hydrogen electrodes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/38—Cleaning of electrodes
-
- H02J7/025—
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Molecular Biology (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The invention relates to a wirelessly-charged self-cleaning PH composite electrode device based on ZIGBEE data transmission. The wirelessly-charged self-cleaning PH composite electrode device comprises a power supply module, a central control module, a wireless communication module, a PH value acquisition module, an electrode maintenance module and a clear water collection module, wherein the electrode maintenance module comprises a KCL replenishing liquid container 21 with an electromagnetic valve, a sample liquid turbidity sensor 7, a KCL solution tank 8 and a sewage discharging pump 9. The sample liquid turbidity sensor 7 is used for detecting the pollution degree of sample liquid in the KCL solution tank 8 and sending acquired information to the central control module, the sewage discharging pump 9 works and discharges out waste liquid when the turbidity is up to a threshold value, the electromagnetic valve at the bottom of the KCL replenishing liquid container 21 above the KCL solution tank 8 is turned on, and KCL replenishing liquid is released. The power supply module comprises an oscillator 3 and a storage battery 4. The wirelessly-charged self-cleaning PH composite electrode device can monitor a wide-range water area for a long period of time.
Description
Technical field
The invention is related to pH value of seawater to monitor field, more particularly to the self-cleaning PH combination electrodes with maintenance function and its
Wireless energy supply mode.
Background technology
Ocean possesses and its rich in natural resources, and in recent years, China increases the development and utilization to marine resources, but extra large
The polytropy of foreign environment is the key factor for restricting marine resources development, therefore is shown for the monitoring of the data target of marine environment
Obtain particularly important, anticipated that the change of marine environment so as to more efficient exploitation marine resources by monitoring us.
Seawater quality monitoring is a long-continued process, and collection, transmitting-receiving of data etc. are movable all to consume substantial amounts of
Electric energy, monitoring device do not have power supply continue a journey equipment cannot long-term work, and wired charging modes at sea extremely inconvenience.PH value is
It is one of most important index in seawater quality monitoring process, if the immersion for a long time of existing PH combination electrodes is in the seawater, electricity
Pole front glass ball bubble surface blocks hydrogen ion passage easily by the impurity covering in seawater, can influence to pH value of seawater data
The accuracy of collection.Meanwhile, the PH information that traditional PH combination electrodes are collected is both needed to reach main frame by wired mode, reduces
Use flexibility ratio.
Existing PH combination electrodes such as are both needed to manually to be cleaned, maintain at the operation, expense when being accomplished manually the operating cost after
Power.The monitoring process of seawater quality can be brought inconvenience.And the data of seawater quality have extremely strong ageing, monitoring personnel is obtained
To time of seawater data, The faster the better.The data volume of ZigBee technology transmission is smaller, with low in energy consumption, low cost, time delay
It is short to wait good characteristic so that the working time of whole device is longer, is conducive to the long term monitoring to seawater quality.And utilize magnetic to be total to
Technology of shaking carries out wireless charging to power supply can be solved the problems, such as to reclaim the extremely inconvenience of whole device electric energy supplement.With regard to this apparently, one
Kind lean on ZigBee real-time Data Transmissions, it is easy to carry, wireless charging and can possess the PH compound electrics of automatic cleaning and maintenance function
Pole device is particularly important.
The content of the invention
It is an object of the invention to provide one kind can real-time Data Transmission, wireless charging and can possess automatic cleaning and maintenance
The PH combination electrode devices of function, to meet marine environment water quality long term monitoring the need for.Technical scheme is as follows：
A kind of wireless charging self-clean type PH combination electrode devices based on ZIGBEE data transfers, including power supply module, in
Centre control module, wireless communication module, pH value acquisition module, electrode maintenance module and clear water acquisition module, wherein,
PH value acquisition module include mechanical arm 2, be fixed on the front end of mechanical arm 2 PH combination electrodes 1, solution pool to be measured 12,
Sample introduction water pump 11, stock layout water pump 10, flush water pump 19, wherein, sample introduction water pump 11 is used to for seawater to be pumped into solution pool to be measured 12,
Stock layout water pump 10 is used for seawater discharge testing liquid pond 12；Mechanical arm 2 is used to for PH combination electrodes 1 to be placed in testing liquid pond 12
Interior or raised, PH combination electrodes 1 measure pH value and transmit to central control module, under the control of central control module, punching
The wash water pumping clear water and PH combination electrodes 1 to raising are cleaned, is moved to electrode and protects through the PH combination electrodes 1 of over cleaning
In the KCL solution pools 8 of foster module.
Electrode maintenance module, including the supplements of the KCL with electromagnetic valve liquid container 21, sample liquid turbidity transducer 7, KCL are molten
Liquid pool 8 and dredge pump 9；Sample liquid turbidity transducer 7 is used to detect the contaminated degree of standard sample liquid in KCL solution pools 8 that it to be adopted
The information of collection is admitted to Central Control Module, and when turbidity reaches threshold value, control of sewage disposal water pump 9 works Central Control Module, row
Go out waste liquid in KCL solution pools 8, the electromagnetic valve positioned at KCL supplement liquid containers 21 bottom of the top of KCL solution pools 8 is opened, release
KCL replenishers.
Clear water acquisition module includes heat conductive silica gel 16, stores seawater pond 17, stores clear water reserviors 18, liquid level gauge 13, intake pump 14, tune
Water saving pump 15 and cold plate 20, intake pump 14 are used for pumping seawater and enter storage seawater pond 17；The main body of heat conductive silica gel 16 is used as storage
The side wall in seawater pond 17, with its maritime interior waters directly contact；Heat conductive silica gel 16 is also connected with solar energy photovoltaic panel 2, for absorbing heat
Amount；The top in storage seawater pond 17 is oblique to be fixed with cold plate 20, and the seawater of evaporation is condensed into liquid by cold plate 20, and will be condensed
Liquid drain enter to store clear water reserviors 18；Liquid level gauge 13 is used to monitor water in storage clear water reserviors 18, and information of its collection is admitted to
Central Control Module, Central Control Module after clear water amount reaches max-thresholds, open, and discharges seawater, no longer by regulation water pump 15
It is evaporated condensation,；When clear water reaches minimum threshold, control intake pump 14 works；
Power supply module includes reception oscillator 3 and battery 4, and reception oscillator 3 receives extraneous hair by resonance mode
Penetrate the energy of oscillator transmission and be translated into electric energy and be transferred in battery 4, for electric energy.
Wireless communication module includes ZigBee communication module, and the data that pH value acquisition module is collected are wireless by the module
Transmit to control room.
Brief description of the drawings
Fig. 1 is the profile of sensor device casing
Fig. 2 is the detail view that PH combination electrodes are cleaned and maintained
Fig. 3 is the theory diagram of the device
Fig. 4 is the flow chart of overall process
Fig. 5 is that power supply supplements energy diagram
1st, PH combination electrodes；2nd, mechanical arm；3rd, reception oscillator；4th, battery；5th, central control module；6th, foam；7、
Turbidity transducer；8th, KCL standard samples liquid pool；9th, 10,11,14,15,19, it is water pump (being not drawn into water pipe)；12nd, testing liquid
Pond 13, liquid level gauge；16th, heat conductive silica gel；17th, seawater pond is stored；18th, clear water reserviors are stored；20th, the cold plate that metal is made；21st, with electricity
The KCL supplement liquid containers of magnet valve door；22nd, ZigBee communication module.
Specific embodiment
Fig. 1 is the structural representation of PH combination electrode devices, a kind of PH compound electrics for possessing automatic cleaning and maintenance function
Pole device, including power supply module, central control module, wireless communication module, pH value acquisition module, electrode maintenance module and clear water
Acquisition module.Specific embodiment of the invention is further described below in conjunction with accompanying drawing.
As shown in figure 1, pH value acquisition module includes mechanical arm 2, PH combination electrodes 1, solution pool to be measured 12, water pump 10, water
Pump 11, water pump 19.PH combination electrodes 1 are controlled to enter testing liquid pond 12 by mechanical arm 2, and water pump 11 works, and seawater enters to be measured
Liquid cell 12, measures pH value and transmits to central control module 5.Water pump 10 works, and discharges seawater.Mechanical arm 2 is by PH combination electrodes 1
Raise, water pump 19 works, draw clear water and rinse combination electrode.During PH combination electrodes 1 are moved to KCL solution pools 8 by mechanical arm 2 again.
It is that electrode maintains module details figure, including supplement liquid container 21, the turbidity sensings of the KCL with electromagnetic valve such as Fig. 2
Device 7, KCL solution pools 8, water pump 9.Contain the impurity such as microorganism, algae, industrial wastes, the i.e. detectable mark of turbidity transducer 7 in seawater
The quasi- contaminated degree of sample liquid.When turbidity reaches threshold value, KCL titers have been contaminated, and must change.Water pump 9 works, and discharges waste liquid.
The electromagnetic valve of KCL supplement liquid containers 21 bottom is opened, and discharges KCL replenishers.Realize the renewal of KCL titers.
Such as Fig. 1, right side clear water acquisition module include heat conductive silica gel 16, store seawater pond 17, store clear water reserviors 18, liquid level gauge 13,
Water pump 14, water pump 15 and cold plate 20.Water pump 14 works, and seawater enters storage seawater pond 17.The connection top layer of heat conductive silica gel 16 foam 6
Heat is absorbed, evaporation of seawater is met cold plate 20 and is condensed into liquid, because cold plate 20 and cystosepiment 6 are inclined with angle, with drawing
Stream is acted on, in the clear water inflow storage clear water reserviors 18 of condensation.Liquid level gauge 13 monitors water, after clear water amount reaches max-thresholds, water pump
15 open, and discharge seawater, are no longer evaporated condensation, it is ensured that seawater will not be crystallized and polluted in casing.When clear water reaches most
Small threshold value, water pump 14 works, and repeats said process.
Such as Fig. 1, power supply module includes reception oscillator 3 and battery 4.In fixed range marine site, launched by ship
Oscillator sends energy, in the range of reception oscillator resonance in all of device receive energy and be translated into electric energy transmission
To in battery 4, realization is charged on a large scale.
As shown in figure 1, wireless communication module includes ZigBee communication module 22, the module collection pH value acquisition module is adopted
The pH value data of collection, and the data of collection are sent at monitoring personnel in time.Realize the real-time Data Transmission of pH value of seawater.
As shown in figure 3, the device is operated by central control module control machinery arm 2, collected using PH combination electrodes 1 and believed
Breath, information is processed by central control module, and be stored in data memory module；Using turbidity transducer and liquid level
Collection data are collected, central control module analysis KCL standard sample liquid dustiness is uploaded to and whether clear water amount is reached threshold value, and control
Water pump and electromagnetic valve are made a response in time, complete the automatic replacing of the automatic data collection and KCL solution of clear water, realize that PH is combined
The automatic cleaning of the device of electrode 1 and maintenance.
Claims (1)
1. a kind of wireless charging self-clean type PH combination electrode devices based on ZIGBEE data transfers, including power supply module, center
Control module, wireless communication module, pH value acquisition module, electrode maintenance module and clear water acquisition module, wherein,
PH value acquisition module includes mechanical arm (2), is fixed on the PH combination electrodes (1), solution pool to be measured of mechanical arm (2) front end
(12), sample introduction water pump (11), stock layout water pump (10), flush water pump (19), wherein, sample introduction water pump (11) is for seawater to be pumped into
Solution pool (12) to be measured, stock layout water pump (10) by seawater for discharging testing liquid pond (12)；Mechanical arm (2) is for PH to be combined
Electrode (1) is placed in testing liquid pond (12) or is raised, and PH combination electrodes (1) measure pH value and transmit to center control mould
Block, under the control of central control module, flush water pump aspirates clear water and the PH combination electrodes (1) to raising are cleaned, and passes through
The PH combination electrodes (1) of over cleaning are moved in the KCL solution pools (8) of electrode maintenance module.
Electrode maintenance module, including supplements liquid container of the KCL with electromagnetic valve (21), sample liquid turbidity transducer (7), KCL are molten
Liquid pool (8) and dredge pump (9)；Sample liquid turbidity transducer (7) is contaminated for detecting the standard sample liquid in KCL solution pools (8)
Degree, its collection information be admitted to Central Control Module, Central Control Module when turbidity reaches threshold value, control of sewage disposal water pump
(9) work, discharge KCL solution pool (8) interior waste liquid, KCL supplements liquid container (21) bottom above KCL solution pools (8)
Electromagnetic valve is opened, and discharges KCL replenishers；
Clear water acquisition module includes heat conductive silica gel (16), stores seawater pond (17), stores clear water reserviors (18), liquid level gauge (13), intake pump
(14), regulation water pump (15) and cold plate (20), intake pump (14) enter storage seawater pond (17) for pumping seawater；Heat conductive silica gel
(16) main body as store seawater pond (17) side wall, with its maritime interior waters directly contact；Heat conductive silica gel (16) is gone back and solar energy
Volt plate (2) connection, for absorbing heat；The top of storage seawater pond (17) is oblique to be fixed with cold plate (20), and cold plate (20) will
The seawater of evaporation is condensed into liquid, and by the liquid drain of condensation enters to store clear water reserviors (18)；Liquid level gauge (13) stores for monitoring
Clear water reserviors (18) interior water, the information of its collection is admitted to Central Control Module, and Central Control Module reaches maximum in clear water amount
After threshold value, regulation water pump (15) is opened, and discharges seawater, is no longer evaporated condensation,；When clear water reaches minimum threshold, control into
Water pump (14) works；
Power supply module includes reception oscillator (3) and battery (4), and reception oscillator (3) receives the external world by resonance mode
Energy that transmitting oscillator sends simultaneously is translated into electric energy and is transferred in battery (4), for electric energy；
Wireless communication module includes ZigBee communication module, and the data that pH value acquisition module is collected are wirelessly transferred by the module
To control room.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611039679.0A CN106706735A (en) | 2016-11-11 | 2016-11-11 | Wirelessly-charged self-cleaning PH composite electrode device based on ZIGBEE data transmission |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611039679.0A CN106706735A (en) | 2016-11-11 | 2016-11-11 | Wirelessly-charged self-cleaning PH composite electrode device based on ZIGBEE data transmission |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106706735A true CN106706735A (en) | 2017-05-24 |
Family
ID=58940308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611039679.0A Pending CN106706735A (en) | 2016-11-11 | 2016-11-11 | Wirelessly-charged self-cleaning PH composite electrode device based on ZIGBEE data transmission |
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2016
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Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010086607A1 (en) * | 2009-01-28 | 2010-08-05 | Biota Guard As | Method of detecting contamination of water using living organisms |
| CN102004142A (en) * | 2010-11-24 | 2011-04-06 | 山东省科学院海洋仪器仪表研究所 | Water quality parameter measuring instrument arranged in super buoy and water quality parameter measuring method |
| GB2504981A (en) * | 2012-08-16 | 2014-02-19 | Natural Enviromental Res Council | Sensing apparatus and method for measuring algal growth |
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Application publication date: 20170524 |