CN106752587A - A kind of kitchen wall surface fireproof mould-proof coating and its production method - Google Patents
A kind of kitchen wall surface fireproof mould-proof coating and its production method Download PDFInfo
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- CN106752587A CN106752587A CN201611214367.9A CN201611214367A CN106752587A CN 106752587 A CN106752587 A CN 106752587A CN 201611214367 A CN201611214367 A CN 201611214367A CN 106752587 A CN106752587 A CN 106752587A
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- 238000000576 coating method Methods 0.000 title claims abstract description 64
- 239000011248 coating agent Substances 0.000 title claims abstract description 63
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 48
- -1 polyoxyethylene Polymers 0.000 claims abstract description 25
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003063 flame retardant Substances 0.000 claims abstract description 23
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 22
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims abstract description 22
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 21
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims abstract description 13
- 241000276489 Merlangius merlangus Species 0.000 claims abstract description 13
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000002148 esters Chemical class 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 11
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 11
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 11
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 11
- 239000011787 zinc oxide Substances 0.000 claims abstract description 11
- 239000000645 desinfectant Substances 0.000 claims abstract description 10
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 12
- 229920001296 polysiloxane Polymers 0.000 claims description 12
- 238000010422 painting Methods 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 8
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 7
- 229910000388 diammonium phosphate Inorganic materials 0.000 claims description 7
- 235000019838 diammonium phosphate Nutrition 0.000 claims description 7
- 229910052725 zinc Inorganic materials 0.000 claims description 7
- 239000011701 zinc Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 5
- 230000001046 anti-mould Effects 0.000 claims description 5
- 239000002546 antimould Substances 0.000 claims description 5
- 239000003899 bactericide agent Substances 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 3
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- 210000000481 breast Anatomy 0.000 claims 1
- 125000004185 ester group Chemical group 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract description 11
- 230000000694 effects Effects 0.000 abstract description 10
- 230000032683 aging Effects 0.000 abstract description 4
- 238000004079 fireproofing Methods 0.000 abstract description 3
- 230000003670 easy-to-clean Effects 0.000 abstract description 2
- 239000002585 base Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 11
- 235000014692 zinc oxide Nutrition 0.000 description 9
- 239000003973 paint Substances 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 5
- 235000005979 Citrus limon Nutrition 0.000 description 4
- 241000233866 Fungi Species 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 3
- 229920002101 Chitin Polymers 0.000 description 3
- 244000131522 Citrus pyriformis Species 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229910000077 silane Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 2
- 239000005510 Diuron Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 description 2
- 239000006013 carbendazim Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 230000001857 anti-mycotic effect Effects 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000002543 antimycotic Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229940058573 b-d glucose Drugs 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 229910001748 carbonate mineral Inorganic materials 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000012412 chemical coupling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000001808 coupling effect Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000012372 quality testing Methods 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000006058 strengthened glass Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to a kind of kitchen wall surface fireproof mould-proof coating and its production method, the coating is to be prepared from the following raw materials in parts by weight：50 60 parts of emulsion；Glutaric acid two（Second methyl-prop）46 parts of ester；γ‑（Ethylenediamine base）1 1.5 parts of propyl trimethoxy silicane；13 parts of citric acid；23 parts of hydroxyethyl cellulose；0.5 1 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether；24 parts of shitosan；361 58 parts of antimildew disinfectant ROCIMA；46 parts of fire retardant；0.5 1.5 parts of acrylate；15 17 parts of water；10 12 parts of zinc oxide；15 20 parts of powdered whiting.The coating that the present invention is prepared has good antibacterial and mouldproof fireproofing function, and the features such as with non-aging, resistance to stifling, oil resistant stain resistance, coating is difficult for drop-off, oil rub resistance, easy to clean, effect are good, the coating for preparing disclosure satisfy that the requirement of kitchen's interior, is particularly suitable for the metope in kitchen and uses.
Description
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of kitchen wall surface fireproof mould-proof coating and its producer
Method.
Background technology
With the development of construction industry, the demand of coating is growing day by day.Coating is a kind of material, and this material can be with not
Same construction technology is coated in object surface, is formed and adhered to firmly, with some strength, continuous solid film, so formation
Film common name film, also known as paint film or coating.Object is corroded among air by oxygen, moisture etc., easily causes
The breakoff phenomenons such as corrosion of metal, foxiness, cement weathering, coating is coated with object surface, forms layer protecting film, can be hindered
Only or postpone the occurrence and development of these breakoff phenomenons, can extend the service life of various materials.
At present, coating use at home is very universal, and many places all use.Kitchen is that each family must
Few, for the room for preparing food and cooked, existing kitchen wall surface material not only has ceramic tile, stainless steel, reinforcing glass
Glass also has PLASTIC LAMINATED and coating.But for the wall decoration of domestic kitchens, decorations are still with ceramic tile and plastic
It is main because this family's Special use region of kitchen pollution resistance, mildew resistance and fire line are existed on decorative cover it is very high
Requirement, such as decorative cover in kitchen will have pollution resistance very high and hardness very high to resist the various oil produced during kitchen is lived
The dirty attachment to decorative cover, while easily to remove；Moisture is heavier in kitchen, easy breeding and the growth of mould and bacterium, because
This mildew resistance requirement to kitchen's interior face is also higher；Kitchen is related to be cooked with naked light, if there is accident, to the danger of human body
Evil property is very big, so requirement of its ornament materials to fire line is also higher etc., and general aqueous architectural coating is difficult to meet this
It is a little to require, therefore, kitchen's interior is fitted up still based on ceramic tile and plastic.But these finishing materials there is also deficiency
Place, such as：Kitchen is fitted up using ceramic tile, decoration cost is high, it is big to overhaul difficulty again, ceramic tile style sheet one, color range of choice are small,
Construction technical requirement is high, and ditch stitches the shortcomings of easily saving bit by bit spot；And the shortcoming of stainless steel be texture compared with cool tone, hard thing is encountered
It is not easy to repair；The shortcoming of strengthened glass is easily to be stained with oil, cleaning trouble etc..
The above shortcoming is all that building coating can be solved effectively, but is specifically applied to kitchen in existing building coating
The coating in room is fewer, and existing kitchen wall surface coating has not oil resistant, non-antibacterial, lacking intolerant to stifling, non-refractory
Point, at the same its fire prevention, fungicidal properties it is poor, it is difficult to meet kitchen wall surface decorate requirement.
Therefore, develop a kind of while having mould proof fire prevention, waterproof, oil resistant, non-aging kitchen wall surface coating, to kitchen
The development of the ornament materials in room plays an important role.
The content of the invention
The purpose of the present invention is directed to the deficiencies in the prior art, there is provided a kind of kitchen wall surface with fireproof mould-proof coating and its
Production method, the coating obtained according to production method production is applied to the spraying of kitchen wall surface, and the coating has good resisting
The mould proof fireproofing function of bacterium, and the features such as with non-aging, resistance to stifling, oil resistant stain resistance, coating is difficult for drop-off, Yi Qing
Reason.
To achieve the above object, the present invention is adopted the following technical scheme that：
A kind of kitchen wall surface fireproof mould-proof coating, the coating is to be prepared from the following raw materials in parts by weight：
Emulsion 50-60 parts；Glutaric acid two（Second-methyl-prop）Ester 4-6 parts；γ-（Ethylenediamine base）Propyl trimethoxy silicane 1-
1.5 parts；Citric acid 1-3 parts；Hydroxyethyl cellulose 2-3 parts；0.5-1 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether；Shitosan 2-4
Part；5-8 parts of antimildew disinfectant ROCIMA 361；Fire retardant 4-6 parts；Acrylate 0.5-1.5 parts；Water 15-17 parts；Oxidation
Zinc 10-12 parts；Powdered whiting 15-20 parts.
Described emulsion is the mixed liquor of silicone acrylic emulsion and pure-acrylic emulsion, and both weight ratios are followed successively by 1.5:1；Wherein,
The A-102 products that silicone acrylic emulsion is produced using Shanghai Zhen Zhou chemistry painting industries Co., Ltd；Pure-acrylic emulsion uses Shanghai and shakes continent
The A-99 products of chemistry painting industry Co., Ltd production.
A-102 silicone acrylic emulsions system third
Olefin(e) acid ester and organosilicon material using modern high technology technology copolymerization anionic emulsion, be milky white micro-strip blue light color liquid
Body, solid content 48 ± 1wt%, pH are 7-9, and viscosity is 1000-3000mpa.s, and glass transition temperature Tg is 30 DEG C, minimum film forming temperature
25 DEG C of degree, 48h is not stratified not to be demulsified.The emulsion has tiny particle diameter and excellent freeze-thaw stability, mechanical stability and calcium
Ion stability, its film has the excellent water resistance of machine, alkali resistance, adhesive force and closed performance, and with prominent anti-soil
Property.The pure third building emulsion systems of A-99 are translucent milky white in blue light with the anionic emulsion of methacrylic acid monomer copolymerization
Color liquid, solid content is 50 ± 1wt%, and 25 DEG C of pH is 7-8.5, and viscosity is 1000-3000mpa.s, and glass transition temperature Tg is 30
DEG C, 20 DEG C of MFT, in mechanical stability（2000r/min, stirs 45min）Under conditions of, do not flocculate, it is not demulsified,
It is not stratified.Pure third building emulsions of A-99 have particle diameter tiny, and viscosity is suitable, and paint film is hard, weather-proof, alkaline-resisting, scrub resistance is good, glue
Knot power and adhesive force are strong, the features such as have good color stuffing bearing capacity, the color developing and various good stabilities of pigment, can be applied to
High-weatherability exterior wall latex paint, interior wall high-performance zero diopter to high gloss emulsion paint, cement tile paint.
Above-mentioned kitchen wall surface fireproof mould-proof coating, described fire retardant is xylenylphosphate, diammonium hydrogen phosphate with
And nano-zinc borate is according to 5:3:2 part by weight is mixed to get.
Described kitchen wall surface uses fireproof mould-proof coating, its preparation method to comprise the following steps:
(1) water, the glutaric acid two of parts by weight are sequentially added in a mixer（Second-methyl-prop）It is ester, citric acid, shitosan, anti-
Mould bactericide ROCIMA 361 and fire retardant, start stirring, and rotating speed is 1000 revs/min, at a high speed dispersion 10min；
(2) start in polyoxyethylene polyoxy propyl alcohol amidogen ether, zinc oxide and powdered whiting addition blender by weight
Stirring, rotating speed be 1100 revs/min, be warmed up to 70 DEG C -80 DEG C, then using dripping method be uniformly added into γ -（Ethylenediamine base）Propyl group
Trimethoxy silane, drop rate is controlled in 1-2 drops/min, continues to stir 20-30min after adding；
(3) emulsion, acrylate and the hydroxyethyl cellulose of parts by weight are finally put into, rotating speed is 500-600 revs/min, low
Speed dispersion 5-10min.
Glutaric acid two used in the present invention（Second-methyl-prop）Ester is a kind of coalescents.Ethoxy of the present invention
Cellulose can play a part of dispersant and thickener in being applied to coating of the invention, can make the viscosity stabilization of product, reduce
Caking, paint film is smooth, coating is had preferable rheological characteristic, be amenable to stronger shear strength, and provides good stream
Levelling, resistance to scratch and pigment uniformity.
Shitosan (chitosan) used by the present invention is the chitin (chitin) being widely present by nature by de-
What acetyl effect was obtained, chemical name be Chitosan (1-4) -2- amino-B-D glucose, relative molecular mass be 2 ×
105~7 × 105, shitosan has the physicochemical properties such as good adsorptivity, film forming, fibre forming property, hygroscopicity and moisture retention, wide spectrum
The excellent biology performances such as antibiotic property, biological functionality, biocompatibility, hypotoxicity, biodegradability, chitin is one
Plant natural antiseptic.Chitosan-phospholipid complex has preferable antibacterial activity, can suppress some fungies, bacterium and virus
Growth and breeding.Shitosan is used to prepare coating, can be to greatly improving the antibiotic property of coating.
Zinc oxide of the present invention is a kind of basic dye, has mould proof effect when consumption is big, in being Chinese white
Tinting strength, tinting power preferably and will not efflorescence pigment, with good light resistance, heat resistance and resistance to chalking.Heavy used by the present invention
Calcium carbonate is to be ground to form by natural carbonate mineral such as calcite, marble, lime stone.With chemical purity is high, inertia big,
Be difficult that chemical reaction, heat endurance are good, will not decompose below 400 DEG C, whiteness high refractive index is low, matter is soft, it is dry, without crystallization
The low wearing valve of water, hardness is small, nontoxic, tasteless, odorless, good dispersion the advantages of.Powdered whiting oil absorbency is low, to emulsion demand
Amount is low, and the thickness of paint film, improve mechanical strength and wearability can be increased using powdered whiting.
γ of the present invention-（Ethylenediamine base）On the one hand propyl trimethoxy silicane can in coating of the invention
Reduce the interfacial tension between liquid-liquid and solid-liquid；On the other hand, γ-（Ethylenediamine base）Propyl trimethoxy silicane can be filled out with inorganic
Expect the hydroxyl reaction on surface, form the monolayer of coupling agent, so as to play chemical coupling effect.γ-（Ethylenediamine base）Propyl group
Long-chain moiety in trimethoxy silane molecule, play with the entanglement effect of polymer molecule and compatibility, improve material and rush
Hit intensity, reduces the surface energy of filler, and the viscosity of system is significantly reduced, and with good lubricity and rheological property.
Beneficial effects of the present invention are：
1st, the antimildew disinfectant ROCIMA 361 for adding in the present invention is the compound product of carbendazim and diuron, carbendazim with
Diuron can play complementary and synergy and cause that the performance of antimycotic antiseptic is higher, and antimildew disinfectant ROCIMA 361 has very strong
Kill the ability of mould, the effect with mildew-resistant algae-resistant.ROCIMA 361 is the anti-phycomycete agent of Compositional type anti-fungal, is applied for metope
Material and plaster have double protection：First, it can prevent coating or grey mud layer as fungi and phycomycete culture medium；Secondly,
When surface moisturizes because of rainwater or condensation, the active material of this product can in an orderly manner ooze out into tide from plaster and dope layer
Wet face, so as to prevent the growth of fungi and phycomycete；Antimildew disinfectant ROCIMA 361 can improve coating in being added to coating
Fungus and mildew resistance performance, makes coating that mould proof effect is played under moister, special environment.
2nd, the fire retardant added in the present invention is xylenylphosphate, diammonium hydrogen phosphate and nano-zinc borate according to 5:3:
What 2 part by weight was mixed to get.The flame retardant effect of fire retardant is good, wherein, film influences after nano-zinc borate brushing
The inherent color of object, brushes on inorganic material matrix, can form inierpeneirating network structure with body surface, and adhesive force is good,
Protective effect with certain heat-insulated, anti-oxidation, anti-corrosion, fire-retardant fireproof, extends the service life of matrix, energy-conserving and environment-protective.And
Flame retardant effect can more be significantly improved when xylenylphosphate, diammonium hydrogen phosphate and nano-zinc borate are used cooperatively, by fire retardant
It is added in coating, it is possible to increase the fire resistance of coating, when there is fire, coating can effectively slow down propagation of flame and propagate
Speed, can prevent burning within a certain period of time.
3rd, the emulsion that uses of kitchen wall surface fireproof mould-proof coating that prepared by the present invention is silicone acrylic emulsion and pure-acrylic emulsion
The film of mixed liquor, wherein silicone acrylic emulsion has the excellent water resistance of machine, alkali resistance, adhesive force and closed performance,
And with prominent pollution resistance；Pure third building emulsion has particle diameter tiny, and viscosity is suitable, and paint film is hard, weather-proof, resistance to
Alkali, scrub resistance are good, the features such as cohesive force and strong adhesive force.Glutaric acid two is added in mixed liquor（Second-methyl-prop）Ester, γ-
（Ethylenediamine base）The coating tool that the materials such as propyl trimethoxy silicane, antimildew disinfectant ROCIMA 361, fire retardant are prepared
There is a good antibacterial and mouldproof fireproofing function, and the features such as with non-aging, resistance to stifling, oil resistant stain resistance, coating is difficult
Come off, oil rub resistance, easy to clean, effect it is good.Oil stain on metope can be wiped, and not interfere with the coating presentation of metope.The present invention
The coating for preparing disclosure satisfy that the requirement of kitchen's interior, is particularly suitable for the metope in kitchen and uses.
Specific embodiment
Embodiment 1
A kind of kitchen wall surface fireproof mould-proof coating, the coating is to be prepared from the following raw materials in parts by weight：
50 parts of emulsion；Glutaric acid two（Second-methyl-prop）4 parts of ester；γ-（Ethylenediamine base）1 part of propyl trimethoxy silicane；Lemon
1 part of acid；2 parts of hydroxyethyl cellulose；0.5 part of polyoxyethylene polyoxy propyl alcohol amidogen ether；2 parts of shitosan；Antimildew disinfectant ROCIMA
361 5 parts；4 parts of fire retardant；0.5 part of acrylate；15 parts of water；10 parts of zinc oxide；15 parts of powdered whiting.
Described emulsion is the mixed liquor of silicone acrylic emulsion and pure-acrylic emulsion, and both weight ratios are followed successively by 1.5:1；Wherein,
The A-102 products that silicone acrylic emulsion is produced using Shanghai Zhen Zhou chemistry painting industries Co., Ltd；Pure-acrylic emulsion uses Shanghai and shakes continent
The A-99 products of chemistry painting industry Co., Ltd production.Described fire retardant is xylenylphosphate, diammonium hydrogen phosphate and nanometer
Firebrake ZB is according to 5:3:2 part by weight is mixed to get.
Described kitchen wall surface uses fireproof mould-proof coating, its preparation method to comprise the following steps:
(1) water, the glutaric acid two of parts by weight are sequentially added in a mixer（Second-methyl-prop）It is ester, citric acid, shitosan, anti-
Mould bactericide ROCIMA 361 and fire retardant, start stirring, and rotating speed is 1000 revs/min, at a high speed dispersion 10min；
(2) start in polyoxyethylene polyoxy propyl alcohol amidogen ether, zinc oxide and powdered whiting addition blender by weight
Stirring, rotating speed be 1100 revs/min, be warmed up to 70 DEG C, then using dripping method be uniformly added into γ-（Ethylenediamine base）Propyl group trimethoxy
Base silane, drop rate is controlled in 1-2 drops/min, continues to stir 30min after adding；
(3) emulsion, acrylate and the hydroxyethyl cellulose of parts by weight are finally put into, rotating speed is 500 revs/min, low speed point
Dissipate 10min.
Embodiment 2
A kind of kitchen wall surface fireproof mould-proof coating, the coating is to be prepared from the following raw materials in parts by weight：
55 parts of emulsion；Glutaric acid two（Second-methyl-prop）5 parts of ester；γ-（Ethylenediamine base）1.2 parts of propyl trimethoxy silicane；Lemon
2 parts of lemon acid；2.5 parts of hydroxyethyl cellulose；0.8 part of polyoxyethylene polyoxy propyl alcohol amidogen ether；3 parts of shitosan；Antimildew disinfectant
361 6 parts of ROCIMA；5 parts of fire retardant；1 part of acrylate；16 parts of water；11 parts of zinc oxide；18 parts of powdered whiting.
Described emulsion is the mixed liquor of silicone acrylic emulsion and pure-acrylic emulsion, and both weight ratios are followed successively by 1.5:1；Wherein,
The A-102 products that silicone acrylic emulsion is produced using Shanghai Zhen Zhou chemistry painting industries Co., Ltd；Pure-acrylic emulsion uses Shanghai and shakes continent
The A-99 products of chemistry painting industry Co., Ltd production.Described fire retardant is xylenylphosphate, diammonium hydrogen phosphate and nanometer
Firebrake ZB is according to 5:3:2 part by weight is mixed to get.
Described kitchen wall surface uses fireproof mould-proof coating, its preparation method to comprise the following steps:
(1) water, the glutaric acid two of parts by weight are sequentially added in a mixer（Second-methyl-prop）It is ester, citric acid, shitosan, anti-
Mould bactericide ROCIMA 361 and fire retardant, start stirring, and rotating speed is 1000 revs/min, at a high speed dispersion 10min；
(2) start in polyoxyethylene polyoxy propyl alcohol amidogen ether, zinc oxide and powdered whiting addition blender by weight
Stirring, rotating speed be 1100 revs/min, be warmed up to 75 DEG C, then using dripping method be uniformly added into γ-（Ethylenediamine base）Propyl group trimethoxy
Base silane, drop rate is controlled in 1-2 drops/min, continues to stir 25min after adding；
(3) emulsion, acrylate and the hydroxyethyl cellulose of parts by weight are finally put into, rotating speed is 550 revs/min, low speed point
Dissipate 8min.
Embodiment 3
A kind of kitchen wall surface fireproof mould-proof coating, the coating is to be prepared from the following raw materials in parts by weight：
60 parts of emulsion；Glutaric acid two（Second-methyl-prop）6 parts of ester；γ-（Ethylenediamine base）1.5 parts of propyl trimethoxy silicane；Lemon
3 parts of acid；3 parts of hydroxyethyl cellulose；1 part of polyoxyethylene polyoxy propyl alcohol amidogen ether；4 parts of shitosan；Antimildew disinfectant ROCIMA 361
8 parts；6 parts of fire retardant；1.5 parts of acrylate；17 parts of water；12 parts of zinc oxide；20 parts of powdered whiting.
Described emulsion is the mixed liquor of silicone acrylic emulsion and pure-acrylic emulsion, and both weight ratios are followed successively by 1.5:1；Wherein,
The A-102 products that silicone acrylic emulsion is produced using Shanghai Zhen Zhou chemistry painting industries Co., Ltd；Pure-acrylic emulsion uses Shanghai and shakes continent
The A-99 products of chemistry painting industry Co., Ltd production.Described fire retardant is xylenylphosphate, diammonium hydrogen phosphate and nanometer
Firebrake ZB is according to 5:3:2 part by weight is mixed to get.
Described kitchen wall surface uses fireproof mould-proof coating, its preparation method to comprise the following steps:
(1) water, the glutaric acid two of parts by weight are sequentially added in a mixer（Second-methyl-prop）It is ester, citric acid, shitosan, anti-
Mould bactericide ROCIMA 361 and fire retardant, start stirring, and rotating speed is 1000 revs/min, at a high speed dispersion 10min；
(2) start in polyoxyethylene polyoxy propyl alcohol amidogen ether, zinc oxide and powdered whiting addition blender by weight
Stirring, rotating speed be 1100 revs/min, be warmed up to 80 DEG C, then using dripping method be uniformly added into γ-（Ethylenediamine base）Propyl group trimethoxy
Base silane, drop rate is controlled in 1-2 drops/min, continues to stir 20min after adding；
(3) emulsion, acrylate and the hydroxyethyl cellulose of parts by weight are finally put into, rotating speed is 600 revs/min, low speed point
Dissipate 5min.
Quality testing
The kitchen wall surface that embodiment of the present invention 1-3 is prepared carries out performance detection with fireproof mould-proof coating, as a result such as table 1 below
It is shown：
From the data in table 1, it is apparent that the kitchen wall surface for preparing of the present invention with fireproof mould-proof coating in different rings
Good film forming, resistance to ag(e)ing, scrub resistance, weatherability, stain resistance, water resistance and alkali resistance are respectively provided with the conditions of border,
And with mould proof fireproof effect, the coating also has good workability, and the coating that the present invention is prepared can expire
The requirement of sufficient kitchen's interior, is particularly suitable for the metope in kitchen and uses.
Claims (4)
1. a kind of kitchen wall surface fireproof mould-proof coating, it is characterised in that：The coating is to be prepared from the following raw materials in parts by weight：
Emulsion 50-60 parts；Glutaric acid two（Second-methyl-prop）Ester 4-6 parts；γ-（Ethylenediamine base）Propyl trimethoxy silicane 1-
1.5 parts；Citric acid 1-3 parts；Hydroxyethyl cellulose 2-3 parts；0.5-1 parts of polyoxyethylene polyoxy propyl alcohol amidogen ether；Shitosan 2-4
Part；5-8 parts of antimildew disinfectant ROCIMA 361；Fire retardant 4-6 parts；Acrylate 0.5-1.5 parts；Water 15-17 parts；Oxidation
Zinc 10-12 parts；Powdered whiting 15-20 parts.
2. kitchen wall surface according to claim 1 fireproof mould-proof coating, it is characterised in that：Described emulsion is the breast of silicon third
The mixed liquor of liquid and pure-acrylic emulsion, both weight ratios are followed successively by 1.5:1；Wherein, silicone acrylic emulsion is applied using shake continent chemical industry of Shanghai
The A-102 products of material Co., Ltd production；Pure-acrylic emulsion uses the A-99 of Shanghai Zhen Zhou chemistry painting industries Co., Ltd production
Product.
3. kitchen wall surface according to claim 1 fireproof mould-proof coating, it is characterised in that：Described fire retardant is phosphoric acid
Diformazan phenyl ester, diammonium hydrogen phosphate and nano-zinc borate are according to 5:3:2 part by weight is mixed to get.
4. kitchen wall surface according to claim 1 fireproof mould-proof coating, it is characterised in that：Its preparation method includes following
Step:
(1) water, the glutaric acid two of parts by weight are sequentially added in a mixer（Second-methyl-prop）It is ester, citric acid, shitosan, anti-
Mould bactericide ROCIMA 361 and fire retardant, start stirring, and rotating speed is 1000 revs/min, at a high speed dispersion 10min；
(2) start in polyoxyethylene polyoxy propyl alcohol amidogen ether, zinc oxide and powdered whiting addition blender by weight
Stirring, rotating speed be 1100 revs/min, be warmed up to 70 DEG C -80 DEG C, then using dripping method be uniformly added into γ -（Ethylenediamine base）Propyl group
Trimethoxy silane, drop rate is controlled in 1-2 drops/min, continues to stir 20-30min after adding；
(3) emulsion, acrylate and the hydroxyethyl cellulose of parts by weight are finally put into, rotating speed is 500-600 revs/min, low
Speed dispersion 5-10min.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114539839A (en) * | 2022-01-21 | 2022-05-27 | 宁国市茂发装饰材料有限公司 | Antibacterial ultrathin fireproof water-based paint and preparation method thereof |
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| CN101595880A (en) * | 2008-06-06 | 2009-12-09 | 比亚迪股份有限公司 | Complex antimicrobials and antimicrobial coating composition and antimicrobial coating material |
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