CN106631398B - Special water-soluble soil conditioning package for saline-alkali soil and preparation method thereof - Google Patents

Special water-soluble soil conditioning package for saline-alkali soil and preparation method thereof Download PDF

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CN106631398B
CN106631398B CN201611106825.7A CN201611106825A CN106631398B CN 106631398 B CN106631398 B CN 106631398B CN 201611106825 A CN201611106825 A CN 201611106825A CN 106631398 B CN106631398 B CN 106631398B
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soil
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nutrient
stirring
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CN106631398A (en
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陈以
马巧荣
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Shaanxi Hantang Agricultural Technology Group Co ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C21/00Methods of fertilising, sowing or planting
    • A01C21/005Following a specific plan, e.g. pattern
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C1/00Ammonium nitrate fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C5/00Fertilisers containing other nitrates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/20Mixtures of one or more fertilisers with additives not having a specially fertilising activity for preventing the fertilisers being reduced to powder; Anti-dusting additives
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Soil Sciences (AREA)
  • Environmental Sciences (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a water-soluble soil conditioning package special for saline-alkali soil and a preparation method thereof. The soil conditioning package comprises a component A: special soil conditioner and B component: the special nutritional agent comprises two parts. Wherein the component A comprises the following components: the special soil conditioner is produced by 50-70 parts of monosodium glutamate tail liquid, 10-20 parts of organic matters, 1-10 parts of amino acids, 10-30 parts of nutrient elements, 0.1-1 part of biological stimulation hormone, 0.01-0.5 part of stress-resistant factors and 0.01-1 part of surfactant through certain steps. And the component B comprises the following components: the index of the special nutritional agent is that the content of K2O is 5-10%; the content of medium nutrient elements (Ca+Mg) is 5 to 15 percent; the total content of the trace nutrient elements (Fe+Mn+Zn+Cu+B) is 0.1 to 1 percent, wherein, fe is 0 to 0.8 percent, mn is 0 to 0.5 percent, zn is 0 to 1 percent, cu is 0 to 0.3 percent, and B is 0 to 1 percent; the content of the anti-caking agent is 3-5%. The conditioning package can condition soil in stages and with key points, and provide nutrition elements beneficial to stress resistance of plants in a targeted manner, so that the re-accumulation of salt is avoided, and the occurrence of the symptom of lack of nutrients of crops is prevented.

Description

Special water-soluble soil conditioning package for saline-alkali soil and preparation method thereof
1. Technical field
The invention relates to a preparation and use method of a soil conditioning package, in particular to a preparation and use method of a water-soluble soil conditioning package special for saline-alkali soil, belonging to the technical field of fertilizer production.
2. Background art
Soil is the root of agricultural planting, and a healthy soil environment is an important guarantee for agricultural development. In recent years, the acid-alkalization salinization of soil is increased due to unreasonable cultivation, excessive planting, unscientific fertilizer use and the like widely existing in various main agricultural areas in China. Saline soil and alkaline earth often coexist in a mixed manner, collectively referred to as saline-alkaline earth. The saline-alkali soil has high salt content, low organic mass, high pH value, poor ventilation and water permeability, and is lack of large, medium and trace elements such as nitrogen, phosphorus, potassium, iron, calcium, boron and the like. Saline-alkali becomes one of the important factors affecting the yield of crops at present, and restricts the healthy growth of crops, so that the yield of crops is reduced to a great extent, and the data show that the saline-alkali hazard causes about 40% yield loss.
At present, the area of Chinese saline-alkali soil is about 2000 ten thousand hectares, and so far about 80% of the Chinese saline-alkali soil is not developed and utilized. The improvement and utilization of saline-alkali soil is a forced matter at present of increasingly lacking cultivated land resources and serious ecological environment damage.
CN 105567240A discloses a method for preparing soil conditioner by using fowl feather, which is prepared by a series of reactions between amino acid obtained by hydrolyzing fowl feather and citric acid, and medium trace elements. The liquid soil conditioner has the defect that on the basis of improving soil, only medium trace elements with fixed content and proportion can be provided for crops, but large amount of major elements with large growth demand are not provided for crops. CN104261988B discloses a special suspension liquid compound fertilizer for saline-alkali soil and a preparation method thereof, wherein the compound fertilizer comprises nitrogen fertilizer, boron fertilizer, EDTA-Zn, EDTA-Mn, humic acid powder, calcium fertilizer, phosphate fertilizer, potash fertilizer, organic matters, soil conditioner, microbial inoculum, wetting dispersant, emulsifier, thickener, antifreezing agent and water in parts by weight. The fertilizer has the defects that the fertilizer mainly provides various nutrient elements required by crops, the soil conditioner is only one of the components of the compound fertilizer, and the conditioner is one or more of mineral powder, is a water-insoluble substance and cannot quickly and effectively improve the acidity and alkalinity of soil. CN 101323548B discloses a plant acid-alkali fertilizer for treating saline-alkali soil, which is prepared from plant straw 37-60%, plant acid 21-42%, compound amino acid 10-26%, polyamide 1-4% and acid liquor 1-4% with total amount of 100%, and has the disadvantages of providing soil improving substances only and not providing large, medium and trace elements necessary for crop growth.
In summary, although there are various special products for improving saline-alkali soil in the market at present, the special products exist in a single product, and the direct improvement of soil and the provision of nutrition for improving stress resistance of plants are not scientifically and reasonably matched in a package manner; the nutrient elements which are beneficial to enhancing the stress resistance of crops can not be matched with the soil conditioning in different growth stages of the crops, so that the purposes of improving the soil, enhancing the stress resistance of the crops and increasing the yield and income are achieved; the special fertilizer or soil conditioner for the saline-alkali soil is difficult to comprehensively apply in a precise water and fertilizer integrated system, because low-grade fertilizer and impurities are difficult to pass through the water and fertilizer integrated filtering system.
3. Summary of the invention
In order to overcome the defects of the prior art, the invention provides a water-soluble fertilizer package which can be used for preventing and improving soil salinization of a water-fertilizer integrated system so as to solve the problem of preventing and controlling soil salinization under the condition of water-fertilizer integration. The soil conditioner can effectively improve the physical and chemical properties of soil, simultaneously meet the requirements of crop growth on various nutrient elements, can condition the soil in stages and with emphasis, and is matched with the nutrient elements which are favorable for enhancing the stress resistance of plants, and the soil conditioner induces the plants to improve the autoimmune power, so that the re-accumulation of salt is avoided, and the occurrence of the symptom of lack of nutrients of crops can be effectively prevented.
The technical scheme of the invention is as follows:
a water-soluble soil conditioning package special for saline-alkali soil is prepared from the following components: special soil conditioner and B component: the special nutritional agent comprises two parts.
The component A comprises the following components: the special soil conditioner consists of the following components in parts by weight:
50 to 70 parts of monosodium glutamate tail liquid, 10 to 20 parts of organic matters, 1 to 10 parts of amino acid, 10 to 30 parts of nutrient elements, 0.1 to 1 part of biological stimulation hormone, 0.01 to 0.5 part of stress-resistant factors and 0.01 to 1 part of surfactant.
The component A comprises the following components: the special soil conditioner is produced by the following steps:
1) Adding monosodium glutamate tail liquid into a reaction kettle according to parts by weight, heating to 90-100 ℃ under normal pressure, keeping stirring for 10-30 minutes, and stopping heating;
2) Adding biological hormone into the liquid obtained in the step 1), stirring while adding until the biological hormone is completely dissolved in monosodium glutamate tail liquid, and stirring for 20-40 minutes;
3) Adding nutrient elements into the liquid obtained in the step 2) while stirring, wherein the addition sequence of the nutrient elements is boron, manganese, iron, copper, zinc, phosphorus, potassium and nitrate nitrogen;
4) Adding organic matters into the liquid obtained in the step 3), and stirring while adding until the organic matters are fully dissolved;
5) After the temperature of the liquid obtained in the step 4) is reduced to below 50 ℃, adding the rest of nitrogen raw materials, and stirring while adding until the rest of nitrogen raw materials are fully dissolved;
6) When the temperature of the liquid obtained in the step 5) is reduced to below 40 ℃, adding amino acid and a stress-resistant factor which is specially treated and soluble in water into the liquid, and stirring while adding until the raw materials are fully dissolved;
7) Adding a surfactant into the liquid obtained in the step 6), and stirring for more than 60 minutes until the surfactant is fully dissolved, wherein the liquid is the component A: special soil conditioner finished product.
The monosodium glutamate tail liquid is mother liquid discharged after glutamic acid is extracted from monosodium glutamate fermentation liquid, and is also called fermentation mother liquid or ion exchange tail liquid. Typical characteristics of such wastewater are: the pH is acidic, and contains a large amount of nitrogen, phosphorus, potassium, sulfur, trace elements, amino acids and organic matters. The monosodium glutamate tail liquid has the effects of improving soil: the nutrient elements, amino acids and organic matters contained in the waste liquid can be utilized by crops, so that the growth condition of the crops is improved, and the contained organic matters can keep the activity of soil microorganisms and the biochemical environment of the soil; the waste liquid is acidic, can neutralize the alkalinity of the soil when being used on saline-alkali soil, can obviously reduce the pH value of the soil, has good persistence, is beneficial to plant growth, and can activate medium and trace elements fixed by the soil; the monosodium glutamate tail solution has stronger acidity, can dissolve insoluble phosphorus and improve the phosphorus content of various forms.
The organic matter is one or more of citric acid, biochemical potassium fulvate, dextrose, mannitol and sorbitol.
The amino acid is one or more of glycine, proline, ornithine, glutamic acid and derivatives thereof.
The nutrient elements are one or more of nitrogen, phosphorus, potassium, iron, manganese, copper, zinc and boron. Wherein the macroelement nitrogen, phosphorus and potassium raw materials are one or more of urea, potassium nitrate, 40% nitric acid, monoammonium phosphate, monopotassium phosphate, 85% phosphoric acid and ammonium polyphosphate. The raw materials of the microelements of iron, manganese, copper, zinc and boron are ferrous sulfate, EDDHA iron, manganese sulfate, copper nitrate, zinc sulfate, zinc nitrate and boric acid respectively. All the above-mentioned macronutrient and macronutrient element raw materials adopt industrial grade raw materials (national standard or industry standard is implemented).
The biostimulant is a substance comprising certain components and organisms, which when applied to a plant or root canal, have the effect of stimulating the natural processes of the plant, including enhancing/benefiting nutrient absorption, nutrient efficacy, abiotic stress resistance and crop quality, independently of the nutrient components. The biological hormone is one or more soluble biological hormones selected from humic acid substances, composite organic substances, beneficial chemical elements, non-organic minerals (including phosphite), seaweed extracts, chitin and chitosan derivatives, anti-transpiration agents or free amino acids.
The particle size of the soluble substance is required to be smaller than 80 microns.
The stress-resistant factor comprises one or more of betaine, flavonoid, abscisic acid, polyamine, paclobutrazol, salicylic acid, cytokinin and 90% brassinolide.
The surfactant is one or more of nonionic surfactants, suitable nonionic surfactants include all such materials commonly used in agrochemical compositions, preferably ethoxylates.
The component A comprises the following components: the nutrition content index of the special soil conditioner is nitrogen (N) +phosphorus (P) 2 O 5 ) +potassium (K) 2 O) is more than or equal to 100g/L, iron (Fe) +manganese (Mn) +copper (Cu) +zinc (Zn) +boron (B) is more than or equal to 5g/L, organic matters are more than or equal to 100g/L, and the component A is: the pH value of the special soil conditioner stock solution is 2-5.
The component B comprises the following components: the special nutritional agent consists of the following components:
macronutrient element K 2 The total content of O is 5-10%; the content of medium nutrient elements (Ca+Mg) is 5 to 15 percent; the total content of the trace nutrient elements (Fe+Mn+Zn+Cu+B) is 0.1 to 1 percent, wherein, fe is 0 to 0.8 percent, mn is 0 to 0.5 percent, zn is 0 to 1 percent, cu is 0 to 0.3 percent, and B is 0 to 1 percent; the content of the anti-caking agent is 3-5%.
The component B comprises the following components: the special nutrient contains nitrogen, potassium, calcium and magnesium, but the proportion of each element and the addition of microelements iron, manganese, zinc, copper and boron can be adjusted within the given range according to the principle of soil testing and fertilization according to the specific situation.
The component B comprises the following components: the special nutrient production steps are as follows:
according to the component B: calculating the quantity of the needed raw materials, quantitatively weighing the dried raw materials, crushing and sieving the granular raw materials, putting the crushed and sieved raw materials into powder fertilizer production equipment, fully mixing and stirring uniformly, and packaging to obtain the finished product.
The potassium fertilizer is preferably potassium nitrate.
The calcium fertilizer is preferably one or more of calcium nitrate, calcium ammonium nitrate and calcium EDTA.
The magnesium fertilizer is preferably one or more of magnesium nitrate and EDTA magnesium.
The micro-fertilizer is one or more of iron (Fe), manganese (Mn), copper (Cu), zinc (Zn) and boron (B), and is respectively selected from one or more of EDTA iron, EDDHA iron, EDTA manganese, copper nitrate, EDTA copper, zinc nitrate, EDTA zinc and boric acid.
The anti-caking agent is a commercial anti-caking agent product without sulfate ions.
The application method of the water-soluble soil conditioning package special for the saline-alkali soil comprises the following steps:
1) The application method of the vegetable crops comprises the following steps: before soil is ploughed, the component A of the special soil conditioning package for the saline-alkali soil is prepared by the following steps: the special soil conditioner is diluted by water for 50-100 times and uniformly sprayed on the ground surface. During flowering and fruiting period, the component A: diluting the special soil conditioner by 200-300 times, and mixing the component B: diluting the special nutrient for 800-1500 times, respectively carrying out drip irrigation or flushing at 7-15 days, and mixing the component B: the special nutrient is diluted 1500-2000 times for one-time foliage spraying.
2) The application method of the grain and cotton crops comprises the following steps: before sowing, the component A: the special soil conditioner is diluted by 100-200 times by water and uniformly sprayed on the ground surface, and then ploughed. Component A in reproductive phase: diluting the special soil conditioner by 200-300 times, performing drip irrigation or flushing, and mixing the component B: the special nutrient is diluted 1500-2000 times and sprayed on the leaves once, and the time interval is 7-15 days.
3) The application method of the fruit tree crops comprises the following steps: after fruit harvest, the a component is applied with base fertilizer: the special soil conditioner is diluted by 50-100 times and comprises the following components: diluting the special nutrient for 800-1000 times, and dripping the nutrient once for 10-15 days; during germination, component A: diluting the special soil conditioner by 200-300 times, and the component B: diluting the special nutrient for 1000-1500 times, and dripping the nutrient once for 10-15 days; during the fruit expanding period, the component B is prepared by the following steps: the special nutrient is diluted 1500-2000 times and sprayed for 1-2 times, and the time interval is 10-15 days.
The application method can increase and decrease the use concentration or the use times at proper time according to the fertilizer requirement rule of specific crops, the local soil climate and other conditions.
Compared with the prior art, the invention has the following excellent effects:
1) The soil conditioning package can be fully dissolved in water, can be applied to soil through a water and fertilizer facility system in different growth stages of crops, directly acts on the root system environment of the crops, and directly improves the root system soil environment and the nutrition condition of the crops. Has the advantages of convenient use, time saving, labor saving, fertilizer saving, quick fertilizer efficiency and the like.
2) The soil conditioning package can regulate plant rhizosphere microenvironment, promote plant root system formation, stimulate the secretion of acidic substances of plant root system, activate soil nutrients and stimulate the self-repairing mechanism of soil.
3) The conditioning package uses the component A at different stages: the special soil conditioner and the special nutrient for B regulate the physical and chemical properties of the soil, avoid the re-accumulation of salt, provide nutrient elements required by growth and development for crops, and effectively prevent the occurrence of the symptom of lack of nutrients for crops.
Fourth, detailed description of the invention
The following description of the present invention will be made clearly and fully, and it will be apparent that the embodiments described are merely a few, but not all, of the embodiments of the present invention. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example one:
the component A in the package: preparation of special soil conditioner:
680kg of monosodium glutamate tail liquid is added into a reaction 1000L reactor according to the proportion, heated to 90-100 ℃ under normal pressure, kept stirring for 30 minutes, and stopped heating; then adding 1kg of potassium fulvate and 0.5kg of soluble chitin, stirring while adding until the potassium fulvate and the soluble chitin are dissolved, and stirring for 20 minutes; adding 6kg of boric acid, stirring for 10 minutes until the boric acid is fully dissolved, then adding 2kg of manganese sulfate, stirring for 20 minutes until the boric acid is fully dissolved, then adding 4kg of ferrous sulfate heptahydrate, stirring for 10 minutes until the ferrous sulfate heptahydrate is fully dissolved, adding 1kg of copper sulfate pentahydrate, stirring for 10 minutes until the boric acid is fully dissolved, adding 14kg of zinc sulfate heptahydrate, stirring for 10 minutes until the boric acid is fully dissolved, adding 20kg of monoammonium phosphate, stirring for more than 20 minutes until the boric acid is fully dissolved, then adding 3kg of potassium nitrate, and stirring for more than 20 minutes until the boric acid is fully dissolved; adding 35kg of citric acid, stirring for more than 30 minutes until the mixture is fully dissolved, adding 50kg of dextrose, and stirring for more than 10 minutes while adding until the mixture is fully dissolved. The temperature of the obtained liquid was reduced to below 50 ℃, 150kg of urea was added while stirring until it was sufficiently dissolved. At this time, the temperature of the liquid was measured, and when the temperature of the liquid was lowered to 40 ℃ or lower, 30kg of glycine and 3kg of betaine were added, and stirring was performed for 10 minutes or more while adding until the raw materials were sufficiently dissolved, 0.05kg of surfactant was added, and stirring was performed for 60 minutes or more, and the liquid at this time, which was uniformly stirred, was the component a: special soil conditioner finished product.
The component A comprises the following components: the nutrition index of the special soil conditioner is nitrogen (N) +phosphorus (P2O 5) +potassium (K2O) more than or equal to 140g/L, wherein the content of the nitrogen, the phosphorus and the potassium is respectively N more than or equal to 120g/L, P2O5 is more than or equal to 12g/L, K2O is more than or equal to 8g/L, organic matters are more than or equal to 130g/L, trace elements of iron (Fe) +manganese (Mn) +copper (Cu) +zinc (Zn) +boron (B) are more than or equal to 5.7g/L,
the component B in the package: preparation of special nutritional agent: weighing 590kg of dried crushed and sieved calcium ammonium nitrate, 140kg of dried magnesium nitrate, 220kg of potassium nitrate, 10kg of boric acid, 10kg of EDTA-Zn and 30kg of nano-scale silicon dioxide, putting into powder fertilizer production equipment, fully mixing and uniformly stirring, and packaging to obtain the finished product.
The component B comprises the following components: the nutrition index content of the special nutritional agent is as follows: the content of K2O is 9.9%, the content of Ca+Mg is 11%, wherein the content of Ca is 10%, the content of Mg is 1%, and the content of trace element B+Zn is 0.3%.
The soil conditioning package obtained in example one was applied to pumpkin shell-less samsung for Gobi seed in North Tun in the region of Altaylor in Xinjiang, 4 to 9 months in 2015. The basic physicochemical properties of the soil in the test field are shown in Table 1:
TABLE 1 soil basic physicochemical Properties of pumpkin test in Altaylor region of Xinjiang
And (3) test design: the test is provided with two treatments, namely T1 peasant habit fertilization and T2 peasant habit fertilization and soil conditioning package of the first embodiment.
Under the T1 treatment, farmers are accustomed to fertilizing methods as follows: the diammonium is 15 kg/mu, the urea is 10 kg/mu, and the additional fertilizer is 8 kg/mu of potassium sulfate.
Under the T2 treatment, on the basis of the habit of peasants for fertilization, a soil conditioning package is used. Before soil is ploughed, the component A in the special soil conditioning package for the saline-alkali soil is prepared: the special soil conditioner is diluted by water for 100 times, is uniformly sprayed on the ground surface before ploughing, and uses diammonium 15 kg/mu during ploughing. During flowering, the A component: the special soil conditioner is diluted 300 times and 10kg of urea is used for drip irrigation. And (3) the component B: the special nutrient is diluted 1500 times for flushing at 15-day intervals, and the component B is mixed in the fruiting period: the special nutrient is diluted 2000 times for one-time foliage spraying.
TABLE 2 influence of saline-alkali soil Conditioning packages on pumpkin yield and soil
As can be seen from Table 2, on the basis of conventional fertilization, the yield of pumpkin seeds (T2 treatment, 113 kg/mu) under the soil conditioning package of example one is increased by 28 kg/mu compared with that of farmers (T1 treatment, 85 kg/mu), and the postprandial yield of pumpkin seeds is increased by 33% compared with that of conventional fertilization by using the soil conditioning package. And the application of the special modifier package for the saline-alkali soil can reduce the total salt content and the soil density of the soil, reduce the pH value of the soil and improve the content levels of quick-acting nitrogen, phosphorus, potassium and organic matters in the soil to different degrees.
Example two:
the component A in the package: preparation of special soil conditioner:
adding 650kg of monosodium glutamate tail liquid into a reaction kettle according to the proportion, heating to 90-100 ℃ under normal pressure, continuously stirring for 30 minutes, and stopping heating; then adding 5kg of water-soluble chitosan, stirring while adding until the water-soluble chitosan is dissolved, and stirring for 50 minutes; adding 6kg of boric acid, stirring for 20 minutes until the boric acid is fully dissolved, then adding 1kg of manganese sulfate monohydrate, stirring for 20 minutes until the manganese sulfate is fully dissolved, then adding 5kg of ferrous sulfate heptahydrate, stirring for 10 minutes until the ferrous sulfate heptahydrate is fully dissolved, adding 1kg of copper sulfate pentahydrate, stirring for 10 minutes until the ferrous sulfate heptahydrate is fully dissolved, adding 13kg of zinc sulfate heptahydrate, stirring for 10 minutes until the zinc sulfate heptahydrate is fully dissolved, adding 10kg of monoammonium phosphate, stirring for more than 20 minutes until the zinc sulfate heptahydrate is fully dissolved, then adding 2kg of potassium nitrate, and stirring for more than 20 minutes until the zinc sulfate heptahydrate is fully dissolved; adding 40kg of citric acid, stirring for more than 30 minutes until the citric acid is fully dissolved, adding 40kg of biochemical potassium fulvate, and stirring for more than 30 minutes while adding until the potassium fulvate is fully dissolved. The temperature of the obtained liquid was reduced to 50℃or lower, and 184.49kg of urea was added thereto while stirring until it was sufficiently dissolved. At this time, the temperature of the liquid was measured, when the temperature of the liquid was lowered to 40 ℃ or lower, 10kg glycine and 30kg proline were added, stirring was performed for 10 minutes or more while adding until the raw materials were sufficiently dissolved, 0.01kg90% of brassinolide was dissolved with a small amount of ethanol, and then added to the solution together with 0.5kg flavonoid, and sufficiently stirred for dissolution, 2kg surfactant was added, stirring was performed for 60 minutes or more, and the liquid at this time was uniformly stirred as a component a: special soil conditioner finished product.
The component A comprises the following components: the special soil conditioner has the nutrition indexes of nitrogen (N) +phosphorus (P2O 5) +potassium (K2O) of more than or equal to 148g/L, wherein the content of nitrogen, phosphorus and potassium is respectively more than or equal to 120g/L, P2O5 is more than or equal to 12g/L, K2O is more than or equal to 8g/L, organic matters are more than or equal to 120g/L, and trace elements of iron (Fe) +manganese (Mn) +copper (Cu) +zinc (Zn) +boron (B) are more than or equal to 5.4g/L.
The component B in the package: preparation of special nutritional agent: weighing 300kg of dried crushed and sieved calcium ammonium nitrate, 440kg of dried magnesium nitrate, 200kg of potassium nitrate, 5kg of boric acid, 20kg of EDTA-Zn, 5kg of EDTA-Mn and 30kg of nano-scale silicon dioxide, putting into powder fertilizer production equipment, fully mixing and uniformly stirring, and packaging to obtain the finished product.
The component B comprises the following components: the nutrition index content of the special nutritional agent is as follows: the content of K2O is 9%, the content of Ca+Mg is 9%, wherein the content of Ca is 5.2%, the content of Mg is 3.8%, and the content of trace elements B+Zn+Mn is 0.37%.
The soil conditioning package obtained in example two was applied to a double pasture sunflower of 181 balls of alemtai in Xinjiang, 4 to 9 months of 2015. The basic physicochemical properties of the soil in the test field are shown in Table 3:
TABLE 3 soil-based physicochemical Properties of sunflower test in Altaylor region of Xinjiang
And (3) test design: the test is provided with two treatments, namely T1 peasant habit fertilization and T2 peasant habit fertilization and soil conditioning package of the second embodiment.
Under the T1 treatment, farmers are accustomed to fertilizing methods as follows: base fertilizer diammonium phosphate 5 kg/mu, 18-18-18 compound fertilizer 5 kg/mu, and additional urea 20 kg/mu.
Under the T2 treatment, on the basis of the habit of peasants for fertilization, a soil conditioning package is used. Before soil is ploughed, the component A in the special soil conditioning package for the saline-alkali soil is prepared: the special soil conditioner is diluted by 100 times by water and uniformly sprayed on the ground surface before ploughing. Before bud emergence, urea is applied, and the component A is formed in the flower disc forming period: drip irrigation is carried out by the special soil conditioner dilution 300, and the component B is prepared at the end of flowering: the special nutrient is diluted 1500 times for flushing, the time interval is 8 days, the fruiting period is that the component B is mixed: the special nutrient is diluted 2000 times for one-time foliage spraying.
TABLE 4 influence of saline-alkali soil Conditioning packages on sunflower yield and soil
As can be seen from Table 4, on the basis of conventional fertilization, the sunflower seed yield (T2 treatment, 158 kg/mu) under the soil conditioning package of example two is increased by 26 kg/mu compared with that of conventional fertilization (T1 treatment, 132 kg/mu) of farmers, and the postprandial yield of the sunflower seeds is increased by 20% compared with that of conventional fertilization by using the soil conditioning package. And the application of the special modifier package for the saline-alkali soil can reduce the total salt content and the soil density of the soil, reduce the pH value of the soil and improve the content levels of quick-acting nitrogen, phosphorus, potassium and organic matters in the soil to different degrees.
Example three:
the component A in the package: preparation of special soil conditioner:
adding 737kg of monosodium glutamate tail liquid into a reaction kettle according to the proportion, heating to 90-100 ℃ under normal pressure, continuously stirring for 30 minutes, and stopping heating; then adding 10kg of 50% alginic acid liquid, stirring while adding until dissolving, stirring for 40 min; adding 5kg of boric acid, stirring for 20 minutes until the boric acid is fully dissolved, then adding 2kg of manganese sulfate monohydrate, stirring for 20 minutes until the manganese sulfate is fully dissolved, then adding 6kg of ferrous sulfate heptahydrate, stirring for 20 minutes until the manganese sulfate is fully dissolved, adding 1kg of copper sulfate pentahydrate, stirring for 10 minutes until the copper sulfate pentahydrate is fully dissolved, adding 15kg of zinc nitrate hexahydrate, stirring for 10 minutes until the zinc nitrate hexahydrate is fully dissolved, adding 25kg of monoammonium phosphate, stirring for more than 20 minutes until the zinc nitrate is fully dissolved, then adding 5kg of potassium nitrate, and stirring for more than 20 minutes until the zinc sulfate pentahydrate is fully dissolved; adding 30kg of dextrose, stirring for more than 30 minutes until the dextrose is fully dissolved, adding 20kg of sorbitol, and stirring for more than 30 minutes while adding until the sorbitol is fully dissolved. The temperature of the obtained liquid was reduced to below 50 ℃, and 100kg of urea was added while stirring until it was sufficiently dissolved. At this time, the temperature of the liquid was measured, and when the temperature of the liquid was lowered to 40 ℃ or lower, 30kg of proline, 5kg of sodium glutamate, and 5kgL ornithine salt were added in order, respectively, with stirring for 10 minutes or more until the raw materials were sufficiently dissolved, 1kg of salicylic acid and 1kg of zeatin were added to the solution, and the solution was sufficiently stirred and dissolved, 2kg of surfactant was added, and stirring was performed for 60 minutes or more, and the liquid at this time was uniformly stirred was the component a: special soil conditioner finished product.
The component A comprises the following components: the special soil conditioner has the nutrition indexes of more than or equal to 130g/L of nitrogen (N) +phosphorus (P2O 5) +potassium (K2O), wherein the content of the nitrogen, the phosphorus and the potassium is respectively more than or equal to 105g/L of N, more than or equal to 16g/L of P2O5, more than or equal to 9g/L of K2O, more than or equal to 115g/L of organic matters, and more than or equal to 6.2g/L of trace elements of iron (Fe) +manganese (Mn) +copper (Cu) +zinc (Zn) +boron (B).
The component B in the package: preparation of special nutritional agent: weighing 550kg of dried magnesium nitrate, 220kg of EDTA-Ca, 120kg of potassium nitrate, 30kg of boric acid, 25kg of EDTA-Zn, 5kg of EDTA-Mn and 50kg of nano-scale silicon dioxide, putting into powder fertilizer production equipment, fully mixing and uniformly stirring, and sub-packaging to obtain the finished product.
The component B comprises the following components: the nutrition index content of the special nutritional agent is as follows: K2O is more than or equal to 5%, ca+Mg is more than or equal to 6.5%, wherein the content of Ca is 1.8%, the content of Mg is 4.7%, and the content of trace elements B+Zn+Mn is 0.9%.
The soil conditioning package obtained in example three was applied to cotton in the region of north of taylor in 2015 for 4 to 10 months. The basic physicochemical properties of the soil of the test field are shown in Table 5:
TABLE 5 soil basic physicochemical Properties of Cotton test in Altaylor region of Xinjiang
And (3) test design: the test is provided with two treatments, namely asking for T1 peasant habit fertilization and T2 peasant habit fertilization and soil conditioning package of the third embodiment.
Under the T1 treatment, farmers are accustomed to fertilizing methods as follows: 10kg of urea and 15kg of diammonium are applied to each mu of base; and (3) additional fertilizer, wherein each mu of urea is 35kg, and 2kg of monopotassium phosphate is sprayed.
Under the T2 treatment, on the basis of the habit of peasants for fertilization, a soil conditioning package is used. Before sowing, the component A: the special soil conditioner is diluted by water for 150 times and uniformly sprayed on the ground surface, urea and diammonium are applied on the ground surface, and then ploughing is carried out. Component A in reproductive phase: diluting the special soil conditioner by 300 times, performing drip irrigation or flushing, and mixing the component B: the special nutrient is diluted 1500 times for foliar spraying once, and the time interval is 12 days.
TABLE 6 impact of saline-alkali soil conditioning packages on cotton yield and soil
As can be seen from Table 6, on the basis of conventional fertilization, the cotton yield (T2 treatment, 149 kg/mu) under the soil conditioning package described in example III was increased by 44 kg/mu compared with that of peasant conventional fertilization (T1 treatment, 105 kg/mu), and the postprandial yield was increased by 42% compared with that of conventional fertilization by using the soil conditioning package. And the application of the special modifier package for the saline-alkali soil can reduce the total salt content and the soil density of the soil, reduce the pH value of the soil and improve the content levels of quick-acting nitrogen, phosphorus, potassium and organic matters in the soil to different degrees.

Claims (5)

1. A special water-soluble soil conditioning package for saline-alkali soil is characterized in that: the package consists of a component A: special soil conditioner and B component: the special nutritional agent is formed by combining two parts:
the component A comprises the following components: the special soil conditioner consists of the following components in parts by weight:
50 to 70 parts of monosodium glutamate tail liquid, 10 to 20 parts of organic matters, 1 to 10 parts of amino acid, 10 to 30 parts of nutrient elements, 0.1 to 1 part of biological hormone, 0.01 to 0.5 part of stress-resistant factors and 0.01 to 1 part of surfactant;
and (3) a component A: the nutrition content index of the special soil conditioner is nitrogen (N) +phosphorus (P) 2 O 5 ) +potassium (K) 2 O) is more than or equal to 100g/L, iron (Fe) +manganese (Mn) +copper (Cu) +zinc (Zn) +boron (B) is more than or equal to 5g/L, organic matters are more than or equal to 100g/L, and pH value of the conditioner stock solution is 2-5;
the component B comprises the following components: the special nutritional agent consists of the following components:
macronutrient element K 2 The total content of O is 5-10%; the content of Ca+Mg in the medium nutrient element is 5 to 15 percent; the total content of the trace nutrient elements of Fe+Mn+Zn+Cu+B is 0.1 to 1 percent, wherein, fe is 0 to 0.8 percent, mn is 0 to 0.5 percent, zn is 0 to 1 percent, cu is 0 to 0.3 percent, and B is 0 to 1 percent; the content of the anti-caking agent is 3-5%;
the soil conditioning package comprises a component A: special soil conditioner:
the monosodium glutamate tail liquid is mother liquid discharged after glutamic acid is extracted from monosodium glutamate fermentation liquor;
the organic matter is one or more of citric acid, biochemical potassium fulvate, dextrose, mannitol and sorbitol;
the amino acid is one or more of glycine, proline, ornithine, glutamic acid and derivatives thereof;
the nutrient elements are one or more of nitrogen, phosphorus, potassium, iron, manganese, copper, zinc and boron, wherein the major element nitrogen, phosphorus and potassium are one or more of urea, potassium nitrate, 40% nitric acid, monoammonium phosphate, monopotassium phosphate, 85% phosphoric acid and ammonium polyphosphate, and the trace element iron, manganese, copper, zinc and boron are respectively ferrous sulfate, EDDHA iron, manganese sulfate, copper nitrate, zinc sulfate, zinc nitrate and boric acid, and the major, middle and trace nutrient element raw materials adopt industrial grade raw materials;
the biological hormone is one or more soluble biological hormones selected from humic acid substances, seaweed extract, chitin and chitosan derivatives, and the particle size of the soluble substances is less than 80 microns;
the stress-resistant factor comprises one or two of betaine, flavonoid, salicylic acid, cytokinin and 90% brassinolide;
the surfactant is one or more of nonionic surfactants.
2. The water-soluble soil conditioning package special for saline-alkali soil as claimed in claim 1, wherein: the component A in the package comprises the following components: the special soil conditioner is produced by the following steps:
1) Adding monosodium glutamate tail liquid into a reaction kettle according to parts by weight, heating to 90-100 ℃ under normal pressure, keeping stirring for 10-30 minutes, and stopping heating;
2) Adding biological hormone into the liquid obtained in the step 1), stirring while adding until the biological hormone is completely dissolved in monosodium glutamate tail liquid, and stirring for 20-40 minutes;
3) Adding nutrient elements into the liquid obtained in the step 2) while stirring, wherein the addition sequence of the nutrient elements is boron, manganese, iron, copper, zinc, phosphorus, potassium and nitrate nitrogen;
4) Adding organic matters into the liquid obtained in the step 3), and stirring while adding until the organic matters are fully dissolved;
5) After the temperature of the liquid obtained in the step 4) is reduced to below 50 ℃, adding the rest of nitrogen raw materials, and stirring while adding until the rest of nitrogen raw materials are fully dissolved;
6) When the temperature of the liquid obtained in the step 5) is reduced to below 40 ℃, adding amino acid and water-soluble stress-resistant factors into the liquid, and stirring while adding until the raw materials are fully dissolved;
7) Adding a surfactant into the liquid obtained in the step 6), and stirring for more than 60 minutes until the surfactant is fully dissolved, wherein the liquid is the component A: special soil conditioner finished product.
3. The water-soluble soil conditioning package special for saline-alkali soil as claimed in claim 1, wherein: the component B in the package comprises the following components: the special nutrient production steps are as follows:
according to the component B: calculating the quantity of the needed raw materials, quantitatively weighing the dried raw materials, crushing and sieving the granular raw materials, putting the crushed and sieved raw materials into powder fertilizer production equipment, fully mixing and stirring uniformly, and packaging to obtain the finished product.
4. The water-soluble soil conditioning package special for saline-alkali soil as claimed in claim 1, wherein:
and the component B comprises the following components: in the special nutrient, the potash fertilizer is preferably potassium nitrate; the calcium fertilizer is preferably one or more of calcium nitrate, calcium ammonium nitrate and calcium EDTA; the magnesium fertilizer is preferably one or more of magnesium nitrate and EDTA magnesium; the trace fertilizer is one or more of iron (Fe), manganese (Mn), copper (Cu), zinc (Zn) and boron (B), and is respectively selected from one or more of EDTA iron, EDDHA iron, EDTA manganese, copper nitrate, EDTA copper, zinc nitrate, EDTA zinc and boric acid; the anti-caking agent is a commercial anti-caking agent product without sulfate ions.
5. The water-soluble soil conditioning package special for saline-alkali soil as claimed in claim 1, wherein the application method is as follows:
1) The application method of the vegetable crops comprises the following steps: before soil is ploughed, the component A of the special soil conditioning package for the saline-alkali soil is prepared by the following steps: the special soil conditioner is diluted by water for 50-100 times and uniformly sprayed on the ground surface; during flowering and fruiting period, the component A: diluting the special soil conditioner by 200-300 times, and mixing the component B: diluting the special nutrient for 800-1500 times, respectively carrying out drip irrigation or flushing at 7-15 days, and mixing the component B: the special nutrient is diluted 1500-2000 times to be sprayed on the leaves once;
2) The application method of the grain and cotton crops comprises the following steps: before sowing, the component A: the special soil conditioner is diluted by 100-200 times by water and uniformly sprayed on the ground surface, and then ploughed; component A in reproductive phase: diluting the special soil conditioner by 200-300 times, performing drip irrigation or flushing, and mixing the component B: the special nutrient is diluted 1500-2000 times and sprayed on the leaves once, and the time interval is 7-15 days;
3) The application method of the fruit tree crops comprises the following steps: after fruit harvest, the a component is applied with base fertilizer: the special soil conditioner is diluted by 50-100 times and comprises the following components: diluting the special nutrient for 800-1000 times, and dripping the nutrient once for 10-15 days; during germination, component A: diluting the special soil conditioner by 200-300 times, and the component B: diluting the special nutrient for 1000-1500 times, and dripping the nutrient once for 10-15 days; during the fruit expanding period, the component B is prepared by the following steps: the special nutrient is diluted 1500-2000 times and sprayed for 1-2 times, and the time interval is 10-15 days.
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