CN106589744A - Environment-friendly plastic and preparation method thereof - Google Patents
Environment-friendly plastic and preparation method thereof Download PDFInfo
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- CN106589744A CN106589744A CN201611163435.3A CN201611163435A CN106589744A CN 106589744 A CN106589744 A CN 106589744A CN 201611163435 A CN201611163435 A CN 201611163435A CN 106589744 A CN106589744 A CN 106589744A
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- rare earth
- compatilizer
- plasticizer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses an environment-friendly plastic. The environment-friendly plastic comprises, by mass, 30-38 parts of ASA resin, 10-15 parts of polyvinyl chloride, 3-5 parts of carbon fibers, 4-8 parts of aluminum hydroxide, 3-5 parts of methylsilicone oil, 5-10 parts of polycaprolactone, 3-5 parts of polycarbonate, 2-4 parts of sodium oleoyl amino fatty acid, 3-5 parts of antimonous oxide, 2-3 parts of rare earth compound stabilizer, 3-4 parts of antioxidant, 1-3 parts of coupling agent, 5-8 parts of toughening agent, 4-7 parts of plasticizer and 2-4 parts of compatilizer. The environment-friendly plastic has the advantages of excellent flame retardance, high resistance to impact and weather and environment friendliness.
Description
Technical field
The present invention relates to a kind of flitch, is specifically a kind of environment-friendly type plastic.
Background technology
With the development of science and technology, field of plastic products has focused on plastic product in appearance, to modeling
The various performances of material products it is also proposed higher requirement, and existing plastic is polluted than larger in manufacturing process,
And bring many adverse effects to plastic, made by plastic intensity, toughness, heat resistance it is poor.
The content of the invention
The technical problem to be solved is, for the shortcoming that above prior art is present, there is provided a kind of with good
Anti-flammability well, impact resistance and weatherability, and the plastics of environmental protection..
The present invention solves the technical scheme of above technical problem：A kind of environment-friendly type plastic, include according to the mass fraction with
Lower component：ASA resin：30-38 parts, polrvinyl chloride：10-15 parts；Carbon fiber：3-5 parts, aluminium hydroxide：4-8 parts, methyl-silicone oil：
3-5 parts, polycaprolactone：5-10 parts, Merlon：3-5 parts, oleoyl amino acid sodium：2-4 parts, antimony oxide：3-5 parts, rare earth
Complex stabilizer：2-3 parts, antioxidant：3-4 parts, coupling agent：1-3 parts, toughener：5-8 parts, plasticizer：4-7 parts, compatilizer
2-4 parts；
The rare earth composite stabilizer includes following components by mass fraction：Mixed chlorinated rare earth 30-40 parts, zinc sulfate 10-15
Part, calcium chloride：10-14 parts, barium sulfate 15-20 parts, sodium hydroxide：16-22 parts, stearic acid：5-10 parts；
The antioxidant is the mixture of p-phenylenediamine and dihydroquinoline；The coupling agent is silane coupler；The toughness reinforcing
Agent is resinae toughener；The plasticizer is dioctyl phthalate or dibutyl phthalate；The compatilizer is
Maleic anhydride is grafted compatilizer.
The technical scheme that further limits of the present invention is：
It is aforesaid to include following components according to the mass fraction：ASA resin：33 parts, polrvinyl chloride：12 parts；Carbon fiber：3 parts, hydrogen-oxygen
Change aluminum：5 parts, methyl-silicone oil：4 parts, polycaprolactone：6 parts, Merlon：4 parts, oleoyl amino acid sodium：3 parts, antimony oxide：3
Part, rare earth composite stabilizer：2 parts, antioxidant：3 parts, coupling agent：2 parts, toughener：5 parts, plasticizer：5 parts, compatilizer 2
Part；
Rare earth composite stabilizer includes following components by mass fraction：34 parts of mixed chlorinated rare earth, 12 parts of zinc sulfate, calcium chloride：
11 parts, 17 parts of barium sulfate, sodium hydroxide：17 parts, stearic acid：7 parts；
Antioxidant is the mixture of p-phenylenediamine and dihydroquinoline；Coupling agent is silane coupler；Toughener increases for resinae
Tough dose；Plasticizer is dioctyl phthalate；Compatilizer is that maleic anhydride is grafted compatilizer.
It is aforesaid to include following components according to the mass fraction：ASA resin：36 parts, polrvinyl chloride：13 parts；Carbon fiber：4 parts,
Aluminium hydroxide：6 parts, methyl-silicone oil：5 parts, polycaprolactone：7 parts, Merlon：5 parts, oleoyl amino acid sodium：4 parts, three oxidations two
Antimony：4 parts, rare earth composite stabilizer：3 parts, antioxidant：4 parts, coupling agent：3 parts, toughener：6 parts, plasticizer：6 parts, it is compatible
3 parts of agent；
Rare earth composite stabilizer includes following components by mass fraction：36 parts of mixed chlorinated rare earth, 13 parts of zinc sulfate, calcium chloride：
13 parts, 18 parts of barium sulfate, sodium hydroxide：20 parts, stearic acid：8 parts；
Antioxidant is the mixture of p-phenylenediamine and dihydroquinoline；Coupling agent is silane coupler；Toughener increases for resinae
Tough dose；Plasticizer is dioctyl phthalate；Compatilizer is that maleic anhydride is grafted compatilizer.
Aforesaid preparation method of rare earth composite stabilizer is specially：First mixed chlorinated rare earth and Caustic soda are dissolved, matter is made into
Amount fraction is 45% and 50% solution, and zinc sulfate, calcium chloride and barium chloride are configured to the solution of 2mol/L, clarify, standby；Then
In there-necked flasks of the 500ml with stirring plus distilled water 200ml, start stirring, put into 45% re chloride 16.7g, 50%
Soda bath 9.05g, solution of zinc sulfate 3ml, calcium chloride solution 4.5ml or barium chloride solution 6ml, stearic acid 35g, be warming up to
70-75 DEG C, insulation reaction 15-20min is added after remaining soda bath is diluted in 20min, continues reaction 20-25min
After terminate, last product is washed, is filtered, be dry, pulverize.
Aforesaid environment-friendly type plastic preparation method for material, specifically includes following steps：
Step one：ASA resin, polrvinyl chloride, Merlon, polycaprolactone, oleoyl amino acid sodium, methyl-silicone oil are put into together
In reactor, 20-25min is stirred with 400-450r/min, temperature rises to 65-73 DEG C, is subsequently adding antimony oxide, hydroxide
Aluminum, antioxidant, plasticizer and compatilizer, stir 30-40min with 480-500r/min, and temperature rises to 95-100 DEG C, Ran Houjia
Enter rare earth composite stabilizer, temperature rises to 120-130 DEG C, be then incubated 3-5min, temperature is down to 50-60 DEG C, add toughener
And coupling agent, 15-20min is stirred with 200-300r/min, temperature is cooled to room temperature；
Step 2：The raw material of step one is stood into 10-13h, then material is added in double screw extruder, by carbon fiber plus
Enter in extruder, Jing melt blendings, extruding pelletization, extrusion temperature is maintained at 180-190 DEG C.
The invention has the beneficial effects as follows：The present invention adds ASA materials, and which has the weatherability of brilliance, can improve the present invention
Weatherability；Addition antimony oxide, improves the fire resistance of the present invention；Rare earth composite stabilizer is with the addition of, to the present invention
With certain lubricant effect, resinae toughener is with the addition of, impact resistance is increased；Addition maleic anhydride grafting compatilizer,
The compatibility of material can be greatly improved, environmental protection, does not result in pollution in manufacturing process,.
Specific embodiment
Embodiment 1
The present embodiment provides a kind of environment-friendly type plastic, according to the mass fraction including following components：ASA resin：33 parts, polychlorostyrene second
Alkene：12 parts；Carbon fiber：3 parts, aluminium hydroxide：5 parts, methyl-silicone oil：4 parts, polycaprolactone：6 parts, Merlon：4 parts, oleoyl ammonia
Base acid sodium：3 parts, antimony oxide：3 parts, rare earth composite stabilizer：2 parts, antioxidant：3 parts, coupling agent：2 parts, toughener：5
Part, plasticizer：5 parts, 2 parts of compatilizer；
Rare earth composite stabilizer includes following components by mass fraction：34 parts of mixed chlorinated rare earth, 12 parts of zinc sulfate, calcium chloride：
11 parts, 17 parts of barium sulfate, sodium hydroxide：17 parts, stearic acid：7 parts；
Antioxidant is the mixture of p-phenylenediamine and dihydroquinoline；Coupling agent is silane coupler；Toughener increases for resinae
Tough dose；Plasticizer is dioctyl phthalate；Compatilizer is that maleic anhydride is grafted compatilizer.
The present embodiment preparation method of rare earth composite stabilizer is specially：
First mixed chlorinated rare earth and Caustic soda are dissolved, the solution that mass fraction is 45% and 50%, zinc sulfate, calcium chloride and chlorine is made into
Change the solution that barium is configured to 2mol/L, clarification is standby；
Then add distilled water 200ml in there-necked flasks of the 500ml with stirring, start stirring, put into 45% re chloride
16.7g, 50% soda bath 9.05g, solution of zinc sulfate 3ml, calcium chloride solution 4.5ml or barium chloride solution 6ml, stearic acid
35g, is warming up to 70-75 DEG C, insulation reaction 15-20min, is added after remaining soda bath is diluted in 20min, continues anti-
Terminate after answering 20-25min, last product is washed, filter, dry, pulverize.
A kind of preparation method of environment-friendly type plastic of the present embodiment, specifically includes following steps：
Step one：ASA resin, polrvinyl chloride, Merlon, polycaprolactone, oleoyl amino acid sodium, methyl-silicone oil are put into together
In reactor, 25min is stirred with 400r/min, temperature rises to 67 DEG C, is subsequently adding antimony oxide, aluminium hydroxide, antioxidation
Agent, plasticizer and compatilizer, stir 35min with 480r/min, and temperature rises to 95 DEG C, is subsequently adding rare earth composite stabilizer, temperature
Degree rises to 123 DEG C, is then incubated 5min, and temperature is down to 53 DEG C, adds toughener and coupling agent, stirs 17min with 250r/min,
Temperature is cooled to room temperature；
Step 2：The raw material of step one is stood into 11h, then material is added in double screw extruder, carbon fiber is added
To in extruder, Jing melt blendings, extruding pelletization maintain extrusion temperature at 185 DEG C.
Embodiment 2
The present embodiment provides a kind of environment-friendly type plastic, according to the mass fraction including following components：ASA resin：36 parts, polychlorostyrene second
Alkene：13 parts；Carbon fiber：4 parts, aluminium hydroxide：6 parts, methyl-silicone oil：5 parts, polycaprolactone：7 parts, Merlon：5 parts, oleoyl ammonia
Base acid sodium：4 parts, antimony oxide：4 parts, rare earth composite stabilizer：3 parts, antioxidant：4 parts, coupling agent：3 parts, toughener：6
Part, plasticizer：6 parts, 3 parts of compatilizer；
Rare earth composite stabilizer includes following components by mass fraction：36 parts of mixed chlorinated rare earth, 13 parts of zinc sulfate, calcium chloride：
13 parts, 18 parts of barium sulfate, sodium hydroxide：20 parts, stearic acid：8 parts；
Antioxidant is the mixture of p-phenylenediamine and dihydroquinoline；Coupling agent is silane coupler；Toughener increases for resinae
Tough dose；Plasticizer is dioctyl phthalate；Compatilizer is that maleic anhydride is grafted compatilizer.
The present embodiment preparation method of rare earth composite stabilizer is specially：
First mixed chlorinated rare earth and Caustic soda are dissolved, the solution that mass fraction is 45% and 50%, zinc sulfate, calcium chloride and chlorine is made into
Change the solution that barium is configured to 2mol/L, clarification is standby；
Then add distilled water 200ml in there-necked flasks of the 500ml with stirring, start stirring, put into 45% re chloride
16.7g, 50% soda bath 9.05g, solution of zinc sulfate 3ml, calcium chloride solution 4.5ml or barium chloride solution 6ml, stearic acid
35g, is warming up to 70-75 DEG C, insulation reaction 15-20min, is added after remaining soda bath is diluted in 20min, continues anti-
Terminate after answering 20-25min, last product is washed, filter, dry, pulverize.
A kind of preparation method of environment-friendly type plastic of the present embodiment, specifically includes following steps：
Step one：ASA resin, polrvinyl chloride, Merlon, polycaprolactone, oleoyl amino acid sodium, methyl-silicone oil are put into together
In reactor, 20min is stirred with 450r/min, temperature rises to 71 DEG C, is subsequently adding antimony oxide, aluminium hydroxide, antioxidation
Agent, plasticizer and compatilizer, stir 32min with 500r/min, and temperature rises to 98 DEG C, is subsequently adding rare earth composite stabilizer, temperature
Degree rises to 127 DEG C, is then incubated 3min, and temperature is down to 55 DEG C, adds toughener and coupling agent, stirs 15min with 300r/min,
Temperature is cooled to room temperature；
Step 2：The raw material of step one is stood into 10h, then material is added in double screw extruder, carbon fiber is added
To in extruder, Jing melt blendings, extruding pelletization maintain extrusion temperature at 187 DEG C.
In addition to the implementation, the present invention can also have other embodiment.All employing equivalents or equivalent transformation shape
Into technical scheme, all fall within the protection domain of application claims.
Claims (5)
1. a kind of environment-friendly type plastic, it is characterised in that according to the mass fraction including following components：ASA resin：30-38 parts, polychlorostyrene
Ethylene：10-15 parts；Carbon fiber：3-5 parts, aluminium hydroxide：4-8 parts, methyl-silicone oil：3-5 parts, polycaprolactone：5-10 parts, poly- carbon
Acid esters：3-5 parts, oleoyl amino acid sodium：2-4 parts, antimony oxide：3-5 parts, rare earth composite stabilizer：2-3 parts, antioxidant：
3-4 parts, coupling agent：1-3 parts, toughener：5-8 parts, plasticizer：4-7 parts, compatilizer 2-4 parts；
The rare earth composite stabilizer includes following components by mass fraction：Mixed chlorinated rare earth 30-40 parts, zinc sulfate 10-15
Part, calcium chloride：10-14 parts, barium sulfate 15-20 parts, sodium hydroxide：16-22 parts, stearic acid：5-10 parts；
The antioxidant is the mixture of p-phenylenediamine and dihydroquinoline；The coupling agent is silane coupler；The toughness reinforcing
Agent is resinae toughener；The plasticizer is dioctyl phthalate or dibutyl phthalate；The compatilizer is
Maleic anhydride is grafted compatilizer.
2. environment-friendly type plastic according to claim 1, it is characterised in that according to the mass fraction including following components：ASA trees
Fat：33 parts, polrvinyl chloride：12 parts；Carbon fiber：3 parts, aluminium hydroxide：5 parts, methyl-silicone oil：4 parts, polycaprolactone：6 parts, poly- carbon
Acid esters：4 parts, oleoyl amino acid sodium：3 parts, antimony oxide：3 parts, rare earth composite stabilizer：2 parts, antioxidant：3 parts, coupling
Agent：2 parts, toughener：5 parts, plasticizer：5 parts, 2 parts of compatilizer；
The rare earth composite stabilizer includes following components by mass fraction：34 parts of mixed chlorinated rare earth, 12 parts of zinc sulfate, chlorination
Calcium：11 parts, 17 parts of barium sulfate, sodium hydroxide：17 parts, stearic acid：7 parts；
The antioxidant is the mixture of p-phenylenediamine and dihydroquinoline；The coupling agent is silane coupler；The toughness reinforcing
Agent is resinae toughener；The plasticizer is dioctyl phthalate；The compatilizer is that maleic anhydride is grafted compatilizer.
3. environment-friendly type plastic according to claim 1, it is characterised in that according to the mass fraction including following components：ASA trees
Fat：36 parts, polrvinyl chloride：13 parts；Carbon fiber：4 parts, aluminium hydroxide：6 parts, methyl-silicone oil：5 parts, polycaprolactone：7 parts, poly- carbon
Acid esters：5 parts, oleoyl amino acid sodium：4 parts, antimony oxide：4 parts, rare earth composite stabilizer：3 parts, antioxidant：4 parts, coupling
Agent：3 parts, toughener：6 parts, plasticizer：6 parts, 3 parts of compatilizer；
The rare earth composite stabilizer includes following components by mass fraction：36 parts of mixed chlorinated rare earth, 13 parts of zinc sulfate, chlorination
Calcium：13 parts, 18 parts of barium sulfate, sodium hydroxide：20 parts, stearic acid：8 parts；
The antioxidant is the mixture of p-phenylenediamine and dihydroquinoline；The coupling agent is silane coupler；The toughness reinforcing
Agent is resinae toughener；The plasticizer is dioctyl phthalate；The compatilizer is that maleic anhydride is grafted compatilizer.
4. environment-friendly type plastic according to claim 1, it is characterised in that the preparation method of rare earth composite stabilizer is concrete
For：First mixed chlorinated rare earth and Caustic soda are dissolved, the solution that mass fraction is 45% and 50%, zinc sulfate, calcium chloride and chlorine is made into
Change the solution that barium is configured to 2mol/L, clarification is standby；Then add distilled water 200ml in there-necked flasks of the 500ml with stirring,
Start stirring, 45% re chloride 16.7g of input, 50% soda bath 9.05g, solution of zinc sulfate 3ml, calcium chloride solution
4.5ml or barium chloride solution 6ml, stearic acid 35g, are warming up to 70-75 DEG C, insulation reaction 15-20min, will be remaining Caustic soda molten
Add in 20min after liquid dilution, terminate after continuing reaction 20-25min, last product is washed, filter, dry, pulverize
.
5. the environment-friendly type plastic preparation method for material according to claim 1-3, it is characterised in that specifically include following steps：
Step one：ASA resin, polrvinyl chloride, Merlon, polycaprolactone, oleoyl amino acid sodium, methyl-silicone oil are put into together
In reactor, 20-25min is stirred with 400-450r/min, temperature rises to 65-73 DEG C, is subsequently adding antimony oxide, hydroxide
Aluminum, antioxidant, plasticizer and compatilizer, stir 30-40min with 480-500r/min, and temperature rises to 95-100 DEG C, Ran Houjia
Enter rare earth composite stabilizer, temperature rises to 120-130 DEG C, be then incubated 3-5min, temperature is down to 50-60 DEG C, add toughener
And coupling agent, 15-20min is stirred with 200-300r/min, temperature is cooled to room temperature；
Step 2：The raw material of step one is stood into 10-13h, then material is added in double screw extruder, by carbon fiber plus
Enter in extruder, Jing melt blendings, extruding pelletization, extrusion temperature is maintained at 180-190 DEG C.
Priority Applications (1)
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| CN201611163435.3A CN106589744A (en) | 2016-12-15 | 2016-12-15 | Environment-friendly plastic and preparation method thereof |
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| CN201611163435.3A CN106589744A (en) | 2016-12-15 | 2016-12-15 | Environment-friendly plastic and preparation method thereof |
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| CN201611163435.3A Pending CN106589744A (en) | 2016-12-15 | 2016-12-15 | Environment-friendly plastic and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107903545A (en) * | 2017-12-26 | 2018-04-13 | 苏州浩焱精密模具有限公司 | A kind for the treatment of process of automobile radiators grille mould |
| CN107936423A (en) * | 2017-12-16 | 2018-04-20 | 苏州纽东精密制造科技有限公司 | A kind of automobile radiators grille and its treatment process |
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