CN106566598A - Universal nonferrous metal and stainless steel cold rolling oil composite additive and preparation method thereof - Google Patents

Universal nonferrous metal and stainless steel cold rolling oil composite additive and preparation method thereof Download PDF

Info

Publication number
CN106566598A
CN106566598A CN201610986121.7A CN201610986121A CN106566598A CN 106566598 A CN106566598 A CN 106566598A CN 201610986121 A CN201610986121 A CN 201610986121A CN 106566598 A CN106566598 A CN 106566598A
Authority
CN
China
Prior art keywords
rolling oil
steel cold
additive
universal
butyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610986121.7A
Other languages
Chinese (zh)
Other versions
CN106566598B (en
Inventor
孙建林
苑光照
张炳涛
束俊洲
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Science and Technology Beijing USTB
Original Assignee
University of Science and Technology Beijing USTB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Science and Technology Beijing USTB filed Critical University of Science and Technology Beijing USTB
Priority to CN201610986121.7A priority Critical patent/CN106566598B/en
Publication of CN106566598A publication Critical patent/CN106566598A/en
Application granted granted Critical
Publication of CN106566598B publication Critical patent/CN106566598B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106—Thiadiazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/047—Thioderivatives not containing metallic elements
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/72—Extended drain
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention provides a universal nonferrous metal and stainless steel cold rolling oil composite additive and a preparation method thereof and belongs to the field of lubricating agents. According to the universal nonferrous metal and stainless steel cold rolling oil composite additive, lauryl alcohol, butyl stearate, pentaerythritol oleate and lauric acid are selected as oily agents; 2,6-di-tert-butyl-4-methylphenol is selected as an antioxidant; benzotriazole and thiadiazole derivatives are used as metal deactivators; dialkyl phosphorodithioate serves as an antiwear agent; and hydrogenated base oil serves as a solvent. The alcohol-ester type oily agents are mainly used for compounding with a little amount of acid oily agents as supplementation; a little amount of dialkyl phosphorodithioate is used as the antiwear agent to reinforce an oil film so as to improve the surface quality of a rolled stock; the service life of rolling oil is prolonged through a little amount of the antioxidant and the metal deactivators, the cyclic use frequency is increased, and rolled pieces are protected against corrosion. The universal nonferrous metal and stainless steel cold rolling oil composite additive is convenient to use, low in cost and little in dosage, and has the characteristics of high oil film strength, good antiwear and antifriction effect, high oxidation resistance and excellent annealing performance.

Description

Universal non-ferrous metal and stainless-steel cold-rolling oil compound additive and preparation method thereof
Technical field
The present invention relates to lubricant and the cold rolling field of metal plate and belt foil, the lubrication belonged in process of metal working is specifically related to And a kind of universal cold-rolled lubricating oil compound additive and preparation method thereof.
Background technology
It is to ensure the operation of rolling during non-ferrous metal stocking (such as aluminium sheet, band, paper tinsel, Copper Foil) and stainless-steel cold-rolling Be smoothed out, and obtain the regular stocking of excellent surface quality, plate shape, it is necessary to adopt Lubrication Technology.
ROLLING OIL is made up of base oil and additive, and the base oil of Modern New predominantly passes through hydrorefined mineral Oil, its composition is mainly the different alkane of carbon chain lengths and cycloalkanes hydrocarbon mixture；Additive can improve the specificity of oil product Matter, improves the greasy property of mineral oil.Generally require to add a certain amount of oiliness improver, antiwear additive, antioxidant etc. in ROLLING OIL with Reaching improves the effect of lubrication.The additive of unitary type can not play comprehensive effect, often using multiple in actual production Additive is closed, film strength is improved, is reduced wear extent, improves ROLLING OIL service life and other effects to reach.
In technical field of lubricant, additive types are various, and various formula species mix in industrialized production, to using Person causes inconvenience.Therefore a kind of universal compound additive of research is needed, for the processing of different metal, from suitable Compound additive consumption, improves the convenience that uses and can reach excellent resultant effect.
The content of the invention
It is an object of the invention to provide a kind of universal non-ferrous metal and stainless-steel cold-rolling oil compound additive, the present invention makes With conveniently, low cost, consumption is few, can reach to use by the consumption of change compound additive for different metal stocking and wants Ask.According to experimental results, the present invention has film strength high, and antiwear and antifriction effect is good, and non-oxidizability is strong, and Annealing Property is excellent Good the characteristics of.
The technical scheme is that：From lauryl alcohol, butyl stearate, PETO and Used as oiliness improver, used as antioxidant, BTA and thiadiazoles derivative are used as gold for 2,6 ditertiary butyl p cresol for lauric acid Category passivator, used as antiwear additive, hydrogenated base oil is used as solvent naphtha for dialkyl dithiophosphate.
The concrete composition of compound additive by mass percentage, in oiliness improver, lauryl alcohol：28～42%；
Butyl stearate and PETO mixed ester：28～42%：
Lauric acid：2～5%；
Antioxidant, is 2,6 ditertiary butyl p cresol：0.5～1%；
In metal deactivator, BTA：0.3～0.9%；
Thiadiazoles derivative：0.3～0.9%；
Antiwear additive, is dialkyl dithiophosphate：0.5～2%；
Solvent naphtha, is hydrogenated base oil：Surplus.
In concrete composition, oiliness improver lauryl alcohol is answered with the mixed ester of butyl stearate and PETO composition It is 2 with mass ratio range:3～3:2, the two gross mass is overall 70% of compound additive；Butyl stearate in mixed ester It is with the compounding mass ratio range of PETO：2:3～3:2, metal deactivator BTA and thiadiazoles spread out Biological compounding mass ratio range is 1:3～3:1.
Above-mentioned universal non-ferrous metal and stainless-steel cold-rolling oil compound additive preparation process be：
First the butyl stearate and PETO of above-mentioned formula ratio are added to into reaction vessel according to correspondence ratio In, then sequentially add lauryl alcohol, lauric acid, 2,6 ditertiary butyl p cresol, BTA, thiadiazoles derivative, dioxane Base phosphorodithioate, is eventually adding hydrogenated base oil.Reaction vessel is placed on thermostatic electromagnetic agitator and is heated while stirring To 60～70 DEG C, mixing speed is 100～180r/min, and constant temperature mixing time is 10～20 minutes until the mixing of each additive is equal It is even, be subsequently cooled to room temperature, that is, obtain a kind of universal non-ferrous metal and stainless-steel cold-rolling oil compound additive.
It is an advantage of the current invention that the comprehensive consideration film strength of ROLLING OIL, antiwear and friction reduction property, non-oxidizability and moving back Fiery detergency.By being combined to oiliness improver, optimization oiliness improver is optimal effect, monoesters in the absorption array of metal surface The butyl stearate of type has excellent annealing cleanness and extreme pressure property is slightly worse, and the PETO of polyhydric alcohol ester type Preferably lubrication and extreme pressure property can be shown, the feature of the two is complementary to one another；By add a small amount of annealing cleanness compared with Good antiwear additive improves the antiwear and antifriction effect of ROLLING OIL, while its content controls to have no significant effect annealing cleanness In the range of；The service life of oil product is improved by adding antioxidant, cost is reduced；Suppress gold by adding metal deactivator The catalytic action of category ion pair ROLLING OIL oxidation, and corrosion of metal is prevented, improve the surface quality of rolled piece.
The present invention carries out assessment of performance using following experimental technique in the lab：
◆ lubricant extreme pressure property algoscopy (four ball method) (GB/T 12583)
◆ lubrication oil antiwear damages performance measurement method (four ball method) (SH/T 0189)
◆ the measure (rotary bomb oxidation test) (SH/T 0193) of lubricating oil oxidation stability
◆ EXXON standard anneal box methods
◆ oil product copper corrosion laboratory method (GB/T 5096)
Specific embodiment
Embodiment 1
The formula of embodiment 1 (based on gross mass 100g) is shown in Table 1：
Table 1
Sequence number Ingredient names Quality (g)
1 Lauryl alcohol 28.0
2 Butyl stearate 16.8
3 PETO 25.2
4 Lauric acid 2.0
5 2,6 ditertiary butyl p cresol 0.5
6 BTA 0.3
7 Thiadiazoles derivative 0.9
8 Dialkyl dithiophosphate 0.5
9 Hydrogenated base oil 25.8
By each component quality formula of upper table, universal non-ferrous metal and stainless-steel cold-rolling oil compound additive are prepared.Will Lauryl alcohol (28.0g), butyl stearate (16.8g), PETO (25.2g), lauric acid (2.0g), the tertiary fourths of 2,6- bis- Base paracresol (0.5g), BTA (0.3g), thiadiazoles derivative (0.9g), dialkyl dithiophosphate (0.5g) and Hydrogenated base oil (25.8g), specifies order to add after container in by specification, be placed on thermostatic electromagnetic agitator top heating side and stir Mix to 60～70 DEG C, constant temperature mixing time is 10～20 minutes, mixing speed is 100～180r/min, until each additive is mixed Close uniform, obtain uniform oil body, be subsequently cooled to room temperature.
Embodiment 2
The formula of embodiment 2 (based on gross mass 100g) is shown in Table 2：
Table 2
Sequence number Ingredient names Quality (g)
1 Lauryl alcohol 35.0
2 Butyl stearate 17.5
3 PETO 17.5
4 Lauric acid 3.0
5 2,6 ditertiary butyl p cresol 0.7
6 BTA 0.5
7 Thiadiazoles derivative 0.5
8 Dialkyl dithiophosphate 1.0
9 Hydrogenated base oil 24.3
By each component quality formula of upper table, universal non-ferrous metal and stainless-steel cold-rolling oil compound additive are prepared.Will Lauryl alcohol (35.0g), butyl stearate (17.5g), PETO (17.5g), lauric acid (3.0g), the tertiary fourths of 2,6- bis- Base paracresol (0.7g), BTA (0.5g), thiadiazoles derivative (0.5g), dialkyl dithiophosphate (1.0g) and Hydrogenated base oil (24.3g), specifies order to add after container in by specification, be placed on thermostatic electromagnetic agitator top heating side and stir Mix to 60～70 DEG C, constant temperature mixing time is 10～20 minutes, mixing speed is 100～180r/min, until each additive is mixed Close uniform, obtain uniform oil body, be subsequently cooled to room temperature.
Embodiment 3
The formula of embodiment 3 (based on gross mass 100g) is shown in Table 3：
Table 3
Sequence number Ingredient names Quality (g)
1 Lauryl alcohol 42.0
2 Butyl stearate 16.8
3 PETO 11.2
4 Lauric acid 5.0
5 2,6 ditertiary butyl p cresol 1.0
6 BTA 0.9
7 Thiadiazoles derivative 0.3
8 Dialkyl dithiophosphate 2.0
9 Hydrogenated base oil 20.8
By each component quality formula of upper table, universal non-ferrous metal and stainless-steel cold-rolling oil compound additive are prepared.Will Lauryl alcohol (42.0g), butyl stearate (16.8g), PETO (11.2g), lauric acid (5.0g), the tertiary fourths of 2,6- bis- Base paracresol (1.0g), BTA (0.9g), thiadiazoles derivative (0.3g), dialkyl dithiophosphate (2.0g) and Hydrogenated base oil (20.8g), specifies order to add after container in by specification, be placed on thermostatic electromagnetic agitator top heating side and stir Mix to 60～70 DEG C, constant temperature mixing time is 10～20 minutes, mixing speed is 100～180r/min, until each additive is mixed Close uniform, obtain uniform oil body, be subsequently cooled to room temperature.
Product performance index
The compound additive formula of above three embodiment is taken, aluminium sheet basis is added to the addition of mass fraction 3% (it is used for aluminium rolling) in oily A100, its performance indications such as table 4：
Table 4
The compound additive formula of above three embodiment is taken, is added in No. 5 white oils with the addition of mass fraction 5% (for copper material and rolled stainless steel), its performance indications such as table 5：
Table 5
The embodiment of the above only preferably applies example for the present invention, not limits the practical range of the present invention with this, therefore All component ratios according to the present invention, the equivalence changes that method and principle are made all should be covered by protection scope of the present invention.

Claims (4)

1. a kind of universal non-ferrous metal and stainless-steel cold-rolling oil compound additive, it is characterised in that from lauryl alcohol, stearic acid , used as oiliness improver, 2,6 ditertiary butyl p cresol is used as antioxidant, BTA for butyl ester, PETO and lauric acid With thiadiazoles derivative as metal deactivator, used as antiwear additive, hydrogenated base oil is used as solvent for dialkyl dithiophosphate Oil.
2. universal non-ferrous metal as claimed in claim 1 and stainless-steel cold-rolling oil compound additive, it is characterised in that compound Additive it is specifically as follows by mass percentage into being grouped into：
Oiliness improver：Lauryl alcohol：28～42%；
Butyl stearate and PETO mixed ester：28～42%；
Lauric acid：2～5%；
Antioxidant：2,6 ditertiary butyl p cresol：0.5～1%；
Metal deactivator：BTA：0.3～0.9%；
Thiadiazoles derivative：0.3～0.9%；
Antiwear additive：Dialkyl dithiophosphate：0.5～2%；
Solvent naphtha：Hydrogenated base oil：Surplus.
3. universal non-ferrous metal as claimed in claim 1 or 2 and stainless-steel cold-rolling oil compound additive, it is characterised in that In concrete composition, the compounding mass ratio of the mixed ester that oiliness improver lauryl alcohol is constituted with butyl stearate and PETO Example scope is 2:3～3:2, lauryl alcohol is overall 70% of compound additive with the gross mass of mixed ester；Stearic acid in mixed ester The compounding mass ratio range of butyl ester and PETO is：2:3～3:2, metal deactivator BTA and thiophene two The compounding mass ratio range of Zole derivatives is 1:3～3:1.
4. the as claimed in claim 2 or claim 3 preparation method of universal non-ferrous metal and stainless-steel cold-rolling oil compound additive, its It is characterised by that concrete preparation process is：
First the butyl stearate and PETO of above-mentioned formula ratio are added in reaction vessel according to correspondence ratio, so After sequentially add lauryl alcohol, lauric acid, 2,6 ditertiary butyl p cresol, BTA, thiadiazoles derivative, dialkyl disulfides Substituted phosphate, is eventually adding hydrogenated base oil；Reaction vessel is placed on thermostatic electromagnetic agitator heat while stirring to 60～ 70 DEG C, mixing speed is 100～180r/min, constant temperature mixing time be 10～20 minutes until each additive mix homogeneously, so After be cooled to room temperature, that is, obtain a kind of universal non-ferrous metal and stainless-steel cold-rolling oil compound additive.
CN201610986121.7A 2016-11-09 2016-11-09 Universal non-ferrous metal and stainless-steel cold-rolling oil compound additive and preparation method thereof Active CN106566598B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610986121.7A CN106566598B (en) 2016-11-09 2016-11-09 Universal non-ferrous metal and stainless-steel cold-rolling oil compound additive and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610986121.7A CN106566598B (en) 2016-11-09 2016-11-09 Universal non-ferrous metal and stainless-steel cold-rolling oil compound additive and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106566598A true CN106566598A (en) 2017-04-19
CN106566598B CN106566598B (en) 2019-05-17

Family

ID=58540844

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610986121.7A Active CN106566598B (en) 2016-11-09 2016-11-09 Universal non-ferrous metal and stainless-steel cold-rolling oil compound additive and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106566598B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108251200A (en) * 2018-02-28 2018-07-06 北京科技大学 A kind of clean type copper-aluminum composite board cold rolling oil and preparation method thereof
CN108865371A (en) * 2018-08-01 2018-11-23 武汉钢铁有限公司 A kind of environmentally friendly ROLLING OIL of secondary cold-rolling
CN114106922A (en) * 2021-12-13 2022-03-01 安美科技股份有限公司 Stainless steel rolling composition
CN114133977A (en) * 2021-10-22 2022-03-04 华润宝润滑科技(宁波)有限公司 Cutting lubricant capable of preventing copper machined part from oxidative discoloration
CN114214108A (en) * 2021-12-20 2022-03-22 南京正明观新材料有限公司 Stainless steel cold rolling oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102660357A (en) * 2012-04-26 2012-09-12 北京科技大学 Calendaring copper foil rolled oil and preparation method thereof
CN103666660A (en) * 2012-09-20 2014-03-26 中国石油化工股份有限公司 Automobile part drawing oil composition and use thereof
CN104342247A (en) * 2013-08-01 2015-02-11 中国石油化工股份有限公司 Oil composition for copper foil rolling and uses thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102660357A (en) * 2012-04-26 2012-09-12 北京科技大学 Calendaring copper foil rolled oil and preparation method thereof
CN103666660A (en) * 2012-09-20 2014-03-26 中国石油化工股份有限公司 Automobile part drawing oil composition and use thereof
CN104342247A (en) * 2013-08-01 2015-02-11 中国石油化工股份有限公司 Oil composition for copper foil rolling and uses thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108251200A (en) * 2018-02-28 2018-07-06 北京科技大学 A kind of clean type copper-aluminum composite board cold rolling oil and preparation method thereof
CN108865371A (en) * 2018-08-01 2018-11-23 武汉钢铁有限公司 A kind of environmentally friendly ROLLING OIL of secondary cold-rolling
CN108865371B (en) * 2018-08-01 2021-06-15 武汉钢铁有限公司 Environment-friendly rolling oil for secondary cold rolling
CN114133977A (en) * 2021-10-22 2022-03-04 华润宝润滑科技(宁波)有限公司 Cutting lubricant capable of preventing copper machined part from oxidative discoloration
CN114106922A (en) * 2021-12-13 2022-03-01 安美科技股份有限公司 Stainless steel rolling composition
CN114214108A (en) * 2021-12-20 2022-03-22 南京正明观新材料有限公司 Stainless steel cold rolling oil

Also Published As

Publication number Publication date
CN106566598B (en) 2019-05-17

Similar Documents

Publication Publication Date Title
CN106566598A (en) Universal nonferrous metal and stainless steel cold rolling oil composite additive and preparation method thereof
CN103589491B (en) Lubricating material for cold rolling and its preparation method and use
CN105038925B (en) Lubricant and preparation method thereof
CN105296085B (en) Punching press fluid composition and application thereof
CN101724498B (en) Emulsified steel plate cold-rolling lubrication oil
CN109370751A (en) A kind of new type stainless steel. corrosion resistance ROLLING OIL and preparation method thereof and application method
CN110747040A (en) Anti-stain rolling oil composition for cold-rolled silicon steel
CN107418656A (en) A kind of low smell automotive gear oil compound additive
CN108570341A (en) A kind of belt steel rolling oil and its production method
CN107892982A (en) Iron powder divergence type rolling oil composition and application thereof
CN104342226B (en) The purposes of tricarboxymethyl propane oleate, the composition containing the material and purposes
CN105255545A (en) Preparation method of lubricating oil for methanol engine
CN116144417A (en) Clean cycloalkyl copper cold-rolled emulsified oil and preparation method and application thereof
CN106939180B (en) Extreme-pressure anti-wear lubricating oil/fat composition and preparation method thereof
CN1126809C (en) Oil composition for cold rolling of stainless steel sheel
CN103789067A (en) Copper foil rolling liquid containing oil-soluble nano Cu and preparation method of copper foil rolling liquid
CN108865365A (en) Stable emulsifying type straight carbon steel cold rolling oil and application thereof
CN104031719A (en) Anti-rust and wear-resistant lubricant and preparation method thereof
CN105623811B (en) Stainless steel calendering dropping board oil
CN106635346A (en) Biological phospholipid based rolling oil and preparation method thereof
CN103421586B (en) Zirconium and zirconium alloy foil cold rolling lubricant
CN111808663A (en) Light-colored metal working fluid additive with good oil solubility and preparation method thereof
CN113061693A (en) Rapid and stable overspeed bright quenching oil and preparation method thereof
CN102925249B (en) Metal rolling oil macromolecule polybasic acid additives and preparation method
CN107312590B (en) Leveling anti-rust oil for cold-rolled steel sheets and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant