CN106368077B - 一种文物保护用无酸内衬纸的制造方法 - Google Patents
一种文物保护用无酸内衬纸的制造方法 Download PDFInfo
- Publication number
- CN106368077B CN106368077B CN201610901873.9A CN201610901873A CN106368077B CN 106368077 B CN106368077 B CN 106368077B CN 201610901873 A CN201610901873 A CN 201610901873A CN 106368077 B CN106368077 B CN 106368077B
- Authority
- CN
- China
- Prior art keywords
- paper
- pulp
- anacidity
- water
- page
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
- D21H11/04—Kraft or sulfate pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/17—Ketenes, e.g. ketene dimers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
- D21H17/29—Starch cationic
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
- D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paper (AREA)
Abstract
本发明公开了一种文物保护用无酸内衬纸的制造方法,包括使用漂白硫酸盐针叶木浆、漂白硫酸盐阔叶木浆经分别打浆、配浆及辅料加入、湿纸页抄造、干燥、压光工艺步骤,制得的碱性无酸内衬纸定量为12‑25g/m2,松厚度不小于1.5cm3/g,水分为5.0‑8.0%,碳酸钙含量:0.4‑14.0%;白度(ISO)大于88%,裂断长纵向大于3000m,铁离子含量小于50ppm,铜离子含量小于5ppm;本发明方法制得的无酸内衬纸具有纸质轻柔、细腻,pH值呈碱性,木素含量和金属离子含量极低,可完全满足不含蛋白质的文物制品的内衬包装要求。本发明生产工艺简单,成本低,易于大规模生产。
Description
技术领域
本发明涉及一种文物保护用无酸内衬纸的制造方法,可用于保存纸类、棉类、麻类、陶瓷等不含蛋白质的文物制品,属于造纸技术领域。
背景技术
无酸纸不含酸性物质,呈中性或碱性,用于文物保存时可有效降低自身和外部环境对文物造成的酸性破坏,延长文物寿命。无酸内衬纸是一种使用时直接与文物接触的内衬保护材料,在文物保存中起到非常重要的保护作用。无酸内衬纸根据文物保护的要求可分为有缓冲剂和无缓冲剂两大类。有缓冲剂(含碳酸钙等碱性物质)的无酸内衬纸呈碱性,可有效中和文物或外部环境中的酸性物质,保护文物,主要用于保存纸类、棉类、麻类、陶瓷等不含蛋白质的文物制品。无缓冲剂的无酸内衬纸呈中性,主要用来保存含蛋白质的文物制品,如羊毛、皮革、丝及其它含蛋白质的纺织品、纸制品等。
中国专利申请CN200810022635.6公开了一种“文物保护专用无酸纸和制备方法”,通过浆料疏解、化学品加入、抄纸、干燥等步骤获得无酸纸。然而该专利申请中所限定的碱性缓冲剂用量上限偏低,制得的无酸纸难以满足较强酸性环境下文物的保存。另外,该专利申请仅表明了成纸的浆料组分含量比例,没有描述对相关原料的处理要求及最终的成纸性能要求(光学性能、强度性能、金属离子含量等),按照该方法无法制备出符合文物保存用的无酸内衬纸。该专利申请未获专利授权许可。文献1(徐文娟,吴来明,戴红旗,馆藏文物包装用无酸纸的性能研究,文物保护与考古科学,26(4):25-29)对文物包装用纸质材料进行了研究,并试制了含有缓冲剂的无酸纸板,但并没有对无酸内衬纸进行研究和试制。
发明内容
本发明的目的是提供一种文物保护用无酸内衬纸的制造方法,可用于保存纸类、棉类、麻类、陶瓷等不含蛋白质的文物制品,有助于延长文物寿命。
本发明采用的技术方案是:一种文物保护用无酸内衬纸的制造方法,包括使用漂白硫酸盐针叶木浆、漂白硫酸盐阔叶木浆经分别打浆、配浆及辅料加入、湿纸页抄造、干燥、压光等工艺步骤,其特征在于:
(1) 浆料重量配比:漂白硫酸盐针叶木浆:漂白硫酸盐阔叶木浆为(50~100):(0-50);
(2) 浆料打浆后打浆度:漂白硫酸盐针叶木浆20-45°SR;漂白硫酸盐阔叶木浆25-55°SR;
(3) 辅料对绝干浆用量为:(a) 施胶剂烷基烯酮二聚体重量比0~0.25%; (b) 阳离子淀粉重量比0~1.5%;(c)碳酸钙填料重量比0.5~15.0%;
(4) 湿纸页抄造
将上述原料用去离子水配置成浆料,经过净化、除气、筛选等工序处理后,进行湿纸页抄造;调节纸机抄造工艺参数,上网浓度:0.1-0.3%;浆网速比:0.98-1.10;操作车速30-800m/min;抄制定量12-25 g/m2的湿纸页;湿纸页经压榨部脱水后进干燥部;
(5) 干燥压光
对压榨部进入的湿纸页进行干燥,控制烘缸表面温度在55-120℃,出干燥部纸页干度≥92%。出干燥部后的纸页进入压光区,对纸页进行压光整饰,压光温度控制在45-110℃,压光压力控制在40-100kN/cm;经过压光后,对纸张进行卷取;即可制得用于保存不含蛋白质类文物制品的无酸内衬纸;
(6) 制得的碱性无酸内衬纸的特性:
定量为12-25g/m2,松厚度不小于1.5cm3/g,水分为5.0-8.0%,碳酸钙含量:0.4-14.0%;白度 (ISO)大于88%,裂断长纵向大于3000m,铁离子含量小于50ppm,铜离子含量小于5ppm;
其中所述步骤(1)中漂白硫酸盐针叶木浆和漂白硫酸盐阔叶木浆的卡伯值小于3;所述步骤(2)、(3)、(4)中的打浆用水,辅料稀释和熬制用水,抄纸用水均为去离子水;所述步骤(4)中的抄造纸机可以采用圆网纸机、长网纸机或叠网纸机中的任意一种。
本发明具有如下优点:
(1)浆料无需使用价格昂贵且难于处理的棉浆、麻将等特种纤维,原料来源广、成本低;化学品使用少,污染负荷低。
(2)制得的无酸内衬纸纸质轻柔、细腻,pH值呈碱性,木素含量和金属离子含量极低,可完全满足纸类、棉类、麻类、陶瓷等不含蛋白质类文物制品的内衬包装要求。
(3)本发明生产工艺简单,成本低,易于大规模生产。
具体实施方式
下面根据具体实施例对本发明作进一步说明:
实施例1:
漂白硫酸盐马尾松浆(卡伯值<3)和漂白硫酸盐桉木浆(卡伯值<3)分别在去离子水中打浆至32-36°SR和38-42°SR,然后按70:30重量比进行配浆;在成浆池中分别加入1.2kg/吨浆烷基烯酮二聚体施胶剂、10kg/吨浆玉米阳离子淀粉、80kg/吨浆高纯轻质碳酸钙填料;成浆池中浆料经冲浆泵送入一级三段锥形除渣器进行净化除渣,然后进入除气罐进行脱气处理;之后经压力筛筛选后送入单圆网纸机流浆箱;调整上网浓度为为0.15 %,浆网速比为0.98,车速为60 m/min,抄制定量为14-16g/m2的湿纸页;湿纸页经压榨后进干燥部;干燥部烘缸表面温度控制在70~120℃对纸页进行干燥处理,至纸页干度≥93%;出干燥部纸页进入压光区进行轻微压光处理,压光温度控制在50-60℃,压光压力控制在55-60kN/cm;经过压光后,对纸张进行卷取,即可制得定量为14-16 g/m2,水分为6.0-7.0%,松厚度为1.7-1.8 cm3/g,白度 (ISO)大于88%,碳酸钙含量6-7%,裂断长纵向大于3000m,铁离子含量小于20ppm,铜离子含量小于5ppm的用于包装不含蛋白质的文物制品的无酸内衬纸。
实施例2:
漂白硫酸盐马尾松浆(卡伯值<3)和漂白硫酸盐桉木浆(卡伯值<3)分别在去离子水中打浆至28-30°SR和32-34°SR,然后按50:50重量比进行配浆;在成浆池中分别加入1kg/吨浆烷基烯酮二聚体施胶剂、12kg/吨浆玉米阳离子淀粉、50kg/吨浆高纯轻质碳酸钙填料,浆料经一级三段锥形除渣器进行净化除渣,然后进入除气罐进行脱气处理;之后进入压力筛进行筛选后送入长网纸机流浆箱,调整上网浓度为为0.25%,浆网速比为0.99,车速为300 m/min,抄制定量为22-24 g/m2的湿纸页;出网部后湿纸页经压榨后进干燥部;干燥部烘缸表面温度控制在60~120℃对纸页进行干燥处理,至纸页干度≥93%;出干燥部纸页进入压光区进行压光处理,压光温度控制在60-90℃,压光压力控制在50-60kN/cm;经过压光后,对纸张进行卷取,即可制得定量为22-24g/m2,水分为6.0-7.0%,松厚度为1.8-1.9 cm3/g,白度 (ISO)大于88%,碳酸钙含量4-4.5%,裂断长纵向大于3000m,铁离子含量小于20ppm,铜离子含量小于5ppm的用于包装不含蛋白质的文物制品的无酸内衬纸。
实施例3:
漂白硫酸盐马尾松浆(卡伯值<3)在去离子水中打浆至32-35°SR,以去离子水稀释配浆;在成浆池中分别加入0.8 kg/吨浆烷基烯酮二聚体施胶剂、10kg/吨浆马铃薯阳离子淀粉、120 kg/吨浆高纯轻质碳酸钙填料;浆料经净化除渣、脱气、压力筛选后送入夹网纸机流浆箱,调整上网浓度为为0.22%,浆网速比为1.01,车速为300 m/min,抄制定量为18-20g/m2的湿纸页;出网部后湿纸页经五辊三压区复合压榨后进干燥部;干燥部烘缸表面温度控制在70~115℃对纸页进行干燥处理,至纸页干度≥93%;出干燥部纸页进入压光区进行压光处理,压光温度控制在60-80℃,压光压力控制在50-60kN/cm;经过压光后,对纸张进行卷取,即可制得定量为18-20 g/m2,水分为6.0-7.0%,松厚度为1.6-1.7 cm3/g,白度 (ISO)大于88%,碳酸钙含量9-10%,裂断长纵向大于3000m,铁离子含量小于20ppm,铜离子含量小于5ppm的用于包装不含蛋白质的文物制品的无酸内衬纸。
以上显示和描述了本发明的基本原理和主要特征及本发明的优点,本行业的技术人员应该了解,本发明不受实施例的限制,上述实施例和说明书中描述的只是本发明的原理,在不脱离本发明精神和范围的前提下,本发明还会有各种变化和改进,这些变化和改进都落入要求保护的本发明范围内,本发明要求保护范围由所附的权利要求及其等效物界定。
Claims (1)
1.一种文物保护用无酸内衬纸的制造方法,包括使用漂白硫酸盐针叶木浆、漂白硫酸盐阔叶木浆经分别打浆、配浆及辅料加入、湿纸页抄造、干燥、压光工艺步骤,其特征在于:
(1) 浆料重量配比:漂白硫酸盐针叶木浆:漂白硫酸盐阔叶木浆为(50~100):(0-50);
(2) 浆料打浆后打浆度:漂白硫酸盐针叶木浆20-45°SR;漂白硫酸盐阔叶木浆25-55°SR;
(3) 辅料对绝干浆用量为:(a) 施胶剂烷基烯酮二聚体重量比0~0.25%; (b) 阳离子淀粉重量比0~1.5%;(c)碳酸钙填料重量比0.5~15.0%;
(4) 湿纸页抄造
将上述原料用去离子水配置成浆料,经过净化、除气、筛选等工序处理后,进行湿纸页抄造;调节纸机抄造工艺参数,上网浓度:0.1-0.3%;浆网速比:0.98-1.10;操作车速30-800m/min;抄制定量12-25 g/m2的湿纸页;湿纸页经压榨部脱水后进干燥部;
(5) 干燥压光
对压榨部进入的湿纸页进行干燥,控制烘缸表面温度在55-120℃,出干燥部纸页干度≥92%;
出干燥部后的纸页进入压光区,对纸页进行压光整饰,压光温度控制在45-110℃,压光压力控制在40-100kN/cm;经过压光后,对纸张进行卷取;即可制得用于保存不含蛋白质类文物制品的无酸内衬纸;
(6) 制得的碱性无酸内衬纸的特性:
定量为12-25g/m2,松厚度不小于1.5cm3/g,水分为5.0-8.0%,碳酸钙含量:0.4-14.0%;白度 (ISO)大于88%,裂断长纵向大于3000m,铁离子含量小于50ppm,铜离子含量小于5ppm;
其中所述步骤(1)中漂白硫酸盐针叶木浆和漂白硫酸盐阔叶木浆的卡伯值小于3;所述步骤(2)、(3)、(4)中的打浆用水,辅料稀释和熬制用水,抄纸用水均为去离子水;所述步骤(4)中的抄造纸机采用圆网纸机、长网纸机或叠网纸机中的任意一种。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610901873.9A CN106368077B (zh) | 2016-10-17 | 2016-10-17 | 一种文物保护用无酸内衬纸的制造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610901873.9A CN106368077B (zh) | 2016-10-17 | 2016-10-17 | 一种文物保护用无酸内衬纸的制造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106368077A CN106368077A (zh) | 2017-02-01 |
CN106368077B true CN106368077B (zh) | 2018-04-24 |
Family
ID=57896355
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610901873.9A Active CN106368077B (zh) | 2016-10-17 | 2016-10-17 | 一种文物保护用无酸内衬纸的制造方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106368077B (zh) |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101328699A (zh) * | 2008-07-18 | 2008-12-24 | 南京林业大学 | 文物保护专用无酸纸和制备方法 |
CN102277776A (zh) * | 2011-08-05 | 2011-12-14 | 长沙理工大学 | 一种微量涂布典雅纯质纸的制造方法 |
CN103741558A (zh) * | 2013-12-31 | 2014-04-23 | 宋俊富 | 一种仿古艺术纸的制造方法 |
CN104195877A (zh) * | 2014-09-11 | 2014-12-10 | 岳阳林纸股份有限公司 | 一种黄色卡纸及其制造方法 |
-
2016
- 2016-10-17 CN CN201610901873.9A patent/CN106368077B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101328699A (zh) * | 2008-07-18 | 2008-12-24 | 南京林业大学 | 文物保护专用无酸纸和制备方法 |
CN102277776A (zh) * | 2011-08-05 | 2011-12-14 | 长沙理工大学 | 一种微量涂布典雅纯质纸的制造方法 |
CN103741558A (zh) * | 2013-12-31 | 2014-04-23 | 宋俊富 | 一种仿古艺术纸的制造方法 |
CN104195877A (zh) * | 2014-09-11 | 2014-12-10 | 岳阳林纸股份有限公司 | 一种黄色卡纸及其制造方法 |
Also Published As
Publication number | Publication date |
---|---|
CN106368077A (zh) | 2017-02-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106894268B (zh) | 一种高强度牛皮箱板纸及其制备方法 | |
FI126699B (en) | Process for making cardboard | |
EP2122051B1 (en) | Process for the production of cellulosic product | |
FI114652B (fi) | Menetelmä paperin valmistamiseksi | |
CA2915969C (en) | Fibrous product and method of producing fibrous web | |
CN101180432A (zh) | 改性的牛皮纤维 | |
CN108468248A (zh) | 一种食盐包装纸的制造方法 | |
CA2999106C (en) | Use of cellulosic fibre pulp with a schopper-riegler number of 70 to 90 | |
CN102002892A (zh) | 一种低定量吸管包装纸的生产工艺 | |
KR100662043B1 (ko) | 제지용 대나무 펄프의 제조방법과 그 펄프 및 그 지류제조방법 | |
CN107254797A (zh) | 一种石膏板护面纸上纸及下纸的生产工艺 | |
CN108130797A (zh) | 一种低定量免涂蜡功能型食品包装纸的制备方法 | |
CN102154927B (zh) | 一种双胶纸及其制备方法 | |
CN108130818A (zh) | 一种双色防油抗菌食品包装纸的制备方法 | |
EP2971350B1 (en) | Processes and compositions for brightness improvement in paper production | |
CN106715797B (zh) | 用于生产纸或纸板的至少一个层的方法以及根据该方法生产的纸或纸板 | |
US20040221977A1 (en) | Retention and Drainage System For the Manufacturing of Paper | |
CN104120633A (zh) | 一种包装纸的生产工艺 | |
CN106368077B (zh) | 一种文物保护用无酸内衬纸的制造方法 | |
CN107964825B (zh) | 一种低克重条盒纸原纸及其生产方法和应用 | |
CN109024054A (zh) | 高透气度滤棒成形纸及其生产方法 | |
US1812832A (en) | Filled pulp and method of making the same | |
CN106436437B (zh) | 一种文物保护用无酸内衬纸的制造方法 | |
CN111851131A (zh) | 一种具有防潮效果的办公用纸的制备方法 | |
CN104099798A (zh) | 一种白板纸的生产工艺 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Liu Yanxin Inventor after: Wang Yulong Inventor after: Wang Yue Inventor before: Wang Yulong Inventor before: Liu Yanxin Inventor before: Wang Yue |
|
GR01 | Patent grant | ||
GR01 | Patent grant |