CN106336541A - Butylbenzene-series environment-friendly type rubber floor glue stock and preparation method thereof - Google Patents
Butylbenzene-series environment-friendly type rubber floor glue stock and preparation method thereof Download PDFInfo
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- CN106336541A CN106336541A CN201610710383.0A CN201610710383A CN106336541A CN 106336541 A CN106336541 A CN 106336541A CN 201610710383 A CN201610710383 A CN 201610710383A CN 106336541 A CN106336541 A CN 106336541A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
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Abstract
The invention discloses butylbenzene-series environment-friendly type rubber floor glue stock and a preparation method thereof. The glue stock is composed of active ingredients of the following raw materials (by weight): styrene butadiene rubber, zinc oxide, stearic acid, an anti-aging agent, paraffin, titanium dioxide, argil, aluminium hydroxide, zinc borate, a fire retardant, white carbon black, nano-kaolin, ultrafine calcium carbonate, an antistatic agent, a dispersant FC-303, a flow promoter, an anti-ultraviolet agent UV531, an antibacterial agent, a vulcanizing agent S-80, a promoter TBZTD, a vulcanizing agent CLD-80, a promoter DDTS and a pigment. The problem that flooring in the prior art has poor skid resistance, has no elasticity, water resistance, wear resistance or fire resistance, has no antibacterial property, is expensive in price and releases harmful gas or radioactive element is solved in the invention.
Description
Technical field
The invention belongs to technical field of polymer materials and in particular to a kind of butylbenzene series environment-friendly type rubber floor covering sizing material, this
The bright preparation method further relating to butylbenzene series environment-friendly type rubber floor covering sizing material.
Background technology
Rubber floor covering is a kind of following ground material having the potentiality that grow a lot, and in west european developed country, annual consumption is all several
Million square metres, China's rubber floor covering development speed and consumption also sharply increase, and annual with 20% speed increase.With
The enforcement of national " industrial powers 2025 ", " top grade, environmental protection, energy-conservation " type rubber floor covering will become the master of rubber ground material development from now on
Stream.Rubber ground material traditional at present still can not meet requirements above, as too low in floor paint/floor wax class;Floor tile is anti-skidding
Property is poor, and frangible, load-bearing is poor;The anti-slippage of stone floor, price, construction trouble, in addition some stone material radons containing radioelement, right
Human body has injury;Timber floor color is single, non-moistureproof, not water-fast, not fire-retardant, and especially a large amount of formaldehyde etc. are contained on some floors inferior
Harmful gass etc.;Carpet price is high, maintenance is difficult, not water-fast, not wear-resisting, do not prevent fires, and some carpet feature of environmental protection inferior are poor, easily
Breed bacteria etc.;Stone moulds that floor tile is easy to wear, easy fragmentation, easily pollution, short life etc.;Pvc plastic floor, be not durable, use in decline
Become phenomenon obvious, nonelastic etc..
Environment-friendly rubber floor coordinates environment-friendly rubber auxiliary agent to process using environmental protection, free of contamination robber materialses
Rubber.This product material therefor is all nontoxic, harmless environmental protection macromolecule material, so the environmental protection ground material that is otherwise known as.Rubber
Adhesive floor, due to spies such as it is wear-resisting, elastic, anti-skidding, moistureproof, fire-retardant, antistatic, beautiful in colour, easy laying, easy cleaning maintenances
Point, especially by different processing technology, can copy into stone material, terrazzo and wood floors pattern rubber floor covering, dimension
Wonderful dimension is skilful.It is applied to the fields such as industry, track traffic, airport, antistatic.With Horizon paint, floor wax, floor tile, stone material
Floor, timber floor, carpet, stone moulds floor tile, pvc floor is compared, and rubber floor covering has with the unmatched characteristic of Shangdi material, rubber ground
Plate effectively overcomes the unfavorable factor on other floors, is the synthetic material floor that future has market prospect most.
Content of the invention
It is an object of the invention to provide a kind of butylbenzene series environment-friendly type rubber floor covering sizing material, with solving present in prior art
The anti-slippage of material, nonelastic, not water-fast, not wear-resisting, do not prevent fires, not antibacterial, price, release harmful gass or the asking of radioactive element
Topic.
It is a further object of the present invention to provide a kind of preparation method of butylbenzene series environment-friendly type rubber floor covering sizing material.
First technical scheme of the present invention is, a kind of butylbenzene series environment-friendly type rubber floor covering sizing material, by weight percentage
It is made up of the active component of following raw material: butadiene-styrene rubber 26%~30%, zinc oxide 1.3%~1.5%, stearic acid 0.5%~
0.6%, antioxidant 2246/616 0.5%~0.6%, paraffin 0.1%~0.15%, titanium dioxide 1.4%~2.7%, potter's clay 0
~12%, aluminium hydroxide 5%~18%, Firebrake ZB 4%~6%, fire retardant bn-18c 1.5%~8.7%, white carbon 3.5%
~12%, nano kaoline 10%~24.5%, calcium carbonate superfine powder 0~19%, antistatic additive 0.5%~0.6%, dispersant
Fc-303 0.5%~0.6%, flow promortor peg4000 0.5%~0.6%, ultraviolet (UV) resistant agent uv531 0.4%~
0.5%, antibacterial cz-kz10 0.4%~0.5%, vulcanizing agent s-80 0.15%~0.20%, accelerator tbzTd0.5%~
0.6%, vulcanizing agent cld-80 0.4%~0.5%, accelerator ddts 0.1%~0.15%, pigment 0.20%~0.30%,
The percentage composition summation of above component is 100%.
The feature of the present invention first technical scheme also resides in,
Butadiene-styrene rubber is 1502e.
Zinc oxide, stearic acid, antioxidant 2246/616, paraffin, titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, fire retardant bn-
18c, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor peg4000, uvioresistant
Line agent uv531, antibacterial cz-kz10, vulcanizing agent s-80, accelerator tbzTd, vulcanizing agent cld-80, accelerator ddts, pigment are equal
For environment-friendly rubber auxiliary agent.
Second technical scheme of the present invention is, a kind of preparation method of butylbenzene series environment-friendly type rubber floor covering sizing material, tool
Body is implemented according to following steps:
Step 1, weigh raw material, weigh butadiene-styrene rubber 26%~30% according to percentage by weight, zinc oxide 1.3%~1.5%, firmly
Fat acid 0.5%~0.6%, antioxidant 2246/616 0.5%~0.6%, paraffin 0.1%~0.15%, titanium dioxide 1.4%~
2.7%, potter's clay 0~12%, aluminium hydroxide 5%~18%, Firebrake ZB 4%~6%, fire retardant bn-18c 1.5%~8.7%,
White carbon 3.5%~12%, nano kaoline 10%~24.5%, calcium carbonate superfine powder 0~19%, antistatic additive 0.5%~
0.6%, dispersant fc-303 0.5%~0.6%, flow promortor peg4000 0.5%~0.6%, ultraviolet (UV) resistant agent uv531
0.4%~0.5%, antibacterial cz-kz10 0.4%~0.5%, vulcanizing agent s-80 0.15%~0.20%, accelerator
tbzTd0.5%~0.6%, vulcanizing agent cld-80 0.4%~0.5%, accelerator ddts 0.1%~0.15%, pigment
0.20%~0.30%, the percentage composition summation of above component is 100%;
Step 2, the butadiene-styrene rubber weighing in step 1 is pressed: roll spacing controls in 4~6mm, and time control is in 1~3min;
Zinc oxide, stearic acid, antioxidant 2246/616, roll spacing is sequentially added in step 3, the butadiene-styrene rubber after step 2 presses
Control in 6~8mm, time control is in 1.5~2.5min;
Step 4, rubber compounding: sequentially add small powder on the basis of step 3: titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB,
Fire retardant bn-18c, White Carbon black, paraffin, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor
Peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, pigment, then stir, and roll spacing controls in 6~8mm, the time
Control in 19~21min;
Step 5, step 4 is kneaded after thin logical 3~4 times of sizing material, roll spacing controls in 1~2mm, and time control is in 3~5min;
Step 6, elastomeric compound add sulfur: vulcanizing agent s-80, accelerator tbztd, vulcanizing agent cld-80, accelerator ddts are sequentially added
Step 5 thin logical after glue stuff compounding in, then stir, then thin logical 3 times, roll spacing controls in 1~2mm, time control is 3
~5min;
Step 7, clot bottom sheet: by plus sulfur elastomeric compound clot 6 times on rubber mixing machine, slice after bag roller, roll spacing controls 8~
10mm, time control, in 2~4min, obtains butylbenzene series environment-friendly type rubber floor covering sizing material.
The feature of the present invention second technical scheme also resides in,
Butadiene-styrene rubber in step 1 is 1502e.
Zinc oxide in step 1, stearic acid, antioxidant 2246/616, paraffin, titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, resistance
Combustion agent bn-18c, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor
Peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, vulcanizing agent s-80, accelerator tbzTd, vulcanizing agent cld-80, rush
Enter agent ddts, pigment is environment-friendly rubber auxiliary agent.
In step 4, whole adition process divides 4 additions, and each addition is titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, fire-retardant
Agent bn-18c, White Carbon black, paraffin, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor
Peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, the 1/4 of pigment total amount, after adding every time, pan feeding to be added with mix
Carrying out charging next time after rubber is compatible.
The invention has the beneficial effects as follows, a kind of butylbenzene series environment-friendly type rubber floor covering sizing material, butadiene-styrene rubber is 1502e, zinc oxide,
Stearic acid, antioxidant 2246/616, paraffin, titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, fire retardant bn-18c, white carbon, receive
Rice Kaolin, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor peg4000, ultraviolet (UV) resistant agent uv531, anti-
Microbial inoculum cz-kz10, vulcanizing agent s-80, accelerator tbzTd, vulcanizing agent cld-80, accelerator ddts, pigment are environment-friendly rubber
Auxiliary agent, this formula is nontoxic, pollution-free, green, environmental protection, efficiently solves that floor tile skid resistance is poor, poor the asking of frangible, load-bearing
Topic.
Brief description
Fig. 1 is a kind of preparation method flow chart of butylbenzene of present invention series environment-friendly type rubber floor covering sizing material.
Specific embodiment
The present invention is described in detail with reference to the accompanying drawings and detailed description.
A kind of butylbenzene of present invention series environment-friendly type rubber floor covering sizing material, by weight percentage by the active component group of following raw material
Become: butadiene-styrene rubber 26%~30%, zinc oxide 1.3%~1.5%, stearic acid 0.5%~0.6%, antioxidant 2246/616
0.5%~0.6%, paraffin 0.1%~0.15%, titanium dioxide 1.4%~2.7%, potter's clay 0~12%, aluminium hydroxide 5%~
18%, Firebrake ZB 4%~6%, fire retardant bn-18c 1.5%~8.7%, white carbon 3.5%~12%, nano kaoline
10%~24.5%, calcium carbonate superfine powder 0~19%, antistatic additive 0.5%~0.6%, dispersant fc-303 0.5%~
0.6%, flow promortor peg40000.5%~0.6%, ultraviolet (UV) resistant agent uv531 0.4%~0.5%, antibacterial cz-kz10
0.4%~0.5%, vulcanizing agent s-80 0.15%~0.20%, accelerator tbzTd 0.5%~0.6%, vulcanizing agent cld-
800.4%~0.5%, accelerator ddts 0.1%~0.15%, pigment 0.20%~0.30%, the content percentage of above component
It is 100% than summation.
Wherein, butadiene-styrene rubber is 1502e.Zinc oxide, stearic acid, antioxidant 2246/616, paraffin, titanium dioxide, potter's clay, hydroxide
Aluminum, Firebrake ZB, fire retardant bn-18c, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, stream
Dynamic auxiliary agent peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, vulcanizing agent s-80, accelerator tbzTd, vulcanizing agent cld-
80th, accelerator ddts, pigment are environment-friendly rubber auxiliary agent.
The preparation method of butylbenzene series environment-friendly type rubber floor covering sizing material, as shown in figure 1, specifically implementing according to following steps:
Step 1, weigh raw material, weigh butadiene-styrene rubber 26%~30% according to percentage by weight, zinc oxide 1.3%~1.5%, firmly
Fat acid 0.5%~0.6%, antioxidant 2246/616 0.5%~0.6%, paraffin 0.1%~0.15%, titanium dioxide 1.4%~
2.7%, potter's clay 0~12%, aluminium hydroxide 5%~18%, Firebrake ZB 4%~6%, fire retardant bn-18c 1.5%~8.7%,
White carbon 3.5%~12%, nano kaoline 10%~24.5%, calcium carbonate superfine powder 0~19%, antistatic additive 0.5%~
0.6%, dispersant fc-303 0.5%~0.6%, flow promortor peg4000 0.5%~0.6%, ultraviolet (UV) resistant agent uv531
0.4%~0.5%, antibacterial cz-kz10 0.4%~0.5%, vulcanizing agent s-80 0.15%~0.20%, accelerator
tbzTd0.5%~0.6%, vulcanizing agent cld-80 0.4%~0.5%, accelerator ddts 0.1%~0.15%, pigment
0.20%~0.30%, the percentage composition summation of above component is 100%;
Step 2, the butadiene-styrene rubber weighing in step 1 is pressed: roll spacing controls in 4~6mm, and time control is in 1~3min;
Zinc oxide, stearic acid, antioxidant 2246/616, roll spacing is sequentially added in step 3, the butadiene-styrene rubber after step 2 presses
Control in 6~8mm, time control is in 1.5~2.5min;
Step 4, rubber compounding: sequentially add small powder on the basis of step 3: titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB,
Fire retardant bn-18c, White Carbon black, paraffin, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor
Peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, pigment, then stir, and roll spacing controls in 6~8mm, the time
Control in 19~21min;
Step 5, step 4 is kneaded after thin logical 3~4 times of sizing material, roll spacing controls in 1~2mm, and time control is in 3~5min;
Step 6, elastomeric compound add sulfur: vulcanizing agent s-80, accelerator tbztd, vulcanizing agent cld-80, accelerator ddts are sequentially added
Step 5 thin logical after glue stuff compounding in, then stir, then thin logical 3 times, roll spacing controls in 1~2mm, time control is 3
~5min;
Step 7, clot bottom sheet: by plus sulfur elastomeric compound clot 6 times on rubber mixing machine, slice after bag roller, roll spacing controls 8~
10mm, time control, in 2~4min, obtains butylbenzene series environment-friendly type rubber floor covering sizing material.
Wherein, the butadiene-styrene rubber in step 1 is 1502e.
Zinc oxide in step 1, stearic acid, antioxidant 2246/616, paraffin, titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, resistance
Combustion agent bn-18c, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor
Peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, vulcanizing agent s-80, accelerator tbzTd, vulcanizing agent cld-80, rush
Enter agent ddts, pigment is environment-friendly rubber auxiliary agent.
In step 4, whole adition process divides 4 additions, and each addition is titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, fire-retardant
Agent bn-18c, White Carbon black, paraffin, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor
Peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, the 1/4 of pigment total amount, after adding every time, pan feeding to be added with mix
Carrying out charging next time after rubber is compatible.
Butylbenzene series environment-friendly type rubber floor covering sizing material of the present invention, nontoxic, pollution-free, green, environmental protection, efficiently solve floor tile
Skid resistance is poor, the poor feature of frangible, load-bearing;Efficiently solve the anti-slippage of stone floor, price, construction trouble, contain radioactivity
Element radon, has the characteristics that injury to human body;Efficiently solve that timber floor color is single, non-moistureproof, not water-fast, not fire-retardant, contain
The feature of the harmful gass such as a large amount of formaldehyde;Efficiently solve that carpet price is high, maintenance is difficult, not water-fast, not wear-resisting, do not prevent fires,
The feature of easy breed bacteria;Efficiently solve stone mould that floor tile is easy to wear, easy fragmentation, easily pollution, short life the features such as;Effectively solving
Pvc plastic floor, be not durable, use in decaying phenomenon substantially, the features such as nonelastic.It is wear-resisting, high resiliency, anti-skidding, moistureproof,
The features such as fire-retardant, antistatic, beautiful in colour, easy laying, easy cleaning are maintained is so as to be applied to industry, track traffic, airport, anti-
The fields such as electrostatic.
Embodiment 1
The preparation method of butylbenzene series environment-friendly type rubber floor covering sizing material, specifically implements according to following steps:
Step 1, weighing raw material, weigh butadiene-styrene rubber 26.55%, zinc oxide 1.3%, stearic acid according to percentage by weight
0.53%, antioxidant 2246/616 0.54%, paraffin 0.13%, titanium dioxide 2.66%, potter's clay 7.97%, aluminium hydroxide
15.93%, Firebrake ZB 5.31%, fire retardant bn-18c 1.99%, white carbon 3.98%, nano kaoline 10.62%, ultra-fine
Calcium Carbonate 18.58%, antistatic additive 0.53%, dispersant fc-303 0.53%, flow promortor peg4000 0.53%, anti-purple
Outside line agent uv531 0.40%, antibacterial cz-kz10 0.40%, vulcanizing agent s-80 0.16%, accelerator tbzTd 0.53%,
Vulcanizing agent cld-800.40%, accelerator ddts 0.13%, pigment 0.27%, the percentage composition summation of above component is
100%;
Step 2, the butadiene-styrene rubber weighing in step 1 is pressed: roll spacing controls in 6mm, and time control is in 3min;
Zinc oxide, stearic acid, antioxidant 2246/616, roll spacing is sequentially added in step 3, the butadiene-styrene rubber after step 2 presses
Control in 8mm, time control is in 2.5min;
Step 4, rubber compounding: sequentially add small powder on the basis of step 3: titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB,
Fire retardant bn-18c, White Carbon black, paraffin, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor
Peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, pigment, then stir, and roll spacing controls in 8mm, and the time is controlled
System is in 21min;
Step 5, step 4 is kneaded after thin logical 4 times of sizing material, roll spacing controls in 2mm, and time control is in 5min;
Step 6, elastomeric compound add sulfur: vulcanizing agent s-80, accelerator tbztd, vulcanizing agent cld-80, accelerator ddts are sequentially added
Step 5 thin logical after glue stuff compounding in, then stir, then thin logical 3 times, roll spacing controls in 2mm, and time control exists
5min;
Step 7, clot bottom sheet: added elastomeric compound clot 6 times on rubber mixing machine of sulfur, slice after bag roller, roll spacing controls
10mm, time control, in 4min, obtains butylbenzene series environment-friendly type rubber floor covering sizing material.
Embodiment 2
The preparation method of butylbenzene series environment-friendly type rubber floor covering sizing material, as shown in figure 1, specifically implementing according to following steps:
Step 1, weighing raw material, weigh butadiene-styrene rubber 29.5%, zinc oxide 1.47%, stearic acid according to percentage by weight
0.59%, antioxidant 2246/616 0.58%, paraffin 0.15%, titanium dioxide 1.47%, potter's clay 11.8%, aluminium hydroxide
5.9%, Firebrake ZB 4.42%, fire retardant bn-18c 4.42%, white carbon 11.8%, nano kaoline 23.6%, antistatic additive
0.59%, dispersant fc-303 0.59%, flow promortor peg4000 0.59%, ultraviolet (UV) resistant agent uv531 0.44%, antibacterial
Agent cz-kz10 0.44%, vulcanizing agent s-80 0.18%, accelerator tbzTd 0.59%, vulcanizing agent cld-80 0.44%, promote
Enter agent ddts0.15%, pigment 0.29%, the percentage composition summation of above component is 100%;
Step 2, the butadiene-styrene rubber weighing in step 1 is pressed: roll spacing controls in 4mm, and time control is in 1min;
Zinc oxide, stearic acid, antioxidant 2246/616, roll spacing is sequentially added in step 3, the butadiene-styrene rubber after step 2 presses
Control in 6mm, time control is in 1.5min;
Step 4, rubber compounding: sequentially add small powder on the basis of step 3: titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB,
Fire retardant bn-18c, White Carbon black, paraffin, nano kaoline, antistatic additive, dispersant fc-303, flow promortor peg4000, anti-
Ultraviolet agent uv531, antibacterial cz-kz10, pigment, then stir, and roll spacing controls in 6mm, and time control is in 19min;
Step 5, step 4 is kneaded after thin logical 3 times of sizing material, roll spacing controls in 1mm, and time control is in 3min;
Step 6, elastomeric compound add sulfur: vulcanizing agent s-80, accelerator tbztd, vulcanizing agent cld-80, accelerator ddts are sequentially added
Step 5 thin logical after glue stuff compounding in, then stir, then thin logical 3 times, roll spacing controls in 1mm, and time control exists
3min;
Step 7, clot bottom sheet: added elastomeric compound clot 6 times on rubber mixing machine of sulfur, slice after bag roller, roll spacing controls
8mm, time control, in 2min, obtains butylbenzene series environment-friendly type rubber floor covering sizing material.
Embodiment 3
The preparation method of butylbenzene series environment-friendly type rubber floor covering sizing material, specifically implements according to following steps:
Step 1, weighing raw material, weigh butadiene-styrene rubber 28.65%, zinc oxide 1.42%, stearic acid according to percentage by weight
0.57%, antioxidant 2246/616 0.58%, paraffin 0.14%, titanium dioxide 1.43%, aluminium hydroxide 17.19%, Firebrake ZB
5.73%, fire retardant bn-18c 8.6%, white carbon 11.46%, nano kaoline 20.05%, antistatic additive 0.57%, dispersion
Agent fc-303 0.57%, flow promortor peg40000.57%, ultraviolet (UV) resistant agent uv531 0.43%, antibacterial cz-kz10
0.43%, vulcanizing agent s-800.17%, accelerator tbzTd 0.57%, vulcanizing agent cld-80 0.43%, accelerator ddts
0.14%, pigment 0.29%, the percentage composition summation of above component is 100%;
Step 2, the butadiene-styrene rubber weighing in step 1 is pressed: roll spacing controls in 5mm, and time control is in 2min;
Zinc oxide, stearic acid, antioxidant 2246/616, roll spacing is sequentially added in step 3, the butadiene-styrene rubber after step 2 presses
Control in 7mm, time control is in 2min;
Step 4, rubber compounding: sequentially add small powder on the basis of step 3: titanium dioxide, aluminium hydroxide, Firebrake ZB, fire-retardant
Agent bn-18c, White Carbon black, paraffin, nano kaoline, antistatic additive, dispersant fc-303, flow promortor peg4000, uvioresistant
Line agent uv531, antibacterial cz-kz10, pigment, then stir, and roll spacing controls in 7mm, and time control is in 20min;
Step 5, step 4 is kneaded after thin logical 4 times of sizing material, roll spacing controls in 1mm, and time control is in 4min;
Step 6, elastomeric compound add sulfur: vulcanizing agent s-80, accelerator tbztd, vulcanizing agent cld-80, accelerator ddts are sequentially added
Step 5 thin logical after glue stuff compounding in, then stir, then thin logical 3 times, roll spacing controls in 1mm, and time control exists
4min;
Step 7, clot bottom sheet: added elastomeric compound clot 6 times on rubber mixing machine of sulfur, slice after bag roller, roll spacing controls
9mm, time control, in 3min, obtains butylbenzene series environment-friendly type rubber floor covering sizing material.
Claims (7)
1. a kind of butylbenzene series environment-friendly type rubber floor covering sizing material is it is characterised in that effective by following raw material by weight percentage
Group is grouped into:
Butadiene-styrene rubber 26%~30%, zinc oxide 1.3%~1.5%, stearic acid 0.5%~0.6%, antioxidant 2246/616
0.5%~0.6%, paraffin 0.1%~0.15%, titanium dioxide 1.4%~2.7%, potter's clay 0~12%, aluminium hydroxide 5%~
18%, Firebrake ZB 4%~6%, fire retardant bn-18c 1.5%~8.7%, white carbon 3.5%~12%, nano kaoline
10%~24.5%, calcium carbonate superfine powder 0~19%, antistatic additive 0.5%~0.6%, dispersant fc-303 0.5%~
0.6%, flow promortor peg4000 0.5%~0.6%, ultraviolet (UV) resistant agent uv531 0.4%~0.5%, antibacterial cz-kz10
0.4%~0.5%, vulcanizing agent s-80 0.15%~0.20%, accelerator tbzTd 0.5%~0.6%, vulcanizing agent cld-80
0.4%~0.5%, accelerator ddts 0.1%~0.15%, pigment 0.20%~0.30%, the percentage composition of above component
Summation is 100%.
2. a kind of butylbenzene series environment-friendly type rubber floor covering sizing material according to claim 1 is it is characterised in that described butylbenzene rubber
Glue is 1502e.
3. a kind of butylbenzene series environment-friendly type rubber floor covering sizing material according to claim 1 is it is characterised in that described oxidation
Zinc, stearic acid, antioxidant 2246/616, paraffin, titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, fire retardant bn-18c, Linesless charcoal
Black, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor peg4000, ultraviolet (UV) resistant agent
Uv531, antibacterial cz-kz10, vulcanizing agent s-80, accelerator tbzTd, vulcanizing agent cld-80, accelerator ddts, pigment are ring
Guarantor's type rubber chemicals.
4. a kind of preparation method of butylbenzene series environment-friendly type rubber floor covering sizing material is it is characterised in that specifically real according to following steps
Apply:
Step 1, weigh raw material, weigh butadiene-styrene rubber 26%~30% according to percentage by weight, zinc oxide 1.3%~1.5%, firmly
Fat acid 0.5%~0.6%, antioxidant 2246/616 0.5%~0.6%, paraffin 0.1%~0.15%, titanium dioxide 1.4%~
2.7%, potter's clay 0~12%, aluminium hydroxide 5%~18%, Firebrake ZB 4%~6%, fire retardant bn-18c 1.5%~8.7%,
White carbon 3.5%~12%, nano kaoline 10%~24.5%, calcium carbonate superfine powder 0~19%, antistatic additive 0.5%~
0.6%, dispersant fc-303 0.5%~0.6%, flow promortor peg4000 0.5%~0.6%, ultraviolet (UV) resistant agent uv531
0.4%~0.5%, antibacterial cz-kz10 0.4%~0.5%, vulcanizing agent s-80 0.15%~0.20%, accelerator tbztd
0.5%~0.6%, vulcanizing agent cld-80 0.4%~0.5%, accelerator ddts 0.1%~0.15%, pigment 0.20%~
0.30%, the percentage composition summation of above component is 100%;
Step 2, the butadiene-styrene rubber weighing in described step 1 is pressed: roll spacing controls in 4~6mm, time control 1~
3min;
Zinc oxide, stearic acid, antioxidant 2246/616 are sequentially added in step 3, the butadiene-styrene rubber after described step 2 presses,
Roll spacing controls in 6~8mm, and time control is in 1.5~2.5min;
Step 4, rubber compounding: sequentially add small powder: titanium dioxide, potter's clay, aluminium hydroxide, boron on the basis of described step 3
Sour zinc, fire retardant bn-18c, White Carbon black, paraffin, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, stream
Dynamic auxiliary agent peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, pigment, then stir, and roll spacing controls 6~
8mm, time control is in 19~21min;
Step 5, described step 4 is kneaded after thin logical 3~4 times of sizing material, roll spacing controls in 1~2mm, time control 3~
5min;
Step 6, elastomeric compound add sulfur: vulcanizing agent s-80, accelerator tbztd, vulcanizing agent cld-80, accelerator ddts are sequentially added
Described step 5 thin logical after glue stuff compounding in, then stir, then thin logical 3 times, roll spacing controls in 1~2mm, and the time is controlled
System is in 3~5min;
Step 7, clot bottom sheet: by plus sulfur elastomeric compound clot 6 times on rubber mixing machine, slice after bag roller, roll spacing controls 8~
10mm, time control, in 2~4min, obtains butylbenzene series environment-friendly type rubber floor covering sizing material.
5. a kind of butylbenzene series environment-friendly type rubber floor covering sizing material according to claim 4 preparation method it is characterised in that
Butadiene-styrene rubber in described step 1 is 1502e.
6. a kind of butylbenzene series environment-friendly type rubber floor covering sizing material according to claim 4 preparation method it is characterised in that
Zinc oxide in described step 1, stearic acid, antioxidant 2246/616, paraffin, titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, resistance
Combustion agent bn-18c, white carbon, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor
Peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, vulcanizing agent s-80, accelerator tbzTd, vulcanizing agent cld-80, rush
Enter agent ddts, pigment is environment-friendly rubber auxiliary agent.
7. a kind of butylbenzene series environment-friendly type rubber floor covering sizing material according to claim 4 preparation method it is characterised in that
In described step 4, whole adition process divides 4 additions, and each addition is titanium dioxide, potter's clay, aluminium hydroxide, Firebrake ZB, fire-retardant
Agent bn-18c, White Carbon black, paraffin, nano kaoline, calcium carbonate superfine powder, antistatic additive, dispersant fc-303, flow promortor
Peg4000, ultraviolet (UV) resistant agent uv531, antibacterial cz-kz10, the 1/4 of pigment total amount, after adding every time, pan feeding to be added with mix
Carrying out charging next time after rubber is compatible.
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