CN106319584A - Machining technology of ultrahigh-surface-density foam nickel - Google Patents

Machining technology of ultrahigh-surface-density foam nickel Download PDF

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Publication number
CN106319584A
CN106319584A CN201610885713.XA CN201610885713A CN106319584A CN 106319584 A CN106319584 A CN 106319584A CN 201610885713 A CN201610885713 A CN 201610885713A CN 106319584 A CN106319584 A CN 106319584A
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CN
China
Prior art keywords
foam
plating
time
electroplating
carried out
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Application number
CN201610885713.XA
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Chinese (zh)
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CN106319584B (en
Inventor
刘云志
何奋
贾雷
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ADVANCED TECHNOLOGY MATERIALS (DALIAN)CO LTD
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ADVANCED TECHNOLOGY MATERIALS (DALIAN)CO LTD
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Priority to CN201610885713.XA priority Critical patent/CN106319584B/en
Publication of CN106319584A publication Critical patent/CN106319584A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/10Electroplating with more than one layer of the same or of different metals
    • C25D5/12Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
    • C25D5/14Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/48After-treatment of electroplated surfaces
    • C25D5/50After-treatment of electroplated surfaces by heat-treatment
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/54Electroplating of non-metallic surfaces
    • C25D5/56Electroplating of non-metallic surfaces of plastics

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

The invention discloses a machining technology of ultrahigh-surface-density foam nickel, and belongs to the field of special foam nickel. Firstly, foam is subject to conductive treatment, preparing before electroplating is carried out, the foam obtained after conductive treatment is electroplated under the state that the four sides have certain tension, hot pressing treatment is carried out after electroplating, secondary electroplating and heat treatment are carried out, the machining technology is easy to operate, the production technology is low in cost, the problems that due to the fact that the density is too high, uneven electroplating appears in electroplating, the stress is too large and deformation is too large, products are poor are solved, the use problem brought by uneven electroplating also can be solved in the technology, and the use rate of the products is greatly improved.

Description

A kind of processing technique of superelevation surface density nickel foam
Technical field
The invention belongs to special nickel foam field, be specifically related to the processing technique of a kind of superelevation surface density nickel foam.
Background technology
In oil recovery business, oil extraction pump pump head needs the drainage screen of high-strength corrosion-resisting good filtration effect, at present major part Using stainless (steel) wire material to make, the drainage screen intensity that steel mesh makes is relatively low, and filter effect is poor, uses high areal density nickel foam Wire netting can effectively improve intensity and filter effect.But the common electroplating processing method of high areal density nickel foam there will be plating The subject matter that layer skewness, product stress are relatively big, deformation of products amount is bigger etc., We conducted respectively for problem above Plant test and finally determine work flow and method.
Summary of the invention
It is an object of the invention to provide the processing technique of a kind of superelevation surface density nickel foam, solve the deficiency of the problems referred to above, Can be produced with highdensity nickel foam meets the market demand by this technique.
The present invention is achieved in the following ways the processing technique of a kind of superelevation surface density nickel foam, its technological process Specifically comprise the following steps that
A: foam gluing or chemical plating or PVD are carried out conductive treatment;
B: the foam after conductionization is under the state that there is some tension on four limits and is arranged on resin edge, prevent the groove that is heated Liquid impulsive force and deform, and in the surrounding of foam, stealing bar is installed and carries out edge current and share, ensure foam with this The uniformity of nickel layer thickness distribution;
C: carrying out electroplating for the first time, cathode-current density now controls at 3-4ASD/dm, and surface density needs to control at 5000- 7000g/m, prevents intensity deficiency and stress problems of too;
D: for the first time after plating, cleans the residual of the tank liquor after plating and dries;
E: the foam after plating for the first time is carried out hot-pressing processing, it is therefore an objective to the stress of nickel dam after release plating, for secondary nickel plating Prepare;
F: second time plating uses 2-3ASD/dm electric current density to be machined to target areal density 1.1 times, offsets postorder deformation with this The surface density caused reduces problem;
G: after second time plating, cleans tank liquor and remains and dry foam;
H: the foam of second time plating is carried out heat treatment, eliminates product stress, the foam defoamed in nickel, reduction surface nickel Layer;
Described hot-pressing processing, hot compression parameters is pressure 2MPa/600 DEG C/1 hour.
Described heat treatment, parameter: speed 30m/h, oxidation panel temperature 600 DEG C, reduction section temperature 900 DEG C.
The processing technique that beneficial effects of the present invention is invented for this is simple to operate, and production technology is with low cost, and solves Occurring, owing to density is too high, the phenomenon that plating is uneven in plating, stress is excessive, it is bad to deform the product caused such as excessive Problem, the use problem brought for plating inequality is solved the most in this process, and the utilization rate of product is greatly improved.
Detailed description of the invention
A kind of processing technique of superelevation surface density nickel foam, a, by foam conductive treatment, then carry out electroplating front preparation, B, make conduction after foam be under the state that there is some tension on four limits and electroplate, prevent from being heated and sent out by tank liquor impulsive force Change shape, and to carry out electric current in product surrounding and share, ensure the uniformity of nickel foam layer thickness profile with this, c, plating Time surface density need to control at 5000-7000g/m, prevent that intensity is not enough and stress problems of too, d, for the first time plating After, clean the residual of the tank liquor after plating and dry, after e, plating, carrying out hot-pressing processing, it is therefore an objective to after release plating, nickel dam should Power, prepares for secondary nickel plating, and f, second time plating use 2-3ASD/dm electric current density to be machined to the 1.1 of target areal density Times, offset, with this, the surface density reduction problem that postorder deformation causes, after g, second time plating, clean tank liquor and remain and dry bubble Cotton, h, the foam finally carrying out heat treatment elimination product stress, defoaming in nickel, reduction surface nickel dam.
Material-uploading style in described step b is that four limits are tensioned, is had the stealing bar of share current by plating material surrounding.
Stress Release after being electroplated by hot pressing in step e, hot compression parameters is pressure 2MPa/600 DEG C/1 hour.
Described step h carries out heat treatment, heat treatment parameter: speed 30m/h, oxidation panel temperature 600 DEG C, reduction section temperature 900℃。

Claims (3)

1. the processing technique of a superelevation surface density nickel foam, it is characterised in that specifically comprising the following steps that of its technological process
A: foam gluing or chemical plating or PVD are carried out conductive treatment;
B: the foam after conductionization is under the state that there is some tension on four limits and is arranged on resin edge, and at foam Surrounding installation stealing bar carries out edge current and shares;
C: carrying out electroplating for the first time, cathode-current density now controls at 3-4ASD/dm, and surface density needs to control at 5000- 7000g/m²;
D: for the first time after plating, cleans the residual of the tank liquor after plating and dries;
E: the foam after plating for the first time is carried out hot-pressing processing, prepares for secondary nickel plating;
F: second time plating uses 2-3ASD/dm electric current density to be machined to target areal density 1.1 times;
G: after second time plating, cleans tank liquor and remains and dry foam;
H: the foam of second time plating is carried out heat treatment.
The processing technique of a kind of superelevation surface density nickel foam the most according to claim 1, it is characterised in that described hot pressing Processing, hot compression parameters is pressure 2MPa/600 DEG C/1 hour.
The processing technique of a kind of superelevation surface density nickel foam the most according to claim 1, it is characterised in that at described heat Reason, parameter: speed 30m/h, oxidation panel temperature 600 DEG C, reduction section temperature 900 DEG C.
CN201610885713.XA 2016-10-11 2016-10-11 A kind of processing technology of superelevation surface density nickel foam Active CN106319584B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610885713.XA CN106319584B (en) 2016-10-11 2016-10-11 A kind of processing technology of superelevation surface density nickel foam

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610885713.XA CN106319584B (en) 2016-10-11 2016-10-11 A kind of processing technology of superelevation surface density nickel foam

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CN106319584A true CN106319584A (en) 2017-01-11
CN106319584B CN106319584B (en) 2018-10-12

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107119274A (en) * 2017-05-04 2017-09-01 爱蓝天高新技术材料(大连)有限公司 The electroplating technology and its equipment of a kind of ni-based foam silver

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60196209A (en) * 1984-03-19 1985-10-04 Sumitomo Metal Ind Ltd Three-layer plated hot rolling roll
CN101092718A (en) * 2007-04-10 2007-12-26 李萌初 Composite material of foamed metal, and preparation method
CN101298686A (en) * 2007-04-30 2008-11-05 比亚迪股份有限公司 Method for preparing foamed metal
CN105525321A (en) * 2014-10-26 2016-04-27 常德力元新材料有限责任公司 Electroplating technology for preparing high-tensile-strength foamed nickel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60196209A (en) * 1984-03-19 1985-10-04 Sumitomo Metal Ind Ltd Three-layer plated hot rolling roll
CN101092718A (en) * 2007-04-10 2007-12-26 李萌初 Composite material of foamed metal, and preparation method
CN101298686A (en) * 2007-04-30 2008-11-05 比亚迪股份有限公司 Method for preparing foamed metal
CN105525321A (en) * 2014-10-26 2016-04-27 常德力元新材料有限责任公司 Electroplating technology for preparing high-tensile-strength foamed nickel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
唐有根等: "《镍氢电池》", 31 May 2007, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107119274A (en) * 2017-05-04 2017-09-01 爱蓝天高新技术材料(大连)有限公司 The electroplating technology and its equipment of a kind of ni-based foam silver
CN107119274B (en) * 2017-05-04 2019-03-05 爱蓝天高新技术材料(大连)有限公司 A kind of electroplating technology of ni-based foam silver

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