CN106317951A - Heat transfer printing disperse dye composition and heat transfer printing disperse dye and preparation method thereof - Google Patents
Heat transfer printing disperse dye composition and heat transfer printing disperse dye and preparation method thereof Download PDFInfo
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- CN106317951A CN106317951A CN201610664774.3A CN201610664774A CN106317951A CN 106317951 A CN106317951 A CN 106317951A CN 201610664774 A CN201610664774 A CN 201610664774A CN 106317951 A CN106317951 A CN 106317951A
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- auxiliary agent
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- 0 CC(C(C(*)C(C(C1*IC)C(c2c3cccc2)=O)C3=O)C1C(**IO)=*)=O Chemical compound CC(C(C(*)C(C(C1*IC)C(c2c3cccc2)=O)C3=O)C1C(**IO)=*)=O 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0041—Blends of pigments; Mixtured crystals; Solid solutions mixtures containing one azo dye
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/382—Contact thermal transfer or sublimation processes
- B41M5/385—Contact thermal transfer or sublimation processes characterised by the transferable dyes or pigments
- B41M5/3858—Mixtures of dyes, at least one being a dye classifiable in one of groups B41M5/385 - B41M5/39
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
- C09B67/0082—Preparations of disperse dyes or solvent dyes in liquid form
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention relates to a heat transfer printing disperse dye composition and heat transfer printing disperse dye and a preparation method and application thereof. The disperse dye composition is composed of a component A with the structure shown in the formula I, a component B with the structure shown in the formula II and a component C with the structure shown in the formula III (please see the formulas in the description). The heat transfer printing disperse dye is prepared from the heat transfer printing disperse dye composition, an auxiliary and water and is high in washing fastness, rubbing fastness, perspiration fastness, lifting force and transfer printing rate and good in repeatability.
Description
Technical field
Invention relates to dyeing and finishing technique field, particularly relates to a kind of thermal transfer disperse dyes extremely preparation method.
Background technology
Thermal transfer refers to the picture and text on intermediate carrier thin film use corresponding pressure transfer to a kind of print on stock
Brush method.Thermal transfer is to be imprinted on by arbitrary graphic pattern on a kind of special heat transfer printing paper, then through thermal transfer firing equipment,
Several minutes is heated to uniform temperature, and the pattern on paper, what color was true to nature is transferred to dacron, porcelain, glass, metal, moulds
The special typography of one in material stool material.
In recent years, thermal transfer is the most extensively got up in the use of different field, some thermal transfer goods with the life of people
Interwoveness, along with the raising of current environmental requirement, the national material to novel product and the environmental protection of thermal transfer disperse dyes thereof
Require more and more higher.In traditional thermal transfer disperse dyes, commonly use not environmentally and disabling dyestuff disperse blue 3, dispersion
Blue 3 is the sensitization dyestuff of a kind of disabling, can cause human body or the skin of animal, mucosa or respiratory tract anaphylaxis.In REACH regulation
In be also described this standard regulation, this dyestuff because there being potential sensitization to human body.
And the colour fastness to perspiration of coloured fibre, yarn or fabric can not use when being less than 4 grades, the sweat proof of disperse blue 3
Stain colour fastness is poor, generally less than 4 grades, further limit its usage range.
Summary of the invention
In view of this, it is an object of the invention to provide a kind of thermal transfer disperse dye composition, thermal transfer disperse dyes
And preparation method thereof, these thermal transfer disperse dyes are water-fastness, sweat proof, fastness to rubbing high, and transferring rate is high, favorable reproducibility, and can
Meet the requirement of environmental protection.
In order to realize foregoing invention purpose, the present invention provides techniques below scheme:
A kind of disperse dye composition, including the component of following weight/mass percentage composition:
Component A:5～40%, preferably 8～30%
Component B:20～75%, preferably 50～60%
Component C:8～30%, preferably 10～15%
Wherein component A has a structure shown in Formulas I:
In Formulas I, X1For nitro, cyano group or halogenic substituent, R1For C1～C4Alkyl or acetylamino, R2And R3Independent choosing
From C1～C4Alkyl；
Component B has a structure shown in Formula II:
Component C has a structure shown in formula III:
In formula III, X2For=O or=NH, R4For C1～C4Alkyl ,-C3H6OCH3、-C3H6OC2H5、-C3H6OC3H7Or-
C3H6OC4H9。
Preferably, one or more during described component A includes compound shown in Formulas I-1, Formulas I-2 and Formulas I-3 mix
Compound:
Preferably, one or more during described component C includes compound shown in formula III-1, formula III-2 formula III
Mixture:
The invention provides a kind of thermal transfer disperse dyes comprising described compositions, also include auxiliary agent and water.
Preferably, the mass ratio of described dye composite, auxiliary agent and water is 25～35:6～20:53～64.
Preferably, described auxiliary agent is naphthalene sulfonic acid-formaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products and sodium lignin sulfonate
In one or more mixture.
Present invention also offers the preparation method of thermal transfer disperse dyes, comprise the following steps:
It is ground obtaining liquid or emulsifiable paste shape disperse dyes after auxiliary agent, water and dye composite being mixed；
Or
Component A, B, C are ground respectively obtaining the slurry of three kinds of components with after auxiliary agent, water mixing respectively；
Liquid or emulsifiable paste shape disperse dyes are obtained after being mixed by the slurry of three kinds of described components.
Preferably described liquid or emulsifiable paste shape disperse dyes are dried to obtain powder disperse dyes.
Preferably, described be dried into be spray-dried, the inlet temperature 120 of spray drying～130 DEG C, outlet temperature be 50～
60℃；Described dried material particular diameter is 0.2～1 μm.
Present invention also offers the method using thermal transfer disperse dyes described in technique scheme to carry out thermal transfer, including
Following steps:
Being mixed with thickener by disperse dyes, allotment obtains mill base；
Described mill base is printed on transfer paper, dry；
The transfer paper after described drying is utilized to transfer.
Advantageous Effects: the invention provides a kind of thermal transfer disperse dye composition, thermal transfer disperse dyes and
Preparation method, these disperse dyes include dye composite, auxiliary agent and water, and the disperse dyes of present invention offer are alternative to be commonly used not
Environmental protection and disabling dyestuff disperse blue 3, solve its problem not environmentally, and than disperse blue 3, there is more excellent performance, as resistance to
Washing, sweat proof, fastness to rubbing height, the features such as transferring rate is high, favorable reproducibility.Utilize this dyestuff can obtain have beautiful in colour and
The blue dyeing and weaving thing of each excellent fastness, is a excellent thermal transfer dyestuff the most not producing waste water.Experimental result table
The thermal transfer disperse dyes that the bright present invention provides are water-fastness, rub resistance, color fastness to perspiration, transferring rate obtain compared with common dye
Improving, lifting force and repeatability are better than common dye.
Detailed description of the invention
The invention provides a kind of thermal transfer disperse dye composition, including the component of following weight/mass percentage composition:
Component A:5～40%；
Component B:20～75%
Component C:8～30%；
Described component A has a structure shown in Formulas I:
In described Formulas I, X1For nitro, cyano group or halogenic substituent, R1For C1～C4Alkyl or acetylamino, R2And R3Independent
Selected from C1～C4Alkyl；
Described component B has a structure shown in Formula II:
Described component C has a structure shown in formula III:
In described formula III, X2For=O or=NH, R4For C1～C4Alkyl ,-C3H6OCH3、-C3H6OC2H5、-C3H6OC3H7
Or-C3H6OC4H9。
The dye composite that the present invention provides includes component A of 5～40%, preferably 8～30%, more preferably 20～
30%；Described component A has structure shown in Formulas I.In the present invention, in described Formulas I, X1For nitro, cyano group or halogenic substituent,
Preferably cyano group or halogenic substituent；R1For C1～C4Alkyl or acetylamino, preferably C1～C2Alkyl or acetylamino；
R2And R3Independent selected from C1～C4Alkyl, preferably C1～C2Alkyl.Concrete, in the present invention, described component A is preferably
One or more mixture including in compound shown in Formulas I-1, Formulas I-2 and Formulas I-3:
The dye combinations that the present invention provides includes component B of 20～75%, preferably 30～70%, more preferably 40～
60%, most preferably 50～60%；Described component B has structure shown in Formula II.
The dye composite that the present invention provides includes component C of 8～30%, preferably 10～25%, more preferably 15～
20%；Described component C has structure shown in formula III.In described formula III, X2For-O or-NH, it is preferably-O；R4For C1～C4
Alkyl ,-C3H6OCH3、-C3H6OC2H5、-C3H6OC3H7-C3H6OC4H9, preferably C1～C4Alkyl ,-C3H6OCH3、-C3H6OC2H5。
Concrete, in the present invention, described component C preferably comprise the one in compound shown in formula III-1, formula III-2 formula III or
Two or more mixture:
Compound in described component A, B, C all can be synthesized by mode well known to those skilled in the art, it is possible to by adopting
Purchase commercial goods to obtain.
The invention provides the thermal transfer disperse dyes of a kind of compositions comprised described in technique scheme, also include helping
Agent and water.
In the present invention, in described thermal transfer disperse dyes, the mass ratio of dye composite, auxiliary agent and water be preferably 25～
35:6～20:53～64, more preferably 30～32:10～15:55～60.
In the present invention, described auxiliary agent is preferably naphthalene sulfonic acid-formaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products and wooden
Element sodium sulfonate one of which or two or more mixture, more preferably condensation compound of methyl naphthalene sulfonic acid and formaldehyde and sodium lignin sulfonate.
In the present invention, described condensation compound of methyl naphthalene sulfonic acid and formaldehyde and sodium lignin sulfonate preferred mass are than being preferably 3:7 or 2:3.
The present invention does not has special restriction to the kind of described water, uses dye solution well known to those skilled in the art i.e.
Can.
The invention provides the preparation method of a kind of thermal transfer disperse dyes, comprise the following steps:
It is ground obtaining liquid or emulsifiable paste shape disperse dyes after auxiliary agent, water and dye composite being mixed；
Or
Component A, B, C are ground respectively obtaining the slurry of three kinds of components with after auxiliary agent, water mixing respectively；
Liquid or emulsifiable paste shape disperse dyes are obtained after being mixed by the slurry of three kinds of described components.
Preferably described liquid or emulsifiable paste shape disperse dyes are dried to obtain powder disperse dyes.
Wherein lapping mode is this area routine lapping mode, and the application preferably employs sand mill or grinder grinds
Mill.
Concrete by component A, B, C respectively mass ratio with auxiliary agent, water mixing be preferably 25～35:6～20:53～
64, more preferably 30～32:10～15:55～60.
The present invention does not has special restriction to described dry method, uses dry skill well known to those skilled in the art
Art scheme；In the present invention, described being dried is preferably spray drying, and the process conditions of described spray drying are preferably: enter
Mouthful temperature 120～130 DEG C, outlet temperature is 50～60 DEG C.In the present invention, the particle diameter of described dried product exhibited is preferably 0.2
～1 μm.
Present invention also offers the method using disperse dyes to carry out thermal transfer, comprise the following steps:
Being mixed with thickener by disperse dyes, allotment obtains mill base；
Described mill base is printed on transfer paper, dry；
The transfer paper after described drying is utilized to transfer.
Disperse dyes are mixed by the present invention with thickener, and allotment obtains mill base.In the present invention, described thickener is preferably C-5；
Mix with described disperse dyes by this area conventional amount used.
After obtaining mill base, described mill base is printed and is transferred by this area usual manner on transfer paper by the present invention.Described
The mode dried is drying mode commonly used in the art, and the application is preferably oven for drying.Dry temperature and be preferably 100 DEG C.
After described drying, the transfer paper obtained is transferred by the present invention by this area conventional transfer mode.
Thermal transfer disperse dye composition, thermal transfer disperse dyes and the system thereof the present invention provided below in conjunction with embodiment
Preparation Method is described in detail, but they can not be interpreted as limiting the scope of the present invention.
Embodiment 1
On the basis of thermal transfer disperse dye composition gross mass, by the 29% compound A with Formulas I-1 structure, 56%
Have the compound B of Formula II structure, the 15% compound C with formula III-2 structure weighs each component of compositions, according to combination
Thing, auxiliary agent and water quality add auxiliary agent and water than the ratio for 30:6:53, and wherein auxiliary agent is by methyl naphthalene sulfonate formaldehyde condensate
Mix with sodium lignin sulfonate 3:7 in mass ratio, be then ground with grinder after above-mentioned each component mix homogeneously,
Slurry grinding obtained is spray-dried, and the process conditions of spray drying are: inlet temperature is 120 DEG C, and outlet temperature is
50 DEG C, obtain the disperse dye composition that particle diameter is 1 μm after drying.
Embodiment 2
On the basis of thermal transfer disperse dye composition gross mass: having Formulas I-2 compound A by 5%, 75% has Formula II
Compound B, the 20% compound C with formula III-1 structure weigh each component of compositions, according to compositions, auxiliary agent and water quality
Adding auxiliary agent and water than the ratio for 35:12:53, wherein auxiliary agent is by methyl naphthalene sulfonate formaldehyde condensate and sodium lignin sulfonate
3:7 in mass ratio mixes, and is then ground with grinder after above-mentioned each component mix homogeneously, grinds the slurry obtained
Being spray-dried, the process conditions of spray drying are: inlet temperature is 125 DEG C, and outlet temperature is 55 DEG C, obtain grain after drying
Footpath is the disperse dye composition of 0.2 μm.
Embodiment 3
On the basis of thermal transfer disperse dye composition gross mass: having Formulas I-3 compound A by 40%, 52% has formula
II compound B, the 8% compound C with formula III-3 structure weigh each component of compositions, according to compositions, auxiliary agent and water quality
Adding auxiliary agent and water than the ratio for 35:8:57, wherein auxiliary agent is by methyl naphthalene sulfonate formaldehyde condensate and sodium lignin sulfonate
2:3 in mass ratio mixes, and is then ground with grinder after above-mentioned each component mix homogeneously, grinds the slurry obtained
Being spray-dried, the process conditions of spray drying are: inlet temperature is 130 DEG C, and outlet temperature is 60 DEG C, obtain grain after drying
Footpath is the disperse dye composition of 0.5 μm.
Embodiment 4
On the basis of thermal transfer disperse dye composition gross mass: having Formulas I-3 compound A by 29%, 56% has formula
II compound B, the 15% compound C with formula III-3 structure weigh each component of compositions, according to compositions, auxiliary agent and water quality
Amount adds auxiliary agent and water than the ratio for 35:8:57, and wherein auxiliary agent is by methyl naphthalene sulfonate formaldehyde condensate and lignin sulfonic acid
Sodium 2:3 in mass ratio mixes, and is then ground with grinder after above-mentioned each component mix homogeneously, grinds the slurry obtained
Material is spray-dried, and the process conditions of spray drying are: inlet temperature is 130 DEG C, and outlet temperature is 60 DEG C, after drying
Particle diameter is the disperse dye composition of 0.5 μm.
Embodiment 5
The present embodiment is with the difference of embodiment 1: having Formulas I-1 structure by 13%, 14% has Formulas I-2 structure
Compound A, 53% has a Formula II structural compounds B, and 10% has formula III-1 structure, 10% chemical combination with formula III-2 structure
Thing C weighs each component of compositions, and auxiliary agent is mixed with sodium lignin sulfonate 10:21 in mass ratio by methyl naphthalene sulfonate formaldehyde condensate
Conjunction forms that remaining is identical, therefore does not repeats at this.
Embodiment 6
Respectively take the disperse dyes that 0.5g embodiment 1～5 prepares, after admixture of disperse dyes and thickener being stirred
Carrying out stamp, put into after 100 DEG C of baking ovens carry out prebake, to transfer interpreter, 210 DEG C of * 1min carry out thermal transfer, are i.e. transferred
After finished product.
Comparative example 1
By 30～35% commercial dispersants indigo plant 3, the auxiliary agent of 12%, wherein auxiliary agent is naphthalene sulfonic acid-formaldehyde condensation product and sulfomethylated lignin
Acid sodium 2:3 in mass ratio mixes, and remaining is ground dispersion with sand mill or grinder after mixing for water, then sprays
Mist is dried and prepares a kind of blue disperse dye.
Comparative example 2
By 30～35% commercial dispersants indigo plant 79, the auxiliary agent of 12%, wherein auxiliary agent is naphthalene sulfonic acid-formaldehyde condensation product and lignin
Sodium sulfonate 2:3 in mass ratio mixes, and remaining is ground dispersion with sand mill or grinder after mixing for water, then carries out
It is spray-dried and prepares a kind of blue disperse dye.
Comparative example 3
By 30～35% commercial dispersants indigo plant 165, the auxiliary agent of 12%, wherein help as naphthalene sulfonic acid-formaldehyde condensation product and sulfomethylated lignin
Acid sodium 2:3 in mass ratio mixes, and remaining is ground dispersion with sand mill or grinder after mixing for water, then sprays
Mist is dried and prepares a kind of blue disperse dye.
Comparative example 4
Respectively take the disperse dyes that 0.5g comparative example 1～3 prepares, after admixture of disperse dyes and thickener being stirred
Carrying out stamp, put into after 100 DEG C of baking ovens carry out prebake, to transfer interpreter, 210 DEG C of * 1min carry out thermal transfer, are i.e. transferred
After finished product.
Performance test
Light fastness, washing fastness, crock fastness, color fastness to perspiration
By above-described embodiment 1～4 and comparative example 1～3 prepare dye mixture and carry out performance test, test as follows:
Respectively take admixture of disperse dyes in 0.5g above-described embodiment and comparative example, add water to 15g so that it is ultrasonic dissolution, so
Rear addition 35g thickener stirs and carries out stamp, puts into after 100 DEG C of baking ovens carry out prebake, 210 DEG C of * to transfer interpreter
1min carries out thermal transfer, the sample cloth after i.e. being transferred.
Observe cloth specimen coloured light and use AATCC 16-2004, AATCC 16-2014, GB/T 3920-2008, AATCC
15-2002 measures its light fastness, washing fastness, fastness to rubbing and color fastness to perspiration, and measurement result is as shown in table 1:
Lifting force (power part)
Observing cloth specimen coloured light and estimate its lifting force, concentration the most then color yield is the highest.(be equivalent to the concentration of 1%,
Color rate is the concentration of 2%).
Transferring rate
Observing cloth specimen coloured light and with the residual volume estimated after it transfers on transfer paper, remnants transferring rate the most at least is the best.
Repeatability
According to compound A, B, C with auxiliary agent mixed process, its color of visual observations changes, and color changes the least blending dye
Material repeatability is the best.
Table 1 performance test table
As can be seen from Table 1, disperse dyes provided by the present invention are compared with common commercial dyes, washing fastness, resistance to
Crock fastness, color fastness to perspiration and transferring rate are high, lifting force and favorable reproducibility.
For the those of ordinary skill in territory, under the premise without departing from the principles of the invention, it is also possible to make some improvement and
Retouching, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (10)
1. a disperse dye composition, including the component of following weight/mass percentage composition:
Component A 5～40%；
Component B 20～75%；
Component C 8～30%；
Described component A has a structure shown in Formulas I:
In described Formulas I, X1For nitro, cyano group or halogenic substituent, R1For C1～C4Alkyl or acetylamino, R2And R3Independent choosing
From C1～C4Alkyl；
Described component B has a structure shown in Formula II:
Described component C has a structure shown in formula III:
In described formula III, X2For=O or=NH, R4For C1～C4Alkyl ,-C3H6OCH3、-C3H6OC2H5、-C3H6OC3H7Or-
C3H6OC4H9。
A kind of disperse dye composition the most according to claim 1, it is characterised in that described component A includes Formulas I-1, formula
One or more mixture in compound shown in I-2 and Formulas I-3:
A kind of disperse dye composition the most according to claim 1, it is characterised in that described component C include formula III-1,
One or more mixture in compound shown in formula III-2 formula III:
4. include the thermal transfer disperse dyes of compositions described in claims 1 to 3 any one, it is characterised in that also include
Auxiliary agent and water.
Disperse dyes the most according to claim 4, it is characterised in that the quality of described dye composite, auxiliary agent and water
Ratio is 25～35:6～20:53～64.
Disperse dyes the most according to claim 4, it is characterised in that described auxiliary agent is naphthalene sulfonic acid-formaldehyde condensation product, alkylnaphthalene
Sulfonic formaldehyde condensation compound and sodium lignin sulfonate one of which or two or more mixture.
7. the preparation method of the disperse dyes described in any one of claim 4～6, it is characterised in that comprise the following steps:
It is ground obtaining liquid or emulsifiable paste shape disperse dyes after auxiliary agent, water and dye composite being mixed；
Or
Component A, B, C are ground respectively obtaining the slurry of three kinds of components with after auxiliary agent, water mixing respectively；
Liquid or emulsifiable paste shape disperse dyes are obtained after being mixed by the slurry of three kinds of described components.
Preparation method the most according to claim 7, it is characterised in that go back after obtaining described liquid or emulsifiable paste shape disperse dyes
Including: described liquid or emulsifiable paste shape disperse dyes are dried.
The preparation method of a kind of disperse dyes the most according to claim 8, it is characterised in that described be dried as spray dried
Dry, the inlet temperature 120 of described spray drying～130 DEG C, outlet temperature is 50～60 DEG C；Described dried material particular diameter is
0.2～1 μm.
10. the method carrying out thermal transfer according to the disperse dyes described in claim 4～6 any one, it is characterised in that
Comprise the following steps:
Being mixed with thickener by disperse dyes, allotment obtains mill base；
Described mill base is printed on transfer paper, dry；
The transfer paper after described drying is utilized to transfer.
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| CN201610664774.3A CN106317951A (en) | 2016-08-12 | 2016-08-12 | Heat transfer printing disperse dye composition and heat transfer printing disperse dye and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111057394A (en) * | 2019-11-05 | 2020-04-24 | 杭州吉华江东化工有限公司 | High-strength disperse slurry dye mixture and application thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4614521A (en) * | 1984-06-06 | 1986-09-30 | Mitsubishi Chemical Industries Limited | Transfer recording method using reactive sublimable dyes |
| JPS6264595A (en) * | 1985-09-18 | 1987-03-23 | Dainippon Printing Co Ltd | Heat transfer sheet |
| US4969951A (en) * | 1985-05-21 | 1990-11-13 | Canon Kabushiki Kaisha | Cloth jet printing method using aqueous ink having hydroxyl or amino-reactive disperse dye |
| JPH06329927A (en) * | 1993-05-17 | 1994-11-29 | Nippon Kayaku Co Ltd | Ink composition for ink jet printing and dyeing method using the same |
| JP2005179827A (en) * | 2003-12-19 | 2005-07-07 | Sumisaburo Seino | Dyeing method by mixed dyes |
| US20110027548A1 (en) * | 2008-03-28 | 2011-02-03 | Clariant Finance (Bvi) Limited | Influencing the Near Infrared Reflectance of Dyed Textile Materials |
| CN103450740A (en) * | 2013-09-29 | 2013-12-18 | 山东德创喷墨科技有限公司 | Sublimation ink-jetting ink used for industrial nozzle and manufacturing method thereof |
-
2016
- 2016-08-12 CN CN201610664774.3A patent/CN106317951A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4614521A (en) * | 1984-06-06 | 1986-09-30 | Mitsubishi Chemical Industries Limited | Transfer recording method using reactive sublimable dyes |
| US4969951A (en) * | 1985-05-21 | 1990-11-13 | Canon Kabushiki Kaisha | Cloth jet printing method using aqueous ink having hydroxyl or amino-reactive disperse dye |
| JPS6264595A (en) * | 1985-09-18 | 1987-03-23 | Dainippon Printing Co Ltd | Heat transfer sheet |
| JPH06329927A (en) * | 1993-05-17 | 1994-11-29 | Nippon Kayaku Co Ltd | Ink composition for ink jet printing and dyeing method using the same |
| JP2005179827A (en) * | 2003-12-19 | 2005-07-07 | Sumisaburo Seino | Dyeing method by mixed dyes |
| US20110027548A1 (en) * | 2008-03-28 | 2011-02-03 | Clariant Finance (Bvi) Limited | Influencing the Near Infrared Reflectance of Dyed Textile Materials |
| CN103450740A (en) * | 2013-09-29 | 2013-12-18 | 山东德创喷墨科技有限公司 | Sublimation ink-jetting ink used for industrial nozzle and manufacturing method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111057394A (en) * | 2019-11-05 | 2020-04-24 | 杭州吉华江东化工有限公司 | High-strength disperse slurry dye mixture and application thereof |
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Application publication date: 20170111 |