CN106219842B - A method of phthalate pollutant in removal water source gathering ground water body - Google Patents
A method of phthalate pollutant in removal water source gathering ground water body Download PDFInfo
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- CN106219842B CN106219842B CN201610696297.9A CN201610696297A CN106219842B CN 106219842 B CN106219842 B CN 106219842B CN 201610696297 A CN201610696297 A CN 201610696297A CN 106219842 B CN106219842 B CN 106219842B
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 96
- 238000000034 method Methods 0.000 title claims abstract description 31
- 239000003344 environmental pollutant Substances 0.000 title claims abstract description 26
- 231100000719 pollutant Toxicity 0.000 title claims abstract description 26
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 title claims abstract description 21
- 239000003673 groundwater Substances 0.000 title claims abstract description 9
- 230000001376 precipitating effect Effects 0.000 claims abstract description 30
- 239000011347 resin Substances 0.000 claims abstract description 23
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 17
- 238000010521 absorption reaction Methods 0.000 claims abstract description 16
- 239000012528 membrane Substances 0.000 claims abstract description 16
- 238000004064 recycling Methods 0.000 claims abstract description 16
- 238000012545 processing Methods 0.000 claims abstract description 14
- 239000000706 filtrate Substances 0.000 claims abstract description 12
- 239000007800 oxidant agent Substances 0.000 claims abstract description 12
- 230000001590 oxidative effect Effects 0.000 claims abstract description 12
- 239000006228 supernatant Substances 0.000 claims abstract description 12
- 238000005286 illumination Methods 0.000 claims abstract description 8
- 238000004062 sedimentation Methods 0.000 claims abstract description 8
- 238000010828 elution Methods 0.000 claims abstract description 7
- 238000001179 sorption measurement Methods 0.000 claims abstract description 7
- 238000005202 decontamination Methods 0.000 claims abstract description 6
- 230000003588 decontaminative effect Effects 0.000 claims abstract description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 57
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
- 238000002156 mixing Methods 0.000 claims description 24
- 235000019441 ethanol Nutrition 0.000 claims description 23
- 229960004756 ethanol Drugs 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 20
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000000047 product Substances 0.000 claims description 19
- 239000004417 polycarbonate Substances 0.000 claims description 16
- 229920000515 polycarbonate Polymers 0.000 claims description 16
- 239000013049 sediment Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 12
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 11
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- 239000003153 chemical reaction reagent Substances 0.000 claims description 10
- 239000012046 mixed solvent Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 10
- 238000013461 design Methods 0.000 claims description 9
- 239000012065 filter cake Substances 0.000 claims description 9
- UMPKMCDVBZFQOK-UHFFFAOYSA-N potassium;iron(3+);oxygen(2-) Chemical group [O-2].[O-2].[K+].[Fe+3] UMPKMCDVBZFQOK-UHFFFAOYSA-N 0.000 claims description 9
- 230000010355 oscillation Effects 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 229920001661 Chitosan Polymers 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 6
- 244000068988 Glycine max Species 0.000 claims description 5
- 235000010469 Glycine max Nutrition 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 claims description 5
- 235000020661 alpha-linolenic acid Nutrition 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 239000010408 film Substances 0.000 claims description 5
- 229960004488 linolenic acid Drugs 0.000 claims description 5
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 claims description 5
- LAIZPRYFQUWUBN-UHFFFAOYSA-L nickel chloride hexahydrate Chemical class O.O.O.O.O.O.[Cl-].[Cl-].[Ni+2] LAIZPRYFQUWUBN-UHFFFAOYSA-L 0.000 claims description 5
- -1 polypropylene Polymers 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 5
- 239000011541 reaction mixture Substances 0.000 claims description 5
- 238000005119 centrifugation Methods 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 4
- 238000000703 high-speed centrifugation Methods 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000010409 thin film Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 239000008213 purified water Substances 0.000 claims description 3
- 229910000404 tripotassium phosphate Inorganic materials 0.000 claims description 3
- 235000019798 tripotassium phosphate Nutrition 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 229920001155 polypropylene Polymers 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000002955 isolation Methods 0.000 abstract 1
- 230000009102 absorption Effects 0.000 description 12
- 230000000694 effects Effects 0.000 description 8
- 230000001954 sterilising effect Effects 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 230000005484 gravity Effects 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 239000000356 contaminant Substances 0.000 description 4
- 238000004332 deodorization Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005189 flocculation Methods 0.000 description 3
- 230000016615 flocculation Effects 0.000 description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000006471 dimerization reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002120 nanofilm Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
Abstract
A method of removal water source gathering ground water body in phthalate pollutant, the method the following steps are included: (1) by the water of gathering ground by sedimentation basin precipitating, the supernatant collected；(2) supernatant is filtered by vibrating filter membrane, removes suspended material therein, obtains filtrate；(3) filtrate is passed through decontamination duct, the laggard horizontal high voltage mercury lamp light source illumination-based disinfection of oxidant is added；(4) water obtained after disinfection is subjected to biochemistry absorption by the adsorption tower of bio-resin, recycling elution processing is carried out to bio-resin, the water after absorption is then passed through the safety of water source reserve pool.Method of the invention can effectively remove phthalate pollutant in the water body of water source gathering ground, by the way that the safety of water source deposit is isolated, it can be secondarily contaminated to avoid water source, the water body of water source gathering ground can be subjected to state isolation simultaneously, guarantee that water source can not only reach environmental requirement, moreover it is possible to meet safe application needs.
Description
Technical field
The present invention relates to purification of water quality processing technology fields, are specifically related to phthalandione in a kind of water body of removal water source gathering ground
The method of esters pollutant.
Background technique
Phthalate (Phthalate Esters, hereinafter referred to as PAEs) is that output is big in the world, people of wide application
Work anthropogenics, can be used as plasticizer, solvent, auxiliary agent, be widely used at present plastic products, farm chemical carrier,
In the products such as pest repellant, packaging material for food, detergent, lubricating oil, paint, coating.With the continuous development of industrial and agricultural production
With being widely used for plastic products.
Phthalate organic matter is widely used in plastic products, is especially occupied in polyvinyl chloride (PVC) high
Ratio.Phthalate ester in plastics over time, can cause the dirt to natural environment by moving to external environment in plastics
Dye.Have been demonstrated that there is the detection of phthalate organic matter in big gas and water, waterworks, soil and food.Due to phthalate ester
Residual life, is longer in the natural environment, and biological terephalic acid ester has stronger enrichment, once into natural ecosystems, it is right
The harm of human health bring is inestimable.Therefore, attention is transferred to in environment by more and more researchers
Come in the degradation problem of existing phthalate ester.In the method for handling this pollutant, photocatalysis oxidation technique is simple easy because of it
Feature capable, economical and practical, without secondary pollution causes the common concern of scholar.
Phthalate (PAEs) pollutant common in the water body of water source gathering ground mainly has two fourth of phthalic acid at present
Ester (DBP) and dioctyl phthalate (DOP), common water purification treatment technology are to have carried out chlorination, flocculation sedimentation to raw water
And filtration treatment, but according to the measurement to the concentration of DBP and DOP in water sample after every cell processing, such water-purifying process is to upper
Stating two kinds of PAEs has apparent removal to act on, but output water DBP is still in exceeded state, it is therefore desirable to further explore new water
The removing method of phthalate pollutant in the water body of source gathering ground, the method for physics are no longer satisfied the demand of environmental protection, need
The method of biology, chemistry, physics is combined, to reach satisfied treatment effect.
Summary of the invention
To solve the shortcomings of the prior art, the purpose of the present invention is to provide in a kind of water body of removal water source gathering ground
The method of phthalate pollutant.
To achieve the above object, the present invention completes by following technical solution: a kind of removal water source gathering ground water
The method of phthalate pollutant in body, the method the following steps are included:
(1) by the water of gathering ground by water pump be pumped into sedimentation basin, precipitating bottom of pond portion be conical design, can make sediment according to
It is precipitated by gravity, conical design can be such that sediment quickly assembles and be conducive to solids discharge, and precipitating reagent is added and carries out
Precipitating sediment is discharged from precipitating bottom of pond portion by the mud valve with filtering function, the supernatant then collected；
(2) supernatant that step (1) is collected into is filtered by vibrating filter membrane, solia particle can be enhanced in oscillation
Suspension effect can preferably remove suspended material therein with this, obtain filtrate；
(3) by the obtained filtrate of step (2) be passed through decontamination duct, the laggard horizontal high voltage mercury lamp light source irradiation of oxidant is added
Disinfection；
(4) by obtained water after step (3) disinfection with the flow velocity of 6-10BV/h by being filled with the adsorption tower of bio-resin
Biochemistry absorption is carried out, recycling elution processing is carried out to bio-resin, to analyze pollutant load and effective recycling, so
The water after absorption is passed through the safety of water source reserve pool afterwards and carries out deposit use.
Further, the precipitating reagent is preferably nanoprecipitation agent and compound precipitants, the compound precipitants system
Preparation Method are as follows: tripotassium phosphate, active powdered carbon, polyacrylamide are sufficiently mixed uniformly, in room temperature by the mass ratio of 1:2-3:3-5
Under 30-60min is sufficiently stirred with 1200r/min revolving speed below, be then added in the purified water that 5-8 times of compounding substances is measured,
After stirring and dissolving, be added into above-mentioned solution trimethylamine that 0.1-0.3 times of mixture quality mass percentage concentration measured is 30% and
The mass ratio of chitosan, the trimethylamine and chitosan is 2:1, and thermostatic control is reacted 2-3 hours at about 60-70 DEG C, turned
It moves in ultrasonator, sonic oscillation 30-60 minutes under the Ultrasonic Conditions that power is 120-180W, frequency is 30Hz,
Obtain the compound precipitants.
Further, the nanoprecipitation agent is polycarbonate/TiO2Nano-complex, preparation method are as follows: by TiO2
It is crushed by nano grinder, then by nano-TiO2Its mixing quality 2- is added to according to the mass ratio of 10:3 with polycarbonate
It is blended in the ethanol solution that the mass concentration of 3 times of amounts is 65-75%, is completely dissolved polymer in time using ultrasonic disperse, will
To 230-250 DEG C of melt blending 10-20min of dissolved matter obtain polycarbonate/TiO2Mixture dissolves obtained mixture
The mass concentration measured to 3-5 times is high speed centrifugation rate 8000-10000rpm, centrifugation time 10- in the ethanol solution of 75-85%
30min is completely dissolved mixture, and recycling ethyl alcohol is then concentrated under reduced pressure, is crushed after dry using nano grinder, particle size range
50-100nm obtains polycarbonate/TiO2Nano-complex.
Further, the filter membrane is two-dimensional ultrathin nickel hydroxide nano thin-film material, and preparation method is by 40 parts
It is added in the mixed solvent after Nickel dichloride hexahydrate, 55 parts of urea mixing, magnetic agitation 30-60min is completely molten to reaction raw materials
Xie Hou, when being heated to 50-60 DEG C, heat preservation after twenty minutes, continues to heat reaction mixture temperature to 85-95 DEG C, lasting stirring is protected
Temperature reaction after sixty minutes, reaction product is centrifugated by cooled to room temperature, filter cake washed with dehydrated alcohol after again repeatedly from
The heart is handled 2 times, obtains nickel hydroxide ultrathin nanometer film after filter cake is spontaneously dried at room temperature, filter membrane can be effective
Cross the acid contaminant in drainage.
Further, the mixed solvent is the mixture of water, methanol and ethyl alcohol, wherein the body of water, methanol and ethyl alcohol
Product is than being 15:5:1.
Further, the oxidant is potassium ferrate, and usage amount volume ratio in water is 1:3000-5000, high
For potassium ferrite when handling the water body of water source gathering ground, sterilizing rate is 100% under low dosage, while having oxidation, absorption, wadding
The comprehensive performance that the eight big features such as solidifying, precipitating, sterilizing, disinfection, decoloration, deodorization are integrated, is that other water treatment agents are incomparable
's.
Further, the high-pressure sodium lamp power of the high-pressure sodium lamp light source illumination-based disinfection is 600-800W, and wavelength is
260-450nm, main peak value are 365nm.
Further, the bio-resin is to react comprising Isosorbide-5-Nitrae-cyclohexane dicarboxylic acid and linolenic acid with soya bean fatty acid
Dimerisation products afterwards, softening point are 100-120 DEG C, and the dimerisation products are added in high-speed mixer, 5- is stirred
10min, the sorbierite that 0.05 times of dimerisation products amount is then slowly added start low speed rotation high-speed cruising and material are being mixed
It is adequately stirred evenly inside machine, stirring at low speed speed is 180-300r/min, low speed runing time 10-30min, high-speed stirred
Speed is 1200-1800r/min, and the high-speed cruising time is 5-15min, and above-mentioned raw material after mixing is put into pelletizer
After being kneaded, melted, being squeezed out, being cooled down pelletizing to get arrive the bio-resin.
Compared with the prior art, the beneficial effects of the present invention are:
1. sediment can be made not only rely on gravity using nanoprecipitation agent or compound precipitants to precipitate, moreover it is possible to enhance
Sedimentation effect, for can not quickly and effectively be precipitated by the suspended matter or solid particulate matter of gravity precipitating in water；
2. being filtered by nickel hydroxide ultrathin nanometer membrane oscillation, the suspension for making phthalate pollutant can be enhanced
Effect can preferably remove pollutant with this；
3. high-pressure sodium lamp light source illumination-based disinfection under the auxiliary of oxidant can play good drop with terephalic acid Ester
Solution effect can be carried out recycling elution processing by bio-resin, go to remove water by multilayer hydrolysis and soda acid adsorption deeply after degradation
Phthalate pollutant in body.
Specific embodiment
The invention will be further described With reference to embodiment.
Embodiment 1: a method of removal water source gathering ground water body in phthalate pollutant, the method include with
Lower step:
(1) by the water of gathering ground by water pump be pumped into sedimentation basin, precipitating bottom of pond portion be conical design, can make sediment according to
It is precipitated by gravity, conical design can be such that sediment quickly assembles and be conducive to solids discharge, and precipitating reagent is added and carries out
Precipitating sediment is discharged from precipitating bottom of pond portion by the mud valve with filtering function, the supernatant then collected；
(2) supernatant that step (1) is collected into is filtered by vibrating filter membrane, solia particle can be enhanced in oscillation
Suspension effect can preferably remove suspended material therein with this, obtain filtrate；
(3) by the obtained filtrate of step (2) be passed through decontamination duct, the laggard horizontal high voltage mercury lamp light source irradiation of oxidant is added
Disinfection；
(4) water obtained after step (3) disinfection is carried out with the flow velocity of 6BV/h by being filled with the adsorption tower of bio-resin
Biochemistry absorption carries out recycling elution processing to bio-resin, to analyze pollutant load and effective recycling, then will
Water after absorption is passed through the safety of water source reserve pool and carries out deposit use.
Wherein, the precipitating reagent is preferably nanoprecipitation agent, and the nanoprecipitation agent is polycarbonate/TiO2Nanometer
Compound, preparation method are as follows: by TiO2It is crushed by nano grinder, then by nano-TiO2With polycarbonate according to 10:3
Mass ratio be added to 2 times of its mixing quality amount mass concentration be 65% ethanol solution in be blended, it is timely using ultrasonic disperse
It is completely dissolved polymer, obtained 230 DEG C of melt blending 10min of dissolved matter are obtained into polycarbonate/TiO2Mixture, will
To mixture be dissolved into 3 times amount mass concentration be 75% ethanol solution in, high speed centrifugation rate 8000rpm, centrifugation time
10min is completely dissolved mixture, and recycling ethyl alcohol is then concentrated under reduced pressure, is crushed after dry using nano grinder, particle size range
50nm obtains polycarbonate/TiO2Nano-complex.The filter membrane is two-dimensional ultrathin nickel hydroxide nano thin-film material,
Preparation method is to be added in the mixed solvent after mixing 40 parts of Nickel dichloride hexahydrates, 55 parts of urea, and magnetic agitation 30min is extremely
After reaction raw materials are completely dissolved, when being heated to 50 DEG C, heat preservation after twenty minutes, continues to heat reaction mixture temperature to 85 DEG C, holds
After sixty minutes, reaction product is centrifugated continuous stirring insulation reaction by cooled to room temperature, after filter cake is washed with dehydrated alcohol
It is centrifuged repeatedly processing 2 times again, nickel hydroxide ultrathin nanometer film, filter membrane are obtained after filter cake is spontaneously dried at room temperature
The acid contaminant in drainage can effectively be crossed.The mixed solvent is the mixture of water, methanol and ethyl alcohol, wherein water, first
The volume ratio of pure and mild ethyl alcohol is 15:5:1.The oxidant is potassium ferrate, and usage amount volume ratio in water is 1:3000,
For potassium ferrate when handling the water body of water source gathering ground, sterilizing rate is 100% under low dosage, while having oxidation, absorption, wadding
The comprehensive performance that the eight big features such as solidifying, precipitating, sterilizing, disinfection, decoloration, deodorization are integrated, is that other water treatment agents are incomparable
's.The high-pressure sodium lamp power of the high-pressure sodium lamp light source illumination-based disinfection is 600W, wavelength 260nm, and main peak value is
365nm.The bio-resin is that the dimerization after reacting comprising Isosorbide-5-Nitrae-cyclohexane dicarboxylic acid and linolenic acid with soya bean fatty acid produces
Object, softening point are 100 DEG C, and the dimerisation products are added in high-speed mixer, 5min is stirred, are then slowly added two
The sorbierite of 0.05 times of poly- product amount starts low speed rotation high-speed cruising and material is adequately stirred evenly inside mixing machine, low
Fast mixing speed is 180r/min, and low speed runing time 10min, high-speed stirred speed is 1200r/min, and the high-speed cruising time is
Above-mentioned raw material after mixing is put into pelletizer after being kneaded, melted, being squeezed out, cool down pelletizing to get to institute by 5min
The bio-resin stated.
Embodiment 2: a method of removal water source gathering ground water body in phthalate pollutant, the method include with
Lower step:
(1) by the water of gathering ground by water pump be pumped into sedimentation basin, precipitating bottom of pond portion be conical design, can make sediment according to
It is precipitated by gravity, conical design can be such that sediment quickly assembles and be conducive to solids discharge, and precipitating reagent is added and carries out
Precipitating sediment is discharged from precipitating bottom of pond portion by the mud valve with filtering function, the supernatant then collected；
(2) supernatant that step (1) is collected into is filtered by vibrating filter membrane, solia particle can be enhanced in oscillation
Suspension effect can preferably remove suspended material therein with this, obtain filtrate；
(3) by the obtained filtrate of step (2) be passed through decontamination duct, the laggard horizontal high voltage mercury lamp light source irradiation of oxidant is added
Disinfection；
(4) water obtained after step (3) disinfection is carried out with the flow velocity of 8BV/h by being filled with the adsorption tower of bio-resin
Biochemistry absorption carries out recycling elution processing to bio-resin, to analyze pollutant load and effective recycling, then will
Water after absorption is passed through the safety of water source reserve pool and carries out deposit use.
Wherein, the precipitating reagent is preferably compound precipitants, and the compound precipitants are the preparation method comprises the following steps: press 1:2.5:
Tripotassium phosphate, active powdered carbon, polyacrylamide are sufficiently mixed uniformly by 4 mass ratio, below with 1200r/min at normal temperature
45min is sufficiently stirred in revolving speed, is then added in the purified water of 6.5 times of compounding substances amounts, after stirring and dissolving, into above-mentioned solution
The trimethylamine and chitosan that the mass percentage concentration of 0.2 times of mixture quality amount is 30%, the trimethylamine and chitosan is added
Mass ratio be 2:1, thermostatic control at about 65 DEG C, react 2.5 hours, be transferred in ultrasonator, power be 150W,
Sonic oscillation 45 minutes is under the Ultrasonic Conditions that frequency is 30Hz to get arriving the compound precipitants.The filter membrane is two
Ultra-thin nickel hydroxide nano thin-film material is tieed up, preparation method is to be added after mixing 40 parts of Nickel dichloride hexahydrates, 55 parts of urea
To in the mixed solvent, after magnetic agitation 45min is completely dissolved to reaction raw materials, when being heated to 55 DEG C, heat preservation after twenty minutes, continues
Heat reaction mixture temperature to 90 DEG C, persistently stir insulation reaction after sixty minutes, cooled to room temperature, by reaction product from
Heart separation, filter cake are centrifuged repeatedly processing 2 times again after being washed with dehydrated alcohol, after filter cake is spontaneously dried at room temperature to obtain the final product
To nickel hydroxide ultrathin nanometer film, filter membrane can effectively cross the acid contaminant in drainage.The mixed solvent is water, first
The mixture of pure and mild ethyl alcohol, wherein the volume ratio of water, methanol and ethyl alcohol is 15:5:1.The oxidant is potassium ferrate,
Usage amount volume ratio in water is 1:4000, and potassium ferrate is when handling the water body of water source gathering ground, the sterilizing rate under low dosage
It is 100%, while the eight big synthesis being integrated such as have the characteristics that oxidation, absorption, flocculation, precipitating, sterilizing, disinfection, decoloration, deodorization
Performance is that other water treatment agents are incomparable.The high-pressure sodium lamp power of the high-pressure sodium lamp light source illumination-based disinfection is
700W, wavelength 350nm, main peak value are 365nm.The bio-resin be comprising Isosorbide-5-Nitrae-cyclohexane dicarboxylic acid and linolenic acid with
Dimerisation products after soya bean fatty acid reaction, softening point are 110 DEG C, and the dimerisation products are added in high-speed mixer,
7.5min is stirred, the sorbierite that 0.05 times of dimerisation products amount is then slowly added starts low speed rotation high-speed cruising and material is existed
It is adequately stirred evenly inside mixing machine, stirring at low speed speed is 240r/min, low speed runing time 20min, high-speed stirred speed
Degree be 1500r/min, the high-speed cruising time be 10min, above-mentioned raw material after mixing is put into pelletizer be kneaded,
Melting, squeeze out, be cooling after pelletizing to get arriving the bio-resin.
Embodiment 3: a method of removal water source gathering ground water body in phthalate pollutant, the method include with
Lower step:
(1) by the water of gathering ground by water pump be pumped into sedimentation basin, precipitating bottom of pond portion be conical design, can make sediment according to
It is precipitated by gravity, conical design can be such that sediment quickly assembles and be conducive to solids discharge, and precipitating reagent is added and carries out
Precipitating sediment is discharged from precipitating bottom of pond portion by the mud valve with filtering function, the supernatant then collected；
(2) supernatant that step (1) is collected into is filtered by vibrating filter membrane, solia particle can be enhanced in oscillation
Suspension effect can preferably remove suspended material therein with this, obtain filtrate；
(3) by the obtained filtrate of step (2) be passed through decontamination duct, the laggard horizontal high voltage mercury lamp light source irradiation of oxidant is added
Disinfection；
(4) by obtained water after step (3) disinfection with the flow velocity of 10BV/h by be filled with the adsorption tower of bio-resin into
The absorption of row biochemistry carries out recycling elution processing to bio-resin, to analyze pollutant load and effective recycling, then
Water after absorption is passed through the safety of water source reserve pool and carries out deposit use.
Wherein, the precipitating reagent is preferably nanoprecipitation agent, and the nanoprecipitation agent is polycarbonate/TiO2Nanometer
Compound, preparation method are as follows: by TiO2It is crushed by nano grinder, then by nano-TiO2With polycarbonate according to 10:3
Mass ratio be added to 3 times of its mixing quality amount mass concentration be 75% ethanol solution in be blended, it is timely using ultrasonic disperse
It is completely dissolved polymer, obtained 250 DEG C of melt blending 20min of dissolved matter are obtained into polycarbonate/TiO2Mixture, will
To mixture be dissolved into the ethanol solution that the mass concentration of 5 times of amounts is 85%, high speed centrifugation rate 10000rpm, when centrifugation
Between 30min, be completely dissolved mixture, recycling ethyl alcohol be then concentrated under reduced pressure, is crushed after dry using nano grinder, partial size model
100nm is enclosed, polycarbonate/TiO is obtained2Nano-complex.The filter membrane is two-dimensional ultrathin nickel hydroxide nano film material
Material, preparation method are to be added in the mixed solvent, magnetic agitation after mixing 40 parts of Nickel dichloride hexahydrates, 55 parts of urea
After 60min is completely dissolved to reaction raw materials, when being heated to 60 DEG C, heat preservation after twenty minutes, continues to heat reaction mixture temperature extremely
95 DEG C, persistently stir insulation reaction after sixty minutes, reaction product is centrifugated by cooled to room temperature, the anhydrous second of filter cake
It is centrifuged repeatedly processing 2 times again after alcohol washing, nickel hydroxide ultrathin nanometer is obtained after filter cake is spontaneously dried at room temperature
Film, filter membrane can effectively cross the acid contaminant in drainage.The mixed solvent is the mixture of water, methanol and ethyl alcohol,
Wherein the volume ratio of water, methanol and ethyl alcohol is 15:5:1.The oxidant is potassium ferrate, usage amount volume ratio in water
For 1:5000, for potassium ferrate when handling the water body of water source gathering ground, sterilizing rate is 100% under low dosage, while having oxygen
The comprehensive performance that the eight big features such as change, absorption, flocculation, precipitating, sterilizing, disinfection, decoloration, deodorization are integrated, is other water process
Agent is incomparable.The high-pressure sodium lamp power of the high-pressure sodium lamp light source illumination-based disinfection is 800W, wavelength 450nm, master
Peak value is 365nm.The bio-resin is after reacting comprising Isosorbide-5-Nitrae-cyclohexane dicarboxylic acid and linolenic acid with soya bean fatty acid
Dimerisation products, softening point are 120 DEG C, and the dimerisation products are added in high-speed mixer, stir 10min, then slowly
The sorbierite of 0.05 times of addition dimerisation products amount start low speed rotation high-speed cruising material adequately stirred inside mixing machine
It mixes uniformly, stirring at low speed speed is 300r/min, and low speed runing time 30min, high-speed stirred speed is 1800r/min, high speed
Runing time is 15min, above-mentioned raw material after mixing is put into pelletizer be kneaded, melted, being squeezed out, cool down after cut
Grain to get arrive the bio-resin.
Experimental verification: choosing the water that repefral concentration is 300mg/L is process object, is divided into three groups, often
Group volume is 50L, carries out phthalate pollutant removal, experiment according to the method for embodiment 1, embodiment 2, embodiment 3 respectively
Detect the repefral concentration in each group water respectively after the completion, testing result is as follows:
| Phthalate pollutant normal concentration | Volume | Concentration before handling | Concentration after processing | |
| Embodiment 1 | 300mg/L | 50L | 298mg/L | 0.05mg/L |
| Embodiment 2 | 300mg/L | 50L | 301mg/L | 0.02mg/L |
| Embodiment 3 | 300mg/L | 50L | 299mg/L | 0.06mg/L |
It, can be in conclusion method of the invention can effectively remove in water source gathering ground phthalate pollutant in water body
Make repefral mean concentration < 0.1mg/L in water, the various components and parameter in the method for the present invention are best
Select the most effective fruit, it can be achieved that the method for the present invention.
The above described is only a preferred embodiment of the present invention, being not that the invention has other forms of limitations, appoint
What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc.
Imitate embodiment.But without departing from the technical solutions of the present invention, according to the technical essence of the invention to above embodiments institute
Any simple modification, equivalent variations and the remodeling made, still fall within the protection scope of technical solution of the present invention.
Claims (2)
1. a kind of method of phthalate pollutant in removal water source gathering ground water body, which is characterized in that the method includes
Following steps:
The water of gathering ground is pumped into sedimentation basin by water pump, precipitating bottom of pond portion is conical design, precipitating reagent is added and is precipitated, from
Sediment is discharged by the mud valve with filtering function for precipitating bottom of pond portion, the supernatant then collected；
The supernatant that step (1) is collected into is filtered by vibrating filter membrane, suspended material therein is removed, obtains filtrate；
By the obtained filtrate of step (2) be passed through decontamination duct, the laggard horizontal high voltage mercury lamp light source illumination-based disinfection of oxidant is added；
(4) water obtained after step (3) disinfection is carried out with the flow velocity of 6-10BV/h by being filled with the adsorption tower of bio-resin
Biochemistry absorption carries out recycling elution processing to bio-resin, to analyze pollutant load and effective recycling, then will
Water after absorption is passed through the safety of water source reserve pool；
The precipitating reagent is preferably nanoprecipitation agent and compound precipitants；
The nanoprecipitation agent is polycarbonate/TiO2Nano-complex, preparation method are as follows: by TiO2Pass through nanometer pulverization
Machine crushes, then by nano-TiO2The quality that 2-3 times of its mixing quality is measured is added to according to the mass ratio of 10:3 with polycarbonate
It is blended in the ethanol solution that concentration is 65-75%, is completely dissolved polymer in time using ultrasonic disperse, the dissolved matter that will be obtained
230-250 DEG C of melt blending 10-20min obtains polycarbonate/TiO2Obtained mixture is dissolved into 3-5 times and measured by mixture
Mass concentration be in the ethanol solution of 75-85%, high speed centrifugation rate 8000-10000rpm, centrifugation time 10-30min make
Mixture is completely dissolved, and recycling ethyl alcohol is then concentrated under reduced pressure, is crushed after dry using nano grinder, particle size range 50-
100nm obtains polycarbonate/TiO2Nano-complex；
The compound precipitants are the preparation method comprises the following steps: by the mass ratio of 1:2-3:3-5 by tripotassium phosphate, active powdered carbon, polypropylene
Amide is sufficiently mixed uniformly, and 30-60min is sufficiently stirred with 1200r/min revolving speed below at normal temperature, is then added to mixing
In 5-8 times of the substance purified water measured, after stirring and dissolving, 0.1-0.3 times of the mixture quality quality measured is added into above-mentioned solution
The mass ratio of the trimethylamine and chitosan that percentage concentration is 30%, the trimethylamine and chitosan is 2:1, and thermostatic control is in 60-
It 70 DEG C, reacts 2-3 hours, is transferred in ultrasonator, under the Ultrasonic Conditions that power is 120-180W, frequency is 30Hz
Sonic oscillation 30-60 minutes is to get arriving the compound precipitants；
The filter membrane be two-dimensional ultrathin nickel hydroxide nano thin-film material, preparation method be by 40 parts of Nickel dichloride hexahydrates,
In the mixed solvent, which is added to, after 55 parts of urea mixing is heated to 50- after magnetic agitation 30-60min is completely dissolved to reaction raw materials
At 60 DEG C, heat preservation after twenty minutes, continues to heat reaction mixture temperature to 85-95 DEG C, persistently stirs insulation reaction after sixty minutes,
Reaction product is centrifugated by cooled to room temperature, and filter cake is centrifuged repeatedly processing 2 times again after being washed with dehydrated alcohol, will be filtered
Cake obtains nickel hydroxide ultrathin nanometer film after spontaneously drying at room temperature；
The mixed solvent is the mixture of water, methanol and ethyl alcohol, and wherein the volume ratio of water, methanol and ethyl alcohol is 15:5:1；
The oxidant is potassium ferrate, and usage amount volume ratio in water is 1:3000-5000；
The high-pressure sodium lamp power of the high-pressure sodium lamp light source illumination-based disinfection is 600-800W, wavelength 260-450nm, main peak
Value is 365nm.
2. the method for phthalate pollutant, feature exist in a kind of removal water source gathering ground water body as described in claim 1
In, the bio-resin is the dimerisation products after reacting comprising Isosorbide-5-Nitrae-cyclohexane dicarboxylic acid and linolenic acid with soya bean fatty acid,
Softening point is 100-120 DEG C, and the dimerisation products are added in high-speed mixer, stirs 5-10min, is then slowly added
The sorbierite for entering 0.05 times of dimerisation products amount starts low speed rotation high-speed cruising and material is adequately stirred inside mixing machine
Even, stirring at low speed speed is 180-300r/min, and low speed runing time 10-30min, high-speed stirred speed is 1200-1800r/
Min, high-speed cruising time are 5-15min, and above-mentioned raw material after mixing is put into pelletizer and is kneaded, melted, squeezed
Out, pelletizing is after cooling to get arriving the bio-resin.
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| CN104291386A (en) * | 2014-10-10 | 2015-01-21 | 九江学院 | Preparation method of two-dimensional nickel hydroxide ultrathin nano-film |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007229717A (en) * | 2007-06-05 | 2007-09-13 | Nippon Arushii Kk | Coagulating agent and coagulating method |
| CN101186719A (en) * | 2007-12-04 | 2008-05-28 | 南京大学 | Composite function resin, preparation method thereof, and method for treating phthalate pollution of water body |
| CN101665298A (en) * | 2009-08-26 | 2010-03-10 | 南京大学 | Method for removing phthalate ester in water body by utilizing solid base catalyst |
| CN103641281A (en) * | 2013-12-25 | 2014-03-19 | 郑州大学环境技术咨询工程公司 | High-salt organic industrial wastewater treatment process method |
| CN104291386A (en) * | 2014-10-10 | 2015-01-21 | 九江学院 | Preparation method of two-dimensional nickel hydroxide ultrathin nano-film |
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