CN106865652A - A kind of concave convex rod water quality cleansing agent and preparation method - Google Patents
A kind of concave convex rod water quality cleansing agent and preparation method Download PDFInfo
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- CN106865652A CN106865652A CN201710233487.1A CN201710233487A CN106865652A CN 106865652 A CN106865652 A CN 106865652A CN 201710233487 A CN201710233487 A CN 201710233487A CN 106865652 A CN106865652 A CN 106865652A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
Abstract
The invention discloses a kind of concave convex rod water quality cleansing agent and preparation method, belong to water-treatment technology field.The cleanser includes following component：Modified attapulgite clay, activated carbon, diatomite, polymeric aluminium ferrum silicate, wood chip, Radix Glycyrrhizae, the root bark of tree peony and lemon peel.Preparation process is：First natural attapulgite clay is purified, is acidified and heat modification, then by modified Concave-convex clay rod, activated carbon, diatomite, wood chip in reaction vessel, add by Radix Glycyrrhizae, the root bark of tree peony, lemon peel extract solution, after mixing and stirring ultrasound, stand to obtain mixture；Polymeric aluminium ferrum silicate is added after mixture is removed water, is dried after stirring；It is placed in Muffle furnace again, is calcined, cooling, crushing obtains final product the water quality cleansing agent.The concave convex rod water quality cleansing agent not only has high-effective cleansing, the effect of removal of impurities, moreover it is possible to the bacterium effectively gone in water removal, prevents bacteria breed, and preparation method is simple and easy to apply, mild condition, is adapted to industrial production.
Description
Technical field
The present invention relates to water-treatment technology field, and in particular to a kind of concave convex rod water quality cleansing agent and preparation method.
Background technology
In recent years, with expanding economy, the progress of industrial or agricultural, what is brought therewith is the destruction to environment for human survival,
To naturally destruction.The production of various products and adjoint byproduct in cause to have arrived the pollution of environment very serious
Stage.The pollution of freshwater resources for the survival of mankind is also increasingly aggravated.In water pollution, the pollution of arsenic has been caused extensively
Concern.The form that is primarily present of arsenic is arsenite ion and arsenic acid radical ion in water.On the top layer of water body, with arsenous anion
The arsenic that form is present usually is oxidized to arsenate.Arsenous anion and arsenic acid radical ion enter soil, i.e., with soil in iron,
Aluminium, calcium, the arsenic compound of magnesium plasma effect generation slightly solubility accumulate on upper soll layer.Metallurgical industry, glass ceramics, process hides,
Compound in dyestuff and the waste water of insecticide production all containing arsenic or arsenic.Arsenic poisoning can also cause cell metabolism disorder, stomach
Road is not normal, renal failure is moved back.In addition, the fluoride pollution in drinking water also increasingly attracts attention, when the concentration of fluorine ion reaches necessarily
During amount, the harm to human body is very big, while soil quality that also can be in welding, it is also possible to cause the mankind and nature biotechnology
Poisoning.Additionally, the pollutant of some organic substances present in water such as humic acid, sanitary sewage and industrial wastewater, not only leads
Water pollution, water quality deterioration are caused, bacteria breed, the health of serious harm people can be also caused.
There is the purifying agent for polluted water of absorption and sterilized many effects on the market at present, treatment effect stability is poor, and handling process is multiple
Miscellaneous, disposable industrial input is big, and residue is more, in such as processing river, well water with ferrous sulfate to microorganism in water, bacterium,
The clearance of algae, harmful heavy metal etc. is not high；Although processing effect preferably with aluminum sulfate, relatively costly, its effect can be with
The passage of time is gradually deteriorated, and purification efficiency is low, high cost, harmful material can be remained in the water after purification, seriously
Influence the quality of drinking water.
Therefore, researching and developing one kind both has high-effective cleansing, removal of impurities, and with certain bactericidal effect, the water of safety and environmental protection
Matter cleanser turns into the emphasis of research at present, it may have preferable application prospect and use value.
The content of the invention
For defect of the prior art, it is an object of the invention to provide a kind of concave convex rod water quality cleansing agent and preparation side
Method, the concave convex rod water quality cleansing agent has the effect of high-effective cleansing, removal of impurities, moreover it is possible to the bacterium effectively gone in water removal, prevents thin
Bacterium grows, and all malicious harmful substance will not be discharged again, for water quality safety provides guarantee, with preferable application prospect, additionally, institute
State preparation method simple and easy to apply, mild condition is adapted to industrial production.
The present invention solves technical problem and adopts the following technical scheme that：
The present invention relates to a kind of concave convex rod water quality cleansing agent, including following weight portion each component：Modified attapulgite clay 50 ~
70 parts, it is 10 ~ 20 parts of activated carbon, 10 ~ 15 parts of diatomite, 5 ~ 15 parts of polymeric aluminium ferrum silicate, 5 ~ 10 parts of wood chip, 3 ~ 10 parts of Radix Glycyrrhizae, red
5 ~ 10 parts of skin, 5 ~ 15 parts of lemon peel, also including appropriate solvent.
Preferably, 60 parts of the modified attapulgite clay, 15 parts of activated carbon, 12 parts of diatomite, polymeric aluminium ferrum silicate 10
Part, 8 parts of wood chip, 6 parts of Radix Glycyrrhizae, 8 parts of the root bark of tree peony, 10 parts of lemon peel.
Preferably, the solvent includes second alcohol and water.
The invention further relates to a kind of method for preparing concave convex rod water quality cleansing agent, comprise the following steps：
（1）The pretreatment of Concave-convex clay rod：Natural attapulgite clay is carried out to be crushed to 100 ~ 200 mesh, is added water, stir shape
Into mud in suspension, then by 10 ~ 20min of ultrasound under Ultrasonic Conditions, upper suspension is taken in the centrifugation of 2500 ~ 3000 turns/min
5 ~ 10min of centrifugal treating in machine, vacuum filtration obtains filter cake after standing；
Filter cake is placed in beaker, ethanol is added, in 10 ~ 20min of ultrasound under Ultrasonic Conditions, vacuum filtration after standing is dried
Obtain pretreated Concave-convex clay rod；
（2）The preparation of modified attapulgite clay：Pretreated Concave-convex clay rod is placed in flask, adds 2mol/L's
Watery hydrochloric acid, in 10 ~ 20min of ultrasound, vacuum filtration after standing under Ultrasonic Conditions, and is cleaned with distilled water, obtains filter cake；
The Concave-convex clay rod filter cake that will be obtained is dried in vacuum drying chamber, is subsequently placed in roasting in 600 DEG C ~ 900 DEG C of Muffle furnace
3 ~ 5h is burnt, particle diameter is ground to after cooling for 100 ~ 200 mesh, obtain modified Concave-convex clay rod；
（3）Radix Glycyrrhizae, the root bark of tree peony, lemon peel are weighed respectively according to proportioning, 80 ~ 100 mesh are crushed to, and is well mixed, obtain mixture；Will
Mixture is placed in apparatus,Soxhlet's, and 3 ~ 5h of extraction is carried out in the mixed solvent of second alcohol and water, obtains extract solution；
（4）Modified Concave-convex clay rod, activated carbon, diatomite, wood chip are weighed respectively according to proportioning to be placed in reaction vessel,
Extract solution is added, mixing and stirring in 20 ~ 30min of ultrasound under Ultrasonic Conditions, then stands 4 ~ 8h, obtains mixture；
（5）To step（4）In the mixture that obtains to remove water to water content be 10% ~ 15%, be subsequently adding polymeric aluminium ferrum silicate, fully
Stir, dried in vacuum drying chamber；
（6）By step（5）In the drying composite that obtains in Muffle furnace, be to slowly warm up to 600 DEG C ~ 800 DEG C, then constant temperature roasting
2 ~ 4h is burnt, cooling, crushing obtains final product the water quality cleansing agent.
Preferably, the step（1）In the weight that adds water be 5 ~ 10 times of Concave-convex clay rod weight.
Preferably, the step（1）In plus the volume of ethanol be 8 ~ 15 times of Concave-convex clay rod quality.
Preferably, the step（2）The volume that middle watery hydrochloric acid is added is 1mL with concave convex rod mass ratio：2g~10g.
Preferably, the step（2）The washing step of middle filter cake includes being placed in filter cake in distilled water, under ultrasound condition
5 ~ 10min of ultrasound, suction filtration is repeated twice operation so that the pH value of filter cake is 5 ~ 6.
Preferably, the step（3）The volume of middle mixed solvent is 10 ~ 20 times of the quality of component of mixture, wherein,
Ethanol is 1 with the volume ratio of water:0.8~1.5.
Compared with prior art, the present invention has following beneficial effect：
（1）Concave convex rod water quality cleansing agent of the present invention, not only with preferably absorption impurities in water ion, particle and floating
The effect of thing, moreover it is possible to the bacterium effectively gone in water removal, prevents bacteria breed, is people for the security of drinking water provides guarantee
Healthy living provide condition, with preferable application value.
（2）Concave convex rod water quality cleansing agent of the present invention using modified Concave-convex clay rod as absorption carrier, by
In Concave-convex clay rod unique chain layer structure and larger specific surface area, preferable adsorption and sedimentation performance is made it have, changed
Concave-convex clay rod after property considerably increases its characterization of adsorption, it is not only had preferable adsorption and sedimentation work(to particle
Can, also there is preferable suction-operated to gas chromatographies such as ion, coloring agents, for purification of water quality provides guarantee.
（3）Concave convex rod water quality cleansing agent of the present invention is added with activated carbon, diatomite, polymeric aluminium ferrum silicate and wood chip,
Play the role of to bring out the best in each other with Concave-convex clay rod, can effectively encourage the adsorption and sedimentation performance of Concave-convex clay rod, Jin Erti
The clean-up effect of cleanser high.
（4）Concave convex rod water quality cleansing agent of the present invention is added with crude drug component Radix Glycyrrhizae, the root bark of tree peony and lemon peel, can
The bacterium in water removal is effectively killed, and can effectively prevent bacteria breed, and this component people eats and not only has no adverse effects afterwards, also
Function of human body can be adjusted, it is useful and harmless to health.
Specific embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.The experimental technique of unreceipted actual conditions in the following example, generally according to normal condition, for example
Sambrook equimoleculars are cloned：Laboratory manual（New York:Cold Spring Harbor Laboratory Press,
1989）Described in condition, or according to the condition proposed by manufacturer.
Embodiment 1：
A kind of concave convex rod water quality cleansing agent and preparation method of the preferred embodiment of the present invention；
The concave convex rod water quality cleansing agent, is prepared from by each component of following weight portion：60 parts of modified attapulgite clay, work
15 parts of charcoal of property, 12 parts of diatomite, 10 parts of polymeric aluminium ferrum silicate, 8 parts of wood chip, 6 parts of Radix Glycyrrhizae, 8 parts of the root bark of tree peony, 10 parts of lemon peel, also wrap
Appropriate solvent is included, wherein, solvent includes second alcohol and water.
The method for preparing concave convex rod water quality cleansing agent of the present invention, comprises the following steps：
（1）The pretreatment of Concave-convex clay rod：Natural attapulgite clay is carried out to be crushed to 200 mesh, adds attapulgite to glue
The water of 8 times of native weight, stirring forms mud in suspension, then by ultrasonic 15 min under Ultrasonic Conditions, take upper suspension in
The min of centrifugal treating 8 in the centrifuge of 3000 turns/min, vacuum filtration obtains filter cake after standing；
Filter cake is placed in beaker, ethanol is added, in ultrasonic 15 min under Ultrasonic Conditions, vacuum filtration after standing, dry
To pretreated Concave-convex clay rod, wherein, plus the volume of ethanol is 10 times of Concave-convex clay rod quality；
（2）The preparation of modified attapulgite clay：Pretreated Concave-convex clay rod is placed in flask, adds 2mol/L's
Watery hydrochloric acid, in ultrasonic 15 min, vacuum filtration after standing under Ultrasonic Conditions, and is cleaned with distilled water, obtains filter cake, wherein, it is dilute
The volume that hydrochloric acid is added is 1mL with concave convex rod mass ratio：8 g；
The Concave-convex clay rod filter cake that will be obtained is dried in vacuum drying chamber, is subsequently placed in 800 DEG C of the h of Muffle kiln roasting 4,
Particle diameter is ground to after cooling for 200 mesh, modified Concave-convex clay rod is obtained；
（3）Radix Glycyrrhizae, the root bark of tree peony, lemon peel are weighed respectively according to proportioning, 100 mesh are crushed to, and is well mixed, obtain mixture；Will be mixed
Compound is placed in apparatus,Soxhlet's, carries out extracting 4 h in the mixed solvent of second alcohol and water, obtains extract solution；
（4）Modified Concave-convex clay rod, activated carbon, diatomite, wood chip are weighed respectively according to proportioning to be placed in reaction vessel,
Extract solution is added, mixing and stirring in ultrasonic 25 min under Ultrasonic Conditions, then stands 6 h, obtains mixture；
（5）To step（4）In the mixture that obtains remove water to water content for 13 %, be subsequently adding polymeric aluminium ferrum silicate, fully stir
Mix uniform, dried in vacuum drying chamber；
（6）By step（5）In the drying composite that obtains in Muffle furnace, be to slowly warm up to 800 DEG C, then the h of constant temperature calcining 3,
Cooling, crushing obtains final product the water quality cleansing agent.
Step（2）The washing step of middle filter cake includes being placed in filter cake in distilled water, in ultrasonic 10 min under ultrasound condition,
Suction filtration, is repeated twice operation so that the pH value of filter cake is 5 ~ 6.
Step（3）The volume of middle mixed solvent is 15 times of the quality of component of mixture, wherein, the volume of ethanol and water
Than being 1:1.2.
Embodiment 2：
A kind of concave convex rod water quality cleansing agent and preparation method of the preferred embodiment of the present invention；
The concave convex rod water quality cleansing agent, is prepared from by each component of following weight portion：50 parts of modified attapulgite clay, work
10 parts of charcoal of property, 10 parts of diatomite, 5 parts of polymeric aluminium ferrum silicate, 5 parts of wood chip, 3 parts of Radix Glycyrrhizae, 5 parts of the root bark of tree peony, 5 parts of lemon peel, also include
Appropriate solvent, wherein, solvent includes second alcohol and water.
The method for preparing concave convex rod water quality cleansing agent of the present invention, comprises the following steps：
（1）The pretreatment of Concave-convex clay rod：Natural attapulgite clay is carried out to be crushed to 100 mesh, adds attapulgite to glue
The water of 5 times of native weight, stirring forms mud in suspension, then by ultrasonic 10 min under Ultrasonic Conditions, take upper suspension in
The min of centrifugal treating 5 in the centrifuge of 2500 turns/min, vacuum filtration obtains filter cake after standing；
Filter cake is placed in beaker, ethanol is added, in ultrasonic 10 min under Ultrasonic Conditions, vacuum filtration after standing, dry
To pretreated Concave-convex clay rod, wherein, plus the volume of ethanol is 8 times of Concave-convex clay rod quality；
（2）The preparation of modified attapulgite clay：Pretreated Concave-convex clay rod is placed in flask, adds 2mol/L's
Watery hydrochloric acid, in ultrasonic 10 min, vacuum filtration after standing under Ultrasonic Conditions, and is cleaned with distilled water, obtains filter cake, wherein, it is dilute
The volume that hydrochloric acid is added is 1mL with concave convex rod mass ratio：2g；
The Concave-convex clay rod filter cake that will be obtained is dried in vacuum drying chamber, is subsequently placed in 900 DEG C of Muffle kiln roasting 3h, cold
But particle diameter is ground to afterwards for 100 mesh, obtains modified Concave-convex clay rod；
（3）Radix Glycyrrhizae, the root bark of tree peony, lemon peel are weighed respectively according to proportioning, 80 mesh are crushed to, and is well mixed, obtain mixture；Will mixing
Thing is placed in apparatus,Soxhlet's, and extraction 3h is carried out in the mixed solvent of second alcohol and water, obtains extract solution；
（4）Modified Concave-convex clay rod, activated carbon, diatomite, wood chip are weighed respectively according to proportioning to be placed in reaction vessel,
Extract solution is added, mixing and stirring in ultrasonic 20 min under Ultrasonic Conditions, then stands 4h, obtains mixture；
（5）To step（4）In the mixture that obtains to remove water to water content be 10%, be subsequently adding polymeric aluminium ferrum silicate, be sufficiently stirred for
Uniformly, dried in vacuum drying chamber；
（6）By step（5）In the drying composite that obtains in Muffle furnace, be to slowly warm up to 600 DEG C, then constant temperature calcining 4h,
Cooling, crushing obtains final product the water quality cleansing agent.
Step（2）The washing step of middle filter cake includes being placed in filter cake in distilled water, in ultrasonic 5 min under ultrasound condition,
Suction filtration, is repeated twice operation so that the pH value of filter cake is 5 ~ 6.
Step（3）The volume of middle mixed solvent is 10 times of the quality of component of mixture, wherein, the volume of ethanol and water
Than being 1:0.8.
Embodiment 3：
A kind of concave convex rod water quality cleansing agent and preparation method of the preferred embodiment of the present invention；
The concave convex rod water quality cleansing agent, is prepared from by each component of following weight portion：70 parts of modified attapulgite clay, work
Property 20 parts of charcoal, 15 parts of diatomite, 15 parts of polymeric aluminium ferrum silicate, 10 parts of wood chip, 10 parts of Radix Glycyrrhizae, 10 parts of the root bark of tree peony, 15 parts of lemon peel, also
Including appropriate solvent, wherein, solvent includes second alcohol and water.
The method for preparing concave convex rod water quality cleansing agent of the present invention, comprises the following steps：
（1）The pretreatment of Concave-convex clay rod：Natural attapulgite clay is carried out to be crushed to 200 mesh, adds attapulgite to glue
The water of 10 times of native weight, stirring forms mud in suspension, then by ultrasound 20min under Ultrasonic Conditions, take upper suspension in
The min of centrifugal treating 10 in the centrifuge of 2500 turns/min, vacuum filtration obtains filter cake after standing；
Filter cake is placed in beaker, ethanol is added, in ultrasonic 20 min under Ultrasonic Conditions, vacuum filtration after standing, dry
To pretreated Concave-convex clay rod, wherein, plus the volume of ethanol is 15 times of Concave-convex clay rod quality；
（2）The preparation of modified attapulgite clay：Pretreated Concave-convex clay rod is placed in flask, adds 2mol/L's
Watery hydrochloric acid, in ultrasonic 20 min, vacuum filtration after standing under Ultrasonic Conditions, and is cleaned with distilled water, obtains filter cake, wherein, it is dilute
The volume that hydrochloric acid is added is 1mL with concave convex rod mass ratio：10g；
The Concave-convex clay rod filter cake that will be obtained is dried in vacuum drying chamber, is subsequently placed in 600 DEG C of Muffle kiln roasting 5h, cold
But particle diameter is ground to afterwards for 200 mesh, obtains modified Concave-convex clay rod；
（3）Radix Glycyrrhizae, the root bark of tree peony, lemon peel are weighed respectively according to proportioning, 100 mesh are crushed to, and is well mixed, obtain mixture；Will be mixed
Compound is placed in apparatus,Soxhlet's, carries out extracting 5 h in the mixed solvent of second alcohol and water, obtains extract solution；
（4）Modified Concave-convex clay rod, activated carbon, diatomite, wood chip are weighed respectively according to proportioning to be placed in reaction vessel,
Extract solution is added, mixing and stirring in ultrasound 30min under Ultrasonic Conditions, then stands 8h, obtains mixture；
（5）To step（4）In the mixture that obtains to remove water to water content be 15%, be subsequently adding polymeric aluminium ferrum silicate, be sufficiently stirred for
Uniformly, dried in vacuum drying chamber；
（6）By step（5）In the drying composite that obtains in Muffle furnace, be to slowly warm up to 800 DEG C, then the h of constant temperature calcining 2,
Cooling, crushing obtains final product the water quality cleansing agent.
Step（2）The washing step of middle filter cake includes being placed in filter cake in distilled water, in ultrasound 10min under ultrasound condition,
Suction filtration, is repeated twice operation so that the pH value of filter cake is 5 ~ 6.
Step（3）The volume of middle mixed solvent is 20 times of the quality of component of mixture, wherein, the volume of ethanol and water
Than being 1:1.5.
In sum, concave convex rod water quality cleansing agent of the present invention, not only with preferably absorption impurities in water ion,
The effect of particle and floating object, moreover it is possible to the bacterium effectively gone in water removal, prevents bacteria breed, for the security of drinking water is provided
Ensure, for the healthy living of people provides condition, with preferable application value, additionally, the preparation method is simple, operate
It is convenient, it is adapted to industrial production.
Specific embodiment of the invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can within the scope of the claims make various deformations or amendments, this not shadow
Sound substance of the invention.
Claims (9)
1. a kind of concave convex rod water quality cleansing agent, it is characterised in that each component including following weight portion：Modified attapulgite clay
50 ~ 70 parts, 10 ~ 20 parts of activated carbon, 10 ~ 15 parts of diatomite, 5 ~ 15 parts of polymeric aluminium ferrum silicate, 5 ~ 10 parts of wood chip, 3 ~ 10 parts of Radix Glycyrrhizae,
5 ~ 10 parts of the root bark of tree peony, 5 ~ 15 parts of lemon peel, also including appropriate solvent.
2. concave convex rod water quality cleansing agent according to claim 1, it is characterised in that the modified attapulgite clay 60
Part, 15 parts of activated carbon, 12 parts of diatomite, 10 parts of polymeric aluminium ferrum silicate, 8 parts of wood chip, 6 parts of Radix Glycyrrhizae, 8 parts of the root bark of tree peony, 10 parts of lemon peel.
3. concave convex rod water quality cleansing agent according to claim 1, it is characterised in that the solvent includes second alcohol and water.
4. the method for preparing the concave convex rod water quality cleansing agent as described in any one of claim 1 ~ 3, it is characterised in that including as follows
Step：
（1）The pretreatment of Concave-convex clay rod：Natural attapulgite clay is carried out to be crushed to 100 ~ 200 mesh, is added water, stir shape
Into mud in suspension, then by 10 ~ 20min of ultrasound under Ultrasonic Conditions, upper suspension is taken in the centrifugation of 2500 ~ 3000 turns/min
5 ~ 10min of centrifugal treating in machine, vacuum filtration obtains filter cake after standing；
Filter cake is placed in beaker, ethanol is added, in 10 ~ 20min of ultrasound under Ultrasonic Conditions, vacuum filtration after standing is dried
Obtain pretreated Concave-convex clay rod；
（2）The preparation of modified attapulgite clay：Pretreated Concave-convex clay rod is placed in flask, adds 2mol/L's
Watery hydrochloric acid, in 10 ~ 20min of ultrasound, vacuum filtration after standing under Ultrasonic Conditions, and is cleaned with distilled water, obtains filter cake；
The Concave-convex clay rod filter cake that will be obtained is dried in vacuum drying chamber, is subsequently placed in roasting in 600 DEG C ~ 900 DEG C of Muffle furnace
3 ~ 5h is burnt, particle diameter is ground to after cooling for 100 ~ 200 mesh, obtain modified Concave-convex clay rod；
（3）Radix Glycyrrhizae, the root bark of tree peony, lemon peel are weighed respectively according to proportioning, 80 ~ 100 mesh are crushed to, and is well mixed, obtain mixture；Will
Mixture is placed in apparatus,Soxhlet's, and 3 ~ 5h of extraction is carried out in the mixed solvent of second alcohol and water, obtains extract solution；
（4）Modified Concave-convex clay rod, activated carbon, diatomite, wood chip are weighed respectively according to proportioning to be placed in reaction vessel,
Extract solution is added, mixing and stirring in 20 ~ 30min of ultrasound under Ultrasonic Conditions, then stands 4 ~ 8h, obtains mixture；
（5）To step（4）In the mixture that obtains to remove water to water content be 10% ~ 15%, be subsequently adding polymeric aluminium ferrum silicate, fully
Stir, dried in vacuum drying chamber；
（6）By step（5）In the drying composite that obtains in Muffle furnace, be to slowly warm up to 600 DEG C ~ 800 DEG C, then constant temperature roasting
2 ~ 4h is burnt, cooling, crushing obtains final product the water quality cleansing agent.
5. the preparation method of concave convex rod water quality cleansing agent according to claim 4, it is characterised in that the step（1）In
The weight for adding water is 5 ~ 10 times of Concave-convex clay rod weight.
6. the preparation method of concave convex rod water quality cleansing agent according to claim 4, it is characterised in that the step（1）In
Plus the volume of ethanol is 8 ~ 15 times of Concave-convex clay rod quality.
7. the preparation method of concave convex rod water quality cleansing agent according to claim 4, it is characterised in that the step（2）In
The volume that watery hydrochloric acid is added is 1mL with concave convex rod mass ratio：2g~10g.
8. the preparation method of concave convex rod water quality cleansing agent according to claim 4, it is characterised in that the step（2）In
The washing step of filter cake includes being placed in filter cake in distilled water, in 5 ~ 10min of ultrasound, suction filtration under ultrasound condition, is repeated twice behaviour
Make so that the pH value of filter cake is 5 ~ 6.
9. the preparation method of concave convex rod water quality cleansing agent according to claim 4, it is characterised in that the step（3）In
The volume of mixed solvent is 10 ~ 20 times of the quality of component of mixture, wherein, ethanol is 1 with the volume ratio of water:0.8~1.5.
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| CN108557943A (en) * | 2018-04-16 | 2018-09-21 | 合肥聪亨新型建材科技有限公司 | A kind of special water purification agent of wastewater treatment and preparation method thereof |
| CN108557920A (en) * | 2018-05-17 | 2018-09-21 | 韩邦森 | A kind of industrial waste water purifying agent and the preparation method and application thereof |
| CN109021371A (en) * | 2018-06-27 | 2018-12-18 | 合肥远科服装设计有限公司 | A kind of preparation method of anti-skid wearable deodorant sole |
| CN108910971A (en) * | 2018-07-10 | 2018-11-30 | 奚永乐 | A kind of purifying domestic sewage agent and preparation method thereof |
| CN109354103A (en) * | 2018-11-22 | 2019-02-19 | 明光市国星凹土有限公司 | A kind of attapulgite modified water purification agent |
| CN109574124A (en) * | 2019-01-24 | 2019-04-05 | 武汉科创伟业生物科技有限公司 | A kind of environment-friendly type clarifying agent and its preparation process |
| CN110402854A (en) * | 2019-08-09 | 2019-11-05 | 武汉中科瑞华生态科技股份有限公司 | A kind of high viability breeding method of C. guichenoti fry |
| CN111204824A (en) * | 2020-01-17 | 2020-05-29 | 广东东日环保股份有限公司 | River surge sewage treatment agent and preparation method thereof |
| CN111545163A (en) * | 2020-05-15 | 2020-08-18 | 河北省廊坊水文水资源勘测局(河北省廊坊水平衡测试中心) | Adsorbent for heavy metal wastewater treatment and preparation method thereof |
| CN111545163B (en) * | 2020-05-15 | 2024-02-02 | 河北省廊坊水文水资源勘测局(河北省廊坊水平衡测试中心) | Adsorbent for heavy metal wastewater treatment and preparation method thereof |
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